CN103768934B - A kind of FCC apparatus regenerated flue gas denitrating technique - Google Patents
A kind of FCC apparatus regenerated flue gas denitrating technique Download PDFInfo
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- CN103768934B CN103768934B CN201210404197.6A CN201210404197A CN103768934B CN 103768934 B CN103768934 B CN 103768934B CN 201210404197 A CN201210404197 A CN 201210404197A CN 103768934 B CN103768934 B CN 103768934B
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Abstract
The invention discloses a kind of FCC apparatus regenerated flue gas denitrating technique, FCC regenerator, deduster, flue gas turbine expander, CO waste heat boiler, SCR denitration reactor, air preheater, desulfurization and dedusting unit and chimney is comprised by flow of flue gas direction, regenerated flue gas is after deduster dedusting, before entering CO waste heat boiler, drawing one flow is former flow 0.1v% ~ 5.0v% smoke evaporative liquefied ammonia or ammoniacal liquor, be re-used as the carrier gas of the ammonia evaporated, after carrier gas mixes with ammonia, enter reactor by the ammonia-spraying grid arranged in SCR denitration reactor; All the other flue gases, after flue gas turbine expander recovers energy, enter CO waste heat boiler, SCR denitration reactor, air preheater, desulfurization and dedusting unit successively, discharge finally by chimney.The present invention both played dilution and rolling action to ammonia, improve the mixed effect of ammonia and flue gas; And save ammonia evaporation and dilution needed for equipment and energy consumption.
Description
Technical field
The present invention relates to the administering method of catalytic cracking (FCC) regenerated flue gas, particularly relate to SCR (SCR) denitrating technique of oil plant FCC apparatus regenerated flue gas process.
Background technology
Nitrogen oxide is generically and collectively referred to as NOx, is one of primary pollution source of atmosphere pollution.Endanger mainly maximum: NO, NO
2.The main harm of NOx is as follows: (1) is to the toxic effect of human body; (2) to the toxic effect of plant; (3) acid rain, acid mist can be formed; (4) photochemical fog is formed with hydrocarbon; (5) damage the ozone layer.
At oil plant, in FCC (fluid catalytic cracking) technique, catalyst granules is iterative cycles between catalytic cracking zone and catalyst regeneration region, at regeneration period, the coke from cracking reaction on catalyst granules is at high temperature removed by air oxidation, the removal of deposits of coke makes the activation recovering of catalyst, and can be utilized in cracking reaction again.
Main generation 3 kinds of NOx, (1) temperature mode NOx(THermolNOx in combustion process): the nitrogen in air is at high temperature oxidized the NOx of generation.(2) Quick-type NOx(PromotNOx): hydrocarbon fuel when air coefficient little (hydrocarbon fuel overrich), a large amount of NOx sharply generated in flame.(3) fuel type NOx(FuelNOx): the NOx that the nitrogen-containing compound in fuel generates in combustion.
NO and NO in the flue gas of catalytic cracked regenerated generation
2all have, but the research of thermodynamics and kinetics shows, mainly generates NO, in total NOx, NO accounts for 90v%, NO
2account for 10v%.NOx in FCC flue gas is almost all from the flue gas that the nitrogenous coke burning on catalyst produces.Therefore due to the regeneration of catalyst, can there is the emission problem of NOx in the FCCU of all process nitrogen-containing materials.At oil plant, FCCU is maximum NOx emission source.
For controlling NOx emission, formulate each class standard abroad.EPA and 13 oil refining enterprise have signed pollutant catabolic gene agreement (ConsentDecree), and all oil plants of European Union requirements perform " comprehensive pollution and control guide ", and Japan has formulated the discharge standard of the NOx of FCCU." air comprehensive pollution thing discharge standard-GB16297-1996 " and " emission standard of air pollutants for boilers-GWPB3-1999 " that China formulates all makes restriction to the discharge of NOx.Along with the increasingly stringent of environmental regulation, can improve NOx emission index request thereupon.Therefore, instant stage has been arrived in NOx pollution control.
