CN103785434B - A kind of g-C 3n 4nanometer sheet/CdS composite visible light catalyst - Google Patents
A kind of g-C 3n 4nanometer sheet/CdS composite visible light catalyst Download PDFInfo
- Publication number
- CN103785434B CN103785434B CN201410082715.6A CN201410082715A CN103785434B CN 103785434 B CN103785434 B CN 103785434B CN 201410082715 A CN201410082715 A CN 201410082715A CN 103785434 B CN103785434 B CN 103785434B
- Authority
- CN
- China
- Prior art keywords
- nanometer sheet
- catalyst
- cds
- visible light
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Catalysts (AREA)
Abstract
The invention discloses a kind of graphite phase carbon nitride (g-C
3n
4) nanometer sheet/cadmium sulfide (CdS) composite visible light catalyst and its preparation method and application, belong to material preparation and light-catalysed technical field.This catalyst is with two-dimensional ultrathin g-C
3n
4nanometer sheet is matrix, with two acetate hydrate cadmiums and thioacetamide for raw material, is directly obtained by the solvent thermal process of ethanol as solvent.The two-dimensional ultrathin g-C that the present invention prepares
3n
4nanometer sheet/CdS and general block g-C
3n
4/ CdS compares, two-dimensional ultrathin g-C
3n
4have between nanometer sheet/CdS composite photo-catalyst two material and contact more closely, and specific area is larger, thus photo-generate electron-hole can be separated better, photocatalysis efficiency is higher.This composite photo-catalyst, under sunlight, has good catalytic degradation effect to this kind of organic pollutants of methyl orange.Preparation method of the present invention is simple to operate, and raw material are easy to get, and visible light catalytic efficiency is high, has broad application prospects in photocatalysis field.
Description
Technical field
The invention belongs to the technical field belonging to material preparation and visible light photocatalysis, be specifically related to a kind of two-dimensional ultrathin g-C
3n
4the application of the preparation of nanometer sheet/CdS composite visible light catalyst and under visible light catalytic degradation organic pollutants.
Background technology
Current energy and environment problem is day by day serious, causes the extensive attention in global range.Photocatalysis technology is then the potential desirable route of one solving this two problems of energy and environment.And mainly low, the photochemical catalyst stability of solar energy utilization ratio is not thus cannot recycle to restrict reason that photochemical catalyst applies in actual production at present.Therefore, in order to can better solar energy be utilized, prepare efficient, stable visible light catalyst, to the current energy of solution and environmental problem, there is far reaching significance.
After having found Graphene, two-dimensional material has had the advantages such as unique electricity and optical property and has caused great concern because of it.G-C
3n
4be band gap be 2.7eV visible light catalyst, being the most stable a kind of carboritride, is also a kind of material with stratiform two-dimensional structure, g-C
3n
4and semiconductor compound photocatalyst also there is potential application foreground water-splitting and depollution of environment aspect under visible light.The g-C of block
3n
4there is the defect that photo-generated carrier is easy to compound, the separative efficiency of photo-generate electron-hole is low, and quantum efficiency is low, well can not utilize sunshine.And pass through the g-C of block
3n
4peel off into two-dimensional ultrathin g-C
3n
4after nanometer sheet, not only increase its specific area, more avtive spot is provided, and improve the separative efficiency of photo-generated carrier.The semiconductor of CdS to be energy gap be 2.4eV, has good visible absorption performance.But CdS is easily oxidized by photohole under light illumination and photoetch phenomenon occurs.Photoetch phenomenon makes the bad stability of CdS catalyst, and photocatalytic activity reduces.In order to improve photostability and the photocatalytic activity of CdS, preparing its composite photo-catalyst becomes research emphasis.Due to g-C
3n
4the band structure of mating is had very much between the two, g-C with CdS
3n
4effectively can lead away photohole thus suppression photoetch effect that CdS produces.Based on above analysis, in conjunction with two-dimensional ultrathin g-C
3n
4with CdS advantage separately, prepare two-dimensional ultrathin g-C
3n
4/ CdS compound, can be conducive to the separative efficiency of photo-generated carrier, effectively improves stability and the photocatalytic activity of catalyst simultaneously.
