CN103785302A - Method for controlling thickness customization aperture porous membrane - Google Patents

Method for controlling thickness customization aperture porous membrane Download PDF

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Publication number
CN103785302A
CN103785302A CN201210417429.1A CN201210417429A CN103785302A CN 103785302 A CN103785302 A CN 103785302A CN 201210417429 A CN201210417429 A CN 201210417429A CN 103785302 A CN103785302 A CN 103785302A
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CN
China
Prior art keywords
aperture
extruder
polyethylene
extruded
molecular weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201210417429.1A
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Chinese (zh)
Inventor
洪力东
陈博裕
沈丹
郭政肇
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ATOP NEW MATERIALS Co Ltd
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ATOP NEW MATERIALS Co Ltd
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Publication date
Application filed by ATOP NEW MATERIALS Co Ltd filed Critical ATOP NEW MATERIALS Co Ltd
Priority to CN201210417429.1A priority Critical patent/CN103785302A/en
Publication of CN103785302A publication Critical patent/CN103785302A/en
Pending legal-status Critical Current

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  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The invention discloses a method for controlling a thickness customization aperture porous membrane, which comprises the following steps: polyethylene with millions of molecular weight and an organic liquid containing a plasticizer and organic alcohol are mixed, and then a mixer is extruded by a first extruder; polyethylene with more than 100 thousands of molecular weight and organic liquid containing the plasticizer are mixed, and the mixer is extruded by a second extruder; and polyethylene with more than 4-50 thousands of molecular weight and mineral oil with 10% of organic alcohol are mixed, and the mixer is extruded by a third extruder. According to the control method, the porous base materials with required aperture uniformity and aperture distribution are produced, the multilayer film is prepared by a film blowing head with multiple layers, each layer of the film is an aperture structure produced by the individual extruder according to an unique formula, the aperture structure has a defined porosity and aperture size, the production cost is reduced, and the work efficiency is increased.

Description

The control method of a kind of thickness customization aperture perforated membrane
Technical field
The invention belongs to perforated membrane and manufacture field, relate in particular to the control method of a kind of thickness customization aperture perforated membrane.
Background technology
Thermally induced phase separation is more than the fusing point of polymer, and polymer is dissolved in to higher boiling, in the solvent of low volatility, forms homogeneous phase solution, then cooling down, and in cooling procedure, system can be separated.Application thermic phase detachment technique is prepared the method for porous substrate, and an aspect is the pore structure of control surface and the pore structure in cross section, on the other hand by what control pore size and porosity.In cooling procedure, greatly affected the thickness of whole base material and the uniformity in aperture, and this kind of cooling effect is difficult to control the Changeization of the base material thickness that whole base material thickness and aperture inhomogeneities cause more.
Summary of the invention
The object of the invention is to utilize the control method of a kind of thickness customization aperture perforated membrane, be intended to solve existing preparation in porous substrate cooling procedure, greatly affected the thickness of whole base material and the uniformity in aperture, this cooling effect is difficult to control the problem of the increase of the base material thickness that whole base material thickness and aperture inhomogeneities cause more.
The control method that the object of the present invention is to provide a kind of thickness customization aperture perforated membrane, described control method comprises: the polyethylene of Number 1,000,000 molecular weight and the organic liquid that contains plasticizer and Organic Alcohol mix, and are extruded by first extruder; The polyethylene of more than 100 ten thousand molecular weight mixes with the organic liquid that comprises plasticizer, is extruded by second extruder; The polyethylene of many hundred million molecular weight of 4-50 and the mineral oil of 10% Organic Alcohol, extruded by the 3rd extruder.
Further described perforated membrane is one and has 3 kinds of different discrete porositys and the film in aperture in whole base material thickness direction (Z direction).
The control method of thickness customization of the present invention aperture perforated membrane, the method technical matters is simple, easy to operate, produces the porous substrate of the required aperture uniformity and pore-size distribution, has improved operating efficiency, has reduced production cost, has good using value.
Accompanying drawing explanation
Fig. 1 is the flow chart of the control method of thickness customization provided by the invention aperture perforated membrane.
The specific embodiment
In order to make object of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The embodiment of the present invention provides the control method of a kind of thickness customization aperture perforated membrane, and this control method comprises: the polyethylene of Number ten thousand molecular weight and the organic liquid that contains plasticizer and Organic Alcohol mix, and are extruded by first extruder; The polyethylene of more than 100 ten thousand molecular weight mixes with the organic liquid that comprises plasticizer, is extruded by second extruder; The polyethylene of many hundred million molecular weight of 4-50 and the mineral oil of 10% Organic Alcohol, extruded by the 3rd extruder.
As a prioritization scheme of the embodiment of the present invention, perforated membrane is one and has 3 kinds of different discrete porositys and the film in aperture in whole base material thickness direction (Z direction).
Referring to accompanying drawing 1, the control method of being prepared by the present invention to thickness customization aperture perforated membrane is described in further detail.
As shown in Figure 1, the perforated membrane control method in a kind of thickness customization aperture of this programme invention, first the polyethylene of Number ten thousand molecular weight and the organic liquid that contains plasticizer and Organic Alcohol are mixed, by extruding as the double screw extruder of ground floor blown-film die, then, the polyethylene of more than 100 ten thousand molecular weight mixes with the organic liquid that comprises plasticizer, is extruded by second double screw extruder as second layer blown-film die; The polyethylene of many hundred million molecular weight of 4-50 and the mineral oil of 10% Organic Alcohol, extruded by the 3rd double screw extruder as the 3rd layer of blown-film die, finally, when film from blown-film die out, it has 3 layer scattering layers, is one and has 3 kinds of different discrete porositys and the film in aperture in whole base material thickness direction (Z direction).
The control method of thickness customization of the present invention aperture perforated membrane, this control method comprises: the Number very much polyethylene of strength mixes with the organic liquid that contains plasticizer and Organic Alcohol, is extruded by first extruder; The polyethylene of more than 100 ten thousand molecular weight mixes with the organic liquid that comprises plasticizer, is extruded by second extruder; The polyethylene of many hundred million molecular weight of 4-50 and the mineral oil of 10% Organic Alcohol, extruded by the 3rd extruder.The control method of thickness customization of the present invention aperture perforated membrane, the method technical matters is simple, easy to operate, produces the porous substrate of the required aperture uniformity and pore-size distribution, has improved operating efficiency, has reduced production cost, has good using value.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.