Current gas denitrifying technology mainly contains: the SCR (selective catalytic reduction) of gas-phase reaction and SNCR (SNCR method), liquid absorption method, solid absorption method, high energy electron active oxidation method (EBA electron beam irradiation method and PPCP impulse electric corona plasma method) etc.
In numerous denitrating flue gas treatment technology, liquid absorption method denitration efficiency is low; Absorption method denitration efficiency is high, but adsorbance is little, and regeneration is frequent, applies not extensive; High energy electron active oxidation method can simultaneous SO_2 and NO removal, but energy consumption is high, and the life-span is short; The escapement ratio of SNCR method ammonia is high, can produce safety problem.
SCR technology, compared with other technologies, has denitration efficiency high, the advantages such as technology maturation, is that Flue Gas Denitrification Engineering applies maximum technology both at home and abroad at present.SCR method refers to reaction temperature 200 ~ 400 DEG C, uses NH
3making reducing agent by NOx catalytic reduction is N
2, the oxygen in waste gas seldom participates in reaction, and thermal discharge is little.
The combustion-type CO waste heat boiler of heavy oil catalytically cracking equipment configuration, vapours is pressed through in mainly utilizing CO that the high temperature regeneration fume afterheat that produces in catalytic cracking (FCC) device production process and regenerator burn generation to produce, CO in flue gas is burnt, and makes CO discharge meet environmental requirement.
Regenerated flue gas adds air and fuel and burns after entering boiler, object is CO in removing regenerated flue gas and other nuisance, reclaims the heat energy adding fuel gas buring CO and produce; Another main application of waste heat boiler is: when catalytic unit disastershutdown, by fuel oil output steam, plays the effect of power boiler, to meet the needs that full factory steam load regulates.
The regenerated flue gas of Conventional catalytic cracking device (FCCU) flows to and is: FCC regenerator → flue gas turbine expander → waste heat boiler → denitration unit → air preheater → desulfurization unit → chimney.Denitrating flue gas unit is generally provided with ammonia-spraying grid and denitrification catalyst module, NH
3being sprayed into by ammonia-spraying grid as reducing agent is provided with in the reactor of denitrification catalyst module, is N by NOx catalytic reduction
2.But ammonia can not, separately at Cemented filling, need to add carrier gas, generally by blower fan, air is delivered to ammonia blender and ammonia is diluted.
CN200920204676.7 discloses a kind of SCR equipment for denitrifying flue gas, comprise catalytic reactor, ammonia/air mixer, ammonia injection barrier, air preheater, one entrance and the dilution air pipe of described ammonia/air mixer connect, and another entry sequence pipe of described ammonia/air mixer is connected to ammonia dashpot, ammonia evaporator, liquefied ammonia storage tank.CN200610044991.9 discloses a kind of high dirt composite SCR smoke denitrating technique and denitration catalyst reaction unit, the flue gas containing nitrogen oxide NOx transported by flue gas generation systems through controlled choke apparatus enter disk annular ammonia spray grid and with spray by disk annular ammonia the ammonia that grid nozzle sprays and mix, the air that described ammonia and air blower are carried is pumped to ammonia-spraying grid by ammonia after ammonia blender mixes.CN200910086856.4 discloses a kind of flue-gas denitration process and system thereof of preparing ammonia with ammonium bicarbonate dry method by pyrolysis, adopts carbonic hydroammonium powder as denitrification reducing agent, adopts dry method ammonia mode to obtain ammonia; Carbonic hydroammonium powder is decomposed out ammonia, carbon dioxide and water under the heat effect of hot-air, mist after pyrolysis flows into surge tank, ammonia air mixer is entered subsequently by control valve, mist after Dilution air enters SCR reactor by ammonia-spraying grid, in the effect of catalyst, NOx is reduced into N by ammonia
2.Said method all needs high-temperature steam that liquefied ammonia or ammoniacal liquor are evaporated to ammonia, and then dilutes; And adopt air as ammonia carrier gas, carrier gas needs special dilution air, adds equipment and energy consumption; Simultaneously the expulsion pressure of carrier gas is relative with jet velocity not high, is unfavorable for mixing of ammonia and flue gas, affects denitration rate.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of FCC apparatus regenerated flue gas denitrating technique.The present invention adopts FCC regenerated flue gas to evaporate liquefied ammonia or ammoniacal liquor, is re-used as the carrier gas of the ammonia evaporated, and both plays dilution and rolling action to ammonia, and improves the mixed effect of ammonia and flue gas; And save ammonia evaporation and dilution needed for equipment and energy consumption.
