CN103805844A - Boron-containing seamless pipe line pipe for ocean oil and gas exploitation - Google Patents
Boron-containing seamless pipe line pipe for ocean oil and gas exploitation Download PDFInfo
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Abstract
The invention discloses a boron-containing seamless pipe line pipe for ocean oil and gas exploitation. The boron-containing seamless pipe line pipe is characterized by comprising the following chemical elements by weight percent: 0.09 to 0.19 percent of C, 0.23 to 0.38 percent of Si, 0.9 to 1.7 percent of Mn, 0.0015 to 0.0025 percent of B, 0.01 to 0.07 percent of Nb, less than or equal to 0.012 percent of P, less than or equal to 0.007 percent of S and the balance of Fe and unavoidable impurities. The boron-containing seamless pipe line pipe is high in tensile strength, good in welding property, excellent in salt water and acid environmental corrosion resistance and good in low-temperature impact resistance, the low-temperature impact resistance can reach 100J under the condition of minus 70 DEG C, and the boron-containing seamless pipe line pipe has the characteristic of high flexibility; by adopting the way for combining hot rolling and tempering heat treatment, the strength can reach the grade of more than 80ksi.
Description
Technical field
The present invention relates to a kind of marine oil and gas exploitation and use boracic seamless line pipe, belong to seamless line pipe technical field.
Background technology
At present, along with the recovery of world economy and the continuous expansion of economics of underdevelopment development scale, the particularly high speed development of China's economic, at present world energy sources and deliver into the situation putting upon the full stretch, each energy consumption big country of the world and oil, Sweet natural gas exporting country carry out new feasibility study report and new pipeline laying plan one after another.Estimate that global total energy consumption will be than present increase by 60% left and right from now on 10～15 years, wherein gas consumption will be doubled.
The CO of Sweet natural gas discharge
2less, therefore the existing trend that the energy uses is the steady transition from oil to Sweet natural gas, different from the conveying of oil, in gas conveying process, adopt high top pressure operation, can improve the efficiency of producing and carrying, cause market constantly to increase the demand of High Pressure Gas Transmitting Pipeline, line pipe has been proposed to more high-intensity requirement simultaneously.For improving gas well production efficiency, require oil well pipe bore larger in addition, tube wall is thinner, can reach the object of attenuate tube wall by improving pipeline steel strength.
But the development of pipeline grade of steel, the raising that only depends on intensity is inadequate, because pipeline Regional Geological Conditions used is extremely complicated severe, need reply such as resisting tomography, earthquake, landslide (move on stratum), ice field, frozen soil (periodically thaw collapse, frost heave) and along adverse environmental factors such as ocean currents (burn into washes away, ocean current moves); This just this class steel pipe over-all properties of the toughness to line pipe, deformability, weldability, low-temperature flexibility and erosion resistance have higher requirement.Design concept to based on stress design (take the hoop internal stress of being born in conduit running as design considerations, do not consider meridional stress and the strain of pipeline, do not consider to occur in conduit running process the motion that geology and external force cause) traditional oils letter shoot spool design concept challenge has been proposed; Then to " based on the method for design of strain ", be and meet above-mentioned Service Environment and consider to adapt to large plastic strain capacity, to ensure security and the integrity of pipeline.Marine drilling platform by the oil and natural gas collecting (comprising combustible ice) by seamless line pipe be delivered to dewater, the device (platform) of desulfurization, purifying treatment, be operated in high temperature or high pressure (>=14MPa) environment, in pipe, bear the corrosion that oil gas corrosion and oil-water mixed-transportation, profit Alternating Transportation are brought, pipe is outer is bearing the corrosion that seawater, marine atmosphere and ocean bottom soil bring simultaneously.Due to Service Environment very severe, safety coefficient, reliability, life requirement are high, and welded tube spool easily lost efficacy and scraps under this environment, therefore conventionally need to adopt, bore is little, the weldless steel tube of thickness of pipe.In recent years, the exploitation of oil-gas field progressively by shallow water to deep water (> 300m), extend in even super deep water (> 1500m) field, the ocean environment that deep-sea seamless line pipe is on active service is more severe: deep water seabed is high static pressure, low temperature environment (low temperature environment of combustible ice can reach-70 ℃ of left and right), face a lot of uncertainties, as stormy waves, ocean surface current, underflow, sea ice, tsunami and storm wave etc. simultaneously.Stability, the particularly control to carbon equivalent and tube end maching precision to tubing inner quality have higher technical requirements, except the corrosion of hydrogen sulfide corrosion resistant, anti-seawater, marine environment, also will meet the low-temperature impact of-70 ℃.Conventional X52 grade of steel seamless line pipe easily under inside and outside burn into low-temperature impact and External Force Acting, produces stress concentration at the fault in material of line pipe and weld defect place and lost efficacy and scrap in this environment.
