CN103719130A - Corn field efficacy enhancement weed killing combination containing thiencarbazone-methyl, mesotrione and atrazine - Google Patents
Corn field efficacy enhancement weed killing combination containing thiencarbazone-methyl, mesotrione and atrazine Download PDFInfo
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- CN103719130A CN103719130A CN201310691313.1A CN201310691313A CN103719130A CN 103719130 A CN103719130 A CN 103719130A CN 201310691313 A CN201310691313 A CN 201310691313A CN 103719130 A CN103719130 A CN 103719130A
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- thiophene ketone
- ketone sulphur
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Abstract
The invention discloses a corn field efficacy enhancement weed killing combination containing thiencarbazone-methyl, mesotrione and atrazine. According to the combination, the weight ratio of thiencarbazone-methyl, mesotrione to atrazine is 1:1 to 15:20 to 100. By performing ternary compounding to thiencarbazone-methyl, mesotrione and atrazine, the obtained novel combination can effectively solve the defect when thiencarbazone-methyl or mesotrione is singly adopted, enlarges the herbicide controlling spectrum to weeds, can basically solve corn field weeds when applied one time, saves labor and time, and meanwhile has certain effects on increasing both production and income of corn. In addition, the usage dosage of pesticide is reduced, the adverse effect on ecological environment by pesticide is lowered, and the generation of drug resistance is delayed.
Description
Technical field
The present invention relates to a kind of composition pesticide, a kind ofly specifically contain that thiophene ketone sulphur is grand, the corn field Herbicidal synergistic ternary recompounded composite of mesotrione and atrazine.
Background technology
Thiophene ketone sulphur is grand, chemical name: methyl 4-[(4,5-dihydro-3-methoxyl group-4-methyl-5-oxo-1H-1,2,4-triazol-1-yl) carbonyl sulfonamide]-5-methylthiophene-3-carboxylic acid, ethyl ester, structural formula is:
This weed killer herbicide is interior absorption medicament, can cross root and leaf absorption, has and tags and residual herbicidal effect, can effectively prevent and kill off corn field grassy weed and broad leaved weed.
Mesotrione, has another name called mesotrione, chemical name: 2-(4-mesyl 2-nitro-benzoyl) thiacyclohexane-1,3-diketone, structural formula is:
This weed killer herbicide is corn field Common Herbicides, with its broad weed-killing spectrum, active high, miscibilty strong, to succession crop safety, use flexibly, Environmental compatibility is strong etc., and feature has compared with great development and is worth and promotes the use of preferably prospect in China.
Atrazine, has another name called atrazine, is corn field Common Herbicides, to corn safety, for soil treatment before bud, can effectively prevent and kill off multiple corn field weed.
The present invention is grand to thiophene ketone sulphur, the mixture of mesotrione and atrazine conducts in-depth research, on the basis of formula indoor screening test and field medicine effect test, find that thiophene ketone sulphur is grand, mesotrione and atrazine show obvious synergistic effect to corn field weed within the scope of certain mixed ratio.Thiophene ketone sulphur is grand, the mixture of mesotrione and atrazine and the invention in corn field application there is no report at present both at home and abroad.
Summary of the invention
The object of the invention has been to provide a kind of synergistic herbicidal compositions, said composition is undertaken composite by grand thiophene ketone sulphur, mesotrione and atrazine, can disposablely prevent and kill off weeds all between corn field, expand that thiophene ketone sulphur is grand, the restriction of mesotrione or atrazine herbicide spectrum separately, improve that thiophene ketone sulphur is grand, mesotrione and the herbicide speed of atrazine to grass family, broad-leaved section weeds.The discovery that the present invention is surprised, the new compositions obtaining has been obtained gain effect on the malignant weed of control of maize field, significantly reduces the amount of the required active component of control of weeds, and the safety to crop.
Be below the technical solution used in the present invention:
The invention provides a kind ofly contain that thiophene ketone sulphur is grand, the corn field Synergistic herbicide compositions of mesotrione and atrazine, it is characterized in that: comprise that three kinds of effective ingredient thiophene ketone sulphur is grand, mesotrione and atrazine, thiophene ketone sulphur is grand, mesotrione and the ratio of weight and number of atrazine in composition are 1~100:1~100:1~100, preferred weight portion rate is 1:1~15:20~100, and particularly preferably ratio of weight and number is 1:1~15:20~60.
Said herbicidal composition adds various auxiliary materials, auxiliary agent according to conventional method, can be processed into following formulation: wetting powder, oil suspending agent, water dispersible granules, aqueous suspension agent, effervescent agent or all passable formulations well known in the art.
Described Herbicidal combinations also contains acceptable insecticides adjuvant in the required agricultural of preparation pesticidal preparations, be selected from one or more in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, bleeding agent, thickener, defoamer, antifreezing agent, disintegrant, binding agent, filler, carrier, medium, surfactant, be known substance, various auxiliary agents conventional in pesticidal preparations, according to different situations, can change to some extent, be not particularly limited.
Take wetting powder as example, can in composition components, add dispersant, wetting agent, filler to implement.Wherein said dispersant is a kind of or any several combination in the conventional dispersant in lignosulfonates, NNO, MF, polyethers and this area; Described wetting agent is a kind of or any several combination in the conventional wetting agent in K12, AEO, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether and sulphate (or phosphoric acid fat) thereof and this area.Described filler is a kind of or any several combination in kaolin, bentonite, diatomite, white carbon, precipitated calcium carbonate, attapulgite.Collocation method is, each active component, dispersant, wetting agent, other filler are dropped in mixing kettle and stirred, then the material mixing is crossed to airslide disintegrating mill, and then stir through mixing kettle, fineness is crossed 325 mesh sieves, packing after indices detection is qualified, obtains Herbicidal combinations wetting powder of the present invention.
Herbicidal combinations provided by the invention, adopts the method for directed spraying to use conventionally, also can adopt as required other operation techniques of the upper application of agricultural.
Creativeness of the present invention and novelty are embodied in:
1, Herbicidal combinations provided by the invention, in certain ratio range, show obvious synergistic effect, the control efficiency of composition is significantly improved than single dose, reduced the using dosage of agricultural chemicals, reduced medication number of times, reduce drug cost, reduced the adverse effect of agricultural chemicals to ecotope.
2, Herbicidal combinations provided by the invention, the combination of three kinds of effective ingredients, has expanded herbicidal spectrum, and a drug can solve various weeds problems, has made up defect and limitation when single dose is used.
3, Herbicidal combinations provided by the invention, three kinds of effective ingredient mechanism of action are different, can overcome long-term single use and easily produce the shortcoming of resistance, extend the service life of medicament, to the comprehensive regulation important in inhibiting of Weed Resistance.
4, Herbicidal combinations provided by the invention, rapidly, the lasting period is long in drug effect performance, and use cost is low, easy to use, time saving and energy saving, and it applies huge economic benefit and social benefit.
Embodiment
The present invention describes as an example of following example example, but does not limit the present invention.Each preparation case study on implementation is corresponding with biological case study on implementation.
example of formulations
1: 35% thiophene ketone sulphur of example of formulations is grand. mesotrione. and atrazine (1:5:29) wetting powder
Successively grand 10 grams of thiophene ketone sulphur, 50 grams of mesotriones, 290 grams of atrazines, 30 grams of NNO, 50 grams of sodium lignin sulfonates, 20 grams of white carbons, 550 grams of kaolin are dropped in blenders, stirring makes mixing of materials even in 30 minutes, then cross airslide disintegrating mill, fineness of materials is crossed 325 mesh sieves.And then in blender, material is carried out to mix and blend, and obtain 35% thiophene ketone sulphur grand. mesotrione. atrazine (1:5:29) wetting powder.
2: 22.5% thiophene ketone sulphur of example of formulations is grand. mesotrione. and atrazine (1:1.5:20) oil-suspending agent
635 grams of soybean oils in suction container, 60 grams of NONYL PHENOL POLYOXYETHYLENEs, 50 grams of castor oil polyoxyethylene ethers, 50 grams of calcium dodecyl benzene sulfonates are added in container, then add while stirring that 10 grams of thiophene ketone sulphur is grand, 15 grams of mesotriones, 200 grams of atrazines, 30 grams of white carbons.Then high speed shear makes mixing of materials even in 30 minutes.Open cycle water control sand mill below 40 degree, material is through sand milling, and fineness is crossed 325 mesh sieves, obtains 22.5% thiophene ketone sulphur grand. mesotrione. and atrazine (1:1.5:20) oil-suspending agent.