CN10319766A discloses a kind of CdS/g-C
3n
4composite visible light catalyst, preparation method and application.This catalyst is prepared by chemical precipitation method, is applied to the degraded of methylene blue and crystal violet solution under visible ray, has good degradation effect.But that this patent system is standby is block g-C
3n
4, do not possess two-dimensional ultrathin g-C
3n
4the special nature had, is also difficult to realize two-dimensional ultrathin g-C
3n
4the close contact such with CdS, therefore photocatalysis efficiency is low.And we utilize ultrasonic stripping method by block g-C
3n
4peel off into two-dimensional ultrathin g-C
3n
4, and obtained the two-dimensional ultrathin g-C of both close contacts at its surface in situ growth CdS nano particle by solvent-thermal method
3n
4/ CdS visible light catalyst, photo-generated carrier transfer impedance is little between the two, and separative efficiency is high.Experiment proves, two-dimensional ultrathin g-C
3n
4/ CdS composite photo-catalyst is obviously better than block g-C at this pollutant of degraded methyl orange
3n
4the photocatalysis effect of/CdS composite photo-catalyst.
Summary of the invention
One is the object of the present invention is to provide to overcome block g-C
3n
4the deficiency that photo-generated carrier separative efficiency is low, the two-dimensional ultrathin g-C suppressing CdS photoetch, there is efficient visible light activity
3n
4the preparation method of nanometer sheet/CdS composite photo-catalyst, and the application of catalytic degradation organic pollutants under visible light.The two-dimensional ultrathin g-C that the present invention prepares
3n
4nanometer sheet/CdS and general block g-C
3n
4/ CdS compares, two-dimensional ultrathin g-C
3n
4have between nanometer sheet/CdS composite photo-catalyst two material and contact more closely, and specific area is larger, thus photo-generate electron-hole can be separated better, photocatalysis efficiency is higher.
For achieving the above object, the present invention adopts following technical scheme:
Two-dimensional ultrathin g-C of the present invention
3n
4nanometer sheet/CdS composite visible light catalyst is by by block g-C
3n
4peel off into two-dimensional ultrathin g-C
3n
4nanometer sheet, and obtained at its surface in situ growth CdS nano particle by solvent-thermal method.G-C in catalyst
3n
4the mass ratio of nanometer sheet and CdS is 1:100-90:100.
Preparation method comprises the following steps:
(1) melamine or urea are obtained block g-C through calcining, cooling, grinding
3n
4;
(2) by block g-C
3n
4join in isopropyl alcohol, ultrasonic 5-20 hour, form the suspension of dispersion; Low-speed centrifugal removes thicker block g-C
3n
4, then the suspension remained by high speed centrifugation, the dry ultra-thin g-C obtaining two dimension
3n
4nanometer sheet;
(3) by the ultra-thin g-C of two dimension
3n
4nanometer sheet joins in the ethanolic solution of two acetate hydrate cadmiums, and ultrasonic, stirring, forms homodisperse suspension;
(4) in the suspension of step (3), add thioacetamide, stir after making it to dissolve completely, carry out solvent thermal reaction;
(5) by the ultra-thin g-C of step (4) products therefrom through centrifugal, washing, dry obtained two dimension
3n
4nanometer sheet/CdS composite visible light catalyst.
In step (1), calcining heat is 400-600 DEG C.
Described catalyst is used for the visible light photocatalytic degradation of target contaminant in water.
Described target contaminant is methyl orange.
Remarkable advantage of the present invention is: two-dimensional ultrathin g-C of the present invention
3n
4nanometer sheet/CdS catalyst is at preparation method, structure composition and catalytic performance and existing CdS/g-C
3n
4catalyst is different.Because the present invention is by the g-C of stripping method by block
3n
4peel off into two-dimensional ultrathin g-C
3n
4nanometer sheet, with block g-C
3n
4compare, two-dimensional ultrathin g-C of the present invention
3n
4nanometer sheet not only increases its specific area, provides more avtive spot, and improves separative efficiency and the photocatalysis efficiency of photo-generated carrier.This composite photo-catalyst, under sunlight, has good catalytic degradation effect to this kind of organic pollutants of methyl orange.Preparation method of the present invention is simple to operate, and raw material are easy to get, and visible light catalytic efficiency is high, has broad application prospects in photocatalysis field.
Accompanying drawing explanation
Fig. 1 is the pure ultra-thin g-C of the present invention
3n
4nanometer sheet, pure CdS, two-dimensional ultrathin g-C
3n
4the XRD figure of nanometer sheet/CdS compound.
Fig. 2 is block g-C of the present invention
3n
4field emission scanning electron microscope figure.
