CN103804884A - Phosphate flame retardant modified polyphenylether material - Google Patents
Phosphate flame retardant modified polyphenylether material Download PDFInfo
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- CN103804884A CN103804884A CN201210458458.2A CN201210458458A CN103804884A CN 103804884 A CN103804884 A CN 103804884A CN 201210458458 A CN201210458458 A CN 201210458458A CN 103804884 A CN103804884 A CN 103804884A
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- flame retardant
- phosphate flame
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- polyphenyl ether
- ether material
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Abstract
The invention relates to a phosphate flame retardant modified polyphenylether material, belonging to the technical field of high polymer materials. The material is prepared from the following raw materials in parts by weight: 30-40 parts of polyphenylether resin, 12-16 parts of polyamide resin, 10-15 parts of reinforcing fiber, 30-50 parts of filler, 3-6 parts of phosphate flame retardant and 0.7-1.0 part of lubricant. The material has the following advantages: the bending strength is 50-60 MPa, the notch impact strength is 80-90 j/m, the heat-deformation temperature is 120-135 DEG C, and the flame retardancy is V-0 (UL-94-V-0-3.0mm).
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of polyphenyl ether material of phosphate flame retardant modification.
Background technology
Owing to forming metaphosphoric acid in phosphate flame retardant burning, metaphosphoric acid belongs to strong dewatering agent, thereby makes organic matter carbonizing around, has stoped burning to be carried out, and does not have obnoxious flavour or objectionable impurities to generate, and is therefore a kind of fire retardant of environmental protection.Polyphenylene oxide is a kind of general engineering plastic materials of having many uses, and is widely used in the products such as electric wire, electrical equipment, electronics.Visible have positive effect with phosphate flame retardant modified polyphenylene ether resin, and technical scheme described below is based on producing under this prerequisite.
Summary of the invention
Task of the present invention is the polyphenyl ether material that a kind of phosphate flame retardant modification will be provided, and this material has higher intensity and flame retardant resistance.
Task of the present invention completes like this, a kind of polyphenyl ether material of phosphate flame retardant modification, and its raw material by following parts by weight forms:
In one embodiment of the invention, described polyphenyl ether material is 2.6 dimethyl 1.4 phenylates.
In another embodiment of the present invention, described polyamide resin is polyamide 66 resin, and its fusing point is 220 ℃.
In yet another embodiment of the present invention, described fortifying fibre is the alkali free glass fibre of length 3mm.
In another embodiment of the present invention, described filler is calcium carbonate superfine powder.
Also have in an embodiment of the present invention, described phosphate flame retardant is Resorcinol tetraphenyldiphosphate.
More of the present invention and in an embodiment, described lubricant is calcium stearate.
By the polyphenyl ether material of phosphate flame retardant modification provided by the invention, there is following performance through test: flexural strength 50～60MPa, notched Izod impact strength 80～90j/m, 120～135 ℃ of heat-drawn wires, flame retardant resistance V-0 (UL-94-V-0-3.0mm).
Embodiment
Embodiment 1:
Embodiment 2:
Embodiment 3:
Embodiment 4:
The polyphenyl ether material of the phosphate flame retardant modification being obtained by above-described embodiment 1 to 1 has the technique effect shown in following table after tested.
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Flexural strength | 50.5 | 52.6 | 57.3 | 59．8 |
| Notched Izod impact strength (J/M) | 80.2 | 84.5 | 86.3 | 89.2 |
| Heat-drawn wire | 121 | 126 | 131 | 135 |
| Flame retardant resistance (UL-94-V-0-3.0mm) | V-0 | V-0 | V-0 | V-0 |
Claims (7)
1.
a polyphenyl ether material for phosphate flame retardant modification, is characterized in that its raw material by following parts by weight forms:
30 ~ 40 parts of polyphenylene oxide resins;
12 ~ 16 parts of polyamide resins;
10 ~ 15 parts of fortifying fibres;
30 ~ 50 parts of fillers;
3 ~ 6 parts of phosphate flame retardants;
0.7 ~ 1.0 part of lubricant.
2.
the polyphenyl ether material of phosphate flame retardant modification according to claim 1, is characterized in that described polyphenyl ether material is 2.6 dimethyl 1.4 phenylates.
3.
the polyphenyl ether material of phosphate flame retardant modification according to claim 1, is characterized in that described polyamide resin is polyamide 66 resin, and its fusing point is 220 ℃.
4.
the polyphenyl ether material of phosphate flame retardant modification according to claim 1, is characterized in that described fortifying fibre is the alkali free glass fibre of length 3mm.
