CN103798252A - 一种硝磺草酮复配除草剂 - Google Patents
一种硝磺草酮复配除草剂 Download PDFInfo
- Publication number
- CN103798252A CN103798252A CN201410068968.8A CN201410068968A CN103798252A CN 103798252 A CN103798252 A CN 103798252A CN 201410068968 A CN201410068968 A CN 201410068968A CN 103798252 A CN103798252 A CN 103798252A
- Authority
- CN
- China
- Prior art keywords
- mesotrione
- bentazone
- herbicide
- compound herbicide
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005578 Mesotrione Substances 0.000 title claims abstract description 21
- 239000004009 herbicide Substances 0.000 title claims abstract description 20
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 17
- -1 Mesotrione compound Chemical class 0.000 title abstract description 14
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000005476 Bentazone Substances 0.000 claims abstract description 11
- ZOMSMJKLGFBRBS-UHFFFAOYSA-N bentazone Chemical compound C1=CC=C2NS(=O)(=O)N(C(C)C)C(=O)C2=C1 ZOMSMJKLGFBRBS-UHFFFAOYSA-N 0.000 claims abstract description 11
- CNBGNNVCVSKAQZ-UHFFFAOYSA-N benzidamine Natural products C12=CC=CC=C2C(OCCCN(C)C)=NN1CC1=CC=CC=C1 CNBGNNVCVSKAQZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- 239000000375 suspending agent Substances 0.000 claims description 9
- 150000002170 ethers Chemical class 0.000 claims description 6
- 239000002552 dosage form Substances 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 abstract description 10
- 238000001228 spectrum Methods 0.000 abstract description 4
- FUHMZYWBSHTEDZ-UHFFFAOYSA-M bispyribac-sodium Chemical compound [Na+].COC1=CC(OC)=NC(OC=2C(=C(OC=3N=C(OC)C=C(OC)N=3)C=CC=2)C([O-])=O)=N1 FUHMZYWBSHTEDZ-UHFFFAOYSA-M 0.000 abstract 2
- 239000004480 active ingredient Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 21
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- 244000025254 Cannabis sativa Species 0.000 description 5
- 240000007594 Oryza sativa Species 0.000 description 5
- 235000007164 Oryza sativa Nutrition 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 230000004224 protection Effects 0.000 description 5
- 235000009566 rice Nutrition 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 239000007900 aqueous suspension Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 244000058871 Echinochloa crus-galli Species 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- FKUYMLZIRPABFK-UHFFFAOYSA-N Plastoquinone 9 Natural products CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCC1=CC(=O)C(C)=C(C)C1=O