CN103805295A - Prepared method of biological alcohol oil - Google Patents
Prepared method of biological alcohol oil Download PDFInfo
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- CN103805295A CN103805295A CN201310556255.1A CN201310556255A CN103805295A CN 103805295 A CN103805295 A CN 103805295A CN 201310556255 A CN201310556255 A CN 201310556255A CN 103805295 A CN103805295 A CN 103805295A
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Abstract
The invention provides a prepared method of biological alcohol oil. According to the preparation method, methyl alcohol, alcohol and acetone are mixed to be uniform, and then a stabilizer, ferrocene and water are added and mixed, thus obtaining the biological alcohol oil. By utilizing the preparation method, deficiencies of the existing biological alcohol oil technology can be effectively solved, heat value of combustion of the biological alcohol oil is improved, combustion stability of the biological alcohol oil is strengthened, and the production cost of the biological alcohol oil is reduced.
Description
Technical field
The present invention relates to biofuel technical field, relate in particular to a kind of preparation method of biological alcohol oil.
Background technology
In today of energy dilemma, bioenergy the supreme arrogance of a person with great power.Biological alcohol oil be a kind of nontoxic, without raffinate, smoke dust, without harmful exhaust, without incrustation, not only safety but also economic fuel.For bio-alcohol oil fuel, widely praised highly.
Owing to being becoming tight world petroleum resource day and price rises steadily, oil in all parts of the country station is to have valency without oily Stress.For alleviating diesel oil situation and pollution problem in short supply, within 07 year, to be combined below by Ministry of Energy, environment general bureau, enter kitchen by complete prohibition diesel oil the coming years, and forbid existing urban at present.The tense situation of fuel supply, huge market demand, the support energetically of national environmental protection policy, this series of being not difficult to find out, develops cheap, clean substitute energy extremely urgent!
Biological alcohol oil is take methyl alcohol as basis a kind of environment friendly biological fuel newly developed, stores at normal temperatures and pressures, transports, uses, and steel cylinder storage with no pressure, only with plain metal or plastic containers storage.Biological alcohol oil has well solved the large historical problem of deficiency, consumption of alcohol-group fuel calorific value, and it is unstable that it has solved alcohol-group fuel first, volatile, unsafe problem.Add 2 ‰ can improve the calorific value of alcohol-group fuel 1/3 left and right.
Bio oil is a kind of clean renewable energy source, also be referred to as " regeneration fuel oil " or " biomass fuel ", it is the petrifaction diesel surrogate of high-quality, conventionally the bio oil of indication is take animal-plant oil as raw material, carries out the fatty acid methyl ester of transesterification reaction generation under the effect of catalyzer with methyl alcohol.About research existing many reports at home and abroad of optimization and characteristic, burning and exhausting, toxicity and the biological degradation etc. of economic feasibility, material choice and the production technique of biofuel.Research thinks that biofuel is with the obvious advantage as petrifaction diesel substitute.
Traditional alcohol-group fuel calorific value is low, only 5300 kilocalories/kg left and right, and the requirement that not reaching makes a fire cooks, and consumption is large, and waste is many, there is no significant economic benefit; Secondly alcohol-group fuel poor stability, volatile, everybody knows that methyl alcohol is a kind of flammable industrial chemicals of very easy volatilization, it will become flammable steam from liquid at temperature 65 degree, burning very easily sets off an explosion in narrow and small nonventilated environment, even suck excessive methanol steam in rather spacious space, also can make people cause methanol poisoning, blind.In transportation, also very easily cause danger, store and also can reduce because of volatilization, therefore must solve heat and the stability of alcohol-group fuel.
Summary of the invention
Object of the present invention is exactly the preparation method that a kind of biological alcohol oil is provided for the defect of above-mentioned existence.Can effectively solve the deficiency in existing biological alcohol oil technology, improve the combustion heat value of biological alcohol oil, strengthen the combustion stability of biological alcohol oil, reduce the manufacturing cost of biological alcohol oil
Preparation method's technical scheme of a kind of biological alcohol oil of the present invention is methyl alcohol, ethanol, acetone are stirred to evenly, then after adding stablizer, ferrocene and water, stirring to make biological alcohol oil.
Each constituent mass per-cent is: methyl alcohol 65%-80%, ethanol 10%-15%, stablizer 5%-10%, acetone 5%-10%, ferrocene 0.1%-1%, water 1%-10%.
Preferred each constituent mass per-cent is: methyl alcohol 70%, ethanol 13%, stablizer 6%, acetone 6%, ferrocene 0.4%, water 4.6%.
Stablizer comprises Oleum Gossypii semen and glycerine.
Preferably, in stablizer, contain by mass percentage 80% Oleum Gossypii semen and 20% glycerine.
