CN103725399A - Castor-based environmental-friendly high-hardness alloy steel cutting fluid - Google Patents
Castor-based environmental-friendly high-hardness alloy steel cutting fluid Download PDFInfo
- Publication number
- CN103725399A CN103725399A CN201310682271.5A CN201310682271A CN103725399A CN 103725399 A CN103725399 A CN 103725399A CN 201310682271 A CN201310682271 A CN 201310682271A CN 103725399 A CN103725399 A CN 103725399A
- Authority
- CN
- China
- Prior art keywords
- castor
- cutting fluid
- alloy steel
- steel cutting
- hardness alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002173 cutting fluid Substances 0.000 title claims abstract description 24
- 229910000851 Alloy steel Inorganic materials 0.000 title claims abstract description 22
- 235000004443 Ricinus communis Nutrition 0.000 title claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000004359 castor oil Substances 0.000 claims abstract description 9
- 235000019438 castor oil Nutrition 0.000 claims abstract description 9
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 9
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 9
- 239000002199 base oil Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000654 additive Substances 0.000 claims abstract description 3
- 239000002131 composite material Substances 0.000 claims abstract description 3
- 239000008367 deionised water Substances 0.000 claims abstract description 3
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 3
- 240000000528 Ricinus communis Species 0.000 claims description 15
- 230000007613 environmental effect Effects 0.000 claims description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 9
- 229960001777 castor oil Drugs 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- -1 polyoxyethylene Polymers 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- SNCZNSNPXMPCGN-UHFFFAOYSA-N butanediamide Chemical compound NC(=O)CCC(N)=O SNCZNSNPXMPCGN-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 4
- 238000001816 cooling Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000013556 antirust agent Substances 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000007957 coemulsifier Substances 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910001060 Gray iron Inorganic materials 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 238000005555 metalworking Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 229910000806 Latten Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention relates to a castor-based environmental-friendly high-hardness alloy steel cutting fluid. Hydrogenated castor oil is used as base oil, and is matched with a plurality of composite additives. The castor-based environment-friendly high-hardness alloy steel cutting fluid comprises a surfactant, an emulgator, an antiwear agent, an extreme pressure agent, a defoaming agent, an antirust agent, a co-emulsifier, a bactericide and deionized water. The castor-based environment-friendly high-hardness alloy steel cutting fluid has the good lubricating, cooling, cleaning and rust prevention effects, can improve the durability of cutters, guarantees the processing quality and precision, improves the production efficiency, reduces the use cost, has good biological degradability, reduces environmental pollution, and is applicable to the processing of high-hardness metal steel.
Description
Technical field
The invention belongs to metal working lubricant, particularly castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid field.
Background technology
High hardness alloy steel cutting fluid is the important supplementary material of high hardness alloy steel machining.In high hardness alloy steel machining, select to have the cutting fluid of good lubricated, cooling, cleaning and rustless property, tool life be can improve, and processing quality and precision guaranteed, enhance productivity, reduction use cost.Yet, along with being widely used of metal working fluid, find that cutting fluid is the primary pollution source of metal cutting processing; Can be to operator's healthy formation harm during except use, the discharge of waste liquid also can cause severe contamination to environment.The security of cutting fluid and the impact on environment, become the major issue that must consider in cutting fluid research and development and use.Therefore, research and development castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid is exactly the requirement that is applicable to this development trend.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of have good lubricated, cooling, cleaning and the effect such as antirust, thereby raising tool life, guarantee processing quality and precision, enhance productivity, reduce use cost, and there is good biological degradability, reduce the castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid of environmental pollution.
The present invention is usingd following technical scheme and is solved the problems of the technologies described above: adopt hydrogenated castor oil as base oil, coordinate multiple composite additive, its each component and mass percent are:
| Component | Content (mass percent) |
| Base oil | 10%～25% |
| Tensio-active agent | 3.0%～5.0% |
| Emulsifying agent | 3.0%～5.0% |
| Anti-wear agent | 3.0%～4.0% |
| Extreme pressure agent | 3.0%～5.0% |
| Rust-preventive agent | 2.0%～4.0% |
| Assistant for emulsifying agent | 1.0%～2.0% |
| Sterilant | 0.1%～0.3% |
| Defoamer | 0.001%～0.01% |
| Water | Surplus |
Base oil is hydrogenated castor oil;
Tensio-active agent is C
8～C
10alkyl-glucoside.
Emulsifying agent is castor oil polyoxyethylene (24) ether.
Anti-wear agent is polyether ester.
Extreme pressure agent is that borate and 50%～60% the alkylphosphonic of mass ratio 50%～40% is compound.
Rust-preventive agent is amine carboxylic acid.
Assistant for emulsifying agent is polyisobutene succinamide.
Sterilant is the Isosorbide-5-Nitrae-morpholine of mass ratio 50%～40% and 50%～60% n-butyl-1, and 2-isothiazoline-3-ketone is compound.
Defoamer is acrylate and ether copolymer.
Castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid of the present invention, has good lubricated, cooling, cleaning and the effect such as antirust, can improve tool life, guarantees processing quality and precision, enhances productivity, and reduces use cost; And there is good biological degradability, reduce environmental pollution; Be applicable to the metallic steel of processing high-hardness.