Summary of the invention
Technical problem to be solved by this invention is the defect that overcomes prior art, a kind of marine oil and gas exploitation boracic seamless line pipe is provided, its tensile strength is high, good welding performance, anti-salt solution and sour environment corrosive nature is good, low-temperature impact property good, low-temperature impact property is issued to 100 joules-70 ℃ of conditions, possesses high tenacity feature, adds modified heat treated mode make its intensity can reach intensity rank more than 80ksi by hot rolling.
In order to solve the problems of the technologies described above, technical scheme of the present invention is: boracic seamless line pipe is used in a kind of marine oil and gas exploitation, and its chemical element and quality percentage composition thereof are as follows:
C：0.09%～0.19%；
Si：0.23%～0.38%；
Mn：0.9%～1.7%；
B：0.0015%～0.0025%；
Nb：0.01%～0.07%；
P:≤0.012%；
S:≤0.007%；
All the other are Fe and other inevitable impurity.
Further, the exploitation of this marine oil and gas with boracic seamless line pipe also have Mo:0.15wt%～0.5wt%, Ni:0.15wt%～0.25wt%, Cr:0.15wt%～0.25wt%, Cu:0.1wt%～0.4wt%, Ti≤0.10wt%, V≤0.10wt%, Al:0.01wt%～0.04wt% wherein at least one.
Further, wherein, Mo:0.2wt%～0.3wt%.
Further, wherein, Nb:0.02wt%～0.06wt%.
Adopt after technique scheme, carbon (C): as most economical in steel, the most basic strengthening element, by solution strengthening and precipitation strength, the intensity that improves steel is had to obvious effect, but improve the ductility of carbon content to steel, toughness and weldability have negative impact, the present invention effectively controls carbon content, toughness and the weldability of steel are promoted, according to welding standard, when carbon content is 0.10%～0.12% during with lower area, for easy welding zone, when carbon content is greater than 0.10%～0.12%, and the region of carbon equivalent ce < 0.49% is can welding zone, when the region of carbon equivalent 0.49%≤CE < 0.69% is more difficult welding zone, must weld by suitable thermal treatment process.The present invention by carbon content control 0.09%～0.19%, manganese (Mn): improving the intensity of steel by solution strengthening, is to compensate the main and most economical strengthening element that causes loss of strength because of the reduction of C content, manganese can also expand γ phase region, and can reduce γ-α transformation temperature of steel, contribute to obtain more tiny phase-change product, improve by this toughness, the reduction ductile-brittle transition temperature of steel, the present invention takes manganese content to be controlled at 0.9%～1.7% design, considers the coupling of C-Mn element, in the time of the every minimizing 0.01% of carbon content, Mn maximum level allows to increase by 0.05%, but maximum is no more than 1.7% design, niobium (Nb): be one of topmost element in modern microalloying line pipe, effect to grain refining is fairly obvious, separate out and hinder the austenitic Recovery and recrystallization of deformation by NbC strain inducing in course of hot rolling, change tiny phase-change product into through controlled rolling with while controlling the cooling deformation austenite structure that makes a derogatory section of non-recrystallization zone rolling in phase transformation, make by this steel there is high strength and high tenacity, Nb content of the present invention is 0.01%～0.07%, target intermediate value 0.05%, molybdenum (Mo): be mainly used to expand γ phase region, while postponing γ-α phase transformation, first separate out ferrite, promote the principal element that acicular ferrite forms, play an important role to controlling phase-change organization, under certain cooling rate and temperature control, the Mo that adds 0.15wt%～0.5wt% just can obtain obvious acicular ferrite structure, because phase transformation changes to low temperature direction, can make to organize further refinement simultaneously, improve the intensity of steel by the phase transformation strengthening of tissue, because Mo is thick atom radius element, add on a small quantity anti-local corrosion and the resisting corrosion of chlorine ion that can effectively increase steel in addition, containing H
2under S condition, also can improve the anti-H of steel