FKUYMLZIRPABFK-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000000442 meristematic effect Effects 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- FKUYMLZIRPABFK-IQSNHBBHSA-N plastoquinone-9 Chemical compound CC(C)=CCC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC\C(C)=C\CC1=CC(=O)C(C)=C(C)C1=O FKUYMLZIRPABFK-IQSNHBBHSA-N 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 description 1
- WTLNOANVTIKPEE-UHFFFAOYSA-N 2-acetyloxypropanoic acid Chemical compound OC(=O)C(C)OC(C)=O WTLNOANVTIKPEE-UHFFFAOYSA-N 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- 241001290610 Abildgaardia Species 0.000 description 1
- 240000007241 Agrostis stolonifera Species 0.000 description 1
- 244000026873 Alternanthera philoxeroides Species 0.000 description 1
- 240000001592 Amaranthus caudatus Species 0.000 description 1
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 239000004151 Calcium iodate Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- 241000234653 Cyperus Species 0.000 description 1
- 244000285790 Cyperus iria Species 0.000 description 1
- QXKAIJAYHKCRRA-JJYYJPOSSA-N D-arabinonic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C(O)=O QXKAIJAYHKCRRA-JJYYJPOSSA-N 0.000 description 1
- 102000016680 Dioxygenases Human genes 0.000 description 1
- 108010028143 Dioxygenases Proteins 0.000 description 1
- 241000759199 Eleocharis acicularis Species 0.000 description 1
- 240000001723 Entada phaseoloides Species 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- RMFGNMMNUZWCRZ-UHFFFAOYSA-N Humulone Natural products CC(C)CC(=O)C1=C(O)C(O)(CC=C(C)C)C(O)=C(CC=C(C)C)C1=O RMFGNMMNUZWCRZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000254158 Lampyridae Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 240000007038 Lindernia dubia Species 0.000 description 1
- 241000091577 Mexicana Species 0.000 description 1
- 241000169076 Monochoria korsakowii Species 0.000 description 1
- 240000000178 Monochoria vaginalis Species 0.000 description 1
- 241001434359 Muhlenbergia phleoides Species 0.000 description 1
- 241000415261 Murdannia Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000173219 Paspalum distichum Species 0.000 description 1
- 241000756999 Potamogetonaceae Species 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 125000006177 alkyl benzyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical group 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000001851 biosynthetic effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- UHWJJLGTKIWIJO-UHFFFAOYSA-L calcium iodate Chemical compound [Ca+2].[O-]I(=O)=O.[O-]I(=O)=O UHWJJLGTKIWIJO-UHFFFAOYSA-L 0.000 description 1
