CN103709968A - Improved formula and technology of emulsion-type transfer composite glue - Google Patents
Improved formula and technology of emulsion-type transfer composite glue Download PDFInfo
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- CN103709968A CN103709968A CN201310480118.4A CN201310480118A CN103709968A CN 103709968 A CN103709968 A CN 103709968A CN 201310480118 A CN201310480118 A CN 201310480118A CN 103709968 A CN103709968 A CN 103709968A
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Abstract
The invention mainly discloses an improved formula and a technology of emulsion-type transfer composite glue, the formula comprises water-based acrylic emulsion or butylbenzene latex and water-soluble acrylic resin with a mass ratio of 100:5-20. Specific operation steps are as follows: in a heating reaction kettle, adding the water-soluble acrylic resin while stirring into the water-based acrylic emulsion or the butylbenzene latex while with the stirring speed of 200-750 RPM at the temperature of 50-85 DEG C. The improved formula improves the paper penetrating property, flow and levelling properties of traditional glue, prolongs the glue open time, no particles and agglomeration may be produced, and the white dot occurrence rate in a recombination process may be reduced.
Description
Technical field
The present invention relates to transfer glue and make field, relevant with a kind of a kind of improvement formula and technique of emulsion-type transfer composite glue especially.
Background technology
In vacuum aluminum-coated transferring paper production process, often use water-based and shift composite glue, for the laminating of vacuum transfer film and all kinds of paper, industry class is referred to as transfer film composite glue, is called for short vacuum aluminum-coated transfer glue, or is directly called transfer glue.The aqueous transfer glue water using is at present mainly ACRYLIC EMULSION and styrene-butadiene latex, is traditional water-based emulsion.In the process of using, conventionally there is following problem:
(1) drawknot fastness bad (adhesive tape gluing is peeled off in flakes);
(2) white point (glue produces particle when rotating continuously);
(3) phenomenon such as levelling property is bad.
Tracing it to its cause, is mainly conventional emulsion type transfer glue,
(1) owing to being that latex particle and water can not become homogeneous phase, can not well be penetrated into paper inside along with the volatilization infiltration of water, adhesive fastness is not strong;
(2) the emulsion-type transfer glue open hour generally fall short of, and latex particle long-time continuous in hopper is easily gathered into particle, caking skinning after rotating, and are prone to white point after compound;
(3) emulsion-type transfer glue is owing to being latex particle along with film forming is assembled in the volatilization of water, therefore flow and levelling property not good, it is bad that the vacuum aluminum-coated transferring paper being composited is opened surface finish.
These phenomenons cause the qualification rate of finished product vacuum aluminum-coated transferring paper low, and spoilage is many, and economic benefit is not high.The quality that improves transfer glue has certain actual effect and economic worth.Therefore the technology of the present invention, by formula and process modification to conventional emulsion type transfer glue, improves product quality, has very high practicality and economic worth.
Summary of the invention
The object of this invention is to provide a kind of improvement formula and technique that a kind of emulsion-type shifts composite glue, improve the paper penetrating quality of traditional glue, the mobile and levelling property of glue, extend the open hour of glue, can not play particle from caking, reduce the white point occurring in recombination process.
In order to achieve the above object, technical solution of the present invention is:
Emulsion-type shifts a kind of improvement formula and a technique for composite glue, carries out proportioning, aqueous acrylic emulsion or styrene-butadiene latex: water soluble acrylic resin=100:5～20 according to following prescription quality per-cent; Concrete operation step in reacting by heating still, stirs and adds water soluble acrylic resin in aqueous acrylic emulsion or styrene-butadiene latex; Stirring velocity 200-650 rev/min, temperature 50-85 ℃.
In described whipping process, add emulsifying agent DB-45, defoamer DF-681F.
Described water-borne acrylic resin select that Jiangsu Miki Chemical Co., Ltd produces EA-184.
Described aqueous acrylic emulsion is selected the RS-998A of the rich Chemical Co., Ltd. of Ahmedabad.
Described water-based styrene-butadiene latex is the SD615 that Shanghai Gaoqiao BASF disperses company limited (BASF).