5.
the polyphenyl ether material of phosphate flame retardant modification according to claim 1, is characterized in that described filler is calcium carbonate superfine powder.
6.
the polyphenyl ether material of phosphate flame retardant modification according to claim 1, is characterized in that described phosphate flame retardant is Resorcinol tetraphenyldiphosphate.
7.
the polyphenyl ether material of phosphate flame retardant modification according to claim 1, is characterized in that described lubricant is calcium stearate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210458458.2A CN103804884A (en) | 2012-11-15 | 2012-11-15 | Phosphate flame retardant modified polyphenylether material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210458458.2A CN103804884A (en) | 2012-11-15 | 2012-11-15 | Phosphate flame retardant modified polyphenylether material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103804884A true CN103804884A (en) | 2014-05-21 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210458458.2A Pending CN103804884A (en) | 2012-11-15 | 2012-11-15 | Phosphate flame retardant modified polyphenylether material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103804884A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0529378A1 (en) * | 1991-08-24 | 1993-03-03 | BASF Aktiengesellschaft | Thermoplastic moulding based on polyamide and polyphenylene ether |
| CN1502650A (en) * | 2002-11-27 | 2004-06-09 | ͨ�õ�����˾ | Additive for thermoplastic resins and flame retardant resin compositions |
| CN101072832A (en) * | 2004-12-03 | 2007-11-14 | 通用电气公司 | Conductive poly(arylene ether)-polyamide compositions, and related methods and articles |
| CN101134841A (en) * | 2006-08-29 | 2008-03-05 | 广州金发科技股份有限公司 | Shockproof conductive polyphenyl ether polyamide compound and method for making same |
| CN101163746A (en) * | 2005-04-13 | 2008-04-16 | 旭化成化学株式会社 | Polyamide-polyphenylene ether resin composition |
| CN101759992A (en) * | 2008-12-23 | 2010-06-30 | 金发科技股份有限公司 | Reinforced halogen-free flame-retardant polyphenyl ether composition and preparation method and application thereof |
| CN101875776A (en) * | 2010-03-31 | 2010-11-03 | 深圳市科聚新材料有限公司 | High-strength PPO/PA66 alloy material and preparation method thereof |
| CN101985491A (en) * | 2009-07-29 | 2011-03-16 | 比亚迪股份有限公司 | Plastic compatibilizer and method for preparing same, and polyphenylene oxide/nylon alloy containing compatibilizer and preparation method thereof |
| CN102732019A (en) * | 2012-07-17 | 2012-10-17 | 上海日之升新技术发展有限公司 | Flame-retardant glass fiber reinforced PA610 (Poly A 610)/PPO (poly-p-phenylene oxide) alloy composition and preparation method thereof |
-
2012
- 2012-11-15 CN CN201210458458.2A patent/CN103804884A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0529378A1 (en) * | 1991-08-24 | 1993-03-03 | BASF Aktiengesellschaft | Thermoplastic moulding based on polyamide and polyphenylene ether |
| CN1502650A (en) * | 2002-11-27 | 2004-06-09 | ͨ�õ�����˾ | Additive for thermoplastic resins and flame retardant resin compositions |
| CN101072832A (en) * | 2004-12-03 | 2007-11-14 | 通用电气公司 | Conductive poly(arylene ether)-polyamide compositions, and related methods and articles |
| CN101163746A (en) * | 2005-04-13 | 2008-04-16 | 旭化成化学株式会社 | Polyamide-polyphenylene ether resin composition |
| CN101134841A (en) * | 2006-08-29 | 2008-03-05 | 广州金发科技股份有限公司 | Shockproof conductive polyphenyl ether polyamide compound and method for making same |
| CN101759992A (en) * | 2008-12-23 | 2010-06-30 | 金发科技股份有限公司 | Reinforced halogen-free flame-retardant polyphenyl ether composition and preparation method and application thereof |
| CN101985491A (en) * | 2009-07-29 | 2011-03-16 | 比亚迪股份有限公司 | Plastic compatibilizer and method for preparing same, and polyphenylene oxide/nylon alloy containing compatibilizer and preparation method thereof |
| CN101875776A (en) * | 2010-03-31 | 2010-11-03 | 深圳市科聚新材料有限公司 | High-strength PPO/PA66 alloy material and preparation method thereof |
| CN102732019A (en) * | 2012-07-17 | 2012-10-17 | 上海日之升新技术发展有限公司 | Flame-retardant glass fiber reinforced PA610 (Poly A 610)/PPO (poly-p-phenylene oxide) alloy composition and preparation method thereof |
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Application publication date: 20140521 |