CN103816716A - Water treatment core component and water treatment device - Google Patents
Water treatment core component and water treatment device Download PDFInfo
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- CN103816716A CN103816716A CN201410089118.6A CN201410089118A CN103816716A CN 103816716 A CN103816716 A CN 103816716A CN 201410089118 A CN201410089118 A CN 201410089118A CN 103816716 A CN103816716 A CN 103816716A
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Abstract
本发明公开一种水处理核心组件及水处理装置。该核心组件包括密封安装连接的柱状内核和圆筒状外壳,其特征在于该核心组件所述内核为表面具有螺线结构的金属棒,所述金属棒的结构如下:总长度为100-400mm;螺线结构模数为2-10,螺线头数为1、2或4,直径系数为10-16,压力角为18-22°,分度圆直径为32-120mm,齿顶圆直径为36-140mm,齿根圆直径为27.2-96mm,轴向齿距为6.28-31.40mm。该水处理装置安装使用该水处理核心组件。
The invention discloses a water treatment core component and a water treatment device. The core component includes a cylindrical inner core and a cylindrical shell that are sealed, installed and connected, and is characterized in that the inner core of the core component is a metal rod with a spiral structure on the surface, and the structure of the metal rod is as follows: the total length is 100-400mm; The modulus of the helical structure is 2-10, the number of helical ends is 1, 2 or 4, the diameter coefficient is 10-16, the pressure angle is 18-22°, the diameter of the index circle is 32-120mm, and the diameter of the addendum circle is 36 -140mm, the diameter of the dedendum circle is 27.2-96mm, and the axial pitch is 6.28-31.40mm. The water treatment device is installed to use the water treatment core component.
Description
技术领域 technical field
本发明涉及水处理技术,具体为一种水处理核心组件及使用该水处理核心组件的水处理装置。 The present invention relates to water treatment technology, specifically a water treatment core component and a water treatment device using the water treatment core component.
背景技术 Background technique
锅炉由于结垢,事故频繁,检修时间增多,还影响生产生活的正常进行,对企业而言,停炉时间多,直接影响生产,降低企业经济效益。因此对工业锅炉用水处理装置核心结构的优化设计具有重要的理论研究价值和现实意义,受到了国内外专家的广泛关注。 Due to fouling of the boiler, frequent accidents and increased maintenance time also affect the normal production and life. For enterprises, the long shutdown time directly affects production and reduces the economic benefits of the enterprise. Therefore, the optimal design of the core structure of industrial boiler water treatment equipment has important theoretical research value and practical significance, and has attracted extensive attention from domestic and foreign experts.
目前国内外有关工业锅炉用水处理装置主要有KDF滤料[US4642192,US5122274,US5135654]和PTH水处理器。美国专利号4,642,192;5,122,274;5,135,654介绍了KDF合金滤料的阻垢机制。KDF合金滤料都是细小的高纯度的铜锌合金实心颗粒,密度很大,而从其净水机理来看,它实际利用的只是表面那部分,这样在应用过程中就存在三方面的问题:滤料通过反应会形成一定量的沉淀物,这些沉淀物覆盖在合金表面,使除杂能力降低,且KDF介质密度较大,反冲洗压力要求较高,可能增加成本;如果不增加设备,滤料堆积可能会堵塞滤床,影响出水流量;水处理工程需要用到大量的铜锌合金滤料,前期投资较大,这是主要问题。因此应该对滤床的设计和KDF合金的形状做进一步的改善,以便使反冲洗变得方便流畅。以色列专利PTH水处理器具有许多其他水处理装置所没有的优点,使用虽然达到了一定的效果,但加工较难,成本较高,价格昂贵,不便于实际应用。 At present, the relevant industrial boiler water treatment devices at home and abroad mainly include KDF filter material [US4642192, US5122274, US5135654] and PTH water processor. US Patent No. 4,642,192; 5,122,274; 5,135,654 introduced the scale inhibition mechanism of KDF alloy filter material. KDF alloy filter materials are small high-purity copper-zinc alloy solid particles with high density, but from the perspective of its water purification mechanism, it actually uses only the surface part, so there are three problems in the application process : The filter material will form a certain amount of precipitates through the reaction, and these precipitates will cover the surface of the alloy, reducing the ability to remove impurities, and the density of the KDF medium is high, and the backwashing pressure is high, which may increase the cost; if no equipment is added, The accumulation of filter material may block the filter bed and affect the water flow; water treatment projects need to use a large amount of copper-zinc alloy filter material, and the initial investment is large, which is the main problem. Therefore, the design of the filter bed and the shape of the KDF alloy should be further improved in order to make backwashing more convenient and smooth. Israel's patented PTH water processor has many advantages that other water treatment devices do not have. Although it has achieved a certain effect, it is difficult to process, high in cost, and expensive, which is not convenient for practical application.
