CN103773195A - Waterproof coating material of alkyd resin - Google Patents
Waterproof coating material of alkyd resin Download PDFInfo
- Publication number
- CN103773195A CN103773195A CN201210401786.9A CN201210401786A CN103773195A CN 103773195 A CN103773195 A CN 103773195A CN 201210401786 A CN201210401786 A CN 201210401786A CN 103773195 A CN103773195 A CN 103773195A
- Authority
- CN
- China
- Prior art keywords
- parts
- acid
- synolac
- organic solvent
- alkyd resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention discloses a waterproof coating material of an alkyd resin, wherein the raw materials comprise, by weight, 100 parts of an alkyd resin, 20-22 parts of carboxymethyl cellulose, 3-5 parts of amyl acetate, 8 parts of magnesium silicate, 6 parts of petroleum ether, 1-3 parts of a defoamer, 0.5-1 part of a dispersant, 0.5 part of a mould inhibitor, 0.5 part of an adhesive, and 60-80 parts of water, wherein the alkyd resin components comprise, by weight, 100 parts of fatty acid, 40-50 parts of polyol, 25-28 parts of crude para phthalic acid, 5.5 parts of benzoic acid, 0.2-0.5 part of phthalic anhydride, 0.15 part of hypophosphorous acid, and 60-80 parts of an acetic ester organic solvent, the fatty acid is castor oil fatty acid, caprylic acid, capric acid or dodecanic acid, and the acetic ester organic solvent is a combination comprising one or a plurality of materials selected from ethyl acetate, sec-butyl acetate or butyl acetate. According to the present invention, characteristics of simple preparation process, low cost and wide application range are provided.
Description
Technical field
The present invention relates to a kind of alkyd resin waterproof paint, belong to chemical industry resin field.
Background technology
Synolac is the oily modified polyester resin being formed by polyvalent alcohol, Tetra hydro Phthalic anhydride and lipid acid or oil (fatty acid triglyceride) condensation polymerization.Number and the structure of pressing two keys in lipid acid (or oil) molecule, can be divided into dryness, semi-drying and non-dryness three classes.Dry alkyd resin can be in air set; Non-dry alkyd resin will mix with aminoresin, could solidify through heating.In addition also can be by the content of lipid acid used (or oil) or Tetra hydro Phthalic anhydride, be divided into short, in, the Synolac of long and extremely long four kinds of oil content.After Synolac film-forming, glossy and toughness, strong adhesion, and there are good wear resistance, weathering resistance and insulativity etc.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the object of the present invention is to provide a kind of preparation technology simple, the waterproof paint of the Synolac of the low and applied range of cost.
Technical scheme: in order to solve above-mentioned purpose, the technical solution adopted in the present invention is: a kind of waterproof paint of Synolac, the component that its raw material contains following parts by weight:
Synolac: 100 parts;
Carboxymethyl cellulose: 20-22 part;
Pentyl acetate: 3-5 part;
Magnesium Silicate q-agent: 8 parts;
Sherwood oil: 6 parts;
Defoamer: 1-3 part;
Dispersion agent: 0.5-1 part;
Mould inhibitor: 0.5 part;
Binding agent: 0.5 part;
Water: 60-80 part;
Wherein, the parts by weight of described alkyd resin component are: lipid acid: 100 parts; Polyvalent alcohol: 40-50 part; Crude terephthalic acid: 25-28 part; Phenylformic acid: 5.5 parts; Phthalic anhydride: 0.2-0.5 part; Hypophosporous Acid, 50: 0.15 part; Acetic ester organic solvent: 60-80 part; Described lipid acid is Castor Oil Fatty Acid, n-caprylic acid, certain herbaceous plants with big flowers acid or laurostearic acid; Described acetic ester organic solvent is one or more combination in vinyl acetic monomer, 2-butyl acetate or N-BUTYL ACETATE.
Being further defined to of technical solution of the present invention, described dispersion agent is ammonium polyacrylate dipersant.
Further, described defoamer is higher alcohols.