2s corrosive power, Mo design of the present invention chooses 0.15%～0.5%, copper (Cu): mainly improve the intensity of steel by solution strengthening, add a certain proportion of Cu simultaneously and can improve the corrosion resisting property of steel, can effectively improve the ability of steel sulfuric acid dew point corrosion resistant, but the addition of Cu is excessive, can cause steel that reduction occurs in 1050 ℃～1150 ℃ these temperature ranges separates out and is attached on crystal boundary, cause the red brittleness of steel to occur, this project Cu design chooses 0.1%～0.4%, according to the anti-corrosion capability of steel grade after test, can suitably improve, but can not exceed 0.4%wt, nickel (Ni): as improving the most effective element of steel low-temperature flexibility, modified 5% nickel steel can be used-162 ℃, nickeliferous 9% can use-196 ℃, but excessive interpolation nickel is uneconomical on the one hand, can damage on the other hand the processing performances such as steel-pipe welding, when excessive interpolation Ni can cause boring a hole, glue the quality of production control problems such as top simultaneously, add element Ni and also can be used to improve the red brittleness easily causing after Cu because adding in steel, the ratio of general and Cu is according to 1～2 times of interpolation, in large wall thickness tube spool, also can compensate because wall thickness increases the strength degradation causing, Ni design of the present invention chooses 0.15%～0.25%, chromium (Cr): can improve the thermodynamic stability of steel, the anodic process of retardance galvanic corrosion, can improve the anti-CO of pipe line steel to a certain extent
2corrosion, Cr design of the present invention chooses 0.15%～0.25%, in addition, vanadium (V): there is higher precipitation strength effect and weak Grain Refinement Effect, in the time that Nb, V, tri-kinds of microalloy units of Ti belong to compound use, V is mainly the intensity by improve steel with VC precipitation strength in ferrite, choose≤0.10wt% of V design of the present invention, target intermediate value 0.06%, titanium (Ti): be strong solid N element, the stoichiometric ratio of Ti/N is 3.42, utilize the Ti of 0.02% left and right just can fix the N below 60ppm in steel, in the time of continuous-casting of steel billet, can form the TiN precipitated phase of tiny high-temperature stable, this tiny TiN particle can effectively hinder the Austenite Grain Growth while reheating, contribute to improve the solid solubility of Nb in austenite, there is obvious effect to improving the impelling strength of welded heat affecting zone simultaneously, choose≤0.10wt% of Ti design of the present invention, boron (B): the hardening capacity that can improve steel, the present invention's design chooses 0.0015%～0.0025%, in sum, as long as guarantee the quality percentage composition of each chemical element in seamless line pipe, just can improve its tensile strength, improve its weldability, improve its anti-salt solution and sour environment corrosive nature, and low-temperature impact property is good, low-temperature impact property is issued to 100 joules in-70 degree conditions, possesses the feature of high tenacity, adding modified heat treated mode by hot rolling makes its intensity can reach intensity rank more than 80ksi.
Embodiment
For content of the present invention is more easily expressly understood, below according to specific embodiment, the present invention is further detailed explanation.
Embodiment mono-
Boracic seamless line pipe is used in a kind of marine oil and gas exploitation, and its chemical element and quality percentage composition thereof are as follows:
C：0.09%；
Si：0.23%；
Mn：1.6%；
Mo：0.15%；
Ni：0.15%；
B：0.0015%；
Cr：0.2%；
Nb：0.06%；
P:0.012%；
S:0.003%；
Cu:0.25%;
V：0.015%；
Al：0.04%；
All the other are Fe and other inevitable impurity.
A manufacture method for boracic seamless line pipe for marine oil and gas exploitation, the step of the method is as follows:
A) adopt steel scrap, the pig iron and batching to obtain pipe after smelting and casting, and in this process, guarantee that this marine oil and gas exploitation meets above-mentioned quality percentage composition with the chemical element of boracic seamless line pipe and requires: the first just refining in electric furnace of steel scrap, the pig iron and batching, then through LF refining, feed again calcium processing, then VD vacuum-treat, and then arc continuous casting, then obtain pipe after the cooling and finishing of pipe;
B) then to heating of pipe blank processing; Wherein Heating temperature is AC
3+ 50 ℃;
C) be rolled again: adopt roll seamless steel tube technique that billet production is become to seamless tube; Rolling equipment adopts the rolling of CPE unit;
D) obtaining this marine oil and gas exploitation after detecting finally by Overheating Treatment, to use boracic seamless line pipe, heat treatment mode be quenching+tempering again, and quenching temperature is 890 ℃ of left and right, and tempering temperature is 590 ℃.