Compared with the prior art the present invention, has the following advantages and positively effect:
1. improve the perviousness of transfer glue, thereby improve the cohesive strength to paper;
2. improve the glue open hour, the glue long period rotates and has been difficult for particle from caking continuously at hopper;
3. flow preferably and flow leveling, the vacuum aluminum-coated transferring paper planeness being composited;
4. thereby improved the qualification rate of vacuum aluminum-coated transferring paper, had certain social value and economic benefit.
Accompanying drawing explanation
Fig. 1 is the design sketch before transfer glue is improved;
Fig. 2 is the schematic diagram of the embodiment of the present invention one;
Fig. 3 is the schematic diagram of the embodiment of the present invention two;
Fig. 4 is the schematic diagram of the embodiment of the present invention three;
Fig. 5 is the schematic diagram of the embodiment of the present invention four.
Embodiment
By reference to the accompanying drawings, preferred embodiment of the present invention is described in further details.
Fig. 1 is the vacuum aluminum-coated transferring paper contrast effect schematic diagram being composited before and after transfer glue is improved, and does not add water soluble acrylic resin, and wherein glue 2 is between vacuum aluminum-coated transfer layer 1 and base stock 3.
Embodiment mono-
For light silver web-like vacuum aluminum-coated transferring paper product, compoiste adhering fastness is less demanding, and rate of drying is fast, and sticky flower loss of gloss requires high product, aqueous acrylic emulsion or styrene-butadiene latex: water soluble acrylic resin=100:5.Concrete operation step: in reacting by heating still, stir and add water soluble acrylic resin in aqueous acrylic emulsion or styrene-butadiene latex; Stirring velocity 200-400 rev/min, temperature 50-65 ℃.In whipping process, add appropriate emulsifying agent DB-45, defoamer DF-681F.Improve shown in rear effect schematic diagram 2.The light silver vacuum aluminum-coated transferring paper (web-like) that for example the red Nanjing of Nanjing Cigarette Factory is used.
Embodiment bis-
For the radium-shine web-like vacuum aluminum-coated transferring paper of partial holography product, compoiste adhering fastness requires general, and rate of drying is fast, and sticky flower loss of gloss requires slightly high; Aqueous acrylic emulsion or styrene-butadiene latex: water soluble acrylic resin=100:10.Concrete operation step: in reacting by heating still, stir and add water soluble acrylic resin in aqueous acrylic emulsion or styrene-butadiene latex; Stirring velocity 300-500 rev/min, temperature 55-70 ℃.In whipping process, add appropriate emulsifying agent DB-45, defoamer DF-681F.Improve shown in rear effect schematic diagram 3.The radium-shine vacuum aluminum-coated transferring paper of partial holography (web-like) that for example Wuhan Cigarette-Making Factory's Yellow Crane Tower Soft Roll is used.
Embodiment tri-
For full version holographic laser web-like vacuum aluminum-coated transferring paper product, compoiste adhering fastness requires general, and rate of drying is general, and sticky flower loss of gloss requires general product, aqueous acrylic emulsion or styrene-butadiene latex: water soluble acrylic resin=100:15.Concrete operation step: in reacting by heating still, stir and add water soluble acrylic resin in aqueous acrylic emulsion or styrene-butadiene latex; Stirring velocity 400-600 rev/min, temperature 60-75 ℃.In whipping process, add appropriate emulsifying agent DB-45, defoamer DF-681F.Improve shown in rear effect schematic diagram 4.The full version holographic laser vacuum aluminum-coated transferring paper (web-like) of classical 100 use of Hongta cigar mill for example.
Embodiment tetra-
For full version holographic laser vacuum aluminum-coated transferring paper sheet product, compoiste adhering fastness is had relatively high expectations, and rate of drying is general, and sticky flower loss of gloss requires lower product, aqueous acrylic emulsion or styrene-butadiene latex: water soluble acrylic resin=100:20.Concrete operation step: in reacting by heating still, stir and add water soluble acrylic resin in aqueous acrylic emulsion or styrene-butadiene latex; Stirring velocity 500-750 rev/min, temperature 65-80 ℃.In whipping process, add appropriate emulsifying agent DB-45, defoamer DF-681F.Improve shown in rear effect schematic diagram 5.The full version holographic laser vacuum aluminum-coated transferring paper (sheet) that for example Changsha Cigarette Factory white sand two substitutes.