Further, described binding agent is cyanoacrylate binding agent or a-cyanoacrylate binding agent.
Beneficial effect: compared with prior art, advantage of the present invention is: the waterproof paint of Synolac of the present invention is glossy and toughness, strong adhesion, and have good wear resistance, weathering resistance and insulativity, and preparation technology is simple, cost is low, applied range.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also make some improvement, these improve and also should be considered as protection scope of the present invention.
embodiment 1: a kind of waterproof paint of Synolac, the component that its raw material contains following parts by weight: Synolac: 100 parts; Carboxymethyl cellulose: 20 parts; Pentyl acetate: 3 parts; Magnesium Silicate q-agent: 8 parts; Sherwood oil: 6 parts; Higher alcohols: 1-3 part; Ammonium polyacrylate dipersant: 0.5-1 part; Mould inhibitor: 0.5 part; Cyanoacrylate binding agent: 0.5 part; Water: 60 parts;
Wherein, the parts by weight of described alkyd resin component are: lipid acid: 100 parts; Polyvalent alcohol: 40-50 part; Crude terephthalic acid: 25-28 part; Phenylformic acid: 5.5 parts; Phthalic anhydride: 0.2-0.5 part; Hypophosporous Acid, 50: 0.15 part; Acetic ester organic solvent: 60-80 part; Described lipid acid is Castor Oil Fatty Acid, n-caprylic acid, certain herbaceous plants with big flowers acid or laurostearic acid; Described acetic ester organic solvent is one or more combination in vinyl acetic monomer, 2-butyl acetate or N-BUTYL ACETATE.
The preparation method of the waterproof paint of above-mentioned Synolac, carries out as follows:
(1) prepare Synolac by the parts by weight of following component: lipid acid: 100 parts; Polyvalent alcohol: 40-50 part; Crude terephthalic acid: 25-28 part; Phenylformic acid: 5.5 parts; Phthalic anhydride: 0.2-0.5 part; Hypophosporous Acid, 50: 0.15 part; Acetic ester organic solvent: 60-80 part; Described lipid acid is Castor Oil Fatty Acid, n-caprylic acid, certain herbaceous plants with big flowers acid or laurostearic acid; Described acetic ester organic solvent is one or more combination in vinyl acetic monomer, 2-butyl acetate or N-BUTYL ACETATE;
(2) 100 parts of Synolac getting preparation in step (1) are as base-material, add 20 parts of carboxymethyl celluloses, 3 parts of pentyl acetates, 8 parts of Magnesium Silicate q-agents, 6 parts of sherwood oils, 1-3 part higher alcohols, 0.5-1 part ammonium polyacrylate dipersant, 0.5 part of mould inhibitor, 0.5 part of cyanoacrylate binding agent and 60 parts of water, high-speed stirring is to mixing, be heated to 80-90 ℃, react after 1 hour, regulate pH value to 7.0-9.0, be cooled to room temperature discharging, both obtain the waterproof paint of Synolac.
embodiment 2: a kind of waterproof paint of Synolac, the component that its raw material contains following parts by weight: Synolac: 100 parts; Carboxymethyl cellulose: 20.5 parts; Pentyl acetate: 4 parts; Magnesium Silicate q-agent: 8 parts; Sherwood oil: 6 parts; Higher alcohols: 1-3 part; Ammonium polyacrylate dipersant: 0.5-1 part; Mould inhibitor: 0.5 part; Cyanoacrylate binding agent: 0.5 part; Water: 67 parts;
Wherein, the parts by weight of described alkyd resin component are: lipid acid: 100 parts; Polyvalent alcohol: 40-50 part; Crude terephthalic acid: 25-28 part; Phenylformic acid: 5.5 parts; Phthalic anhydride: 0.2-0.5 part; Hypophosporous Acid, 50: 0.15 part; Acetic ester organic solvent: 60-80 part; Described lipid acid is Castor Oil Fatty Acid, n-caprylic acid, certain herbaceous plants with big flowers acid or laurostearic acid; Described acetic ester organic solvent is one or more combination in vinyl acetic monomer, 2-butyl acetate or N-BUTYL ACETATE.