Claims (2)

1. a control method for thickness customization aperture perforated membrane, is characterized in that described control method comprises:
The polyethylene of Number 1,000,000 molecular weight and the organic liquid that contains plasticizer and Organic Alcohol mix, and are extruded by first extruder; The polyethylene of more than 100 ten thousand molecular weight mixes with the organic liquid that comprises plasticizer, is extruded by second extruder; The polyethylene of many hundred million molecular weight of 4-50 and the mineral oil of 10% Organic Alcohol, extruded by the 3rd extruder.
2. a control method for thickness customization aperture perforated membrane, is characterized in that described perforated membrane is to have 3 kinds of different discrete porositys and the film in aperture at whole base material thickness and formula direction.
CN201210417429.1A 2012-10-29 2012-10-29 Method for controlling thickness customization aperture porous membrane Pending CN103785302A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210417429.1A CN103785302A (en) 2012-10-29 2012-10-29 Method for controlling thickness customization aperture porous membrane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210417429.1A CN103785302A (en) 2012-10-29 2012-10-29 Method for controlling thickness customization aperture porous membrane

Publications (1)

Publication Number Publication Date
CN103785302A true CN103785302A (en) 2014-05-14

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Country Status (1)

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CN (1) CN103785302A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09100368A (en) * 1995-10-05 1997-04-15 Mitsubishi Chem Corp Porous polyethylene resin molding
CN1767948A (en) * 2003-04-04 2006-05-03 旭化成化学株式会社 Polyolefin microporous membrane
CN101031421A (en) * 2004-10-01 2007-09-05 旭化成化学株式会社 Polyolefin microporous membrane
CN101384429A (en) * 2006-03-30 2009-03-11 旭化成化学株式会社 Polyolefin microporous film
US20110183203A1 (en) * 2010-01-27 2011-07-28 Molecular Nanosystems, Inc. Polymer supported electrodes
CN102501419A (en) * 2011-11-25 2012-06-20 佛山市金辉高科光电材料有限公司 Polyolefin multilayer micro-porous membrane and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09100368A (en) * 1995-10-05 1997-04-15 Mitsubishi Chem Corp Porous polyethylene resin molding
CN1767948A (en) * 2003-04-04 2006-05-03 旭化成化学株式会社 Polyolefin microporous membrane
CN101031421A (en) * 2004-10-01 2007-09-05 旭化成化学株式会社 Polyolefin microporous membrane
CN101384429A (en) * 2006-03-30 2009-03-11 旭化成化学株式会社 Polyolefin microporous film
US20110183203A1 (en) * 2010-01-27 2011-07-28 Molecular Nanosystems, Inc. Polymer supported electrodes
CN102501419A (en) * 2011-11-25 2012-06-20 佛山市金辉高科光电材料有限公司 Polyolefin multilayer micro-porous membrane and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
徐思亭等: "《塑料材料与助剂》", 31 July 2007, 天津大学出版社 *
石淑先: "《生物材料制备与加工》", 31 August 2009, 化学工业出版社 *

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Application publication date: 20140514