CN103788770B - A kind of colloid micro ball ink of adding lustre to for textiles digit printing structure and application thereof - Google Patents
A kind of colloid micro ball ink of adding lustre to for textiles digit printing structure and application thereof Download PDFInfo
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Abstract
The present invention relates to a kind of textiles digital printing technology, especially a kind of colloid micro ball ink of adding lustre to for textiles digit printing structure and application thereof.A kind of colloid micro ball ink added lustre to for textiles digit printing structure, it is characterized in that it obtains by the mixture mainly comprising following parts by weight of component is dispersed: particle diameter is monodisperse latex 0.5-1.5 part (in solid content) of 200-400nm, anion surfactant (dispersion agent) 0.05-0.15 part, pH adjusting agent (regulating pH=7-8) 0.05-0.5 part, deionized water 100 parts.The colloid micro ball ink set related in the present invention is special in adapting to performance development that textiles digit printing structure adds lustre to.For adapting to the needs of textiles ecological safety, various materials involved in the present invention are nontoxic, tasteless; For adapting to the requirement of textiles flexibility, the present invention is sprayed as required by number and builds ultrathin photon crystal structure film, affects fabric feeling hardly.
Description
Technical field
The present invention relates to a kind of textiles digital printing technology, especially a kind of colloid micro ball ink of adding lustre to for textiles digit printing structure and application thereof.
Background technology
The main path of current textile coloration produces color by being applied with color substance (dyestuff or pigment) on the textile, and then produce color with special physical structure the many organisms of occurring in nature, that is: structure is added lustre to.The generation of schemochrome need not the existence of the chemical stain such as dyestuff and pigment agent, its essence is the visual effect that particular tissues structure produces the physical phenomenon such as dispersion, scattering, interference and diffraction of light.
Photonic crystal (PCs) is a class forbidden photon band material, is one of main reason of occurring in nature schemochrome, as namely: bright-colored gorgeous colors such as peacock feather, opal result from photon crystal structure.So-called photon crystal structure refers to by two kinds or the two or more material with the differing refraction indices special construction that formed of periodic arrangement according to certain rules.When the forbidden photon band of photonic crystal is positioned at visible light wave range (380-780nm), light due to forbidden band corresponding wavelength can not be propagated and by selective reflection in this photon crystal structure, and then form coherent diffraction at the photon crystal surface of periodic arrangement, when the reflected light of constructive interference stimulates human eye, just produce schemochrome effect.Photonic crystal structure color has the characteristics such as high brightness, high saturation, iris phenomenon (color changes with viewing angle).
The approach that to take colloid micro ball as structural unit build photon crystal structure (i.e. colloidal crystal ColloidalPCs) by self-assembling method is the simple and effective approach obtaining photon crystal structure.In various self-assembling method, settling methods, vertical sedimentation method are modal self-assembling methods.Although these self-assembling methods are easy but there is many deficiencies, because it realizes in the mode of immersed substrate usually, there is built-up time length, waste of material, the problems such as assembling is painted can not be located as required.At field of textiles, rarely has report about the research obtaining photonic crystal structure color at fabric face.
Summary of the invention
The invention provides a kind of colloid micro ball ink set, this ink has stability when normal temperature is deposited, microballoon is not reunited and sedimentation, and has suitable mobility and can be used for digital spray printing, after on spray printing to fabric, colloid micro ball energy self-assembly wherein produces schemochrome.
The present invention also provides a kind of textiles digital printing method utilizing described colloidal inks to carry out.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of colloid micro ball ink added lustre to for textiles digit printing structure, it is characterized in that it obtains by the mixture mainly comprising following parts by weight of component is dispersed: particle diameter is monodisperse latex 0.5-1.5 part (in solid content) of 200-400nm, anion surfactant (dispersion agent) 0.05-0.15 part, pH adjusting agent (regulating pH=7-8) 0.05-0.5 part, deionized water 100 parts.