中国专利文献CN1765758A公开了一种加有稀土成分的铜锌合金以及以其为原料制备的水处理设备,该合金能够形成具有多重电位能级的原电池,起到活化水、缓蚀、阻垢、杀菌和净化作用,可以通过该合金的处理使得水中的钙盐生成悬浮的碳酸钙微粒而不会附着在锅炉冷壁上。然而该文献中公开采用该合金制备的水处理设备中采用了合金粉粒作为填料,存在阻力大,易堵塞,合金表面易覆盖沉淀,造成处理能力下降的缺点。 Chinese patent document CN1765758A discloses a copper-zinc alloy with rare earth components and water treatment equipment prepared from it. The alloy can form a primary battery with multiple potential levels, which can activate water, inhibit corrosion, and prevent scale. , Sterilization and purification, through the treatment of the alloy, the calcium salt in the water can form suspended calcium carbonate particles without adhering to the cold wall of the boiler. However, the document discloses that the water treatment equipment made of this alloy uses alloy powder as a filler, which has the disadvantages of high resistance, easy blockage, and easy coverage and precipitation on the surface of the alloy, resulting in a decrease in processing capacity.
中国专利文献CN102010070A公开了一种具有双螺旋结构的悬浮水处理填料,用于污水处理的生化反应,然而这种结构的水处理填料用于污水处理,操作流速较低,需要尽量利用其表面发生生化反应,与锅炉进水装置的水处理技术领域不同,且根据该专利文献公开的内容,这种填料需要加工成薄壁结构,而当用于锅炉进水处理时,由于操作条件需要较大的水流量,薄壁结构的填料强度无法满足使用要求。 Chinese patent document CN102010070A discloses a suspended water treatment filler with a double helix structure, which is used for biochemical reactions in sewage treatment. However, the water treatment filler with this structure is used for sewage treatment, and the operating flow rate is low. Biochemical reaction is different from the water treatment technical field of the boiler water inlet device, and according to the content disclosed in the patent document, this kind of packing needs to be processed into a thin-walled structure, and when used for boiler water treatment, due to the large operating conditions The water flow rate is too high, and the packing strength of the thin-walled structure cannot meet the use requirements.
发明内容 Contents of the invention
针对现有技术的不足,本发明拟解决的技术问题是,提供一种水处理核心组件及水处理装置。该核心组件及其构成水处理装置工作时,不仅与水有较大的接触面积,处理水效果好,同时结构简单,加工容易,使用方便,价格较低,适于工业化应用。 Aiming at the deficiencies of the prior art, the technical problem to be solved by the present invention is to provide a water treatment core component and a water treatment device. When the core component and the water treatment device it constitutes work, they not only have a large contact area with water and have good water treatment effect, but also have simple structure, easy processing, convenient use, low price, and are suitable for industrial application.
本发明解决所述核心组件技术问题的技术方案是,设计一种水处理核心组件,包括密封安装连接的柱状内核和圆筒状外壳,其特征在于该核心组件所述内核为表面具有螺线结构的金属棒,所述金属棒的结构如下:总长度为100-400mm;螺线结构模数为2-10,螺线头数为1、2或4,直径系数为10-16,压力角为18-22°,分度圆直径为32-120mm,齿顶圆直径为36-140mm,齿根圆直径为27.2-96mm,轴向齿距为6.28-31.40mm。 The technical solution of the present invention to solve the technical problem of the core component is to design a core component for water treatment, which includes a cylindrical inner core and a cylindrical shell that are sealed, installed and connected, and is characterized in that the inner core of the core component has a spiral structure on the surface The metal rod, the structure of the metal rod is as follows: the total length is 100-400mm; -22°, the pitch circle diameter is 32-120mm, the addendum circle diameter is 36-140mm, the dedendum circle diameter is 27.2-96mm, and the axial pitch is 6.28-31.40mm.