Wherein idiographic flow b), c) and d) is: and ring furnace heating → three-high cross piercing → push pipe → crop end → reheat → dephosphorize by high pressure water → a subtract → cold bed is cooling → and gang saw cuts scale → aligning → thermal treatment → physical and chemical inspection → aligning → flaw detection → packing and puts in storage.
Embodiment bis-
Boracic seamless line pipe is used in a kind of marine oil and gas exploitation, and its chemical element and quality percentage composition thereof are as follows:
C：0.13%；
Si：0.35%；
Mn：1.2%；
Mo：0.25%；
Ni：0.2%；
B：0.0025%；
Cr：0.23%；
Nb：0.04%；
P:0.01%；
S:0.005%；
Cu:0.35%;
Al：0.03%
All the other are Fe and other inevitable impurity.
A manufacture method for boracic seamless line pipe for marine oil and gas exploitation, the step of the method is as follows:
A) adopt steel scrap, the pig iron and batching to obtain pipe after smelting and casting, and the above-mentioned quality percentage composition that meets of guaranteeing the chemical element of this marine oil and gas exploitation boracic seamless line pipe in this process requires: the first just refining in electric furnace of steel scrap, the pig iron and batching, then through LF refining, feed again calcium processing, then VD vacuum-treat, and then arc continuous casting, then obtain pipe after the cooling and finishing of pipe;
B) then to heating of pipe blank processing; Wherein Heating temperature is AC
3temperature;
C) be rolled again: adopt roll seamless steel tube technique that billet production is become to seamless tube; Rolling equipment adopts the rolling of CPE unit;
D) obtaining this marine oil and gas exploitation after detecting finally by Overheating Treatment, to use boracic seamless line pipe, heat treatment mode be quenching+tempering again; Quenching temperature is 840 ℃ of left and right, and tempering temperature is 530 ℃ of left and right.
Wherein idiographic flow b), c) and d) is: and ring furnace heating → three-high cross piercing → push pipe → crop end → reheat → dephosphorize by high pressure water → a subtract → cold bed is cooling → and gang saw cuts scale → aligning → thermal treatment → physical and chemical inspection → aligning → flaw detection → packing and puts in storage.
Embodiment tri-
Boracic seamless line pipe is used in a kind of marine oil and gas exploitation, and its chemical element and quality percentage composition thereof are as follows:
C：0.15%；
Si：0.3%；
Mn：1%；
Mo：0.4%；
Ni：0.2%；
B：0.002%；
Cr：0.15%；
Nb：0.02%；
P:0.01%；
S:0.006%；
Cu:0.4%;
Al：0.04%；
All the other are Fe and other inevitable impurity.
A manufacture method for boracic seamless line pipe for marine oil and gas exploitation, the step of the method is as follows:
A) adopt steel scrap, the pig iron and batching to obtain pipe after smelting and casting, and the above-mentioned quality percentage composition that meets of guaranteeing the chemical element of this marine oil and gas exploitation boracic seamless line pipe in this process requires: the first just refining in electric furnace of steel scrap, the pig iron and batching, then through LF refining, feed again calcium processing, then VD vacuum-treat, and then arc continuous casting, then obtain pipe after the cooling and finishing of pipe;
B) then to heating of pipe blank processing; Wherein Heating temperature is AC
3+ 100 ℃;
C) be rolled again: adopt roll seamless steel tube technique that billet production is become to seamless tube; Rolling equipment adopts the rolling of CPE unit;
D) obtaining this marine oil and gas exploitation after detecting finally by Overheating Treatment, to use boracic seamless line pipe, heat treatment mode be quenching+tempering again.Quenching temperature is 950 ℃ of left and right, and tempering temperature is 640 ℃ of left and right.
Wherein idiographic flow b), c) and d) is: and ring furnace heating → three-high cross piercing → push pipe → crop end → reheat → dephosphorize by high pressure water → a subtract → cold bed is cooling → and gang saw cuts scale → aligning → thermal treatment → physical and chemical inspection → aligning → flaw detection → packing and puts in storage.
Embodiment tetra-
Boracic seamless line pipe is used in a kind of marine oil and gas exploitation, and its chemical element and quality percentage composition thereof are as follows:
C：0.15%；
Si：0.35%；
Mn：1.7%；
B：0.0023%；
Nb：0.07%；
P:0.01%；
S:0.005%；
All the other are Fe and other inevitable impurity.