A preparation method for the waterproof paint of Synolac, carries out as follows:
(1) prepare Synolac by the parts by weight of following component: lipid acid: 100 parts; Polyvalent alcohol: 40-50 part; Crude terephthalic acid: 25-28 part; Phenylformic acid: 5.5 parts; Phthalic anhydride: 0.2-0.5 part; Hypophosporous Acid, 50: 0.15 part; Acetic ester organic solvent: 60-80 part; Described lipid acid is Castor Oil Fatty Acid, n-caprylic acid, certain herbaceous plants with big flowers acid or laurostearic acid; Described acetic ester organic solvent is one or more combination in vinyl acetic monomer, 2-butyl acetate or N-BUTYL ACETATE;
(2) 100 parts of Synolac getting preparation in step (1) are as base-material, add 20.5 parts of carboxymethyl celluloses, 4 parts of pentyl acetates, 8 parts of Magnesium Silicate q-agents, 6 parts of sherwood oils, 1-3 part higher alcohols, 0.5-1 part ammonium polyacrylate dipersant, 0.5 part of mould inhibitor, 0.5 part of cyanoacrylate binding agent and 67 parts of water, high-speed stirring is to mixing, be heated to 80-90 ℃, react after 1 hour, regulate pH value to 7.0-9.0, be cooled to room temperature discharging, both obtain the waterproof paint of Synolac.
embodiment 3: a kind of waterproof paint of Synolac, the component that its raw material contains following parts by weight: Synolac: 100 parts; Carboxymethyl cellulose: 21 parts; Pentyl acetate: 4.5 parts; Magnesium Silicate q-agent: 8 parts; Sherwood oil: 6 parts; Higher alcohols: 1-3 part; Ammonium polyacrylate dipersant: 0.5-1 part; Mould inhibitor: 0.5 part; A-cyanoacrylate binding agent: 0.5 part; Water: 75 parts;
Wherein, the parts by weight of described alkyd resin component are: lipid acid: 100 parts; Polyvalent alcohol: 40-50 part; Crude terephthalic acid: 25-28 part; Phenylformic acid: 5.5 parts; Phthalic anhydride: 0.2-0.5 part; Hypophosporous Acid, 50: 0.15 part; Acetic ester organic solvent: 60-80 part; Described lipid acid is Castor Oil Fatty Acid, n-caprylic acid, certain herbaceous plants with big flowers acid or laurostearic acid; Described acetic ester organic solvent is one or more combination in vinyl acetic monomer, 2-butyl acetate or N-BUTYL ACETATE.
A preparation method for the waterproof paint of Synolac, carries out as follows:
(1) prepare Synolac by the parts by weight of following component: lipid acid: 100 parts; Polyvalent alcohol: 40-50 part; Crude terephthalic acid: 25-28 part; Phenylformic acid: 5.5 parts; Phthalic anhydride: 0.2-0.5 part; Hypophosporous Acid, 50: 0.15 part; Acetic ester organic solvent: 60-80 part; Described lipid acid is Castor Oil Fatty Acid, n-caprylic acid, certain herbaceous plants with big flowers acid or laurostearic acid; Described acetic ester organic solvent is one or more combination in vinyl acetic monomer, 2-butyl acetate or N-BUTYL ACETATE;
(2) 100 parts of Synolac getting preparation in step (1) are as base-material, add 21 parts of carboxymethyl celluloses, 4.5 parts of pentyl acetates, 8 parts of Magnesium Silicate q-agents, 6 parts of sherwood oils, 1-3 part higher alcohols, 0.5-1 part ammonium polyacrylate dipersant, 0.5 part of mould inhibitor, 0.5 part of a-cyanoacrylate binding agent and 75 parts of water, high-speed stirring is to mixing, be heated to 80-90 ℃, react after 1 hour, regulate pH value to 7.0-9.0, be cooled to room temperature discharging, both obtain the waterproof paint of Synolac.