与现有技术相比,本发明核心组件设计为表面具有螺线结构的金属棒,工作时可有效增大水流流过时的接触表面积;同时螺线型内核结构具有圆滑的外表面,能够保证一定的回流速度,因此可以保证较好的水处理效率。本发明核心组件构成的水处理装置不仅与水有较大的接触面积,处理水效果好,同时结构简单,加工容易,使用方便,价格较低,适于工业化应用。实验表明,采用本发明核心组件的水处理装置用于工业锅炉水处理时,意想不到的实现了大水流量和阻止硬垢产生的积极效果。 Compared with the prior art, the core component of the present invention is designed as a metal rod with a spiral structure on the surface, which can effectively increase the contact surface area when the water flows through it; at the same time, the spiral core structure has a smooth outer surface, which can ensure a certain The reflux speed can ensure better water treatment efficiency. The water treatment device composed of the core components of the present invention not only has a larger contact area with water, but also has a good water treatment effect, and at the same time has a simple structure, easy processing, convenient use, low price, and is suitable for industrial application. Experiments show that when the water treatment device adopting the core components of the present invention is used for industrial boiler water treatment, it unexpectedly realizes the positive effect of large water flow rate and prevention of hard scale.
附图说明 Description of drawings
图1为本发明水处理核心组件一种实施例的螺线型金属棒内核结构示意图。 Fig. 1 is a schematic diagram of the core structure of a helical metal rod core of an embodiment of the water treatment core component of the present invention.
图2为本发明水处理核心组件一种实施例的水处理装置外壳结构示意图。其中,图2(a)为本发明所述水处理装置外壳主视结构示意图;图2(b)为本发明所述水处理装置外壳A-A剖面结构示意图。 Fig. 2 is a schematic structural diagram of a shell of a water treatment device according to an embodiment of the water treatment core component of the present invention. Among them, Fig. 2(a) is a schematic diagram of the front view of the casing of the water treatment device of the present invention; Fig. 2(b) is a schematic diagram of the A-A section structure of the casing of the water treatment device of the present invention.
图3为本发明采用水处理核心组件的水处理装置一种实施例的锅炉水循环模拟装置示意图。 Fig. 3 is a schematic diagram of a boiler water circulation simulation device of an embodiment of a water treatment device using a water treatment core component according to the present invention.
具体实施方式 Detailed ways
下面结合实施例及其附图进一步叙述本发明。 Further describe the present invention below in conjunction with embodiment and accompanying drawing thereof.
本发明设计的水处理核心组件(简称核心组件,参见图1-2),包括密封安装连接的柱状内核4-1和圆筒状外壳4-2,其特征在于该核心组件所述内核4-1为表面具有螺线结构的金属棒,所述金属棒的结构如下:总长度H为100-400mm;螺线结构模数m为2-10,螺线头数z为1、2或4,直径系数q为10-16,压力角α为18-22°,分度圆直径d为32-120mm,齿顶圆直径da为36-140mm,齿根圆直径df为27.2-96mm,轴向齿距p为6.28-31.40mm。 The water treatment core assembly designed in the present invention (referred to as the core assembly, see Fig. 1-2) includes a cylindrical inner core 4-1 and a cylindrical shell 4-2 that are sealed, installed and connected, and is characterized in that the inner core 4-2 of the core assembly 1 is a metal rod with a spiral structure on the surface. The structure of the metal rod is as follows: the total length H is 100-400mm; Coefficient q is 10-16, pressure angle α is 18-22°, index circle diameter d is 32-120mm, addendum circle diameter d a is 36-140mm, dedendum circle diameter d f is 27.2-96mm, axial The tooth pitch p is 6.28-31.40mm.