Marine oil and gas exploitation in above-mentioned four embodiment is as follows with the performance perameter table of boracic seamless line pipe:
As can be seen from the above table, marine oil and gas of the present invention exploitation is high by the tensile strength of boracic seamless line pipe, good welding performance, anti-salt solution and sour environment corrosive nature is good, low-temperature impact property good, low-temperature impact property is issued to 100 joules-70 ℃ of conditions, possesses high tenacity feature; Grain fineness number meets 5-9 level, the requirement of differential≤2 grade; Meet the requirements completely.
Quenching temperature in above-described embodiment in step d) can be 830 ℃～960 ℃, and described tempering temperature can be 520 ℃～650 ℃.
Principle of work of the present invention is as follows:
Carbon (C): as most economical in steel, the most basic strengthening element, by solution strengthening and precipitation strength, the intensity that improves steel is had to obvious effect, but improve the ductility of carbon content to steel, toughness and weldability have negative impact, the present invention effectively controls carbon content, toughness and the weldability of steel are promoted, according to welding standard, when carbon content is 0.10%～0.12% during with lower area, for easy welding zone, when carbon content is greater than 0.10%～0.12%, and the region of carbon equivalent ce < 0.49% is can welding zone, when the region of carbon equivalent 0.49%≤CE < 0.69% is more difficult welding zone, must weld by suitable thermal treatment process.The present invention by carbon content control 0.09%～0.19%;
Manganese (Mn): improving the intensity of steel by solution strengthening, is to compensate the main and most economical strengthening element that causes loss of strength because of the reduction of C content; Manganese can also expand γ phase region, and can reduce γ-α transformation temperature of steel, contribute to obtain more tiny phase-change product, improve by this toughness, the reduction ductile-brittle transition temperature of steel, the present invention takes manganese content to be controlled at 0.9%～1.7% design, considers the coupling of C-Mn element, in the time of the every minimizing 0.01% of carbon content, Mn maximum level allows to increase by 0.05%, but maximum is no more than 1.7% design;
Niobium (Nb): be one of topmost element in modern microalloying line pipe, effect to grain refining is fairly obvious, separate out and hinder the austenitic Recovery and recrystallization of deformation by NbC strain inducing in course of hot rolling, change tiny phase-change product into through controlled rolling with while controlling the cooling deformation austenite structure that makes a derogatory section of non-recrystallization zone rolling in phase transformation, make by this steel there is high strength and high tenacity, Nb content of the present invention is 0.01%～0.07%, target intermediate value 0.05%;
Molybdenum (Mo): be mainly used to expand γ phase region, while postponing γ-α phase transformation, first separate out ferrite, promote the principal element that acicular ferrite forms, play an important role to controlling phase-change organization, under certain cooling rate and temperature control, the Mo that adds 0.15wt%～0.5wt% just can obtain obvious acicular ferrite structure; Because phase transformation changes to low temperature direction, can make to organize further refinement simultaneously, improve the intensity of steel by the phase transformation strengthening of tissue; Because Mo is thick atom radius element, add on a small quantity anti-local corrosion and the resisting corrosion of chlorine ion that can effectively increase steel in addition, containing H
2under S condition, also can improve the anti-H of steel
2s corrosive power, Mo design of the present invention chooses 0.15%～0.5%;
Copper (Cu): mainly improve the intensity of steel by solution strengthening, add a certain proportion of Cu simultaneously and can improve the corrosion resisting property of steel, can effectively improve the ability of steel sulfuric acid dew point corrosion resistant; But the addition of Cu is excessive, can cause steel that reduction occurs in 1050 ℃～1150 ℃ these temperature ranges separates out and is attached on crystal boundary, cause the red brittleness of steel to occur, this project Cu design chooses 0.1%～0.4%, according to the anti-corrosion capability of steel grade after test, can suitably improve, but can not exceed 0.4%wt;