FCC apparatus regenerated flue gas denitrating technique of the present invention, FCC regenerator, deduster, flue gas turbine expander, CO waste heat boiler, SCR denitration reactor, air preheater, desulfurization and dedusting unit and chimney is comprised by flow of flue gas direction, regenerated flue gas is after deduster dedusting, before entering CO waste heat boiler, drawing one flow is former flow 0.1v% ~ 5.0v% smoke evaporative liquefied ammonia or ammoniacal liquor, be re-used as the carrier gas of the ammonia evaporated, after carrier gas mixes with ammonia, enter reactor by the ammonia-spraying grid arranged in SCR denitration reactor; All the other flue gases, after flue gas turbine expander recovers energy, enter CO waste heat boiler, SCR denitration reactor, air preheater, desulfurization and dedusting unit successively, discharge finally by chimney.
In the present invention, the oxygen concentration of carrier gas is 0.1v% ~ 5.0v%, and temperature is 550 ~ 650 DEG C, and pressure is 0.1 ~ 0.33MPa, CO concentration is 0.1v% ~ 10v%.
In the present invention, for avoiding explosion limit, the concentration after ammonia dilution is not more than 5v%.Carrier gas both played dilution and rolling action to ammonia, improve the mixed effect of ammonia and flue gas; And save ammonia evaporation and dilution needed for equipment and energy consumption.
In the present invention, deduster can adopt various high-effective dust-removing equipment, can remove the dust being greater than 10mm, preferably adopt cyclone dust collectors, and the extraction location of carrier gas is three to revolve or four outlets of revolving deduster.
In the present invention, after carrier gas mixes with ammonia, spray into SCR denitration reactor by ammonia-spraying grid to mix with flue gas, expulsion pressure is not less than 0.1MPa, jet velocity reaches 10 ~ 15m/s, much larger than expulsion pressure 1 ~ 4KPa, the jet velocity 4 ~ 5m/s of the ammonia-spraying grid of other denitrating technique, improves the mixed effect of ammonia and flue gas, be beneficial to the denitration reaction of SCR denitration module, do not need to arrange separately special ammonia/flue gas blender.
In the present invention, in SCR denitration reactor, be provided with SCR denitration module.
In the present invention, arrange the grey grid of gear and ash discharging hole on SCR denitration module top, the gradient of keeping off grey grid is 5 ° ~ 50 °.Avoid dust to drop blocking catalyst, ensure denitrating catalyst denitration rate and service life.
In the present invention, flue gas enters SCR denitration module, and flue-gas temperature is 300 ~ 400 DEG C, NOx in ammonia and flue gas, and under denitrating catalyst effect, reaction generates N
2and H
2o.
In the present invention, SCR denitration is the honeycomb catalyst that active component is coated on honeycomb support, and aperture is 1 ~ 10mm, and active component is transition metal oxide.Active component is specially the oxide of the oxide of V, the oxide of Ti, the oxide of W and Mo, and active component is that honeycomb substrate quality is as follows with oxide basis: V(0.1wt% ~ 4wt%), Ti(1wt% ~ 90wt%), W(1wt% ~ 15wt%) and Mo(0.1wt% ~ 10wt%).