- 235000019390 calcium iodate Nutrition 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 235000021466 carotenoid Nutrition 0.000 description 1
- 150000001747 carotenoids Chemical class 0.000 description 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 1
- 210000003763 chloroplast Anatomy 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000018927 edible plant Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- VMSLCPKYRPDHLN-NRFANRHFSA-N humulone Chemical compound CC(C)CC(=O)C1=C(O)C(CC=C(C)C)=C(O)[C@@](O)(CC=C(C)C)C1=O VMSLCPKYRPDHLN-NRFANRHFSA-N 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229950000081 metilsulfate Drugs 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- QIIPQYDSKRYMFG-UHFFFAOYSA-N phenyl hydrogen carbonate Chemical compound OC(=O)OC1=CC=CC=C1 QIIPQYDSKRYMFG-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 108010001545 phytoene dehydrogenase Proteins 0.000 description 1
- 244000112814 pipewort Species 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical class [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229960004306 sulfadiazine Drugs 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
一种硝磺草酮复配除草剂，其特征在于，所述复合除草剂包含硝磺草酮、灭草松、双草醚三种活性成分，其中硝磺草酮、灭草松、双草醚的重量比为1～30：1～30：1～20。本发明提供了一种安全，速度快，杀草谱广，施药期长，受环境影响小的除草剂。
Description
技术领域
本发明涉及一种硝磺草酮复配除草剂。
背景技术
水稻是我国重要的粮食作物，事关国计民生及国家的粮食安全。灭草松（bentazone)化学名称为：3-异丙基-（1H）-苯并-2,1,3-噻二嗪-4-酮-2，2-二氧化物,灭草松是光合作用抑制剂，主要通过叶片吸收，旱田茎叶喷雾后，先通过叶片渗透进入叶绿体内抑制光合作用，水稻田使用还可通过根吸收传到茎叶。不能被未发芽的种子吸收，幼芽通过土层过程中吸收药剂也很少，所以只能在杂草出土后茎叶喷雾法使用。落入土壤的药剂很少被吸附，易淋入土壤深层，也易被土壤微生物分解，因而不宜用作土壤处理。杀草作用快，施药后10h，叶片开始萎蔫变黄。
硝磺草酮（mesotrione)化学名称：2-（2-硝基-4-甲磺酰基苯加酰）环己烷-1,3-二酮。硝磺草酮抑制对-羟基丙酮酸双加氧酶（HPPD）的活性，HPPD可将氨基酸洛氨酸转化为质体醌。质体醌是八氢番茄红素去饱和酶的辅助因子。是类胡萝卜素生物合成的关键酶。使用硝磺草酮3-5天内植物分生组织出现黄化症状随之引起枯斑，两星期后遍及整株植物。具有弱酸性，在大多数酸性土壤中，能紧紧吸附在有机物质上，在中性或碱性土壤中，以不易被吸收的阴离子形式存在。是一种新型的三酮类除草剂，既可以苗前土表处理，也可以在苗后进行茎叶喷雾，在见效快的同时，硝磺草酮在土壤中残留期短，对后茬作物安全。同时，其生物活性超过磺草酮10倍以上，更具有开发潜力与竞争力。
双草醚，又名农美利，水杨酸双嘧啶，化学名称：2，6-双(4，6-二甲氧嘧啶基-2-氧基)苯酸钠。属苯氧羧酸类除草剂，主要通过根叶吸收抑制醋乳酸合成而阻碍氨基酸生物合成支链，为选择性除草剂，在水稻直播田中使用，除草谱广。双草醚属于苯甲酸类除草剂，是高活性的乙酰乳酸合成酶(ALS)抑制剂，双草醚在喷施到杂草上后可以很快被杂草的茎叶吸收，并传导至整个植株，抑制植物分生组织生长，从而杀死杂草，高效、广谱、用量低。双草醚能有效防除稻田稗草及其他禾本科杂草，兼治大多数阔叶杂草、一些莎草科杂草及对其它除草剂产生抗性的稗草。如：稗草、双穗雀稗(红拌根草、过江龙)、稻李氏禾、马唐、匍茎剪股颖、看麦娘、东北甜茅、狼巴草、异形莎草、日照瓢拂草、碎米莎草、萤蔺、日本草、扁秆草、鸭舌草、雨久花、野慈菇、泽泻、眼子菜、谷精草、牛毛毡、节节菜、陌上菜、水竹叶、空心莲子草、花蔺等水稻田常见的绝大部分杂草。
发明内容
技术问题