embodiment 4: a kind of waterproof paint of Synolac, the component that its raw material contains following parts by weight: Synolac: 100 parts; Carboxymethyl cellulose: 22 parts; Pentyl acetate: 5 parts; Magnesium Silicate q-agent: 8 parts; Sherwood oil: 6 parts; Higher alcohols: 1-3 part; Ammonium polyacrylate dipersant: 0.5-1 part; Mould inhibitor: 0.5 part; A-cyanoacrylate binding agent: 0.5 part; Water: 80 parts;
Wherein, the parts by weight of described alkyd resin component are: lipid acid: 100 parts; Polyvalent alcohol: 40-50 part; Crude terephthalic acid: 25-28 part; Phenylformic acid: 5.5 parts; Phthalic anhydride: 0.2-0.5 part; Hypophosporous Acid, 50: 0.15 part; Acetic ester organic solvent: 60-80 part; Described lipid acid is Castor Oil Fatty Acid, n-caprylic acid, certain herbaceous plants with big flowers acid or laurostearic acid; Described acetic ester organic solvent is one or more combination in vinyl acetic monomer, 2-butyl acetate or N-BUTYL ACETATE.
A preparation method for the waterproof paint of Synolac, carries out as follows:
(1) prepare Synolac by the parts by weight of following component: lipid acid: 100 parts; Polyvalent alcohol: 40-50 part; Crude terephthalic acid: 25-28 part; Phenylformic acid: 5.5 parts; Phthalic anhydride: 0.2-0.5 part; Hypophosporous Acid, 50: 0.15 part; Acetic ester organic solvent: 60-80 part; Described lipid acid is Castor Oil Fatty Acid, n-caprylic acid, certain herbaceous plants with big flowers acid or laurostearic acid; Described acetic ester organic solvent is one or more combination in vinyl acetic monomer, 2-butyl acetate or N-BUTYL ACETATE;
(2) 100 parts of Synolac getting preparation in step (1) are as base-material, add 22 parts of carboxymethyl celluloses, 5 parts of pentyl acetates, 8 parts of Magnesium Silicate q-agents, 6 parts of sherwood oils, 1-3 part higher alcohols, 0.5-1 part ammonium polyacrylate dipersant, 0.5 part of mould inhibitor, 0.5 part of a-cyanoacrylate binding agent and 80 parts of water, high-speed stirring is to mixing, be heated to 80-90 ℃, react after 1 hour, regulate pH value to 7.0-9.0, be cooled to room temperature discharging, both obtain the waterproof paint of Synolac.
Claims (4)
1. a waterproof paint for Synolac, is characterized in that, the component that its raw material contains following parts by weight:
Synolac: 100 parts;
Carboxymethyl cellulose: 20-22 part;
Pentyl acetate: 3-5 part;
Magnesium Silicate q-agent: 8 parts;
Sherwood oil: 6 parts;
Defoamer: 1-3 part;
Dispersion agent: 0.5-1 part;
Mould inhibitor: 0.5 part;
Binding agent: 0.5 part;
Water: 60-80 part;
Wherein, the parts by weight of described alkyd resin component are: lipid acid: 100 parts; Polyvalent alcohol: 40-50 part; Crude terephthalic acid: 25-28 part; Phenylformic acid: 5.5 parts; Phthalic anhydride: 0.2-0.5 part; Hypophosporous Acid, 50: 0.15 part; Acetic ester organic solvent: 60-80 part; Described lipid acid is Castor Oil Fatty Acid, n-caprylic acid, certain herbaceous plants with big flowers acid or laurostearic acid; Described acetic ester organic solvent is one or more combination in vinyl acetic monomer, 2-butyl acetate or N-BUTYL ACETATE.
2. the waterproof paint of a kind of Synolac according to claim 1, is characterized in that, described dispersion agent is ammonium polyacrylate dipersant.
3. the waterproof paint of a kind of Synolac according to claim 1, is characterized in that, described defoamer is higher alcohols.
4. the waterproof paint of a kind of Synolac according to claim 1, is characterized in that, described binding agent is cyanoacrylate binding agent or a-cyanoacrylate binding agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210401786.9A CN103773195A (en) | 2012-10-22 | 2012-10-22 | Waterproof coating material of alkyd resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210401786.9A CN103773195A (en) | 2012-10-22 | 2012-10-22 | Waterproof coating material of alkyd resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103773195A true CN103773195A (en) | 2014-05-07 |
Family
ID=50565978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210401786.9A Pending CN103773195A (en) | 2012-10-22 | 2012-10-22 | Waterproof coating material of alkyd resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103773195A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449294A (en) * | 2014-12-04 | 2015-03-25 | 江苏科技大学 | Composition with rust paint containing cyano functional molecule compound and preparation method of composition |
| CN107250302A (en) * | 2015-02-18 | 2017-10-13 | 东亚合成株式会社 | 2 cyanoacrylate system adhesive compositions |
-
2012
- 2012-10-22 CN CN201210401786.9A patent/CN103773195A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449294A (en) * | 2014-12-04 | 2015-03-25 | 江苏科技大学 | Composition with rust paint containing cyano functional molecule compound and preparation method of composition |
| CN104449294B (en) * | 2014-12-04 | 2017-04-05 | 江苏科技大学 | A kind of structure contains compositionss of on rust paint of cyano group functional molecular compound and preparation method thereof |
| CN107250302A (en) * | 2015-02-18 | 2017-10-13 | 东亚合成株式会社 | 2 cyanoacrylate system adhesive compositions |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103044667A (en) | Alkyd resin for amino baking paint and preparation method thereof | |
| CN102643416A (en) | Isocyanate modified alkyd resin and preparation method thereof | |
| CN107857873B (en) | A kind of alkyd resin and preparation method thereof of 90% large arch dam | |
| CN103044668B (en) | Matt alkyd resin and preparation method thereof | |
| CN103160099B (en) | Modified alkyd resin and preparation method thereof and two-component primer | |
| CN101445593A (en) | Aquosity short oil alkyd resin and preparation method thereof | |
| CN104987468A (en) | Water-borne acrylic-modified alkyd resin emulsion and preparation method thereof | |
| CN103709254B (en) | Preparation method of medium-viscosity cellulose acetate butyrate | |
| CN104311750A (en) | Styrene modified alkyd resin, preparation method thereof and alkyd resin paint | |
| CN103773195A (en) | Waterproof coating material of alkyd resin | |
| CN103232593A (en) | A fast-drying alkyd resin used for wood lacquers, and a preparation method thereof | |
| CN109776347A (en) | A kind of thermosetting property plant oil base acrylate derivative and its preparation method and application | |
| CN103601877A (en) | High-solid alkyd resin and preparation method thereof | |
| CN105418903B (en) | One kind is without colophony type high solid alkyd resin and preparation method thereof | |
| CN105949439A (en) | Preparation method of waterborne modified epoxy resin | |
| CN107353811A (en) | A kind of net taste furniture lacquer of novel environment friendly and its preparation method and application | |
| CN103772675A (en) | Alkyd resin | |
| CN104448268B (en) | Modified alkyd resin and preparation method thereof, two component light top coat top coats and preparation method thereof | |
| CN107099227B (en) | 100% unsaturated polyester resin of solid content and low VOC ordor removing PE varnish | |
| CN103772676A (en) | Preparation method of alkyd resin | |
| CN104744678A (en) | Alkyd resin and preparation method thereof | |
| CN105254865A (en) | Alkyd resin for high-solid low-viscosity PU (polyurethane) matte topcoat and preparation method of alkyd resin | |
| CN103773194A (en) | Preparation method of waterproof paint containing alkyd resins | |
| CN103509413A (en) | Energy-saving pencil dipping head photocuring nitrolacquer | |
| CN103880611B (en) | A kind of preparation method of bis-hydroxypropyl bisphenol fluorene ether |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140507 |