The present invention has following beneficial effect: (1) adopts FCC regenerated flue gas evaporation liquefied ammonia or ammoniacal liquor, is re-used as the carrier gas of the ammonia evaporated, and plays dilution and rolling action, improve the mixed effect of ammonia and flue gas to ammonia; (2) liquefied ammonia or ammoniacal liquor evaporation do not need special outer confession steam, and ammonia dilution does not need special dilution air, and ammonia mixing does not need special blender, saves equipment, reduces energy consumption.(3) improve expulsion pressure and the jet velocity of ammonia, substantially increase the mixed effect of ammonia and flue gas, improve denitration rate.
Accompanying drawing explanation
Fig. 1 is the process unit flow chart of FCC apparatus regenerated flue gas denitrating technique of the present invention.
Wherein: 1, FCC regenerator, 2, deduster, 3, flue gas turbine expander, 4, CO waste heat boiler, 5, SCR denitration reactor, 6, air preheater, 7, desulfurization and dedusting unit, 8, chimney, 9, evaporimeter, 10, liquefied ammonia or ammoniacal liquor; I, ammonia-spraying grid.
Fig. 2 is the process unit flow chart of comparative example of the present invention.
Wherein: 11, FCC regenerator, 12, deduster, 13, flue gas turbine expander, 14, CO waste heat boiler, 15, SCR denitration reactor, 16, air preheater, 17, desulfurization and dedusting unit, 18, chimney, 19, blower fan, 20, evaporimeter, 21, steam, 22, liquefied ammonia or ammoniacal liquor; J, ammonia-spraying grid.
Detailed description of the invention
Below by specific embodiment, FCC regenerated flue gas denitrating technique of the present invention is elaborated.In the present invention, v% is volume fraction, wt% mass fraction.
Embodiment 1
Denitrating technique flow process shown in Figure 1, the regenerated flue gas that FCC regenerator 1 produces, regenerator outlet parameter is: flow is 120,000 Nm
3/ h, oxygen concentration is 2.3v%, and temperature is 600 DEG C, and pressure is 0.33MPa, CO concentration is 6v%.
Regenerated flue gas after cyclone dust collectors 2 removing is greater than the dust of 10mm, separate one flow be the flue gas of the 1.25v% of former regenerated flue gas flow as the steam of ammonia and carrier gas, temperature is 600 DEG C, and pressure is 0.33MPa.All the other flue gases, after flue gas turbine expander 3 recovers energy, send into CO waste heat boiler 4.
It is ammonia that liquefied ammonia 10 enters evaporimeter 9 by the smoke evaporative of the 1.25v% of flow, is re-used as the carrier gas of the ammonia evaporated.Flow 48Nm
3the ammonia of/h and 1500Nm
3enter SCR denitration reactor 5 after the mixing of/h carrier gas, ammonia concentration is about 3.0v%.Namely regenerated flue gas as the steam of ammonia, saves energy consumption; And both dilution and rolling action were played to ammonia as carrier gas, and do not need special dilution air, save equipment and energy consumption.
After ammonia mixes with carrier gas, spray into reactor by the 5 ammonia-spraying grid i arranged in SCR denitration reactor, expulsion pressure is 0.33MPa, and jet velocity reaches 15m/s.The gradient arranged before mixed flue gas arrives SCR denitration module is the gear ash barrier h of 30 °, and the dust removed regularly is discharged by ash discharging hole.Now flue-gas temperature is 350 DEG C, under the effect of denitrating catalyst, NOx and NH in flue gas
3carry out denitration reaction, generate N
2and H
2o.
The excellent specific properties such as catalyst adopts honeycomb, and it is large that this structure has active area, and anti-clogging is resistance to poisoning, aging, catalyst is divided into 3 ~ 6 layers, and wherein 1 layer is set to reserved layer, is convenient to change and add catalyst.Denitrating catalyst is the denitrating catalyst that active component is coated on honeycomb support, aperture is 5mm, active component is transition metal oxide, be specially the oxide of the oxide of V, the oxide of Ti, the oxide of W and Mo, be that honeycomb substrate quality is as follows: V:2wt%, Ti:90wt%, W:7wt% and Mo:0.5wt% with oxide basis, this catalyst has good catalytic activity to SCR denitration reaction.