有鉴于此，本发明要解决的技术问题是，提供一种高效的复合除草剂。
解决方案
为了解决上述技术问题，本发明提供了一种硝磺草酮复配除草剂，其特征在于，所述复合除草剂包含硝磺草酮、灭草松、双草醚两种活性成分，其中硝磺草酮、灭草松、双草醚的重量比为1～30：1～30：1～20。
优选的，硝磺草酮、灭草松、双草醚的重量比为2：2：1。
优选的，所述活性成分在复合除草剂中的质量百分比为5-70%。
优选的，所述组合物剂型是悬浮剂。
有益效果
本发明提供了一种安全，速度快，杀草谱广，施药期长，受环境影响小的除草剂。
具体实施方式
制剂实施例
发明人发现，本配方采用油悬剂（油悬剂、水悬剂）的效果较好。
悬浮剂是指将固体农药原药以4微米以下的微粒均匀分散于水中的制剂，国际代号为SC，又称浓悬浊剂，流动剂，水悬剂，胶悬剂。难溶于水的固体农药与助剂经过研磨、分散在水介质中的悬浊液。连续相为水。由于SC没有像可湿粉(WP)那样的粉尘飞扬问题，不易燃易爆，粒径小，生物活性高，比重较大，包装体积较小，相对其他农药剂型安全环保。
悬浮剂分为水悬浮剂和油悬浮剂两种。水悬浮剂是水作溶剂。油悬浮剂是以油类为主要溶剂，不含水。
分散剂为木质素磺酸盐、木质素碘酸钙、月桂醇聚氧乙烯醚硫酸钠、烷基奈甲醛缩合物磺酸盐、十二烷基苯磺酸钠、十二烷基硫酸钠、烷基聚氧乙烯醚磺酸盐、烷基酚聚氧乙烯基醚甲醛缩合物、烷基酚聚氧乙烯基醚壬基酚聚氧乙烯基醚、聚氧乙烯聚氧丙烯基醚嵌段共聚物、拉开粉、高分子羧酸盐、亚甲基双荼磺酸钠、聚乙烯醇、改性的萘磺酸盐、聚羧酸盐、烷基萘磺酸盐、烷基酚聚氧乙烯醚、EO/PO嵌段聚醚、JFC、拉开粉、壬基酚聚氧乙烯醚、辛基酚聚氧乙烯硫酸钠、脂肪醇硫酸盐、烷基萘磺酸盐、脂肪酰胺N-甲基磺酸盐、脂肪醇聚氧乙烯硫酸钠、脂肪酸硫酸盐、脂肪醇聚氧乙烯醚、烷基酚聚氧乙烯醚、烷基苄基二甲基氯化铵、烷基胺氧化物中的一种或两种以上的组合物。
润湿剂为烷基硫酸盐、烷基磺酸盐、萘磺酸盐、木质素磺酸钠、脂肪醇聚氧乙烯醚、烷基酚聚氧乙烯醚、短链EO/PO嵌段聚醚、壬基酚聚氧乙烯醚、非离子乙氧基化物、十二烷基硫酸钠、十二烷基磺酸钠、TERSPERSE2700、TERSPERSE1004、木质素磺酸钠、NNO、聚氧乙烯聚氧丙烯基醚嵌段共聚物、烷基酚聚氧乙烯基醚磷酸酯或水溶性高分子化合物CMC、PVA其中的一种或两种以上的组合物。
乳化剂为一种或多种阴离子、非离子表面活性剂的复合物，非离子表面活性剂如脱水山梨醇脂肪酸酯、烷基酚聚氧乙烯聚氧丙烯醚、聚氧乙烯烷基胺等，阴离子表面活性剂如十二烷基苯磺酸钙、十二烷基苯磺酸钠等，可以为其中的一种或两种以上的组合物。
增稠剂为聚乙烯醇、甲基纤维素、黄原胶、羟甲基纤维素、有机膨润土、硅酸镁铝、阿拉伯酸胶中的一种或几种。
施药10天后结果
施药20天后结果
各处理小区内的水稻长势良好，各处理小区未见任何药斑，说明本发明的复配药剂对水稻均安全。
以上所述，仅为本发明的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，可轻易想到变化或替换，都应涵盖在本发明的保护范围之内。因此，本发明的保护范围应所述以权利要求的保护范围为准。
Claims (3)
1.一种硝磺草酮复配除草剂，其特征在于，所述复合除草剂包含硝磺草酮、灭草松、双草醚三种活性成分，其中硝磺草酮、灭草松、双草醚的重量比为1～30：1～30：1～20，所述组合物剂型是悬浮剂。
2.根据权利要求1所述的硝磺草酮复配除草剂，其特征在于，所述硝磺草酮、灭草松、双草醚的重量比为2：2：1。
3.根据权利要求1和2所述的硝磺草酮复配除草剂，其特征在于，所述活性成分在复合除草剂中的质量百分比为5-70%。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410068968.8A CN103798252B (zh) | 2014-02-27 | 2014-02-27 | 一种硝磺草酮复配除草剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410068968.8A CN103798252B (zh) | 2014-02-27 | 2014-02-27 | 一种硝磺草酮复配除草剂 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103798252A true CN103798252A (zh) | 2014-05-21 |
| CN103798252B CN103798252B (zh) | 2016-04-13 |
Family
ID=50696027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410068968.8A Active CN103798252B (zh) | 2014-02-27 | 2014-02-27 | 一种硝磺草酮复配除草剂 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103798252B (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113207875A (zh) * | 2017-11-29 | 2021-08-06 | 上海师范大学 | 一种硝磺草酮水悬浮剂及其制备方法和应用 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002015694A2 (en) * | 2000-08-25 | 2002-02-28 | Basf Aktiengesellschaft | Herbicidal mixtures |
| CN101595886A (zh) * | 2009-07-10 | 2009-12-09 | 合肥星宇化学有限责任公司 | 用于水稻田的除草组合物 |