This seminar adopts the conventional self-assembling method such as settling methods, vertical sedimentation method to achieve textile constructions to add lustre to effect in early-stage Study, on this basis, the present invention discloses and a kind ofly realizes to simulate digital ink-jet printed method the method that textile surface photonic crystal self-assembled structures adds lustre to.The bionical dye technology that photon crystal structure adds lustre to by this invention combines with digital ink-jet printed technology, first colloid micro ball is made ink-jet ink, spray to fabric face by the digital location as required that controls again, and by suitable aftertreatment, colloid micro ball is added lustre at fabric face self-assembled structures.This method can not only realize the effect producing schemochrome on textiles flexible materials without chemical stain agent, and can realize locating painted effect as required.By the method for adding lustre in conjunction with conventional pigment colored and digital spray structure, printing in textiles can be made to produce special agile changeable, lifelike printing effect.
As preferably, described monodisperse latex is polystyrene (PSt) colloid micro ball, polystyrene-methacrylic acid (P (St-MAA)) colloid micro ball or silicon-dioxide (SiO
2) colloid micro ball.
As preferably, the particle dispersion coefficient of described monodisperse colloid microballoon is less than 0.08.
As preferably, described anion surfactant is sodium laurylsulfonate (SDS).
A kind of preparation method of described colloid micro ball ink, detailed process is as follows: take colloid micro ball liquid according to proportion speed, anion surfactant, deionized water is added successively in colloid micro ball liquid, be 7-8 with pH adjusting agent regulation system pH, mixing solutions is placed in ultrasonic dispersers and disperses more than 15min, obtains finely dispersed colloid micro ball ink.
For being at least about the monodisperse latex of 200-400nm in the colloid micro ball ink that textiles digit printing structure is added lustre to containing particle diameter, be used as the elementary cell of assembling photon crystal structure, its particle diameter is the principal element determining photonic crystal structure color, the target of schemochrome effect is produced for selective reflection need be carried out in visible ray (380-780nm) scope, the particle size range needed for colloid micro ball can be calculated, the photonic crystal constructed by the colloid micro ball of different-grain diameter and schemochrome difference thereof according to the Bragg diffraction formula revised.The monodispersity of colloid micro ball is the important factor determining photon crystal structure regularity, the regularity of photonic crystal then affects vividness (saturation ratio) and the brightness of schemochrome, should be less than 0.08 for the particle dispersion coefficient building the colloid micro ball of photon crystal structure.At least containing tensio-active agent, as dispersion agent, in order to improve the stability of colloid micro ball ink, kind and the consumption of dispersion agent directly affect dispersion effect.At least containing pH adjusting agent, under different pH conditions, the charging property of colloid micro ball is different, thus has influence on shelf stability and the self-assembly effect of ink.It should be noted that the charging property of different colloid micro ball itself is different, other composition thus in ink system need do corresponding optimization and adjustment, but similar with thinking of the present invention, all within protection scope of the present invention.
The digital ink-jet printed structure of textiles that a kind of described colloid micro ball ink carries out is added lustre to method, comprise the steps: a, described colloid micro ball ink be added in the ink tank of numerical control ink Jet system of simulation digit printing, by the size of the selection of jet size and the regulable control liquid droplets of spraying pressure, and accurately control spray printing position by three-dimension numerical controlled program setting, through suitable pre-treatment treat PRINTED FABRIC surface by design floral designs colloid micro ball ink carry out spray printing; B, by the fabric of good for spray printing colloid micro ball ink 70-80 DEG C of temperature and with the condition of air blast under process 10-15min, make colloid micro ball complete self assembling process at fabric face, produce schemochrome.Fig. 1 is the digital ink-jet printed schematic diagram of simulation and Fig. 2 is colloid micro ball self assembling process schematic diagram.
As preferably, described treats that the pre-treatment of PRINTED FABRIC is conventional textiles water repellent finish or refuses water top finish, its effect is the surface property changing fabric, fabric is made to have certain hydrophobicity (initial contact angle of water is greater than 110 degree), be conducive to keeping the microenvironment needed for colloid micro ball self-assembly, obtain large-area ordered photon crystal structure and bright-coloured bright schemochrome.
As preferably, described fabric to be printed is black ground yarn dyed fabric.What forbidden photon band can not be prohibited is absorbed by black ground colour through luminous energy, thus the schemochrome that photonic crystal selective reflection light is produced is more bright-coloured.
The textiles digital printing method that colloid micro ball ink of the present invention carries out will pay special attention to the condition (temperature and convection of air etc.) printing rear self assembling process, well completes the realization with photonic crystal structure color with what ensure colloid micro ball self assembling process.The too low easy generation of temperature " coffee ring " effect, temperature is too high, and the defect of self-assembling photonic crystal can be made to increase, and preferred temperature range is 70-80 DEG C.Strengthen convection of air to be conducive to realizing large-area ordered colloid micro ball self-assembly.
