CN103756762A - Biological ceramic conversion self-repairing protective agent - Google Patents
Biological ceramic conversion self-repairing protective agent Download PDFInfo
- Publication number
- CN103756762A CN103756762A CN201310718165.8A CN201310718165A CN103756762A CN 103756762 A CN103756762 A CN 103756762A CN 201310718165 A CN201310718165 A CN 201310718165A CN 103756762 A CN103756762 A CN 103756762A
- Authority
- CN
- China
- Prior art keywords
- parts
- protective material
- protective agent
- selfreparing
- biological ceramics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 9
- 239000003223 protective agent Substances 0.000 title abstract 5
- 239000002199 base oil Substances 0.000 claims abstract description 9
- 239000000654 additive Substances 0.000 claims abstract description 7
- 230000000996 additive effect Effects 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 238000002360 preparation method Methods 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 15
- 230000001681 protective effect Effects 0.000 claims description 13
- -1 siloxanes Chemical class 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 241000158728 Meliaceae Species 0.000 claims description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 3
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical compound [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229910000071 diazene Inorganic materials 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 8
- 239000002184 metal Substances 0.000 abstract description 8
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- 238000005461 lubrication Methods 0.000 description 4
- 241001201614 Prays Species 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000011195 cermet Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses a biological ceramic conversion self-repairing protective agent. A preparation method of the self-repairing protective agent comprises the steps of adding 100 parts of base oil, 1-3 parts of surfactant and 10-25 parts of additive into a reaction kettle; heating to 75 DEG C and stirring for 1-2 hours until the end the reaction to obtain the biological ceramic self-repairing protective agent. The biological ceramic conversion self-repairing protective agent disclosed by the invention can realize ceramic conversion of the friction part of metal machinery, and the high-temperature application range of the metal machinery is effectively expanded.
Description
Technical field
The present invention relates to the field of metal mechanical friction abrasion protection agent, relate in particular to a kind of biological ceramics selfreparing protective material.
Background technology
The friction of various mechanical means with lubricated be the eternal theme of of the puzzlement mankind.The measuring and calculating of internal authority mechanism, 30～50% of the disposable energy in the world consumes in frictionloss, mechanical means has consumed more than 60% power, mechanical means is damaged and lost efficacy approximately 80% has frictional wear to cause, and the overwear vt. that the serious accident origin of more than 50% mechanized equipment and lubrication failure cause.Annual global Material Wear consumption and very surprising for overcoming the energy that friction mechanism equipment consumes.Lubrication technology can less mechanical means frictional wear.
The lubricant effect of conventional lubrication oil is mainly that the physical adsorption oil film forming on metallic surface is contact form, prays and reduce friction between mechanical friction secondary surface, and protection working interface is to support wear-resistant effect.Along with the rising of temperature, the boundary film that lubricating oil forms at surface of friction pair can lose efficacy gradually, causes bonding and the surface breakdown on sliding metal surface.When facility cold start-up, oil is lepthymenia, lost efficacy or during without oil condition, metallic surface produces rapidly metal to-metal contact, thereby causes the heavy wear of facility, even damages facility, not only wastes mass energy and material, and directly causes environmental pollution.
Summary of the invention
The object of the invention is the deficiency for conventional lubrication oil, a kind of biological ceramics selfreparing protective material of Wear vesistance excellence is provided.
The technical scheme that technical solution problem of the present invention adopts is: a kind of biological ceramics selfreparing protective material; protectant preparation method is as follows in described selfreparing: the base oil of 100 parts, the interfacial agent of 1 ~ 3 part and the additive of 10 ~ 25 parts are added in reactor; be heated to 75 ℃; stir 1 ~ 2 hour; finish reaction, obtain biological ceramics selfreparing protective material.
Preferably, described interfacial agent is a kind of in the chain compound that contains siloxanes or the chain compound that contains succimide; Described additive comprises the sulphur phosphorus fourth octyl group zinc salt of 0.5 ~ 2 part, the tritolyl phosphate of 2 ~ 4 parts, the ethylene-propylene copolymer of 10 ~ 20 parts and the barium mahogany sulfonate of 0.5 ~ 1 part.