Fig. 3 is two-dimensional ultrathin g-C of the present invention
3n
4the field emission scanning electron microscope figure of nanometer sheet/CdS composite photo-catalyst.
Fig. 4 is the pure ultra-thin g-C of the present invention
3n
4nanometer sheet, pure CdS, two-dimensional ultrathin g-C
3n
4nanometer sheet/CdS compound is to the visible light catalytic design sketch of methyl orange.
Fig. 5 is the two-dimensional ultrathin g-C of homogenous quantities of the present invention ratio
3n
4nanometer sheet/CdS and block g-C
3n
4/ CdS composite photo-catalyst is to the visible light catalytic design sketch of methyl orange.
Detailed description of the invention
Enumerate embodiment below and further illustrate the present invention.
embodiment 1 block g-C
3
n
4
the preparation of catalyst
Take 10 grams of melamines to put in corundum Noah's ark, be placed in the middle part of tube furnace, be heated to 550 DEG C with the heating rate of 2 DEG C/min, and 550 DEG C of insulations 4 hours, whole process is carried out in a nitrogen atmosphere, by its taking-up mortar grinder after naturally cooling, obtains yellow powder sample.
embodiment 2 two-dimensional ultrathin g-C
3
n
4
the preparation of nanometer sheet
Take 0.4 gram, sample in embodiment 1 and put into wide-mouth bottle, add 80 milliliters of isopropyl alcohols, tighten bottle cap.The wide-mouth bottle that sample is housed is placed in and within inside ultrasonic machine ultrasonic 10 hours, makes it to form suspension, afterwards by suspension 3000 revs/min of centrifugal 10 minutes removing sediments, then upper suspension 12000 revs/min of high speed centrifugations are got off to obtain faint yellow solid sample.
embodiment 3
By the catalyst that the method for embodiment 1 and 2 is synthesized, after X-ray diffractometer scanning, seeing Fig. 1, is g-C
3n
4.
embodiment 4
By the catalyst of embodiment 1 method synthesis, through field emission microscopy observation, see Fig. 2, synthesized catalyst is the g-C of block
3n
4.
embodiment 5 block g-C
3
n
4
the preparation of/CdS composite catalyst
Take 0.072 gram, gained sample in embodiment 1 join dissolved 1.333 grams (5 mMs) two acetate hydrate cadmium 50 milliliters of absolute ethyl alcohols in, stirring makes it fully mix in 5 hours, add 0.376 gram of (5 mMs) thioacetamide again and stir dissolving mixing in 1 hour, wherein two-dimensional ultrathin g-C
3n
4be 1:10 with the mass ratio of CdS.Afterwards, put it in reactor, be incubated 12 hours at being placed in 180 DEG C, baking oven, Temperature fall is to room temperature subsequently, and gained precipitate with deionized water washs 3 times, and after absolute ethyl alcohol washes 2 times, gained is deposited in 100 DEG C of vacuum drying ovens and dries 12 hours.
embodiment 6 two-dimensional ultrathin g-C
3
n
4
the preparation of nanometer sheet/CdS composite catalyst
Take 0.072 gram, gained sample in embodiment 2 join dissolved 1.333 grams (5 mMs) two acetate hydrate cadmium 50 milliliters of absolute ethyl alcohols in, after ultrasonic 30 minutes, stirring makes it fully mix in 5 hours, add 0.376 gram of (5 mMs) thioacetamide again and stir dissolving mixing in 1 hour, wherein two-dimensional ultrathin g-C
3n
4be 1:10 with the mass ratio of CdS.Afterwards, put it in reactor, be incubated 12 hours at being placed in 180 DEG C, baking oven, Temperature fall is to room temperature subsequently, and gained precipitate with deionized water washs 3 times, and after absolute ethyl alcohol washes 2 times, gained is deposited in 100 DEG C of vacuum drying ovens and dries 12 hours.
the preparation of embodiment 7 CdS catalyst
Take 1.333 grams of (5 mMs) Cadmium diacetate dihydrates and add 50 milliliters of absolute ethyl alcohol and stirring, until its dissolve after, stirs 5 hours, then add 0.376 gram of (5 mMs) thioacetamide stir 1 hour dissolve mix.Afterwards, put it in reactor, be incubated 12 hours at being placed in 180 DEG C, baking oven, Temperature fall is to room temperature subsequently, and gained precipitate with deionized water washs 3 times, and after absolute ethyl alcohol washes 2 times, gained is deposited in 100 DEG C of vacuum drying ovens and dries 12 hours.