本发明核心组件所述金属棒的结构做如下优选:螺线结构模数m为2;所述螺线头数z为1;所述直径系数q为16mm;所述压力角α为20°。 The structure of the metal rod in the core component of the present invention is optimized as follows: the spiral structure modulus m is 2; the number z of the spiral ends is 1; the diameter coefficient q is 16mm; the pressure angle α is 20°.
所述螺线结构采用现有机械加工方法进行加工。 The spiral structure is processed by existing mechanical processing methods.
本发明核心组件所述具有螺线结构的内核4-1是通过对国内外现有的水处理装置结构研究分析,依据机械和流体力学知识,对水处理核心组件内核结构进行的设计,提高了内核结构与水接触的表面积,同时兼顾对水流流速的影响小,保证使用寿命,提高了阻垢效率。 The inner core 4-1 with the helical structure described in the core component of the present invention is through the research and analysis of the existing water treatment device structure at home and abroad, based on the knowledge of machinery and fluid mechanics, the design of the core structure of the core component of water treatment is carried out, and the improvement is improved. The surface area of the core structure in contact with water, while taking into account the small impact on the flow rate of water, ensures the service life and improves the scale inhibition efficiency.
本发明核心组件所述外壳4-2为圆筒形状,可采用PP-R塑料或不锈钢材质制成。圆筒状外壳4-2与柱状内核4-1采用过盈配合。这样既可以保护内核4-1的结构,又可以对通过水流起到限定或导向作用,使得水流通过时,按照螺线形状经过内核4-1结构,保证水流与内核4-1的充分接触。 The shell 4-2 of the core component of the present invention is in the shape of a cylinder and can be made of PP-R plastic or stainless steel. The cylindrical shell 4-2 and the columnar inner core 4-1 adopt an interference fit. This can not only protect the structure of the inner core 4-1, but also limit or guide the passing water flow, so that when the water flow passes through the structure of the inner core 4-1 in a spiral shape, sufficient contact between the water flow and the inner core 4-1 is ensured.
本发明核心组件4主要结构是将柱状内核4-1与圆筒状外壳4-2密封安装连接组装在一起。实施例的核心组件4的两端由GB/T 6170 M36型号螺母固定,通过GB8163-1999无缝钢管连接水处理装置的进、出水管道、流量计和阀门等就构成了水处理装置(参见图3)。本发明水处理装置特别适用于做低中压工业热水锅炉和蒸汽锅炉水处理系统。 The main structure of the core component 4 of the present invention is that the cylindrical inner core 4-1 and the cylindrical outer shell 4-2 are sealed, installed, connected and assembled together. The two ends of the core component 4 of the embodiment are fixed by GB/T 6170 M36 type nuts, and the water treatment device is formed by connecting the inlet and outlet pipes, flow meters and valves of the water treatment device through GB8163-1999 seamless steel pipes (see Fig. 3). The water treatment device of the present invention is particularly suitable for low and medium pressure industrial hot water boilers and steam boiler water treatment systems.