Flue gas after denitration enters air preheater 6 successively, desulfurization and dedusting unit 7, finally enters air from chimney 8.
Adopt the denitrating technique route of the inventive method, SCR denitration Reactor inlet NOx is 400mg/Nm
3, outlet NOx is 36mg/Nm
3, NOx clearance is 91wt%.
Comparative example 1
Denitrating technique flow process shown in Figure 2, processes the FCC regenerated flue gas identical with embodiment 1.
Blower fan 19 is used to carry 1500Nm
3the air of/h is as ammonia carrier gas, and the pressure of carrier gas is 3kPa, and temperature is normal temperature.
After the flue gas that FCC regenerator 11 produces remove and is greater than the dust of 10mm in deduster 12, enter after flue gas turbine expander 13 recovers energy, feeding CO waste heat boiler 14.
After regenerated flue gas after flue gas turbine expander 13 recovers energy enters CO waste heat boiler 14, add fuel and combustion air burns CO, CO is converted into CO
2.The flue gas out of CO waste heat boiler 14 enters SCR denitration reactor 15, and the dilution ammonia sprayed into ammonia-spraying grid j mixes.
Liquefied ammonia 22 enters evaporimeter 20 and is evaporated to ammonia by steam 21, flow 48Nm
3the ammonia of/h and 1500Nm
3after the mixing of/h air, the ammonia-spraying grid j arranged by SCR reactor is sprayed into, and fully mixes with regenerated flue gas.The fashionable expulsion pressure of diluted ammonia gas blowout is 3kPa, and jet velocity reaches 5m/s.NOx and NH in flue gas
3carry out denitration reaction, generate N
2and H
2o.
In SCR denitration reactor, the operating temperature of catalytic reaction is 350 DEG C, and catalyst adopts honeycomb, and it is large that this structure has active area, anti-clogging, resistance to poisoning, the excellent specific property such as aging, catalyst is divided into 3 ~ 6 layers, and wherein 1 layer is set to reserved layer, is convenient to change and add catalyst.Denitrating catalyst is the denitrating catalyst that active component is coated on honeycomb support, and aperture is 5mm.Active component is transition metal oxide, be specially the oxide of the oxide of V, the oxide of Ti, the oxide of W and Mo, be that honeycomb substrate quality is as follows: V:2wt%, Ti:90wt%, W:7wt% and Mo:0.5wt% with oxide basis, this catalyst has good catalytic activity to SCR reaction.
Flue gas after denitration is discharged through SCR denitration reactor outlet, enters air preheater 16 successively, desulfurization and dedusting unit 17, finally enters air from chimney 18.
Adopt the method for denitration route of comparative example, SCR denitration Reactor inlet NOx is 400mg/Nm
3, the NOx of outlet is 72mg/Nm
3, NOx clearance is 82wt%.Because gas speed is low, it is slightly poor that dilution ammonia enters the effect that boiler mixes with flue gas, and therefore denitration rate is only 82wt%.
Claims (10)
1. a FCC apparatus regenerated flue gas denitrating technique, FCC regenerator, deduster, flue gas turbine expander, CO waste heat boiler, SCR denitration reactor, air preheater, desulfurization and dedusting unit and chimney is comprised by flow of flue gas direction, regenerated flue gas is after deduster dedusting, before entering CO waste heat boiler, drawing one flow is former flow 0.1v% ~ 5.0v% smoke evaporative liquefied ammonia or ammoniacal liquor, be re-used as the carrier gas of the ammonia evaporated, after carrier gas mixes with ammonia, enter reactor by the ammonia-spraying grid arranged in SCR denitration reactor; All the other flue gases, after flue gas turbine expander recovers energy, enter CO waste heat boiler, SCR denitration reactor, air preheater, desulfurization and dedusting unit successively, discharge finally by chimney.