3: 45% thiophene ketone sulphur of example of formulations is grand. mesotrione. and atrazine (2:3:40) water dispersible granules
Successively grand 20 grams of thiophene ketone sulphur, 30 grams of mesotriones, 400 grams of atrazines, 40 grams of naphthalenesulfonate formaldehyde condensation compounds, 50 grams of calcium lignosulfonates, 20 grams of K12,20 grams of sodium sulphate, 20 grams of polyethylene glycol, 400 grams of kaolin are dropped in blenders, stirring makes mixing of materials even in 30 minutes, then cross airslide disintegrating mill, fineness of materials is crossed 325 mesh sieves.Add 100 milliliters of left and right of water to be mixed into wet feed, wet method is made 20 order grains, dries 2 hours, after oven dry in pallet in hot-air oven at about 45 ℃, after the whole grain of 18 mesh sieves, both obtained 45% thiophene ketone sulphur grand. mesotrione. atrazine (2:3:40) water dispersible granules.
4: 25% thiophene ketone sulphur of example of formulations is grand. mesotrione. and atrazine (0.5:5.5:19) aqueous suspension agent
670 grams of deionized waters in suction container, 60 grams of polystyrene phenol polyoxyethylene phosphonates, 20 ethylene glycol are added in container, then add while stirring that 20 grams of thiophene ketone sulphur is grand, 20 grams of mesotriones, 180 grams of atrazines, 25 grams of aluminium-magnesium silicates, 5 grams of xanthans, high speed shear makes mixing of materials even in 30 minutes.Open cycle water control sand mill below 40 degree, material is through sand milling, and fineness is crossed 325 mesh sieves, obtains 25% thiophene ketone sulphur grand. mesotrione. and atrazine (0.5:5.5:19) aqueous suspension agent.
5: 25% thiophene ketone sulphur of example of formulations is grand. mesotrione. and atrazine (0.5:4.5:20) effervescent agent
Successively grand 5 grams of thiophene ketone sulphur, 45 grams of mesotriones, 200 grams of atrazines, 110 grams of lauryl sodium sulfate, 40 grams of wooden sodium sulfonates, 200 grams of citric acids, 250 grams of sodium bicarbonates, 50 grams of kaolin are dropped in blenders, stirring makes mixing of materials even in 30 minutes, then cross airslide disintegrating mill, fineness of materials is crossed 325 mesh sieves.Add 100 milliliters of 10% poly-vinyl alcohol solutions that prepare in advance, wet method is made 20 order grains, being placed in pallet dries 2 hours at about 45 ℃ at hot-air oven, after oven dry, add again 50 grams of dolomols, 50 grams of superfine silica gel powders, mix and with tablet press machine, carry out the whole grain of compressing tablet to obtain 25% thiophene ketone sulphur grand afterwards. mesotrione. and atrazine (0.5:4.5:20) effervescent agent.
biological Examples
When the effect of active compound combinations exceedes the summation of the effect when each reactive compound is used separately, there is synergistic function.The predictive role of the particular combination of three kinds of reactive compounds can be used " Colby formula " (referring to S.R. Colby, " Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 1967,15,20-22) calculate as follows: if
A is the activity when using consumption for mg/ha or the concentration reactive compound A that is mppm;
B is the activity when using consumption for ng/ha or the concentration reactive compound B that is nppm, is expressed as the percentage that accounts for untreated control; C is the activity when using consumption for hg/ha or the concentration reactive compound C that is hppm, is expressed as the percentage that accounts for untreated control; E is to be m when using consumption, n, and h g/ha or concentration are m, n, the reactive compound A of hppm, expection activity when B and C,
(N=3)
If the activity of actual observation (O) is greater than expection active (E), said composition has synergistic effect so.
Inventor is by a large amount of screening tests, the different proportionings of, mesotrione grand to thiophene ketone sulphur and atrazine have carried out test and preventive effect analysis a large amount of, discovery is in certain ratio range, the Herbicidal combinations obtaining has synergistic effect, and be not only the simple addition of three kinds of medicaments, be illustrated with following biologicall test example.
Reagent agent: the grand wetting powder of 30% thiophene ketone sulphur, 15% mesotrione oil-suspending agent, 38% atrazine aqueous suspension agent and preparation 1-5 are company's self-configuring product.
1: 35% thiophene ketone sulphur of preparation is grand. mesotrione. and atrazine (1:5:29) wetting powder
2: 22.5% thiophene ketone sulphur of preparation is grand. mesotrione. and atrazine (1:1.5:20) oil-suspending agent
3: 45% thiophene ketone sulphur of preparation is grand. mesotrione. and atrazine (2:3:40) water dispersible granules
4: 25% thiophene ketone sulphur of preparation is grand. mesotrione. and atrazine (0.5:5.5:19) aqueous suspension agent
5: 25% thiophene ketone sulphur of preparation is grand. mesotrione. and atrazine (0.5:4.5:20) effervescent agent
For trying weeds: lady's-grass, eleusine indica, green foxtail, kitchen garden, piemarker etc.