Preferably, described base oil is class base oil 150 SN.
Further, the described chain compound that contains succimide is two Ashless butyl diimide dispersants.
The invention has the beneficial effects as follows: compared with prior art, biological ceramics selfreparing protective material provided by the invention is comprised of base oil, interfacial agent and additive.Active group in interfacial agent has crosslinked function of extending under certain condition, easily in metallic surface, sprawls, and at the low concave point of friction pair and wearing and tearing ditch dug with a plow place, prays the effect of filling a gap, and makes surface finish repaired, and produces the effect of similar polishing.Under the effect of additive, interfacial agent interaction of molecules, forms complete, fine and close cermet coating at surface of friction pair, realizes self-repair procedure.Meanwhile, the pairing pair that the reconditioning layer of this ceramic structure forms is not easy to occur sticking action, thereby has effectively reduced the wearing and tearing of surfaces of metallic rubbing pairs, plays the prolonged mechanical effect in work-ing life of saving energy and reduce the cost.Biological ceramics selfreparing protective material provided by the invention can have been realized the ceramic at metal mechanical friction position, efficient extn the high temperature range of application of metal machinery.
Embodiment
Embodiment 1
One class base oil 150 SN of 100 parts, two Ashless butyl diimide dispersants of 1.5 parts, the sulphur phosphorus fourth octyl group zinc salt of 1 part, the tritolyl phosphate of 3 parts, the ethylene-propylene copolymer of 15 parts and the barium mahogany sulfonate of 0.5 part are added in reactor; be heated to 75 ℃; stir 2 hours; finish reaction, in reactor, be biological ceramics selfreparing protective material.
Claims (4)
1. a biological ceramics selfreparing protective material; it is characterized in that the protectant preparation method of described selfreparing is as follows: the base oil of 100 parts, the interfacial agent of 1 ~ 3 part and the additive of 10 ~ 25 parts are added in reactor; be heated to 75 ℃; stir 1 ~ 2 hour; finish reaction, obtain biological ceramics selfreparing protective material.
2. a kind of biological ceramics selfreparing protective material as claimed in claim 1, is characterized in that described interfacial agent is a kind of in the chain compound that contains siloxanes or the chain compound that contains succimide; Described additive comprises the sulphur phosphorus fourth octyl group zinc salt of 0.5 ~ 2 part, the tritolyl phosphate of 2 ~ 4 parts, the ethylene-propylene copolymer of 10 ~ 20 parts and the barium mahogany sulfonate of 0.5 ~ 1 part.
3. a kind of biological ceramics selfreparing protective material as claimed in claim 1, is characterized in that described base oil is class base oil 150 SN.
4. a kind of biological ceramics selfreparing protective material as claimed in claim 2, is characterized in that the described chain compound that contains succimide is for two Ashless butyl diimide dispersants.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310718165.8A CN103756762B (en) | 2013-12-24 | 2013-12-24 | A kind of biological ceramics selfreparing protective material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310718165.8A CN103756762B (en) | 2013-12-24 | 2013-12-24 | A kind of biological ceramics selfreparing protective material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103756762A true CN103756762A (en) | 2014-04-30 |
| CN103756762B CN103756762B (en) | 2016-01-20 |
Family
ID=50524092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310718165.8A Active CN103756762B (en) | 2013-12-24 | 2013-12-24 | A kind of biological ceramics selfreparing protective material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103756762B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802715A (en) * | 2016-04-20 | 2016-07-27 | 江苏南山冶金机械制造有限公司 | Self-repairing lubricating oil for bearing |