本发明进一步特征是所述的金属棒为铜锌合金材料,并按如下质量配方冶炼制备而成:铜50-70%、锌20-35%、锡5-15%、镍5-10%、铁0.5-1%、锰0.01-0.1%、稀土元素钕或铈0.01-0.15%,以及硅1-3%、镁1-3%、铬0.1-1.0%、钼0.1-1.0%和钒0.1-1.0%中的一种或多种,各组分之和为100%。该合金材料是申请人的在先专利技术(CN1765758A)。研究表明,当水流通过内核结构时,合金中铜、锌、锡、镍等重金属元素是细菌等微生物的抑制成分,能够使细菌蛋白凝固,失去活性,从而减少粘稠性物质的分泌,避免或减少附着在其壁上的硬垢的形成;合金中的镁、锌等离子能够与形成的水垢碳酸钙、硫酸钡等形成离子置换,由于离子半径的差异,导致形成水垢的晶体结构发生变异,结果使形成的水垢致密度降低;合金中的稀土元素的次外层带有不饱和过渡电子,能够定扎在金属晶体的结合面上,抑制晶体的过分长大,同时能够产生过渡能级,使合金的电极电位发生变化,形成铜锌、锌镍、锌锡、镍锡原电池,进而发生一系列的氧化还原反应,还能够使既存的水垢和锈的阴、阳离子平衡受到破坏,从而实现阻垢、净化效果。特别是本发明核心组件的独特构造可产生流体力学冲击效果,能够在水流流过核心组件表面时产生湍流,使水流与核心组件充分作用,同时减小对水流流速的影响;本发明核心组件具有更大的表面积,加大了水流与合金作用面积,从而加强了合金的阻垢作用效果,实现了大流量、低阻力,长寿命的效果。 A further feature of the present invention is that the metal rod is a copper-zinc alloy material, and is prepared by smelting according to the following quality formula: 50-70% copper, 20-35% zinc, 5-15% tin, 5-10% nickel, Iron 0.5-1%, manganese 0.01-0.1%, rare earth elements neodymium or cerium 0.01-0.15%, and silicon 1-3%, magnesium 1-3%, chromium 0.1-1.0%, molybdenum 0.1-1.0% and vanadium 0.1- One or more of 1.0%, the sum of each component is 100%. The alloy material is the applicant's prior patented technology (CN1765758A). Studies have shown that when water flows through the core structure, heavy metal elements such as copper, zinc, tin, and nickel in the alloy are the inhibitory components of bacteria and other microorganisms, which can coagulate bacterial proteins and lose their activity, thereby reducing the secretion of viscous substances, avoiding or Reduce the formation of hard scale attached to its wall; the magnesium and zinc plasma in the alloy can form ion replacement with the formed scale calcium carbonate, barium sulfate, etc. Due to the difference in ionic radius, the crystal structure of the scale formed changes, and the result Reduce the density of the formed scale; the sub-outer layer of the rare earth elements in the alloy has unsaturated transition electrons, which can be fixed on the joint surface of the metal crystal, inhibiting the excessive growth of the crystal, and at the same time can generate a transition energy level, so that The electrode potential of the alloy changes to form a copper-zinc, zinc-nickel, zinc-tin, nickel-tin primary battery, and then a series of redox reactions occur, which can also destroy the anion and cation balance of the existing scale and rust, thereby realizing resistance. Dirt, purification effect. In particular, the unique structure of the core assembly of the present invention can produce a hydrodynamic impact effect, which can generate turbulent flow when the water flows through the surface of the core assembly, so that the water flow can fully interact with the core assembly, and at the same time reduce the impact on the flow rate of the water flow; the core assembly of the present invention has The larger surface area increases the interaction area between the water flow and the alloy, thereby enhancing the anti-scaling effect of the alloy and achieving the effects of large flow, low resistance and long life.
本发明核心组件4主要用于水处理装置中,特别是工业锅炉水处理装置中。采用本发明核心组件4的水处理装置(如常规锅炉水循环模拟装置,参见图3),主要包括水泵1,阀门2、5、6和7,流量计3、8和9,水处理装置4,热交换器10,容器11,模拟锅炉12和水箱13。本发明的水处理装置4安装在进水管路中,两端分别与流量计3、阀门5相连接。运行锅炉水循环模拟装置,将总流速调至400L/h,冷却水流速调为100L/h,设置两组对比试验,检测合金内核对水流流速的影响。出水流速为正常水管流速,连接水处理装置的连接管直径为16mm。实验表明,当连接管内水流速为1.0-2.0m/s时,模拟锅炉运转60天后开盖检查,锅炉内壁及管道壁上均未出现结垢现象,水中无方解石硬垢出现,只有大量的文石型软垢悬浮物,说明该水处理装置具有阻垢和防垢双重效果,可以达到锅炉阻垢防垢目的。本发明核心组件4可以并联使用。
The core component 4 of the present invention is mainly used in water treatment devices, especially industrial boiler water treatment devices. The water treatment device adopting the core component 4 of the present invention (such as a conventional boiler water circulation simulation device, see FIG. 3 ), mainly includes a water pump 1,
本发明未述及之处适用于现有技术。 What is not mentioned in the present invention is applicable to the prior art.