embodiment 8
By the catalyst that embodiment 6 and 7 method is synthesized respectively, after X-ray diffractometer scanning, see Fig. 1, synthesized catalyst is two-dimensional ultrathin g-C
3n
4nanometer sheet/CdS composite photo-catalyst and pure CdS.
embodiment 9
By the catalyst of embodiment 6 method synthesis, through field emission microscopy observation, see Fig. 3, synthesized catalyst has thickness to be the g-C of several nanometer
3n
4nanometer sheet and CdS nano particle composition.
embodiment 10 two-dimensional ultrathin g-C
3
n
4
the application of nanometer sheet/CdS composite catalyst degradable organic pollutant
Catalyst 30 milligrams obtained in Example 6, join in the methyl orange solution of 80 milliliter of 10 mg/litre, through the dark adsorption reaction of half an hour, under 800 turns of magnetic agitation, adopt xenon lamp simulated solar light source, carry out irradiation after 50 minutes, centrifugal, filter, get supernatant, detected by Carry50 ultraviolet-uisible spectrophotometer, degradation efficiency is 97.4%.
The foregoing is only preferred embodiment of the present invention, all equalizations done according to the present patent application the scope of the claims change and modify, and all should belong to covering scope of the present invention.
Claims (4)
1. a g-C
3n
4nanometer sheet/CdS composite visible light catalyst, is characterized in that: in catalyst, carbonitride is graphite phase carbon nitride nanometer sheet, and g-C
3n
4the mass ratio of nanometer sheet and CdS is 1:100-90:100;
Preparation method comprises the following steps:
(1) melamine or urea are obtained block g-C through calcining, cooling, grinding
3n
4;
(2) by block g-C
3n
4join in isopropyl alcohol, ultrasonic 5-20 hour, form the suspension of dispersion; Low-speed centrifugal removes thicker block g-C
3n
4, then the suspension remained by high speed centrifugation, dry acquisition g-C
3n
4nanometer sheet;
(3) by g-C
3n
4nanometer sheet joins in the ethanolic solution of two acetate hydrate cadmiums, and ultrasonic, stirring, forms homodisperse suspension;
(4) in the suspension of step (3), add thioacetamide, stir after making it to dissolve completely, carry out solvent thermal reaction;
(5) step (4) products therefrom is obtained g-C through centrifugal, washing, drying
3n
4nanometer sheet/CdS composite visible light catalyst.
2. g-C according to claim 1
3n
4nanometer sheet/CdS composite visible light catalyst, is characterized in that: in step (1), calcining heat is 400-600 DEG C.
3. a g-C as claimed in claim 1
3n
4the application of nanometer sheet/CdS composite visible light catalyst, is characterized in that: described catalyst is used for the visible light photocatalytic degradation of target contaminant in water.
4. application according to claim 3, is characterized in that: described target contaminant is methyl orange.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410082715.6A CN103785434B (en) | 2014-03-10 | 2014-03-10 | A kind of g-C 3n 4nanometer sheet/CdS composite visible light catalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410082715.6A CN103785434B (en) | 2014-03-10 | 2014-03-10 | A kind of g-C 3n 4nanometer sheet/CdS composite visible light catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103785434A CN103785434A (en) | 2014-05-14 |
| CN103785434B true CN103785434B (en) | 2015-08-12 |
Family
ID=50661740
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410082715.6A Expired - Fee Related CN103785434B (en) | 2014-03-10 | 2014-03-10 | A kind of g-C 3n 4nanometer sheet/CdS composite visible light catalyst |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103785434B (en) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104624219B (en) * | 2015-02-09 | 2016-09-21 | 武汉理工大学 | Efficiently C3n4the situ converting preparation method of-CdS composite photocatalyst material |
| CN104801329A (en) * | 2015-05-08 | 2015-07-29 | 南昌航空大学 | CdS quantum dot/superthin g-C3N4 nanosheet composite photocatalyst and preparation method thereof |