| CN102265884A (zh) * | 2010-06-03 | 2011-12-07 | 南京华洲药业有限公司 | 一种含灭草松、烟嘧磺隆和硝磺草酮的混合除草剂及其应用 |
| CN103155928A (zh) * | 2013-03-29 | 2013-06-19 | 北京燕化永乐农药有限公司 | 一种复配除草剂 |
| CN103518744A (zh) * | 2013-09-30 | 2014-01-22 | 山东滨农科技有限公司 | 一种玉米田用除草组合物 |
-
2014
- 2014-02-27 CN CN201410068968.8A patent/CN103798252B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002015694A2 (en) * | 2000-08-25 | 2002-02-28 | Basf Aktiengesellschaft | Herbicidal mixtures |
| CN101595886A (zh) * | 2009-07-10 | 2009-12-09 | 合肥星宇化学有限责任公司 | 用于水稻田的除草组合物 |
| CN102265884A (zh) * | 2010-06-03 | 2011-12-07 | 南京华洲药业有限公司 | 一种含灭草松、烟嘧磺隆和硝磺草酮的混合除草剂及其应用 |
| CN103155928A (zh) * | 2013-03-29 | 2013-06-19 | 北京燕化永乐农药有限公司 | 一种复配除草剂 |
| CN103518744A (zh) * | 2013-09-30 | 2014-01-22 | 山东滨农科技有限公司 | 一种玉米田用除草组合物 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113207875A (zh) * | 2017-11-29 | 2021-08-06 | 上海师范大学 | 一种硝磺草酮水悬浮剂及其制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103798252B (zh) | 2016-04-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101088336A (zh) | 增效种子处理组合物 | |
| EA030243B1 (ru) | Гербицидные композиции, содержащие комбинацию имазетапира и имазамокса и фомезафен | |
| CN102379289A (zh) | 含有氰氟草酯与双草醚的除草组合物 | |
| CN104054716B (zh) | 一种含有环磺酮的除草组合物 | |
| CN103783066A (zh) | 一种氟嘧肟草醚除草剂组合物 | |
| CN104472501A (zh) | 增效除草组合物 | |
| CN102057924A (zh) | 一种含有环苯草酮和五氟磺草胺的复配组合物 | |
| CN104115835A (zh) | 一种除草剂组合物 | |
| CN108719305A (zh) | 含有呋喃磺草酮和氟酮磺草胺以及磺酰脲类除草剂的除草组合物 | |
| WO2024078365A1 (zh) | 一种含苯嘧草唑和精草铵膦的除草组合物及其应用 | |
| CN105432644A (zh) | 一种含氯吡嘧磺隆与氟噻草胺的混合除草剂 | |
| CN102258024B (zh) | 一种除草组合物 | |
| CN103798252B (zh) | 一种硝磺草酮复配除草剂 | |
| CN103783062A (zh) | 一种噁嗪草酮复合除草剂 | |
| CN103329937A (zh) | 一种杀菌活性成分组合物 | |
| CN103053575A (zh) | 烟嘧磺隆和莠去津混合除草剂 | |
| CN105284829A (zh) | 含有嘧草醚和乙氧氟草醚以及丙炔噁草酮的除草组合物 | |
| CN102258027B (zh) | 一种增效除草组合物 | |
| CN102283224B (zh) | 一种小麦田除草组合物及其制剂 | |
| CN108770851A (zh) | 含有呋喃磺草酮和噁嗪草酮以及磺酰脲类除草剂的除草组合物 | |
| CN104585188B (zh) | 含有氟氯吡啶酯和吡草醚以及唑啉草酯的除草组合物 | |
| CN103081944A (zh) | 一种除草组合物及除草剂 | |
| CN105265464A (zh) | 含有嘧草醚和乙氧氟草醚以及磺酰脲类除草剂的除草组合物 | |
| CN103798267A (zh) | 一种用于直播稻田的除草剂组合物 | |
| CN103798236B (zh) | 一种毒草胺复配除草剂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A compound herbicide of sulfamethoxazole Granted publication date: 20160413 Pledgee: Bank of Nanjing Co.,Ltd. Changzhou Branch Pledgor: JIANGSU INSTITUTE OF ECOMONES Co.,Ltd. Registration number: Y2024980005561 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |