CN103771515B - A kind of phosphoric acid arsenic slag odor removal - Google Patents
A kind of phosphoric acid arsenic slag odor removal Download PDFInfo
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- CN103771515B CN103771515B CN201310747143.4A CN201310747143A CN103771515B CN 103771515 B CN103771515 B CN 103771515B CN 201310747143 A CN201310747143 A CN 201310747143A CN 103771515 B CN103771515 B CN 103771515B
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- pump
- filter
- basin
- phosphoric acid
- reactive tank
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Abstract
A kind of phosphoric acid arsenic slag odor removal, mainly arrange reactive tank, washing bath, filter, pump, basin and drying with steam equipment, the connection of this device is: reactive tank, pump I, filter I, washing bath, pump II, filter II connect successively; The lower end of basin I is connected with pump I, and the upper end of basin I is connected with the lower end of filter I; The lower end of basin II is connected with pump II, and the upper end of basin II is connected with the lower end of filter II.This device utilizes phosphoric acid enterprise self to produce phosphoric acid and directly does odorless process to arsenic slag, without the need to other chemical processing agent, avoids causing secondary pollution; Pickling, washing and the heat energy needed for red arsenic drying, all from the residue steam in phosphoric acid production, greatly reduce energy consumption.This device arranges the recycle system, improves P
2s
5the service efficiency of dearsenic agent, apparatus structure is simple, and equipment investment is few, and production cost is low, and arsenic slag good deodorization effect, has good economic benefit, social benefit and ecological benefits.
Description
technical field:
The invention belongs to technical field of phosphorous chemical industry, relate to a kind of phosphoric acid arsenic slag odor removal.
background technology:
The treatment process of arsenic sulfide slag is mainly divided into two kinds: pyrogenic process and wet method.Pyrogenic process, i.e. roasting method are the domestic methods reclaiming white arsenic and the most generally adopt from arsenic sulfide slag.Adopt oxidizing roasting, reducing roasting and vacuum baking etc. to process, arsenic directly reclaims with the form of white arsenic.The major equipment of pyrogenic process is air-flow stoving oven and reverberatory furnace, relies on that burning a large amount of fuel (as coal, coal gas, the heavy oil etc.) hot gas that produces carries out drying to arsenic sulfide slag, roasting obtains thick white arsenic, then distils with reverberatory furnace again and obtain pure white arsenic.Whole technological process power consumption is huge, and produces secondary pollution.The method process arsenic slag that namely wet method adopts acidleach, alkali leaching or salt to soak, first separates arsenic, and then reclaims arsenic product further or carry out harmless treatment from slag.This method have employed the treatment agents such as strong acid and strong base, and flow process is complicated, tediously long, not only introduces new impurity and causes secondary pollution, also greatly increases the processing cost of arsenic slag.
Given this, the present invention proposes that a kind of flow process is simple, energy consumption is low, high efficiency arsenic Slag treatment device, i.e. a kind of phosphoric acid arsenic slag odor removal.
summary of the invention:
Object of the present invention: be the economy in order to solve existing phosphoric acid arsenic Slag treatment method and technical problem, aim to provide that a kind of flow process is simple, energy consumption is low, high efficiency arsenic Slag treatment device, an i.e. phosphoric acid arsenic slag odor removal, improves the economic and social benefit of phosphoric acid production.
Technical scheme of the present invention is:
Utilize phosphoric acid enterprise self to produce the advantage of phosphoric acid, adopt excessive industrial phosphoric acid to remove the P of hydrogen sulfide in arsenic slag and remnants
2s
5, obtain the red arsenic product of higher degree while eliminating arsenic slag stink, the heat energy in reaction process and needed for red arsenic drying all from the by-product hot steam in phosphoric acid production, without the need to extra heat source.Do not introduce new impurity, non-secondary pollution on the one hand; Greatly reduce the energy consumption of arsenic Slag treatment on the other hand; In addition, the industrial phosphoric acid after embathing recycles or goes dearsenification reactor to carry out dearsenification, improves P
2s
5the service efficiency of dearsenic agent, reduces production cost, avoids secondary pollution.
The present invention is achieved in that
A kind of phosphoric acid arsenic slag odor removal, it is characterized in that: mainly arrange reactive tank, washing bath, filter I, filter II, agitator II, pump I, pump II, basin I, basin II and drying with steam equipment, the connection of this device is: reactive tank, pump I, filter I, washing bath, pump II, filter II connect successively.
The concrete connection of above-described pump I is: pump I inlet end, except being connected with reactive tank, is also connected with basin I, and the exit end of pump I, except being connected with filter I, is also connected with the acid inlet tube of reactive tank; Described basin I is separately connected with filter I.
The concrete connection of above-described pump II is: pump II inlet end, except being connected with washing bath, is also connected with basin II, and the exit end of pump II, except being connected with filter II, is also connected with the water inlet pipe of washing bath; Described basin II is separately connected with filter II.
The discharge port of above-described phosphoric acid feed-pipe and water inlet pipe is taper Huo Pian Gu shape discharge port.
The above-described discharge port of phosphoric acid feed-pipe and the discharge port of water inlet pipe, be separately positioned on the hypomere in reactive tank and washing bath.
Above-described reactive tank and washing bath all arrange chuck heating, and arrange agitator I and agitator II respectively.
Above-described reactive tank, agitator I, pump I, filter I, washing bath, agitator II, pump II, filter II, basin II, basin I and install pipeline, accessory material adopt plastics, enamel, pottery and stainless steel more than one.
Principle of work of the present invention is:
This phosphoric acid arsenic slag odor removal, utilizes phosphoric acid enterprise self to produce the advantage of phosphoric acid, adopts excessive industrial phosphoric acid directly to do odorless process to arsenic slag, without the need to other chemical processing agent; Pickling, washing and the heat energy needed for red arsenic drying all greatly reduce energy consumption from the residue steam in phosphoric acid production.The pickling of phosphoric acid arsenic slag will to be heated pickle solution circulation at pump I, the discharging mouth of pipe of the phosphoric acid feed-pipe of pickling be taper or partially the Gu shape discharging mouth of pipe punching of phosphoric acid arsenic slag is penetrated, and be issued to the deodorizing of phosphoric acid arsenic slag in agitator effect.By the phosphoric acid arsenic slag through pickling at pump II warm water washing lotion circulation circulating water wash, and be issued to phosphoric acid arsenic slag cleaning object in agitator effect, after drying, obtain the phosphoric acid arsenic slag of odorless.
Advantage of the present invention and positively effect:
1, phosphoric acid enterprise self is utilized to produce the advantage of phosphoric acid, excessive industrial phosphoric acid is adopted directly to do odorless process to arsenic slag, without the need to other chemical processing agent, reduce processing cost, avoid causing secondary pollution, pickling tank, washing bath and drying with steam equipment are provided with chuck heating, and pickling, washing and the heat energy needed for red arsenic drying all greatly reduce energy consumption from the residue steam in phosphoric acid production.
2, the treatment agent using industrial phosphoric acid as arsenic slag, absorbing hydrogen sulphide Posterior circle uses, or delivers to dearsenification reactor continuation dearsenification purification depending on the arsenic content height of phosphoric acid, improves P
2s
5the service efficiency of dearsenic agent, reduces production cost.
3, this apparatus structure is simple, and equipment investment is few, and can not take side greatly, production cost is low, the residue steam in Appropriate application phosphoric acid production, and arsenic slag good deodorization effect, has good economic benefit, social benefit and ecological benefits.
accompanying drawing illustrates:
Accompanying drawing 1: be structural representation of the present invention.
Identify in figure: 1-reactive tank, 2-agitator I, 3-pump I, 4-filter I, 5-washing bath, 6-agitator II, 7-pump II, 8-filter II, 9-basin II, 10-basin I.
embodiment:
Below in conjunction with drawings and Examples, the present invention is further described, and listed embodiment is only the present invention is described and is not limited to the present invention.
embodiment one:
This phosphoric acid arsenic slag odor removal, main plastics and the stainless material of adopting is made.Arrange reactive tank 1, washing bath 5, filter I 4, filter II 8, agitator II 6, pump I 3, pump II 7, basin I 10, basin II 9 and drying with steam equipment, the connection of this device is: reactive tank 1, pump I 3, filter I 4, washing bath 5, pump II 7, filter II 8 connect successively.