Embodiment
Embodiment 1:
Following component is in harmonious proportion and is formed by mass percentage:
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion and is formed by mass percentage:
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| Hydrogenated castor oil | 20% |
| C 8～C 10Alkyl-glucoside | 4.0% |
| Castor oil polyoxyethylene (24) ether | 4.0% |
| Polyether ester | 3.5% |
| The borate of mass ratio 45% and 55% alkylphosphonic are compound | 4.0% |
| Amine carboxylic acid | 3.0% |
| Polyisobutene succinamide | 1.54% |
| Isosorbide-5-Nitrae-the morpholine of mass ratio 50% and 50% n-butyl-1,2-isothiazoline-3-ketone | 0.155% |
| Compound | ? |
| Acrylate and ether copolymer | 0.005% |
| Deionized water | 59.8% |
Above component summation is 100%.
The typical physical and chemical index of embodiment 3 products is:
| Project | Quality index |
| 40 ℃ of kinematic viscosity/(mm 2﹒s -1) | 29.5 |
| Viscosity index | 196 |
| Pour point/℃ | -30 |
| Flash-point (opening)/℃ | 232 |
| Mechanical impurity (m)/% | Nothing |
| Moisture (m)/% | Vestige |
| 5% diluent pH value | 9.0～11.0 |
| 5% diluent defoaming (standing 10min)/mL | 0 |
| Corrosion test (copper sheet, 100 ℃, 3h), level | 1 |
| Rust prevention test (35 ℃ ± 2 ℃), one-level grey cast iron monolithic (24h) | A level |
| 5% diluent corrosion test (entirely soaking 35 ℃ ± 2 ℃), one-level grey cast iron (24h) | A level |
| T 3Copper sheet (24h) | A level |
| H 62Number latten(-tin) (24h) | A level |
| 5% diluent P BValue/N | 1005 |
Claims (10)
1. a castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid, is characterized in that adopting hydrogenated castor oil as base oil, coordinates multiple composite additive, and its each component and mass percent are:
2. castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid as claimed in claim 1, is characterized in that base oil is hydrogenated castor oil.
3. castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid as claimed in claim 1, is characterized in that tensio-active agent is C
8～C
10alkyl-glucoside.
4. castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid as claimed in claim 1, is characterized in that emulsifying agent is castor oil polyoxyethylene (24) ether.
5. castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid as claimed in claim 1, is characterized in that anti-wear agent is polyether ester.
6. castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid as claimed in claim 1, is characterized in that extreme pressure agent is that borate and 50%～60% the alkylphosphonic of mass ratio 50%～40% is compound.
7. castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid as claimed in claim 1, is characterized in that rust-preventive agent is amine carboxylic acid.
8. castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid as claimed in claim 1, is characterized in that assistant for emulsifying agent is polyisobutene succinamide.
9. castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid as claimed in claim 1, is characterized in that sterilant is the Isosorbide-5-Nitrae-morpholine of mass ratio 50%～40% and 50%～60% n-butyl-1, and 2-isothiazoline-3-ketone is compound.
10. castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid as claimed in claim 1, is characterized in that defoamer is acrylate and ether copolymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310682271.5A CN103725399B (en) | 2013-12-14 | 2013-12-14 | Castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310682271.5A CN103725399B (en) | 2013-12-14 | 2013-12-14 | Castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103725399A true CN103725399A (en) | 2014-04-16 |
| CN103725399B CN103725399B (en) | 2015-10-07 |
Family
ID=50449699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310682271.5A Expired - Fee Related CN103725399B (en) | 2013-12-14 | 2013-12-14 | Castor-oil plant base environmental friendliness high hardness alloy steel cutting fluid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103725399B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359522A (en) * | 2018-02-05 | 2018-08-03 | 镇江艾润润滑油有限公司 | A kind of Biostatic type metal working fluid and preparation method thereof |
| CN113501685A (en) * | 2021-07-28 | 2021-10-15 | 太原鸿鑫景泰建材有限公司 | Sulfate and chloride corrosion resistant recycled concrete and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050245403A1 (en) * | 2004-05-03 | 2005-11-03 | Harris Charles P | Gear cutting oil |
| CN103103013A (en) * | 2011-11-11 | 2013-05-15 | 沈阳创达技术交易市场有限公司 | Environmentally-friendly cutting fluid |
-
2013
- 2013-12-14 CN CN201310682271.5A patent/CN103725399B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050245403A1 (en) * | 2004-05-03 | 2005-11-03 | Harris Charles P | Gear cutting oil |
| CN103103013A (en) * | 2011-11-11 | 2013-05-15 | 沈阳创达技术交易市场有限公司 | Environmentally-friendly cutting fluid |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359522A (en) * | 2018-02-05 | 2018-08-03 | 镇江艾润润滑油有限公司 | A kind of Biostatic type metal working fluid and preparation method thereof |
| CN113501685A (en) * | 2021-07-28 | 2021-10-15 | 太原鸿鑫景泰建材有限公司 | Sulfate and chloride corrosion resistant recycled concrete and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103725399B (en) | 2015-10-07 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151007 |
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| CF01 | Termination of patent right due to non-payment of annual fee |