CN103772888A - ABS (acrylonitrile-butadiene-styrene) flame-retardant plastic - Google Patents
ABS (acrylonitrile-butadiene-styrene) flame-retardant plastic Download PDFInfo
- Publication number
- CN103772888A CN103772888A CN201410029423.6A CN201410029423A CN103772888A CN 103772888 A CN103772888 A CN 103772888A CN 201410029423 A CN201410029423 A CN 201410029423A CN 103772888 A CN103772888 A CN 103772888A
- Authority
- CN
- China
- Prior art keywords
- parts
- mass parts
- abs
- flame
- flame retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an ABS (acrylonitrile-butadiene-styrene) flame-retardant plastic which is prepared from the following raw materials in parts by weight: 70-76 parts of ABS, 9-12 parts of organic silicon resin, 8-10 parts of trimethylsilyl dimethyl methyl phosphonate, 7-9 parts of metastannic acid, 8-10 parts of triphenyl phosphate, 8-10 parts of hollow glass beads, 4-7 parts of triphenyl phosphate, 5-7 parts of resorcinol bis-diphenylphosphate, 5-8 parts of zinc borate and 5-6 parts of montmorillonite. The flame-retardant plastic can not be easily combusted under high-temperature or other hazardous conditions, is safer to use, has uniform and stable elasticity, can not deform after long-term usage, and also has favorable properties in other high polymer materials, such as the advantages of high strength, favorable toughness, favorable freezing resistance and the like.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of ABS flame retardant plastics.
Technical background
At present, plastics are not subject to the performance of humidity effect and are applied to more and more widely in a lot of fields with good resistance electrical property and the high-frequency insulation of its uniqueness.But because plastics itself do not have flame retardant resistance, when for electronic apparatus, building, aviation and automobile industry, because it has inflammableness, thus initiation fire.At present, along with the progress of technology, ubiquitous product innovation, new things have been brought convenient and swift hungry service to people's life, work, and earth-shaking variation has occurred in people's life.In order to ensure national public property and citizen's personnel safety, in order to eliminate disaster hidden-trouble, enjoying the comfort, fast in life, " high quality is lived safely " will become important factor indispensable in life gradually.Under historical background at a tremendous pace like this, fire retardant plastic material has also just become the favorite in market.This material is applicable to the fields such as switch on wall, socket, tubing, breaker of plastic casing, motor component, sheet material because having the superior characteristics such as good flame retardant resistance, low density, low cost, good over-all properties.In recent years, also there are many manufacturing enterprises to begin one's study both at home and abroad and develop flame retardant plastics, but the fire retardant adding is at present more with halogenated flame retardant, in life-time service process, especially in combustion processes, understand the toxic substance that produces hydrogen halide, the health to people and environment all can cause great harm.
Summary of the invention
The present invention seeks to, in order to overcome the deficiencies in the prior art, provides a kind of ABS flame retardant plastics.
The object of the invention is to be achieved through the following technical solutions: a kind of ABS flame retardant plastics, it is made up according to weight proportion of following raw materials according: 70-76 mass parts ABS, 9-12 mass parts silicone resin, 8-10 mass parts trimethylsilyl dimethyl methyl phosphonate, 7-9 quality metastannic acid, 8-10 mass parts triphenylphosphate, 8-10 mass parts hollow glass bead, 4-7 mass parts triphenylphosphate, the two hexichol phosphoric acid ester of 5-7 mass parts Resorcinol, 5-8 mass parts zinc borate, the polynite of 5-6 mass parts.
Described silicone resin is SFR100, for U.S. GE produces.
Described ABS is PA757.
Beneficial effect: flame retardant plastics of the present invention is not easy burning at high temperature or other hazardous conditions, use safer insurance, and elastic force is even, stable, life-time service can not produce distortion, and have the premium properties of other macromolecular materials concurrently, the advantage such as high in intensity, good toughness, winter hardiness are good.
Embodiment
embodiment 1
A kind of ABS flame retardant plastics, it is made up according to weight proportion of following raw materials according: 70-76 mass parts ABS, 9-12 mass parts silicone resin, 8-10 mass parts trimethylsilyl dimethyl methyl phosphonate, 7-9 quality metastannic acid, 8-10 mass parts triphenylphosphate, 8-10 mass parts hollow glass bead, 4-7 mass parts triphenylphosphate, the two hexichol phosphoric acid ester of 5-7 mass parts Resorcinol, 5-8 mass parts zinc borate, the polynite of 5-6 mass parts.Silicone resin is SFR100, for U.S. GE produces.ABS is PA757.
Formula of the present invention can be produced plastics by the making equipment that uses existing routine, its preparation method: 1. according to formula raw materials weighing, raw material is joined in high-speed kneading machine, and in the time that the temperature of mixture is increased to 100 ℃ to 140 ℃, discharging is also cooled to envrionment temperature; 2. mixture is joined to extrusion moulding in screw extrusion press and obtain strip-shaped materials, making drop temperature is 180 ℃ ~ 200 ℃; 3. strip-shaped materials is carried out air-cooledly, then directly strip-shaped materials guided to pelletizing in dicing machine and obtain pellet.
embodiment 2
A kind of ABS flame retardant plastics, it is made up according to weight proportion of following raw materials according: 70 mass parts ABS, 9 mass parts silicone resins, 8 mass parts trimethylsilyl dimethyl methyl phosphonates, 7 quality metastannic acids, 8 mass parts triphenylphosphates, 8 mass parts hollow glass beads, 4 mass parts triphenylphosphates, the two hexichol phosphoric acid ester of 5 mass parts Resorcinols, 5 mass parts zinc borates, 5 mass parts polynites.Silicone resin is SFR100, for U.S. GE produces.ABS is PA757.
Performance test: the plastics in embodiment are made to standard bar and carry out performance test according to the similar plastics all standard of country, the salient features of the material of preparing is as follows: flexural strength (MPa): 60.1, notched Izod impact strength (KJ/m
2): 24.3, vertical combustion rank UL-94 is V0, oxygen index: 32%.
embodiment 3
A kind of ABS flame retardant plastics, it is made up according to weight proportion of following raw materials according: 76 mass parts ABS, 12 mass parts silicone resins, 10 mass parts trimethylsilyl dimethyl methyl phosphonates, 9 quality metastannic acids, 10 mass parts triphenylphosphates, 10 mass parts hollow glass beads, 7 mass parts triphenylphosphates, the two hexichol phosphoric acid ester of 7 mass parts Resorcinols, 8 mass parts zinc borates, 56 mass parts polynites.Silicone resin is SFR100, for U.S. GE produces.ABS is PA757.
Performance test: the plastics in embodiment are made to standard bar and carry out performance test according to the similar plastics all standard of country, the salient features of the material of preparing is as follows: flexural strength (MPa): 60.2, notched Izod impact strength (KJ/m
2): 24.5, vertical combustion rank UL-94 is V0, oxygen index: 33%.
Claims (3)
1. an ABS flame retardant plastics, it is characterized in that it is made up according to weight proportion of following raw materials according: 70-76 mass parts ABS, 9-12 mass parts silicone resin, 8-10 mass parts trimethylsilyl dimethyl methyl phosphonate, 7-9 quality metastannic acid, 8-10 mass parts triphenylphosphate, 8-10 mass parts hollow glass bead, 4-7 mass parts triphenylphosphate, the two hexichol phosphoric acid ester of 5-7 mass parts Resorcinol, 5-8 mass parts zinc borate, the polynite of 5-6 mass parts.
2. a kind of ABS flame retardant plastics according to claim 1, is characterized in that described silicone resin is SFR100.