The concrete connection of described pump I 3 is: pump I 3 inlet end, except being connected with reactive tank 1, is also connected with basin I 10, and pump I 3 exit end, except being connected with filter I 4, is also connected with the acid inlet tube of reactive tank 1; Described basin I 10 is separately connected with filter I 4.
The concrete connection of described pump II 7 is: pump II 7 inlet end, except being connected with washing bath 5, is also connected with basin II 9, and pump II 7 exit end, except being connected with filter II 8, is also connected with the water inlet pipe of washing bath 5; Described basin II 9 is separately connected with filter II 8.
The discharge port Wei Pian Gu shape discharge port of described phosphoric acid feed-pipe and water inlet pipe.
The described discharge port of phosphoric acid feed-pipe and the discharge port of water inlet pipe, be separately positioned on the hypomere in reactive tank 1 and washing bath 5.
Described reactive tank 1 and washing bath 5 all arrange chuck heating, and arrange agitator I 2 and agitator II 6 respectively.
embodiment two:
This phosphoric acid arsenic slag odor removal, main plastics and the enamel material of adopting is made.Arrange reactive tank 1, washing bath 5, filter I 4, filter II 8, agitator II 6, pump I 3, pump II 7, basin I 10, basin II 9 and drying with steam equipment, the connection of this device is: reactive tank 1, pump I 3, filter I 4, washing bath 5, pump II 7, filter II 8 connect successively.
The concrete connection of described pump I 3 is: pump I 3 inlet end, except being connected with reactive tank 1, is also connected with basin I 10, and pump I 3 exit end, except being connected with filter I 4, is also connected with the acid inlet tube of reactive tank 1; Described basin I 10 is separately connected with filter I 4.
The concrete connection of described pump II 7 is: pump II 7 inlet end, except being connected with washing bath 5, is also connected with basin II 9, and pump II 7 exit end, except being connected with filter II 8, is also connected with the water inlet pipe of washing bath 5; Described basin II 9 is separately connected with filter II 8.
Described phosphoric acid feed-pipe and the discharge port of water inlet pipe are conical discharge port.
The described discharge port of phosphoric acid feed-pipe and the discharge port of water inlet pipe, be separately positioned on the middle hypomere in reactive tank 1 and washing bath 5.
Described reactive tank 1 and washing bath 5 all arrange chuck heating, and arrange agitator I 2 and agitator II 6 respectively.
embodiment three:
This phosphoric acid arsenic slag odor removal, main enamel and the stainless material of adopting is made.Arrange reactive tank 1, washing bath 5, filter I 4, filter II 8, agitator II 6, pump I 3, pump II 7, basin I 10, basin II 9 and drying with steam equipment, the connection of this device is: reactive tank 1, pump I 3, filter I 4, washing bath 5, pump II 7, filter II 8 connect successively.
The concrete connection of described pump I 3 is: pump I 3 inlet end, except being connected with reactive tank 1, is also connected with basin I 10, and pump I 3 exit end, except being connected with filter I 4, is also connected with the acid inlet tube of reactive tank 1; Described basin I 10 is separately connected with filter I 4.
The concrete connection of described pump II 7 is: pump II 7 inlet end, except being connected with washing bath 5, is also connected with basin II 9, and pump II 7 exit end, except being connected with filter II 8, is also connected with the water inlet pipe of washing bath 5; Described basin II 9 is separately connected with filter II 8.
The discharge port Wei Pian Gu shape discharge port of described phosphoric acid feed-pipe and water inlet pipe.
The described discharge port of phosphoric acid feed-pipe and the discharge port of water inlet pipe, be separately positioned on the hypomere in reactive tank 1 and washing bath 5.
Described reactive tank 1 and washing bath 5 all arrange chuck heating, and arrange agitator I 2 and agitator II 6 respectively.