| CN105080572B (en) * | 2015-08-03 | 2017-09-15 | 南京信息工程大学 | A kind of flake cadmium sulfide antimony trisulfide compound and preparation method and application |
| CN105289684A (en) * | 2015-09-29 | 2016-02-03 | 北京化工大学 | Method for preparing porous flake-like graphite phase carbon nitride on large scale, and application thereof |
| CN105271369A (en) * | 2015-10-27 | 2016-01-27 | 南昌航空大学 | Method for preparing g-C3N4/CdS composite by organic molten salt method |
| CN105562055A (en) * | 2016-01-14 | 2016-05-11 | 天津理工大学 | Method for preparing cadmium sulfide graphite-like carbon nitride compound photocatalyst |
| CN105664997A (en) * | 2016-03-18 | 2016-06-15 | 中国海洋大学 | Method for preparing carbon nitride hetero-junction photocatalysts and application thereof |
| CN105688945B (en) * | 2016-03-22 | 2018-06-15 | 福州大学 | MoS2Nanometer sheet/CdS nanowire core shell structure composite photo-catalysts |
| CN105854921B (en) * | 2016-04-19 | 2018-11-27 | 淮北师范大学 | A kind of synthetic method of large-area two-dimensional composite nano materials |
| CN106076381A (en) * | 2016-06-01 | 2016-11-09 | 上海交通大学附属中学嘉定分校 | Super-thin sheet-shaped carbon nitrogen visible light catalyst of waste rubber tire doping and its preparation method and application |
| CN106124585B (en) * | 2016-06-20 | 2018-01-16 | 济南大学 | A kind of preparation method and application based on PPy/CdS/g C3N4 photoelectricity aptamer sensors |
| CN106384675A (en) * | 2016-10-17 | 2017-02-08 | 江苏大学 | Carbon nitride/cobalt sulfide super capacitor electrode material, preparation method thereof, and application thereof |
| CN106732719B (en) * | 2016-12-05 | 2019-04-16 | 厦门大学 | A kind of preparation method of carbonitride/stannic disulfide quantum dot composite photo-catalyst |
| CN107376943B (en) * | 2017-07-20 | 2020-02-21 | 江苏大学 | Preparation method and application of potassium calcium niobate/cadmium sulfide composite material |
| CN107570196B (en) * | 2017-09-20 | 2020-04-28 | 广东工业大学 | Modified graphite-phase carbon nitride/CdS composite photocatalyst, preparation method thereof and hydrogen production method |
| CN108144635B (en) * | 2018-01-16 | 2020-06-09 | 开封大学 | Preparation method of graphite phase carbon nitride-cadmium sulfide composite material |
| CN110404569A (en) * | 2018-04-28 | 2019-11-05 | 奥为（天津）环保科技有限公司 | A kind of Metal Supported g-C3N4The preparation method of photochemical catalyst |
| CN108722438A (en) * | 2018-05-23 | 2018-11-02 | 天津科技大学 | A kind of preparation method of visible light catalyst cadmium sulfide |
| CN108906102A (en) * | 2018-06-11 | 2018-11-30 | 中国科学院地质与地球物理研究所兰州油气资源研究中心 | A method of uranium extraction is carried out using photocatalysis technology under visible light |
| CN109126854B (en) * | 2018-09-12 | 2020-09-04 | 华东理工大学 | CdS/g-C3N4Preparation method of double nanosheet composite photocatalyst |
| CN109289925B (en) * | 2018-09-20 | 2021-03-26 | 西北师范大学 | Preparation and application of graphite-like phase carbon nitride/cadmium organic coordination polymer nanocomposite |
| CN109126856B (en) * | 2018-10-18 | 2021-01-08 | 太原理工大学 | Preparation method of visible light photocatalyst with tight connection |
| CN109395758A (en) * | 2018-11-12 | 2019-03-01 | 江苏大学 | A kind of dimensional thinlayer CdS/g-C3N4The Preparation method and use of composite photo-catalyst |
| CN109806900B (en) * | 2019-02-20 | 2021-10-12 | 江苏大学 | Molecular imprinting type Ag/Ag3VO4Preparation method and application of/CN nanosheet composite photocatalyst |
| CN110745792B (en) * | 2019-04-24 | 2022-04-08 | 河海大学 | g-C stacked alternately in single layer3N4Method for preparing two-dimensional superlattice |
| CN110064426A (en) * | 2019-05-06 | 2019-07-30 | 东南大学 | A kind of LixMoS2/CdS/g-C3N4The preparation and its decomposition aquatic products hydrogen application of composite photo-catalyst |
| KR20200139509A (en) * | 2019-06-04 | 2020-12-14 | 울산과학기술원 | Ultraviolet absorber, method for producing the same, and ultraviolet screening article containing the same |
