CN103725039A - Formula of reactive dye - Google Patents

Formula of reactive dye Download PDF

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Publication number
CN103725039A
CN103725039A CN201310702371.XA CN201310702371A CN103725039A CN 103725039 A CN103725039 A CN 103725039A CN 201310702371 A CN201310702371 A CN 201310702371A CN 103725039 A CN103725039 A CN 103725039A
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China
Prior art keywords
parts
sodium
dye
reactive dyestuffs
type
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CN201310702371.XA
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Chinese (zh)
Inventor
蔡洛波
郑春涛
苏创钊
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GUANGDONG JINCHAO GROUP CO Ltd
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GUANGDONG JINCHAO GROUP CO Ltd
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Priority to CN201310702371.XA priority Critical patent/CN103725039A/en
Publication of CN103725039A publication Critical patent/CN103725039A/en
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Abstract

The invention relates to a formula of reactive dye, and belongs to the technical field of printing dye. The formula comprises the following constituents in parts by weight: 20 to 40 parts of 2,4-difluoro-5-chloropyrimidine dye, 30 to 50 parts of vinyl sulfone dye, 20 to 40 parts of alpha-bromo-acrylic amide dye, 1 to 8 parts of dye leveller peregal O, 1 to 10 parts of sodium sulfate, 1 to 10 parts of sodium chloride, 2 to 8 parts of disodium hydrogen phosphate, 10 to 20 parts of sodium dihydrogen phosphate, 5 to 15 parts of sodium hydroxide, 1 to 20 parts of sodium carbonate, and 5 to 15 parts of urea. The dye has relatively high fastness and wet fastness, bright color, excellent performance and high applicability, and both the color and the performance of the dye can meet the requirements on fiber and apparel fabric by the market.

Description

A kind of formula of reactive dyestuffs
Technical field
The present invention relates to a kind of formula of reactive dyestuffs, be specifically related to a kind of fastness, wet fastness is higher, bright in colour, excellent performance, suitability is strong, its form and aspect and performance all can adapt to the reactive dyestuffs of market to fiber and dress material requirement, belong to printing dye technical field.
Background technology
China's textile industry year water loss exceedes 10,000,000,000 tons, and wastewater discharge accounts for the 6th of national every profession and trade, wherein serious with dyeing waste discharge amount, accounts for 80%, and water consumption is external 2-3 times by unit weight textiles.Dyeing and finishing processing is to carry out under comparatively high temps mostly, and energy consumption is large, and unit consumption is external 3-5 times.Energy-saving and emission-reduction are important policies that country formulates, and how energy-saving and emission-reduction being implemented is textile printing and dyeing and common responsibility and the mission of two industries of DYE PRODUCTION.
Reactive dyestuffs are topmost dyestuffs that cellulose dyeing is used, because chromatogram broadness, lovely luster, excellent performance, suitability are strong, and therefore and widely application.Approximately 250,000 tons of world's reactive dyestuffs year outputs, account for 20% left and right of dyestuff total amount.Approximately 160,000 tons of China's reactive dyestuffs annual production 2005,2006 17. 4 ten thousand tons, account for 25% of China's dyestuff ultimate production.Since reactive dyestuffs in 1956 come out, through 50 years develop rapidly, progressively replace glacial dye, substantive dyestuff, thioxine dyes and vat dyes, become the main raw material of cellulosic fibre (comprising cotton, artificial silk, flax, copper amine fiber and cellulosic short fiber cloth) printing and dyeing.
Why Modem Reactive Dyestuffs is so made a pet of, and mainly contains following five reasons:
(1) reactive dyestuffs are one of optimal selections that replace forbidding dyestuff and other Dyestuffs Used for Cellulose Fibres (as glacial dye, thioxine dyes and vat dyes etc.);
(2) reactive dyestuffs are one of optimal selections that replace wool and poly-phthalein amine metalliferous dye (as mordanting dye, metallized dye etc.) for fiber;
(3) reactive dyeing process economy, simple to operate, and every fastness particularly wet fastness is higher;
(4) wide, the lovely luster of reactive dyestuffs chromatogram, excellent performance, suitability are strong, and its form and aspect and performance adapt to the requirement of market to fiber and dress material substantially;
(5) be applicable to the printing and dyeing needs of new cellulose fiber product (as Lyocell fiber etc.).
China Patent Publication No.: CN1704524 discloses a kind of cloth dyeing technology, specifically, relates to operation sequence simple, and cost is moderate, not only can dye grey cloth, also coloured printcloth can be dyeed again, and the cloth dyeing technology of a kind of capable of re-dyeing not fading.But this dyestuff of dying cloth is not used in reactive dyestuffs, therefore, develops a kind of reactive dyestuffs and be of great significance.
The present invention adopts difluoro one chloropyrimide type dye, Vinyl-Sulfone Type dyestuff, alpha-brominated acid/acrylic amide type reactive dyestuffs, dye leveller paregal O, sodium sulfate, sodium-chlor, Sodium phosphate dibasic, SODIUM PHOSPHATE, MONOBASIC, sodium hydroxide, sodium carbonate, urea is prepared a kind of reactive dyestuffs, and this dyestuff patent has not yet to see report at home.
Summary of the invention
The object of this invention is to provide a kind of fastness, wet fastness is higher, bright in colour, excellent performance, suitability is strong, its form and aspect and performance all can adapt to the dyestuff of market to fiber and dress material requirement.
In order to address the above problem, the technical solution adopted in the present invention is:
A formula for reactive dyestuffs, its each component consists of:
Difluoro one chloropyrimide type dye 20-40 part, Vinyl-Sulfone Type dyestuff 30-50 part, alpha-brominated acid/acrylic amide type reactive dyestuffs 20-40 part, dye leveller paregal O 1-8 part, sodium sulfate 1-10 part, sodium-chlor 1-10 part, Sodium phosphate dibasic 2-8 part, SODIUM PHOSPHATE, MONOBASIC 10-20 part, sodium hydroxide 5-15 part, sodium carbonate 1-20 part, urea 5-15 part.
A formula for reactive dyestuffs, its each component consists of:
Difluoro one chloropyrimide type dye 20-30 part, Vinyl-Sulfone Type dyestuff 30-40 part, alpha-brominated acid/acrylic amide type reactive dyestuffs 20-30 part, dye leveller paregal O 1-5 part, sodium sulfate 1-5 part, sodium-chlor 1-5 part, Sodium phosphate dibasic 4-8 part, SODIUM PHOSPHATE, MONOBASIC 15-20 part, sodium hydroxide 10-15 part, sodium carbonate 10-20 part, urea 10-15 part.
A formula for reactive dyestuffs, its each component consists of:
Difluoro one chloropyrimide type dye 20-25 part, Vinyl-Sulfone Type dyestuff 30-35 part, alpha-brominated acid/acrylic amide type reactive dyestuffs 20-25 part, dye leveller paregal O 1-3 part, sodium sulfate 1-3 part, sodium-chlor 1-3 part, Sodium phosphate dibasic 6-8 part, SODIUM PHOSPHATE, MONOBASIC 17-20 part, sodium hydroxide 12-15 part, sodium carbonate 15-20 part, urea 13-15 part.
A formula for reactive dyestuffs, its each component consists of:
21 parts of difluoro one chloropyrimide type dyes, 32 parts of Vinyl-Sulfone Type dyestuffs, 22 parts of alpha-brominated acid/acrylic amide type reactive dyestuffs, 1 part of dye leveller paregal O, 2 parts, sodium sulfate, 2 parts, sodium-chlor, 6 parts of Sodium phosphate dibasics, 18 parts of SODIUM PHOSPHATE, MONOBASIC, 13 parts, sodium hydroxide, 17 parts, sodium carbonate, 13 parts, urea.
A formula for reactive dyestuffs, its each component consists of:
25 parts of difluoro one chloropyrimide type dyes, 35 parts of Vinyl-Sulfone Type dyestuffs, 20 parts of alpha-brominated acid/acrylic amide type reactive dyestuffs, 3 parts of dye leveller paregal Os, 3 parts, sodium sulfate, 3 parts, sodium-chlor, 8 parts of Sodium phosphate dibasics, 19 parts of SODIUM PHOSPHATE, MONOBASIC, 15 parts, sodium hydroxide, 20 parts, sodium carbonate, 15 parts, urea.
Above-mentioned dyestuff is applicable to the cloth dyeing of soybean fibers.
The present invention with respect to the beneficial effect of prior art is:
Reactive dyestuffs of the present invention are that a kind of fastness, wet fastness are higher, bright in colour, excellent performance, and suitability is strong, and its form and aspect and performance all can adapt to the dyestuff of market to fiber and dress material requirement.
Embodiment
Below by embodiment, the present invention is described in further details, these embodiment are only used for illustrating the present invention, do not limit the scope of the invention.
Embodiment 1
A formula for reactive dyestuffs, its each component consists of:
21 parts of difluoro one chloropyrimide type dyes, 32 parts of Vinyl-Sulfone Type dyestuffs, 22 parts of alpha-brominated acid/acrylic amide type reactive dyestuffs, 1 part of dye leveller paregal O, 2 parts, sodium sulfate, 2 parts, sodium-chlor, 6 parts of Sodium phosphate dibasics, 18 parts of SODIUM PHOSPHATE, MONOBASIC, 13 parts, sodium hydroxide, 17 parts, sodium carbonate, 13 parts, urea.
Embodiment 2
A formula for reactive dyestuffs, its each component consists of:
25 parts of difluoro one chloropyrimide type dyes, 35 parts of Vinyl-Sulfone Type dyestuffs, 20 parts of alpha-brominated acid/acrylic amide type reactive dyestuffs, 3 parts of dye leveller paregal Os, 3 parts, sodium sulfate, 3 parts, sodium-chlor, 8 parts of Sodium phosphate dibasics, 19 parts of SODIUM PHOSPHATE, MONOBASIC, 15 parts, sodium hydroxide, 20 parts, sodium carbonate, 15 parts, urea.
Embodiment 3
A formula for reactive dyestuffs, its each component consists of:
35 parts of difluoro one chloropyrimide type dyes, 45 parts of Vinyl-Sulfone Type dyestuffs, 35 parts of alpha-brominated acid/acrylic amide type reactive dyestuffs, 6 parts of dye leveller paregal Os, 9 parts, sodium sulfate, 9 parts, sodium-chlor, 7 parts of Sodium phosphate dibasics, 18 parts of SODIUM PHOSPHATE, MONOBASIC, 13 parts, sodium hydroxide, 15 parts, sodium carbonate, 13 parts, urea.
Embodiment 4
A formula for reactive dyestuffs, its each component consists of:
38 parts of difluoro one chloropyrimide type dyes, 48 parts of Vinyl-Sulfone Type dyestuffs, 35 parts of alpha-brominated acid/acrylic amide type reactive dyestuffs, 6 parts of dye leveller paregal Os, 8 parts, sodium sulfate, 8 parts, sodium-chlor, 5 parts of Sodium phosphate dibasics, 15 parts of SODIUM PHOSPHATE, MONOBASIC, 12 parts, sodium hydroxide, 15 parts, sodium carbonate, 10 parts, urea.
Embodiment 5
A formula for reactive dyestuffs, its each component consists of:
35 parts of difluoro one chloropyrimide type dyes, 45 parts of Vinyl-Sulfone Type dyestuffs, 35 parts of alpha-brominated acid/acrylic amide type reactive dyestuffs, 6 parts of dye leveller paregal Os, 6 parts, sodium sulfate, 7 parts, sodium-chlor, 6 parts of Sodium phosphate dibasics, 15 parts of SODIUM PHOSPHATE, MONOBASIC, 11 parts, sodium hydroxide, 10 parts, sodium carbonate, 8 parts, urea.