Nickel (Ni): as improving the most effective element of steel low-temperature flexibility, modified 5% nickel steel can be used-162 ℃, nickeliferous 9% can use-196 ℃, but excessive interpolation nickel is uneconomical on the one hand, can damage on the other hand the processing performances such as steel-pipe welding, when excessive interpolation Ni can cause boring a hole, glue the quality of production control problems such as top simultaneously; Add element Ni and also can be used to improve the red brittleness easily causing after Cu because adding in steel, the ratio of general and Cu is according to 1～2 times of interpolation; In large wall thickness tube spool, also can compensate because wall thickness increases the strength degradation causing, Ni design of the present invention chooses 0.15%～0.25%;
Chromium (Cr): can improve the thermodynamic stability of steel, the anodic process of retardance galvanic corrosion, can improve the anti-CO of pipe line steel to a certain extent
2corrosion, Cr design of the present invention chooses 0.15%～0.25%;
In addition, vanadium (V): there is higher precipitation strength effect and weak Grain Refinement Effect, in the time that Nb, V, tri-kinds of microalloy units of Ti belong to compound use, V is mainly the intensity by improve steel with VC precipitation strength in ferrite, choose≤0.10wt% of V design of the present invention, target intermediate value 0.06%;
Titanium (Ti): be strong solid N element, the stoichiometric ratio of Ti/N is 3.42, utilize the Ti of 0.02% left and right just can fix the N below 60ppm in steel, in the time of continuous-casting of steel billet, can form the TiN precipitated phase of tiny high-temperature stable, this tiny TiN particle can effectively hinder the Austenite Grain Growth while reheating, contribute to improve the solid solubility of Nb in austenite, there is obvious effect to improving the impelling strength of welded heat affecting zone simultaneously, choose≤0.10wt% of Ti design of the present invention;
Boron (B): can improve the hardening capacity of steel, the present invention's design chooses 0.0015%～0.0025%;
In sum, as long as guarantee the quality percentage composition of each chemical element in seamless line pipe, just can improve its tensile strength, improve its weldability, improve its anti-salt solution and sour environment corrosive nature, and low-temperature impact property is good, low-temperature impact property is issued to 100 joules in-70 degree conditions, possess the feature of high tenacity, add modified heat treated mode by hot rolling and make its intensity can reach intensity rank more than 80ksi.
Above-described specific embodiment; technical problem, technical scheme and beneficial effect that the present invention is solved further describe; institute is understood that; the foregoing is only specific embodiments of the invention; be not limited to the present invention; within the spirit and principles in the present invention all, any modification of making, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (4)
1. a boracic seamless line pipe is used in marine oil and gas exploitation, it is characterized in that: its chemical element and quality percentage composition thereof are as follows:
C：0.09%～0.19%；
Si：0.23%～0.38%；
Mn：0.9%～1.7%；
B：0.0015%～0.0025%；
Nb：0.01%～0.07%；
P:≤0.012%；
S:≤0.007%；
All the other are Fe and other inevitable impurity.
2. boracic seamless line pipe is used in a kind of marine oil and gas exploitation according to claim 1, it is characterized in that: also have Mo:0.15wt%～0.5wt%, Ni:0.15wt%～0.25wt%, Cr:0.15wt%～0.25wt%, Cu:0.1wt%～0.4wt%, Ti≤0.10wt%, V≤0.10wt%, Al:0.01wt%～0.04wt% wherein at least one.
3. boracic seamless line pipe is used in a kind of marine oil and gas exploitation according to claim 2, it is characterized in that: wherein, and Mo:0.2wt%～0.3wt%.
4. boracic seamless line pipe is used in a kind of marine oil and gas exploitation according to claim 1, it is characterized in that: wherein, and Nb:0.02wt%～0.06wt%.
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| CN106756537A (en) * | 2016-11-29 | 2017-05-31 | 武汉钢铁股份有限公司 | A kind of resistance to H2The excellent high tough normalizing pipe line steel of S corrosive natures and production method |
| CN107964626A (en) * | 2017-11-10 | 2018-04-27 | 山东钢铁股份有限公司 | A kind of yield strength 500MPa grade low-temp high tenacity is hot rolled H-shaped and preparation method thereof |
| CN107974614A (en) * | 2017-11-23 | 2018-05-01 | 武汉钢铁有限公司 | The production method of the X80 level pipe line steels of resistance against hydrogen cracking |
| CN107974613A (en) * | 2017-11-23 | 2018-05-01 | 武汉钢铁有限公司 | The production method of the X80 level pipe line steels of resisting sulfide stress corrosion cracking |
| CN110340147A (en) * | 2019-07-12 | 2019-10-18 | 林州凤宝管业有限公司 | A kind of outer small-caliber seamless steel pipe production method through being less than 60mm |
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