The colloid micro ball ink set related in the present invention is special in adapting to performance development that textiles digit printing structure adds lustre to.For adapting to the needs of textiles ecological safety, various materials involved in the present invention are nontoxic, tasteless; For adapting to the requirement of textiles flexibility, the present invention is sprayed as required by number and builds ultrathin photon crystal structure film, affects fabric feeling hardly.
Compared with prior art, the advantage had is in the present invention:
(1) photonic crystal structure color is realized with colloid micro ball self-assembly, need not the painted required chemical stain agent (dyestuff or pigment) of conventional textile, meet the needs of ecological, environmental protective;
(2) digital ink-jet printed to add lustre to biomimetic features is combined, locating structure as required can be realized to add lustre to effect, make the privileged sites of printing in textiles (as: position such as animal eyes, pistil) produce special agile changeable printing effect, be conducive to the practical application that structure is added lustre to;
(3) replace the methods such as conventional gravity self-assembly with number spraying self-assembling method, there is advantage that is quantitatively controlled and saving material.
Accompanying drawing explanation
Fig. 1 is that the present invention simulates digital ink-jet printed schematic diagram;
Fig. 2 is colloid micro ball self assembling process schematic diagram of the present invention.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in further detail.Should be appreciated that enforcement of the present invention is not limited to the following examples, any pro forma accommodation make the present invention and/or change all will fall into scope.
In the present invention, if not refer in particular to, all parts, per-cent are weight unit, and the equipment adopted and raw material etc. all can be buied from market or this area is conventional.Method in following embodiment, if no special instructions, is the ordinary method of this area.
Simulation digital code spray-jet system: adopt digital fluid dispensing system, D-585 type, Nordson Asymtek company of the U.S. produces.
Embodiment 1:
(1) (particle diameter is 202nm accurately to take homemade P (St-MAA) colloid micro ball emulsion, dispersion coefficient is 0.05) 0.5 part (in solid content), add anion surfactant SDS0.05 part, deionized water 100 parts, then add sodium carbonate solution regulation system pH (to add while stirring) within the scope of 7-8, be placed in ultrasonic dispersers again and disperse 15min, obtain finely dispersed colloid micro ball ink;
The preparation method of note: P (St-MAA) colloid micro ball sees reference document---Zhu Wen, Huang Fangting, Zhang Ming, Zhou Jian, the preparation of styrene/methacrylic acid copolymerization microsphere and performance characterization thereof, " functional materials ", 2012,43 (11): 1418-1424.Concrete grammar is: prepared by surfactant-free emulsion polymerization, and monomer is respectively vinylbenzene (St), methacrylic acid (MAA); Initiator is Potassium Persulphate (KPS), and the mass ratio fed intake is: m(St) ﹕ m(MAA) ﹕ m(H
2o) ﹕ m(KPS)=200 ﹕ 30 ﹕ 2000 ﹕ 1.Concrete operations are as follows: the vinylbenzene of measured amounts, methacrylic acid and deionized water, add in four-hole boiling flask respectively; Be placed in thermostat water bath under room temperature to stir, rotating speed is 300r/min.Under the condition of nitrogen protection and condensing reflux, be slowly warming up to 70 DEG C, then add a certain amount of persulfate aqueous solution, constant temperature polyreaction 8h.After reaction terminates, product is crossed and filters by product, stand-by.
(2) colloid micro ball ink previous step obtained is added in the ink tank of the numerical control ink Jet system of simulation digit printing, by the size of the selection of jet size and the regulable control liquid droplets of spraying pressure, and accurately control spray printing position by three-dimension numerical controlled program setting, after setting spray printing parameter, carry out spray printing at the black terylene fabric face through conventional water and oil repellent finish by the floral designs colloid micro ball ink of design;
The pre-treatment of polyester piece good is conventional textiles water repellent finish or refuses water top finish, and those skilled in the art can select voluntarily according to the knowledge grasped, and this is the research emphasis of routine techniques, non-invention, does not do tired stating at this.
(3) fabric of spray printing colloid micro ball ink is placed in electric heating constant temperature baking oven, temperature be 70-80 DEG C and with the condition of air blast under process 15min, make colloid micro ball complete self assembling process at fabric face, produce schemochrome, formed floral designs.