| CN108167525A (en) * | 2017-12-11 | 2018-06-15 | 安徽银龙泵阀股份有限公司 | A kind of heatproof corrosion resistant spool and its manufacture craft |
| CN108164725A (en) * | 2017-12-10 | 2018-06-15 | 安徽银龙泵阀股份有限公司 | A kind of pump valve pipeline with self-repair function |
| CN108192173A (en) * | 2017-12-11 | 2018-06-22 | 安徽银龙泵阀股份有限公司 | A kind of pressure resistance spool and its manufacture craft |
| CN108215040A (en) * | 2017-12-11 | 2018-06-29 | 安徽银龙泵阀股份有限公司 | A kind of ceramic cartridge and its manufacture craft |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101705144A (en) * | 2009-11-20 | 2010-05-12 | 王恩臣 | Lubricating oil for methanol fuel engine and preparation method thereof |
-
2013
- 2013-12-24 CN CN201310718165.8A patent/CN103756762B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101705144A (en) * | 2009-11-20 | 2010-05-12 | 王恩臣 | Lubricating oil for methanol fuel engine and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802715A (en) * | 2016-04-20 | 2016-07-27 | 江苏南山冶金机械制造有限公司 | Self-repairing lubricating oil for bearing |
| CN108164725A (en) * | 2017-12-10 | 2018-06-15 | 安徽银龙泵阀股份有限公司 | A kind of pump valve pipeline with self-repair function |
| CN108167525A (en) * | 2017-12-11 | 2018-06-15 | 安徽银龙泵阀股份有限公司 | A kind of heatproof corrosion resistant spool and its manufacture craft |
| CN108192173A (en) * | 2017-12-11 | 2018-06-22 | 安徽银龙泵阀股份有限公司 | A kind of pressure resistance spool and its manufacture craft |
| CN108215040A (en) * | 2017-12-11 | 2018-06-29 | 安徽银龙泵阀股份有限公司 | A kind of ceramic cartridge and its manufacture craft |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103756762B (en) | 2016-01-20 |
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| C06 | Publication | ||
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| TR01 | Transfer of patent right |
Effective date of registration: 20180420 Address after: 314005 No. 1985 Shuanglong Road, Nanhu District, Zhejiang, Jiaxing, Fengzhen Patentee after: ZHEJIANG FENGCHUAN ELECTRONIC TECHNOLOGY Co.,Ltd. Address before: 314005 new Fengzhen new Fengzhen Road, Nanhu District, Jiaxing, Zhejiang Patentee before: ZHEJIANG 605 ENERGY DEVELOPMENT Co.,Ltd. |
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| CP01 | Change in the name or title of a patent holder |
Address after: 314005 No. 1985 Shuanglong Road, Nanhu District, Zhejiang, Jiaxing, Fengzhen Patentee after: Zhejiang FengChuan electronic environmental protection technology Co.,Ltd. Address before: 314005 No. 1985 Shuanglong Road, Nanhu District, Zhejiang, Jiaxing, Fengzhen Patentee before: ZHEJIANG FENGCHUAN ELECTRONIC TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20210118 Address after: 314200 the ground floor of Pinghu Feiyun plastic products yard, north of Caosheng Road, Caoqiao Industrial Park, Caoqiao street, Pinghu City, Jiaxing City, Zhejiang Province Patentee after: Pinghu likude Lubricating Oil Co.,Ltd. Address before: No. 1985, Shuanglong Road, Xinfeng Town, Nanhu District, Jiaxing City, Zhejiang Province, 314005 Patentee before: Zhejiang FengChuan electronic environmental protection technology Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A bioceramic self repairing protective agent Effective date of registration: 20221109 Granted publication date: 20160120 Pledgee: Pinghu Zhejiang rural commercial bank Limited by Share Ltd. Cao Qiao Branch Pledgor: Pinghu likude Lubricating Oil Co.,Ltd. Registration number: Y2022990000799 |
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| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20231213 Granted publication date: 20160120 Pledgee: Pinghu Zhejiang rural commercial bank Limited by Share Ltd. Cao Qiao Branch Pledgor: Pinghu likude Lubricating Oil Co.,Ltd. Registration number: Y2022990000799 |
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Denomination of invention: A bioceramic self-healing protective agent Effective date of registration: 20231221 Granted publication date: 20160120 Pledgee: Pinghu Zhejiang rural commercial bank Limited by Share Ltd. Cao Qiao Branch Pledgor: Pinghu likude Lubricating Oil Co.,Ltd. Registration number: Y2023980072790 |