2. according to flue-gas denitration process according to claim 1, it is characterized in that: the oxygen concentration of carrier gas is 0.1v% ~ 5.0v%, and temperature is 550 ~ 650 DEG C, pressure is 0.1 ~ 0.33MPa, CO concentration is 0.1v% ~ 10v%.
3. according to the flue-gas denitration process described in claim 1 or 2, it is characterized in that: the concentration after ammonia dilution is not more than 5v%.
4. according to flue-gas denitration process according to claim 1, it is characterized in that: deduster adopts cyclone dust collectors, the extraction location of carrier gas is three to revolve or four outlets of revolving deduster.
5. according to flue-gas denitration process according to claim 1, it is characterized in that: after carrier gas mixes with ammonia, spray into SCR denitration reactor by ammonia-spraying grid and mix with flue gas, expulsion pressure is not less than 0.1MPa, and jet velocity reaches 10 ~ 15m/s.
6. according to flue-gas denitration process according to claim 1, it is characterized in that: in SCR denitration reactor, be provided with SCR denitration module.
7. according to flue-gas denitration process according to claim 6, it is characterized in that: arrange the grey grid of gear and ash discharging hole on SCR denitration module top, the gradient of keeping off grey grid is 5 ° ~ 50 °.
8. according to the flue-gas denitration process described in claim 1 or 6, it is characterized in that: flue gas enters SCR denitration module, flue-gas temperature is 300 ~ 400 DEG C, NOx in ammonia and flue gas, and under denitrating catalyst effect, reaction generates N
2and H
2o.
9. according to the flue-gas denitration process described in claim 1 or 6, it is characterized in that: SCR denitration is the honeycomb catalyst that active component is coated on honeycomb support, aperture is 1 ~ 10mm, and active component is transition metal oxide.
10. according to flue-gas denitration process according to claim 9, it is characterized in that: active component is specially the oxide of the oxide of V, the oxide of Ti, the oxide of W and Mo, and active component is that honeycomb substrate quality is as follows: V:0.1wt% ~ 4wt%, Ti:1wt% ~ 90wt%, W:1wt% ~ 15wt% and Mo:0.1wt% ~ 10wt% with oxide basis.
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| CN105289299A (en) * | 2015-10-30 | 2016-02-03 | 太仓东能环保设备有限公司 | SCR flue gas denitration process |
| CN106669419A (en) * | 2015-11-11 | 2017-05-17 | 中国石油化工股份有限公司 | Denitration method for FCC (Fluid Catalytic Cracking) device regenerated fume |
| CN108072046A (en) * | 2018-01-23 | 2018-05-25 | 上海云汇环保科技有限公司 | A kind of CO stoves combustion product gases processing system |
| CN109647183A (en) * | 2018-12-07 | 2019-04-19 | 华电电力科学研究院有限公司 | A kind of gas internal-combustion engine distributed energy SCR denitration system and its working method |
| CN111701452A (en) * | 2020-05-27 | 2020-09-25 | 姚磊 | Grate rotary kiln pelletizing flue gas reposition of redundant personnel deNOx systems |
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| WO2010036558A1 (en) * | 2008-09-26 | 2010-04-01 | Exxonmobil Research And Engineering Company | A method for treating refinery waste streams in a fluid catalytic cracking unit and an improved catalytic cracking unit for processing refinery waste streams |
| CN201643982U (en) * | 2009-10-27 | 2010-11-24 | 中国石油化工股份有限公司 | FCC flue gas denitration catalytic reactor |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010036558A1 (en) * | 2008-09-26 | 2010-04-01 | Exxonmobil Research And Engineering Company | A method for treating refinery waste streams in a fluid catalytic cracking unit and an improved catalytic cracking unit for processing refinery waste streams |
| CN201643982U (en) * | 2009-10-27 | 2010-11-24 | 中国石油化工股份有限公司 | FCC flue gas denitration catalytic reactor |
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