Concrete steps are:
1. in A container, Oleum Gossypii semen, glycerine are heated, be stirred well to evenly, make stablizer for subsequent use;
2. in B container, add methyl alcohol, ethanol, acetone to be stirred to evenly;
3. in C container, add water, ferrocene;
4. the solution in A, C container is added in B container, fully stir, make biological alcohol oil.
Step 1. in, Oleum Gossypii semen, glycerine are heated to 230 ℃.
Step adds the solution in A, C container in B container in 4., stirs 20-60 minute.
Beneficial effect of the present invention is: the present invention's Oleum Gossypii semen used is lower with respect to soya-bean oil price, is conducive to reduce costs.The present invention has added ferrocene, and that ferrocene has is combustion-supporting, smoke abatement, hyperchromic and energy saving and efficiency increasing effect.Ferrocene can increase the fuel value of this biological alcohol oil, makes its burning completely to improve fire temperature.Secondly, smoke abatement effect of ferrocene can solve fan stove core on fire, close fire, throttle when excessive, have the problem of little cigarette because can not fully burning.
Raw material sources of the present invention are extensive, and cost is low, and technique is simple, and quality is easy to control, and fuel value is high, and flameholding is non-volatile, water-soluble, and while catching fire, water one waters and goes out, safe and reliable; When use, adopt potential difference feed, do not need pressurization, do not need preheating, can be in unlimited burner the abundant vaporization combustion of multilayer, flame size is adjustable, easy to use; Without raffinate, smoke dust, without carbon deposit, be both conducive to the healthy of operator, meet again environmental requirement.Product prepared by the present invention can replace other fuel to use special stove as fuel for cooking.
embodiment:
In order to understand better the present invention, describe technical scheme of the present invention in detail with specific examples below, but the present invention is not limited thereto.
Embodiment 1
The preparation method of a kind of biological alcohol oil of the present invention, is that methyl alcohol, ethanol, acetone are stirred to evenly, then after adding stablizer, ferrocene and water, stirring makes biological alcohol oil.
Each constituent mass per-cent is:
Methyl alcohol 65%
Ethanol 15%
Stablizer 5%
Acetone 10%
Ferrocene 0.1%
Water 4.9%
In stablizer, contain by mass percentage 80% Oleum Gossypii semen and 20% glycerine.
Concrete steps are:
1. in A container, Oleum Gossypii semen, glycerine are heated to 230 ℃, are stirred well to evenly, make stablizer for subsequent use;
2. in B container, add methyl alcohol, ethanol, acetone to be stirred to evenly;
2. in C container, add water, ferrocene;
3. the solution in A, C container is added in B container, stir 40 minutes, make biological alcohol oil.
The performance test data of products obtained therefrom is as shown in table 1:
Table 1
Embodiment 2:
The preparation method of a kind of biological alcohol oil of the present invention, is that methyl alcohol, ethanol, acetone are stirred to evenly, then after adding stablizer, ferrocene and water, stirring makes biological alcohol oil.
Each constituent mass per-cent is:
Methyl alcohol 70%
Ethanol 13%
Stablizer 6%
Acetone 6%
Ferrocene 0.4%
Water 4.6%
In stablizer, contain by mass percentage 80% Oleum Gossypii semen and 20% glycerine.
Concrete steps are:
1. in A container, Oleum Gossypii semen, glycerine are heated to 230 ℃, are stirred well to evenly, make stablizer for subsequent use;
2. in B container, add methyl alcohol, ethanol, acetone to be stirred to evenly;
3. in C container, add water, ferrocene;
4. the solution in A, C container is added in B container, stir 60 minutes, make biological alcohol oil.
The performance test data of products obtained therefrom is as shown in table 2:
Table 2
。
Embodiment 3:
The preparation method of a kind of biological alcohol oil of the present invention, is that methyl alcohol, ethanol, acetone are stirred to evenly, then after adding stablizer, ferrocene and water, stirring makes biological alcohol oil.
Each constituent mass per-cent is:
Methyl alcohol 80%
Ethanol 10%
Stablizer 6%
Acetone 12%
Ferrocene 0.8%
Water 1.2%
In stablizer, contain by mass percentage 80% Oleum Gossypii semen and 20% glycerine.
Concrete steps are:
1. in A container, Oleum Gossypii semen, glycerine are heated to 230 ℃, are stirred well to evenly, make stablizer for subsequent use;
2. in B container, add methyl alcohol, ethanol, acetone to be stirred to evenly;
3. in C container, add water, ferrocene;
4. the solution in A, C container is added in B container, stir 20 minutes, make biological alcohol oil.
The performance test data of products obtained therefrom is as shown in table 3:
Table 3
。
Claims (8)
1. a preparation method for biological alcohol oil, is characterized in that, methyl alcohol, ethanol, acetone are stirred to evenly, then after adding stablizer, ferrocene and water, stirring makes biological alcohol oil.