3. a kind of ABS flame retardant plastics according to claim 1, is characterized in that described ABS is PA757.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410029423.6A CN103772888A (en) | 2014-01-23 | 2014-01-23 | ABS (acrylonitrile-butadiene-styrene) flame-retardant plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410029423.6A CN103772888A (en) | 2014-01-23 | 2014-01-23 | ABS (acrylonitrile-butadiene-styrene) flame-retardant plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103772888A true CN103772888A (en) | 2014-05-07 |
Family
ID=50565685
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410029423.6A Pending CN103772888A (en) | 2014-01-23 | 2014-01-23 | ABS (acrylonitrile-butadiene-styrene) flame-retardant plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103772888A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107011615A (en) * | 2016-08-23 | 2017-08-04 | 南通久聚高分子科技有限公司 | A kind of Flame-retardant ABS plastic |
| CN107163488A (en) * | 2017-06-09 | 2017-09-15 | 东莞市联洲知识产权运营管理有限公司 | A kind of hydrotalcite-modified ABS composite material of high-weatherability |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033326A (en) * | 2007-04-20 | 2007-09-12 | 浙江工业大学 | Special-purpose material for environmental protection flame-proof ABS and preparing method thereof |
| CN102558868A (en) * | 2011-12-21 | 2012-07-11 | 天津金发新材料有限公司 | Flame-retarding synergist and flame-retarding alkyl benzene sulphonate (ABS) prepared by flame-retarding synergist |
| CN102898684A (en) * | 2012-10-25 | 2013-01-30 | 上海韬鸿化工科技有限公司 | Composite environment-friendly flame retardant for ABS (Acrylonitrile Butadiene Styrene) and ABS flame-retardant plastic |
-
2014
- 2014-01-23 CN CN201410029423.6A patent/CN103772888A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033326A (en) * | 2007-04-20 | 2007-09-12 | 浙江工业大学 | Special-purpose material for environmental protection flame-proof ABS and preparing method thereof |
| CN102558868A (en) * | 2011-12-21 | 2012-07-11 | 天津金发新材料有限公司 | Flame-retarding synergist and flame-retarding alkyl benzene sulphonate (ABS) prepared by flame-retarding synergist |
| CN102898684A (en) * | 2012-10-25 | 2013-01-30 | 上海韬鸿化工科技有限公司 | Composite environment-friendly flame retardant for ABS (Acrylonitrile Butadiene Styrene) and ABS flame-retardant plastic |
Non-Patent Citations (1)
| Title |
|---|
| 欧育湘: "《阻燃剂》", 30 September 2009, 国防工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107011615A (en) * | 2016-08-23 | 2017-08-04 | 南通久聚高分子科技有限公司 | A kind of Flame-retardant ABS plastic |
| CN107163488A (en) * | 2017-06-09 | 2017-09-15 | 东莞市联洲知识产权运营管理有限公司 | A kind of hydrotalcite-modified ABS composite material of high-weatherability |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9856356B2 (en) | Halogen-free flame-retardant polyolefin composite foam material and preparation method thereof | |
| CN103694615B (en) | A kind of anti-static halogen-free environment friendly flame-retardant sheet molding compound and preparation method thereof | |
| CN104004348A (en) | High-thermal-oxidative stability and heat-resistant regeneration nylon material and preparation method thereof | |
| CN102875893B (en) | Thermoplastic fire retardant plastic | |
| CN103772821A (en) | Polypropylene (PP) flame-retardant plastic | |
| CN105199304A (en) | Polymer composite high in heat-conducting property | |
| CN103421266A (en) | Halogen-free flame-retardant high impact polystyrene and preparation method thereof | |
| CN106633702A (en) | Flame-retardant plastic using ionic liquid as flame retardant and preparation method thereof | |
| CN103146058B (en) | Toughened polypropylene composite material and preparation method thereof | |
| CN104725817A (en) | Environmentally-friendly flame-retardant reinforced impact-resistant PC composite material | |
| CN103772888A (en) | ABS (acrylonitrile-butadiene-styrene) flame-retardant plastic | |
| KR20210061420A (en) | Flame-retardant HIPS material and its manufacturing method | |
| CN103772943A (en) | PC (Polycarbonate) flame retardant plastic | |
| CN104725797A (en) | Method for preparing flame-retardant plastic composite material | |
| CN103849022A (en) | Glass fiber reinforced halogen-free flame retardant polyethylene powder and preparation method thereof | |
| CN102993663A (en) | Preparation method of halogen-free unsaturated polyester glass reinforced plastic molding material | |
| CN102167882B (en) | Benzoxazine-containing high-gloss halogen-free flame-retardant plastic and application thereof | |
| CN103772792A (en) | Polyethylene flame-retardant plastic | |
| CN103772944B (en) | A kind of environment-friendly type PC flame retardant plastics | |
| CN103788487A (en) | Environment-friendly polypropylene (PP) flame retardant plastic | |
| CN103772824B (en) | A kind of low-smoke flame-retardant polypropylene alkene material and preparation method thereof | |
| CN114350025B (en) | High-char-forming halogen-free composite intumescent flame retardant and flame-retardant polystyrene resin | |
| CN102643526A (en) | Halogen-free flame-retarding polyphenylene oxide composition with ultrahigh heat resistance | |
| CN103788524A (en) | Polystyrene flame-retardant plastic | |
| CN104844883A (en) | Polyethylene antistatic powder and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140507 |