| CN110292940A (en) * | 2019-07-11 | 2019-10-01 | 福州大学 | CdS/ZnO composite piezoelectric photochemical catalyst and its preparation method and application |
| CN110368979B (en) * | 2019-08-08 | 2022-04-22 | 南京邮电大学 | Tubular g-C3N4/CuS/Cu2S nano composite material and preparation method and application thereof |
| CN110801851B (en) * | 2019-09-09 | 2022-09-09 | 杭州电子科技大学 | Preparation method and application of black phosphorus nanosheet/cadmium sulfide photocatalytic nitrogen fixation catalyst |
| CN110787821B (en) * | 2019-09-10 | 2022-06-03 | 温州大学 | Graphite-phase nitrogen carbide/cadmium sulfide photocatalytic nano composite material with burred spherical structure and preparation method and application thereof |
| CN110586041B (en) * | 2019-09-19 | 2020-05-12 | 山东省分析测试中心 | Perfluoroalkyl compound extraction and analysis method based on MOFs stripping graphite phase nitrogen carbide adsorbent |
| CN111036262A (en) * | 2019-12-04 | 2020-04-21 | 北京氦舶科技有限责任公司 | Supported monatomic rhodium-based catalyst and preparation method and application thereof |
| CN111036274B (en) * | 2019-12-31 | 2021-07-09 | 浙江大学 | Modified BiVO4Preparation method of nanosheet |
| CN111359631B (en) * | 2020-03-07 | 2022-07-15 | 青岛科技大学 | Preparation method and application of ultrahigh-activity modified CdS material piezoelectric catalytic material |
| CN111974432A (en) * | 2020-07-06 | 2020-11-24 | 东南大学 | Preparation method of oxygen-doped graphite-phase carbon nitride-cadmium sulfide composite material |
| CN111957335A (en) * | 2020-07-30 | 2020-11-20 | 太原理工大学 | Graphite phase carbon nitride composite material and preparation method and application thereof |
| CN112158878B (en) * | 2020-09-29 | 2022-08-30 | 陕西科技大学 | Preparation method of hexagonal pyramid-like CdS and application of hexagonal pyramid-like CdS in field of photocatalytic hydrogen production |
| CN112717973A (en) * | 2020-11-16 | 2021-04-30 | 中北大学 | Preparation of rod-like g-C by microwave hydrothermal method3N4Method and application of nanosheet |
| CN112642483A (en) * | 2020-12-27 | 2021-04-13 | 上海应用技术大学 | N-GQDs-PS @ CdS core-shell nano-catalyst as well as preparation method and application thereof |
| CN112742437B (en) * | 2021-01-22 | 2022-03-01 | 西华师范大学 | Composite visible light catalyst and preparation method thereof |
| CN113117718B (en) * | 2021-03-29 | 2023-03-14 | 安徽建筑大学 | NiCoP-g-C 3 N 4 CdS composite photocatalyst, preparation method and application thereof |
| CN113134382A (en) * | 2021-04-28 | 2021-07-20 | 广西科技师范学院 | Preparation method of graphite-phase carbon nitride-cadmium sulfide composite photocatalyst |
| CN114405520B (en) * | 2022-01-26 | 2023-01-24 | 中国矿业大学 | Ternary composite photocatalyst containing heteropoly acid and preparation method and application thereof |
| CN114602507A (en) * | 2022-03-25 | 2022-06-10 | 青海民族大学 | Cadmium sulfide @ graphite phase carbon nitride composite photocatalyst and preparation method and application thereof |
| WO2023242864A1 (en) * | 2022-06-14 | 2023-12-21 | Council Of Scientific And Industrial Research An Indian Registered Body Incorporated Under The Regn. Of Soc. Act (Act Xxi Of 1860) | Process for preparation of 2-d nanostructured sheet based photocatalyst and application thereof |
| CN115634709B (en) * | 2022-11-15 | 2023-12-08 | 常州大学 | Preparation of NMOs/g-C by self-assembly 3 N 4 Method for producing sheets composite material and application thereof |
| CN115739163B (en) * | 2022-12-20 | 2024-05-17 | 西安交通大学 | Sulfide-nitride heterojunction composite photocatalyst and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103191766A (en) * | 2013-04-15 | 2013-07-10 | 南京理工大学 | CdS/g-C3N4 composite visible light catalyst, preparation method and application |
-
2014
- 2014-03-10 CN CN201410082715.6A patent/CN103785434B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103191766A (en) * | 2013-04-15 | 2013-07-10 | 南京理工大学 | CdS/g-C3N4 composite visible light catalyst, preparation method and application |
Non-Patent Citations (3)