2. the preparation method of a kind of biological alcohol oil according to claim 1, is characterized in that, each constituent mass per-cent is: methyl alcohol 65%-80%, ethanol 10%-15%, stablizer 5%-10%, acetone 5%-10%, ferrocene 0.1%-1%, water 1%-10%.
3. the preparation method of a kind of biological alcohol oil according to claim 2, is characterized in that, each constituent mass per-cent is: methyl alcohol 70%, ethanol 13%, stablizer 6%, acetone 6%, ferrocene 0.4%, water 4.6%.
4. the preparation method of a kind of biological alcohol oil according to claim 1, is characterized in that, stablizer comprises Oleum Gossypii semen and glycerine.
5. the preparation method of a kind of biological alcohol oil according to claim 4, is characterized in that, contains by mass percentage 80% Oleum Gossypii semen and 20% glycerine in stablizer.
6. the preparation method of a kind of biological alcohol oil according to claim 4, is characterized in that, concrete steps are:
1. in A container, Oleum Gossypii semen, glycerine are heated, be stirred well to evenly, make stablizer for subsequent use;
2. in B container, add methyl alcohol, ethanol, acetone to be stirred to evenly;
3. in C container, add water, ferrocene;
4. the solution in A, C container is added in B container, fully stir, make biological alcohol oil.
7. the preparation method of a kind of biological alcohol oil according to claim 6, is characterized in that, step 1. in, Oleum Gossypii semen, glycerine are heated to 230 ℃.
8. the preparation method of a kind of biological alcohol oil according to claim 6, is characterized in that, step adds the solution in A, C container in B container in 4., stirs 20-60 minute.
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| CN201310556255.1A CN103805295A (en) | 2013-11-11 | 2013-11-11 | Prepared method of biological alcohol oil |
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| CN201310556255.1A CN103805295A (en) | 2013-11-11 | 2013-11-11 | Prepared method of biological alcohol oil |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753604A (en) * | 2016-12-20 | 2017-05-31 | 墨宝股份有限公司 | A kind of novel energy-saving environment-friendly is without benzene low-carbon (LC) machinery alcohol-based fuel |
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| CN1103659A (en) * | 1994-05-14 | 1995-06-14 | 海口长寿篷布制品联营公司 | Synthetic civil alcohols fuel |
| CN1117075A (en) * | 1994-08-16 | 1996-02-21 | 孙明路 | Synthetic liquid fuel and its producing process |
| CN1667094A (en) * | 2005-04-08 | 2005-09-14 | 谷宝龙 | Alcohol-base liquid fuel |
| CN1861763A (en) * | 2006-06-07 | 2006-11-15 | 广州市波鑫环保科技有限公司 | Water-soluble ol group liquid fuel |
| CN101875867A (en) * | 2009-04-28 | 2010-11-03 | 秦光校 | Novel environmentally-friendly biological alcohol oil formula |
| CN101885995A (en) * | 2009-05-13 | 2010-11-17 | 陈新征 | Method for preparing environmentally-friendly biological alcohol oil |
| CN101921630A (en) * | 2009-06-17 | 2010-12-22 | 李德军 | Novel bio-alcohol oil fuel |
| CN103232876A (en) * | 2013-05-27 | 2013-08-07 | 深圳市明灯科技有限公司 | Boiler coking inhibitor |
-
2013
- 2013-11-11 CN CN201310556255.1A patent/CN103805295A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1103659A (en) * | 1994-05-14 | 1995-06-14 | 海口长寿篷布制品联营公司 | Synthetic civil alcohols fuel |
| CN1117075A (en) * | 1994-08-16 | 1996-02-21 | 孙明路 | Synthetic liquid fuel and its producing process |
| CN1667094A (en) * | 2005-04-08 | 2005-09-14 | 谷宝龙 | Alcohol-base liquid fuel |
| CN1861763A (en) * | 2006-06-07 | 2006-11-15 | 广州市波鑫环保科技有限公司 | Water-soluble ol group liquid fuel |
| CN101875867A (en) * | 2009-04-28 | 2010-11-03 | 秦光校 | Novel environmentally-friendly biological alcohol oil formula |
| CN101885995A (en) * | 2009-05-13 | 2010-11-17 | 陈新征 | Method for preparing environmentally-friendly biological alcohol oil |
| CN101921630A (en) * | 2009-06-17 | 2010-12-22 | 李德军 | Novel bio-alcohol oil fuel |
| CN103232876A (en) * | 2013-05-27 | 2013-08-07 | 深圳市明灯科技有限公司 | Boiler coking inhibitor |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753604A (en) * | 2016-12-20 | 2017-05-31 | 墨宝股份有限公司 | A kind of novel energy-saving environment-friendly is without benzene low-carbon (LC) machinery alcohol-based fuel |
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Application publication date: 20140521 |