本发明内核结构与市场上类似的部件相比,加工起来较容易,表面积大,与水作用时合金的利用率较高,且水作用的过程中流速不会受到太大的影响。 Compared with similar components on the market, the core structure of the present invention is easier to process, has a larger surface area, and has a higher utilization rate of the alloy when it interacts with water, and the flow rate will not be greatly affected during the action of water.
实施例1-4 Example 1-4
实施例1-4设计的所述内核结构金属棒具体参数列于表1。 The specific parameters of the core structure metal rods designed in Examples 1-4 are listed in Table 1.
表1 实施例1-4的内核结构具体参数表 Table 1 The specific parameter table of the kernel structure of the embodiment 1-4
实施例1-4均采用以申请人在先专利(CN1765758A)提供的铜锌合金材料为原料制备的金属棒,对其进行机械加工,构成核心组件,安装在锅炉水循环模拟装置的进水管路中。运行锅炉水循环模拟装置,检测合金内核对水流流速的影响。当连接管内水流速为1.0-2.0m/s时,模拟锅炉运转60天后开盖检查,锅炉内壁及管道壁上均未出现结垢现象,水中无方解石硬垢出现,只有大量的文石型软垢悬浮物。 Examples 1-4 all use metal rods prepared from the copper-zinc alloy material provided by the applicant’s prior patent (CN1765758A) as raw materials, which are machined to form core components and installed in the water inlet pipeline of the boiler water circulation simulation device . Run the boiler water cycle simulator to examine the effect of the alloy core on the water flow rate. When the water flow rate in the connecting pipe is 1.0-2.0m/s, the simulated boiler is opened for inspection after 60 days of operation. There is no scale phenomenon on the inner wall of the boiler and the pipe wall. There is no calcite hard scale in the water, only a large amount of aragonite soft scale. Scale suspension.
实施例5Example 5
设计所述内核结构参数与实施例1相同。在与实施例1相同的条件下运行。 Designing the kernel structure parameters is the same as that in Embodiment 1. Run under the same conditions as in Example 1.
所述铜锌合金材料金属棒的原料配方为:铜60%,锌25%,锡5%,镍5%,铁 0.5%,锰0.1%,铈0.1%,硅1%,镁1%,铬0.8%,钼1%和钒0.5%。 The raw material formula of the copper-zinc alloy metal rod is: 60% copper, 25% zinc, 5% tin, 5% nickel, 0.5% iron, 0.1% manganese, 0.1% cerium, 1% silicon, 1% magnesium, chromium 0.8%, Molybdenum 1% and Vanadium 0.5%.
实施例6Example 6
设计所述内核结构参数与实施例1相同。在与实施例1相同的条件下运行。 Designing the kernel structure parameters is the same as that in Embodiment 1. Run under the same conditions as in Example 1.
所述合金棒原料配方为:铜65%,锌20%,锡5%,镍5%,铁 0.75%,锰0.1%,铈0.15%,硅1%,铬1%,钼1%和钒1%。 The raw material formula of the alloy rod is: 65% copper, 20% zinc, 5% tin, 5% nickel, 0.75% iron, 0.1% manganese, 0.15% cerium, 1% silicon, 1% chromium, 1% molybdenum and 1% vanadium %.
实施例7Example 7
将实施例5中的水处理核心组件两个并联,接入锅炉水循环模拟系统水处理装置4的位置,其他在与实施例5相同的条件下运行。当连接管内水流速为1.0-2.0m/s时,模拟锅炉运转75天后开盖检查,锅炉内壁及管道壁上均未出现结垢现象,水中无方解石硬垢出现,只有大量的文石型软垢悬浮物。 The two water treatment core components in Example 5 are connected in parallel, connected to the water treatment device 4 of the boiler water circulation simulation system, and the others are operated under the same conditions as in Example 5. When the water flow rate in the connecting pipe is 1.0-2.0m/s, the simulated boiler is opened for inspection after 75 days of operation. There is no scale phenomenon on the inner wall of the boiler and the pipe wall. There is no calcite hard scale in the water, only a large amount of aragonite soft scale. Scale suspension.
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