Claims (6)

1. a formula for reactive dyestuffs, is characterized in that: the weight part of each component is:
Difluoro one chloropyrimide type dye 20-40 part, Vinyl-Sulfone Type dyestuff 30-50 part, alpha-brominated acid/acrylic amide type reactive dyestuffs 20-40 part, dye leveller paregal O 1-8 part, sodium sulfate 1-10 part, sodium-chlor 1-10 part, Sodium phosphate dibasic 2-8 part, SODIUM PHOSPHATE, MONOBASIC 10-20 part, sodium hydroxide 5-15 part, sodium carbonate 1-20 part, urea 5-15 part.
2. a formula for reactive dyestuffs, is characterized in that: the weight part of each component is:
Difluoro one chloropyrimide type dye 20-30 part, Vinyl-Sulfone Type dyestuff 30-40 part, alpha-brominated acid/acrylic amide type reactive dyestuffs 20-30 part, dye leveller paregal O 1-5 part, sodium sulfate 1-5 part, sodium-chlor 1-5 part, Sodium phosphate dibasic 4-8 part, SODIUM PHOSPHATE, MONOBASIC 15-20 part, sodium hydroxide 10-15 part, sodium carbonate 10-20 part, urea 10-15 part.
3. a formula for reactive dyestuffs, is characterized in that: the weight part of each component is:
Difluoro one chloropyrimide type dye 20-25 part, Vinyl-Sulfone Type dyestuff 30-35 part, alpha-brominated acid/acrylic amide type reactive dyestuffs 20-25 part, dye leveller paregal O 1-3 part, sodium sulfate 1-3 part, sodium-chlor 1-3 part, Sodium phosphate dibasic 6-8 part, SODIUM PHOSPHATE, MONOBASIC 17-20 part, sodium hydroxide 12-15 part, sodium carbonate 15-20 part, urea 13-15 part.
4. a formula for reactive dyestuffs, is characterized in that: the weight part of each component is:
21 parts of difluoro one chloropyrimide type dyes, 32 parts of Vinyl-Sulfone Type dyestuffs, 22 parts of alpha-brominated acid/acrylic amide type reactive dyestuffs, 1 part of dye leveller paregal O, 2 parts, sodium sulfate, 2 parts, sodium-chlor, 6 parts of Sodium phosphate dibasics, 18 parts of SODIUM PHOSPHATE, MONOBASIC, 13 parts, sodium hydroxide, 17 parts, sodium carbonate, 13 parts, urea.
5. a formula for reactive dyestuffs, is characterized in that: the weight part of each component is:
25 parts of difluoro one chloropyrimide type dyes, 35 parts of Vinyl-Sulfone Type dyestuffs, 20 parts of alpha-brominated acid/acrylic amide type reactive dyestuffs, 3 parts of dye leveller paregal Os, 3 parts, sodium sulfate, 3 parts, sodium-chlor, 8 parts of Sodium phosphate dibasics, 19 parts of SODIUM PHOSPHATE, MONOBASIC, 15 parts, sodium hydroxide, 20 parts, sodium carbonate, 15 parts, urea.
6. according to the formula of a kind of reactive dyestuffs described in claim 1 to 5 any one, it is characterized in that: this dyestuff is applicable to the cloth dyeing of soybean fibers.
CN201310702371.XA 2013-12-19 2013-12-19 Formula of reactive dye Pending CN103725039A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105200825A (en) * 2015-09-25 2015-12-30 桐乡市新艺虹电气有限公司 Linen fabric dyeing and coloring auxiliary
CN105603776A (en) * 2015-10-30 2016-05-25 无锡市长安曙光手套厂 Formula of reactive dye
CN105968876A (en) * 2016-06-30 2016-09-28 叶文佳 Compound type reactive dye formula
CN107022203A (en) * 2017-05-09 2017-08-08 南通薇星纺织科技有限公司 A kind of compound reactive dye formula for fiber cloth
CN107044056A (en) * 2017-05-09 2017-08-15 南通薇星纺织科技有限公司 A kind of compound reactive dye formula for home textile cloth
CN108193515A (en) * 2018-01-30 2018-06-22 江苏华艺服饰有限公司 One kind hangs dye dye formulation
CN108252123A (en) * 2018-01-30 2018-07-06 江苏华艺服饰有限公司 One kind hangs dye diffusible dyess formula
CN108265536A (en) * 2018-01-30 2018-07-10 江苏华艺服饰有限公司 A kind of activity hangs dye dye formulation
CN109137563A (en) * 2018-07-20 2019-01-04 启东市新利来制衣有限公司 A kind of reactive dye formula for being not easy to fade
CN109440495A (en) * 2018-10-22 2019-03-08 徐州双辰服饰有限公司 A kind of formula of garment panel

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105200825A (en) * 2015-09-25 2015-12-30 桐乡市新艺虹电气有限公司 Linen fabric dyeing and coloring auxiliary
CN105603776A (en) * 2015-10-30 2016-05-25 无锡市长安曙光手套厂 Formula of reactive dye
CN105968876A (en) * 2016-06-30 2016-09-28 叶文佳 Compound type reactive dye formula
CN107022203A (en) * 2017-05-09 2017-08-08 南通薇星纺织科技有限公司 A kind of compound reactive dye formula for fiber cloth
CN107044056A (en) * 2017-05-09 2017-08-15 南通薇星纺织科技有限公司 A kind of compound reactive dye formula for home textile cloth
CN108193515A (en) * 2018-01-30 2018-06-22 江苏华艺服饰有限公司 One kind hangs dye dye formulation
CN108252123A (en) * 2018-01-30 2018-07-06 江苏华艺服饰有限公司 One kind hangs dye diffusible dyess formula
CN108265536A (en) * 2018-01-30 2018-07-10 江苏华艺服饰有限公司 A kind of activity hangs dye dye formulation
CN109137563A (en) * 2018-07-20 2019-01-04 启东市新利来制衣有限公司 A kind of reactive dye formula for being not easy to fade
CN109440495A (en) * 2018-10-22 2019-03-08 徐州双辰服饰有限公司 A kind of formula of garment panel

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Application publication date: 20140416