Claims (3)
1. a phosphoric acid arsenic slag odor removal, it is characterized in that: mainly arrange reactive tank (1), washing bath (5), filter I (4), filter II (8), agitator II (6), pump I (3), pump II (7), basin I (10), basin II (9) and drying with steam equipment, the connection of this device is: reactive tank (1), pump I (3), filter I (4), washing bath (5), pump II (7), filter II (8) connect successively;
The concrete connection of described pump I (3) is: pump I (3) inlet end, except being connected with reactive tank (1), is also connected with basin I (10), and pump I (3) exit end, except being connected with filter I (4), is also connected with the acid inlet tube of reactive tank (1); Described basin I (10) is separately connected with filter I (4);
The concrete connection of described pump II (7) is: pump II (7) inlet end, except being connected with washing bath (5), is also connected with basin II (9), and pump II (7) exit end, except being connected with filter II (8), is also connected with the water inlet pipe of washing bath (5); Described basin II (9) is separately connected with filter II (8).
2. a kind of phosphoric acid arsenic slag odor removal according to claim 1, it is characterized in that: the discharge port of the acid inlet tube of described reactive tank (1) and the water inlet pipe of washing bath (5) and water outlet are respectively taper Huo Pian Gu shape discharge port and water outlet, and be separately positioned on the middle hypomere in reactive tank (1) and washing bath (5).
3. a kind of phosphoric acid arsenic slag odor removal according to claim 1, is characterized in that: described reactive tank (1) and washing bath (5) all arrange chuck heating, and arrange agitator I (2) and agitator II (6) respectively.
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CN201310747143.4A CN103771515B (en) | 2013-12-30 | 2013-12-30 | A kind of phosphoric acid arsenic slag odor removal |
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CN201310747143.4A CN103771515B (en) | 2013-12-30 | 2013-12-30 | A kind of phosphoric acid arsenic slag odor removal |
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CN103771515A CN103771515A (en) | 2014-05-07 |
CN103771515B true CN103771515B (en) | 2015-12-30 |
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Citations (5)
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---|---|---|---|---|
SU421625A1 (en) * | 1972-01-24 | 1974-03-30 | METHOD FOR PROCESSING PHOSPHATE SLUDGE | |
CN102284463A (en) * | 2011-06-08 | 2011-12-21 | 湖北三宁化工股份有限公司 | Treatment method and device for wet discharging and dry stacking of ardealite |
CN103191637A (en) * | 2013-04-23 | 2013-07-10 | 瓮福(集团)有限责任公司 | Industrial exhaust gas desulfurizer |
CN103352219A (en) * | 2013-06-08 | 2013-10-16 | 海尚集团有限公司 | Recovery processing method for phosphorization cleaning wastewater and corresponding recovery device |
CN103435021A (en) * | 2013-08-19 | 2013-12-11 | 瓮福(集团)有限责任公司 | Wet process phosphoric acid production device and method |
-
2013
- 2013-12-30 CN CN201310747143.4A patent/CN103771515B/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU421625A1 (en) * | 1972-01-24 | 1974-03-30 | METHOD FOR PROCESSING PHOSPHATE SLUDGE | |
CN102284463A (en) * | 2011-06-08 | 2011-12-21 | 湖北三宁化工股份有限公司 | Treatment method and device for wet discharging and dry stacking of ardealite |
CN103191637A (en) * | 2013-04-23 | 2013-07-10 | 瓮福(集团)有限责任公司 | Industrial exhaust gas desulfurizer |
CN103352219A (en) * | 2013-06-08 | 2013-10-16 | 海尚集团有限公司 | Recovery processing method for phosphorization cleaning wastewater and corresponding recovery device |
CN103435021A (en) * | 2013-08-19 | 2013-12-11 | 瓮福(集团)有限责任公司 | Wet process phosphoric acid production device and method |
Non-Patent Citations (3)
Title |
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"100 kt/a磷酸一铵装置冷却水、密封水封闭循环改造";孙杰生等;《磷肥与复肥》;20130930;第28卷(第5期);第38页 * |
"从磷酸废砷渣中回收砷的碱浸工艺研究";黎铉海等;《广西大学学报:自然科学版》;20120630;第37卷(第3期);第417-420页 * |
"由工业磷酸连续操作生产食品级磷酸";骆德池;《硫磷设计与粉体工程》;20051231(第6期);第27-29页 * |
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