Implementation method: adopt indoor biometrics method, using every the seed of each weeds 100 as a processing, the wherein integrated treatment of each 20 of the seed of integrating representation lady's-grass, eleusine indica, green foxtail, kitchen garden, piemarker, indoor cultivation, after broadcasting, weeds grow to the processing of spraying of 3-5 leaf phase before seedling or after emerging, observe the victimization state of weeds, and add up test of pesticide effectiveness result.
The control efficiency of table 1 reagent agent to weeds
Analytical table 1 data can be found out: the composite preventive effect of composition, higher than the control efficiency of three corresponding single doses, illustrates that three kinds of compound combinations can improve preventive effect, expand herbicide spectrum.
Above with a general description of the specific embodiments the present invention is described in detail; but on basis of the present invention, can to some modifications of do and improvement, therefore; these modifications and the improvement made without departing from theon the basis of the spirit of the present invention, all belong to the scope of protection of the invention.
Claims (4)
- One kind contain that thiophene ketone sulphur is grand, the corn field Synergistic herbicide compositions of mesotrione and atrazine, it is characterized in that: comprise that three kinds of effective ingredient thiophene ketone sulphur is grand, mesotrione and atrazine, thiophene ketone sulphur is grand, mesotrione and the ratio of weight and number of atrazine in composition are 1:1~15:20~100.
- 2., mesotrione grand according to the thiophene ketone sulphur described in claim 1 and atrazine Herbicidal combinations, is characterized in that: thiophene ketone sulphur is grand, mesotrione and the ratio of weight and number of atrazine in composition are 1:1~15:20~60.
- 3., mesotrione grand according to the thiophene ketone sulphur described in claim 1 and atrazine Herbicidal combinations, is characterized in that: the formulation of described Herbicidal combinations can be the one in wetting powder, water dispersible granules, suspending agent, oil-suspending agent, effervescent agent.
- 4., mesotrione grand according to the thiophene ketone sulphur described in claim 1 or 2 and the application of atrazine Herbicidal combinations in the annual weed of control of maize field.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104522031A (en) * | 2014-12-29 | 2015-04-22 | 陕西上格之路生物科学有限公司 | Thiencarbazone-methyl-containing cornfield herbicidal composition |
CN104738070A (en) * | 2015-03-16 | 2015-07-01 | 广东中迅农科股份有限公司 | Cornfield weeding composite |
CN105010376A (en) * | 2015-04-18 | 2015-11-04 | 广东中迅农科股份有限公司 | Herbicide composition comprising thiencarbazone-methyl, aminopyralid and bromoxynil octanoate |
CN105340939A (en) * | 2015-11-18 | 2016-02-24 | 广东中迅农科股份有限公司 | Corn field weeding composition |
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CN101642125A (en) * | 2009-09-08 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Oil-suspended injection composition containing mesotrione |
CN101642122A (en) * | 2009-07-17 | 2010-02-10 | 陕西上格之路生物科学有限公司 | Herbicide composition |
CN101743988A (en) * | 2010-01-25 | 2010-06-23 | 陕西上格之路生物科学有限公司 | Herbicide composition for corn fields |
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- 2013-12-17 CN CN201310691313.1A patent/CN103719130A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101642122A (en) * | 2009-07-17 | 2010-02-10 | 陕西上格之路生物科学有限公司 | Herbicide composition |
CN101642125A (en) * | 2009-09-08 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Oil-suspended injection composition containing mesotrione |
CN101743988A (en) * | 2010-01-25 | 2010-06-23 | 陕西上格之路生物科学有限公司 | Herbicide composition for corn fields |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104522031A (en) * | 2014-12-29 | 2015-04-22 | 陕西上格之路生物科学有限公司 | Thiencarbazone-methyl-containing cornfield herbicidal composition |
CN104738070A (en) * | 2015-03-16 | 2015-07-01 | 广东中迅农科股份有限公司 | Cornfield weeding composite |
CN104738070B (en) * | 2015-03-16 | 2018-02-06 | 广东中迅农科股份有限公司 | Cornfield weeding composition |
CN105010376A (en) * | 2015-04-18 | 2015-11-04 | 广东中迅农科股份有限公司 | Herbicide composition comprising thiencarbazone-methyl, aminopyralid and bromoxynil octanoate |
CN105340939A (en) * | 2015-11-18 | 2016-02-24 | 广东中迅农科股份有限公司 | Corn field weeding composition |
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Application publication date: 20140416 |