Embodiment 2:
(particle diameter is 253nm accurately to take homemade P (St-MAA) colloid micro ball emulsion, dispersion coefficient is 0.04) 0.8 part (in solid content), add anion surfactant SDS0.08 part, deionized water 100 parts, then adding sodium carbonate solution regulates pH=7-8(to add while stirring), be placed in ultrasonic dispersers again and disperse 15min, obtain finely dispersed colloid micro ball ink;
Spray printing and self-assembly condition identical with embodiment 1 with method.
Embodiment 3:
(particle diameter is 264nm accurately to take homemade P (St-MAA) colloid micro ball emulsion, dispersion coefficient is 0.03) 1.2 parts (in solid content), add anion surfactant SDS0.10 part, deionized water 100 parts, then adding sodium carbonate solution regulates pH=7-8(to add while stirring), be placed in ultrasonic dispersers again and disperse 15min, obtain finely dispersed colloid micro ball ink;
Spray printing and self-assembly condition identical with embodiment 1 with method.
Embodiment 4:
(particle diameter is 280nm accurately to take homemade P (St-MAA) colloid micro ball emulsion, dispersion coefficient is 0.05) 1.5 parts (in solid content), add anion surfactant SDS0.12 part, deionized water 100 parts, then adding sodium carbonate solution regulates pH=7-8(to add while stirring), be placed in ultrasonic dispersers again and disperse 15min, obtain finely dispersed colloid micro ball ink;
Spray printing and self-assembly condition identical with embodiment 1 with method.
Embodiment 5:
(particle diameter is 310nm accurately to take homemade P (St-MAA) colloid micro ball emulsion, dispersion coefficient is 0.06) 1.0 parts (in solid content), add anion surfactant SDS0.1 part, deionized water 100 parts, then adding sodium carbonate solution regulates pH=7-8(to add while stirring), be placed in ultrasonic dispersers again and disperse 15min, obtain finely dispersed colloid micro ball ink;
Spray printing and self-assembly condition identical with embodiment 1 with method.
Embodiment 6:
(particle diameter is 240nm accurately to take homemade PSt colloid micro ball emulsion, dispersion coefficient is 0.06) 1.0 parts (in solid content), add anion surfactant SDS0.1 part, deionized water 100 parts, then adding sodium carbonate solution regulates pH=7-8(to add while stirring), be placed in ultrasonic dispersers again and disperse 15min, obtain finely dispersed colloid micro ball ink;
Spray printing and self-assembly condition identical with embodiment 1 with method.
Note: the preparation method of PSt colloid micro ball sees reference document: Chu Huijuan, Dai Jinhui, Lai Lin, Lu Tonglei, Song Wenwen, Liu Xizhong. the preparation of monodisperse polystyrene microsphere and the self-assembly of two-dimensional colloidal crystal, " material Leader ", volume the 6th phase June the 24th in 2010,37-39 page.
Embodiment 7:
Accurately take homemade SiO
2(particle diameter is 198nm to colloid micro ball emulsion, dispersion coefficient is 0.08) 1.0 parts (in solid content), add anion surfactant SDS0.1 part, deionized water 100 parts, be placed in ultrasonic dispersers again and disperse 15min, obtain finely dispersed colloid micro ball ink;
Spray printing and self-assembly condition identical with embodiment 1 with method.
Note: the preparation method of SiO2 colloid micro ball sees reference document: Wei Miaoju, the preparation of silica colloid particle and the research [D] of formation mechenism thereof. department of chemistry of the Institute of Technology of East China Normal University, 2007 (5): 17.
In above-described embodiment 1-7, the particle diameter of colloid micro ball used and dispersion coefficient thereof test acquisition on dynamic light scattering particle size analyzer (Nano-S, Malvern company, Britain).The schemochrome of sample is absorbed under natural light by Canon's digital camera (EOS600D, EF-S18-55mm f/3.5-5.6IS II).
The effect of fabric after spray printing colloid micro ball ink and self-assembling photonic crystal structure add lustre to of above-described embodiment 1-7 is listed in table 1.
The schemochrome of the different colloid micro ball of table 1 after polyester piece good surface self-organization
* schemochrome changes with the change of viewing angle, and what this tabular went out is the most bright-coloured bright schemochrome tone.