| Title |
|---|
| Enhanced Photoresponsive Ultrathin Graphitic-Phase C3N4 Nanosheets for Bioimaging;Xiaodong Zhang et al.;《J. Am. Chem. Soc.》;20121217;第135卷;第18-21页，第S1-S14页 * |
| In-situ growth of CdS quantum dots on g-C3N4 nanosheets for highly efficient photocatalytic hydrogen generationun der visible light irradiation;Shao-Wen Cao et al.;《International journal of hydrogen energy》;20121202;第38卷;第1258-1266页 * |
| Novel C3N4–CdS composite photocatalysts with organic–inorganic heterojunctions: in situ synthesis, exceptional activity, high stability and photocatalytic mechanism;Jie Fu et al.;《Journal of Materials Chemistry A》;20131231;第1卷;第3083-3090页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103785434A (en) | 2014-05-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103785434B (en) | A kind of g-C 3n 4nanometer sheet/CdS composite visible light catalyst | |
| Yuan et al. | In-situ synthesis of 3D microsphere-like In2S3/InVO4 heterojunction with efficient photocatalytic activity for tetracycline degradation under visible light irradiation | |
| Jiao et al. | A visible light-response flower-like La-doped BiOBr nanosheets with enhanced performance for photoreducing CO2 to CH3OH | |
| Chen et al. | Two-dimensional heterojunction photocatalysts constructed by graphite-like C3N4 and Bi2WO6 nanosheets: enhanced photocatalytic activities for water purification | |
| Zhong et al. | Utilizing photocorrosion-recrystallization to prepare a highly stable and efficient CdS/WS2 nanocomposite photocatalyst for hydrogen evolution | |
| CN102974373B (en) | Preparation method of visible-light photocatalytic material | |
| CN103934012B (en) | SnS 2/ g-C 3n 4composite nano plate photochemical catalyst and preparation method | |
| Zhao et al. | Unique bar-like sulfur-doped C3N4/TiO2 nanocomposite: excellent visible light driven photocatalytic activity and mechanism study | |
| CN105032468A (en) | Cu2O-TiO2/g-C3N4 ternary complex and preparation and application method thereof | |
| CN103191766A (en) | CdS/g-C3N4 composite visible light catalyst, preparation method and application | |
| CN107537501B (en) | ZnO/CuO composite material with hierarchical structure and preparation method thereof | |
| CN106944074B (en) | A kind of visible-light response type composite photo-catalyst and its preparation method and application | |
| CN103861618A (en) | Preparation method for SnO2-based composite visible light photocatalyst | |
| CN110152711A (en) | A kind of CeO2@MoS2/g-C3N4Three-element composite photocatalyst and preparation method thereof | |
| Wang et al. | Construction of tubular g-C3N4/TiO2 S-scheme photocatalyst for high-efficiency degradation of organic pollutants under visible light | |
| CN106693996B (en) | Preparation method and application of bismuth sulfide-bismuth ferrite composite visible-light-driven photocatalyst | |
| CN105964277A (en) | CdS/BiVO4 composite photocatalyst and preparation method thereof | |
| CN107098429B (en) | BiVO4/BiPO4Composite material and preparation method and application thereof | |
| CN113967481B (en) | Spherical MoP-HCCN-like composite photocatalyst and preparation method and application thereof | |
| CN104646003A (en) | Preparation and application of Nd<3-x>CoxNbO7-zincosilicate molecular sieve composite porous nanometer catalytic material | |
| CN105214710A (en) | A kind of nonmetal composite visible light catalyst g-C of new green environment protection 3n 4the preparation of/SiC and application thereof | |
| CN108502922A (en) | A kind of anatase titania microballoon and preparation method thereof | |
| Yu et al. | Construction of CoS/CeO2 heterostructure nanocages with enhanced photocatalytic performance under visible light | |
| Liu et al. | S-scheme heterojunction ZnO/g-C3N4 shielding polyester fiber composites for the degradation of MB | |
| CN104801308A (en) | NiFe2O4/TiO2/sepiolite composite photocatalyst and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150812 Termination date: 20180310 |