As needed further proving effect, the photochrome of the schemochrome that the present inventor can provide described experiment to be formed.
Above-described embodiment is one of the present invention preferably scheme, not does any pro forma restriction to the present invention, also has other variant and remodeling under the prerequisite not exceeding the technical scheme described in claim.
Claims (5)
1., for the colloid micro ball ink that textiles digit printing structure is added lustre to, it is characterized in that it obtains by the mixture mainly comprising following parts by weight of component is dispersed:
Particle diameter is monodisperse latex 0.5-1.5 part of 200-400nm, in solid content;
Dispersion agent---anion surfactant 0.05-0.15 part;
Regulate pH adjusting agent 0.05-0.5 part of pH=7-8;
Deionized water 100 parts;
Described monodisperse latex is polystyrene (PSt) colloid micro ball, polystyrene-methacrylic acid (P (St-MAA)) colloid micro ball or silicon-dioxide (SiO
2) colloid micro ball, the particle dispersion coefficient of described monodisperse colloid microballoon is less than 0.08; Described anion surfactant is sodium laurylsulfonate (SDS).
2. the preparation method of a colloid micro ball ink according to claim 1, it is characterized in that detailed process is as follows: take colloid micro ball liquid according to proportion speed, anion surfactant, deionized water is added successively in colloid micro ball liquid, be 7-8 with pH adjusting agent regulation system pH, mixing solutions is placed in ultrasonic dispersers and disperses more than 15min, obtains finely dispersed colloid micro ball ink.
3. the digital ink-jet printed structure of textiles utilizing the colloid micro ball ink described in claim 1 to carry out is added lustre to a method, it is characterized in that comprising the steps:
A, described colloid micro ball ink is added in the ink tank of numerical control ink Jet system of simulation digit printing, by the size of the selection of jet size and the regulable control liquid droplets of spraying pressure, and accurately control spray printing position by three-dimension numerical controlled program setting, through pre-treatment treat PRINTED FABRIC surface by design floral designs colloid micro ball ink carry out spray printing;
B, by the fabric of good for spray printing colloid micro ball ink 70-80 DEG C of temperature and with the condition of air blast under process 10-15min, make colloid micro ball complete self assembling process at fabric face, produce schemochrome.
4. the digital ink-jet printed structure of the textiles utilizing colloid micro ball ink to carry out according to claim 3 is added lustre to method, it is characterized in that: described treats that the pre-treatment of PRINTED FABRIC is textiles water repellent finish.
5. the digital ink-jet printed structure of the textiles utilizing colloid micro ball ink to carry out according to claim 3 or 4 is added lustre to method, it is characterized in that: described fabric to be printed is black background color fabric.
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| CN108442138A (en) * | 2018-02-08 | 2018-08-24 | 浙江理工大学 | A kind of textile digital spray printing self assembly adsorption dye-type nanoparticle structure is added lustre to the preparation method of ink |
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Effective date of registration: 20220413 Address after: 310013 room 304, unit 1, building 31, zone 4, Cuiyuan new village, Xihu District, Hangzhou City, Zhejiang Province Patentee after: Shao Jianzhong Address before: 314408 room 317, No. 11, Weisan Road, Haining high tech Industrial Park, Jiaxing City, Zhejiang Province Patentee before: Haining Green Shield Textile Technology Co.,Ltd. Effective date of registration: 20220413 Address after: 314408 room 317, No. 11, Weisan Road, Haining high tech Industrial Park, Jiaxing City, Zhejiang Province Patentee after: Haining Green Shield Textile Technology Co.,Ltd. Address before: 310018 Room 303, building 18, Key Laboratory of the Ministry of education, Xiasha campus, Zhejiang University of technology, No. 928, No. 2 street, Xiasha Higher Education Park, Hangzhou, Zhejiang Province Patentee before: ZHEJIANG SCI-TECH University |
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Effective date of registration: 20220610 Address after: 312000 Room 202, building 1, east of Dong'Er Road, Ma'an street, Keqiao District, Shaoxing City, Zhejiang Province Patentee after: Zhejiang zhongdiefang New Material Technology Co.,Ltd. Address before: 310013 room 304, unit 1, building 31, zone 4, Cuiyuan new village, Xihu District, Hangzhou City, Zhejiang Province Patentee before: Shao Jianzhong |