Above-described embodiment is only for the inventive concept of the present invention of explaining, but not restriction to rights protection of the present invention, allly utilizes this design to carry out the change of unsubstantiality to the present invention, all should fall into protection scope of the present invention.
Claims (5)
1. emulsion-type shifts a kind of improvement formula and a technique for composite glue, it is characterized in that: according to following prescription quality per-cent, carry out proportioning, aqueous acrylic emulsion or styrene-butadiene latex: water soluble acrylic resin=100:5～20; Concrete operation step in reacting by heating still, stirs and adds water soluble acrylic resin in aqueous acrylic emulsion or styrene-butadiene latex; Stirring velocity 200-750 rev/min, temperature 50-85 ℃.
2. a kind of emulsion-type as claimed in claim 1 shifts a kind of improvement formula and the technique of composite glue, it is characterized in that: in described whipping process, add emulsifying agent DB-45, defoamer DF-681F.
3. a kind of emulsion-type as claimed in claim 1 shifts a kind of improvement formula and the technique of composite glue, it is characterized in that: described water-borne acrylic resin select that Jiangsu Miki Chemical Co., Ltd produces EA-184.
4. a kind of emulsion-type as claimed in claim 1 shifts a kind of improvement formula and the technique of composite glue, it is characterized in that: described aqueous acrylic emulsion is selected the RS-998A of the rich group company of Ahmedabad.
5. a kind of emulsion-type as claimed in claim 1 shifts a kind of improvement formula and the technique of composite glue, it is characterized in that: described water-based styrene-butadiene latex is the SD615 of the Shanghai Gaoqiao BASF dispersion BASF of company limited.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310480118.4A CN103709968A (en) | 2013-10-15 | 2013-10-15 | Improved formula and technology of emulsion-type transfer composite glue |
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| CN201310480118.4A CN103709968A (en) | 2013-10-15 | 2013-10-15 | Improved formula and technology of emulsion-type transfer composite glue |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105219162A (en) * | 2015-10-17 | 2016-01-06 | 广东翊翔民俗文化有限公司 | A kind of hot-melting type printing-ink of alumite thermoprinting foil and compound method thereof |
| CN107663434A (en) * | 2017-09-29 | 2018-02-06 | 上海睿途新材料科技有限公司 | A kind of composite glue of anti-rotation paper transfer loss of gloss phenomenon and its application |
| CN108753212A (en) * | 2018-07-24 | 2018-11-06 | 湖北华工图像技术开发有限公司 | The production method of aqueous compound adhesive and holographic positioning transfer paper |
| CN112500815A (en) * | 2020-11-23 | 2021-03-16 | 东莞海丽化学材料有限公司 | Water-based adhesive for vacuum aluminum-plated paper and preparation method thereof |
| CN114989777A (en) * | 2022-06-22 | 2022-09-02 | 湖北绿新环保包装科技有限公司 | Environment-friendly water-based transfer glue capable of improving firmness of paper |
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| CN101880988A (en) * | 2010-03-29 | 2010-11-10 | 深圳市高氏粘合剂制品有限公司 | Aqueous environment-friendly paper product laminating-imitation coating preparation and preparation technique thereof |
| CN101880512A (en) * | 2010-07-14 | 2010-11-10 | 浙江德尚化工科技有限公司 | Aqueous binding agent and preparation method thereof |
| CN102363933A (en) * | 2011-06-30 | 2012-02-29 | 上海乘鹰新材料有限公司 | Environmentally-friendly aqueous matte aluminized paper undercoating paint and preparation method as well as application thereof |
| CN103013383A (en) * | 2012-12-27 | 2013-04-03 | 广东达美新材料有限公司 | Aqueous pressure-sensitive adhesive and preparation method thereof |
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2013
- 2013-10-15 CN CN201310480118.4A patent/CN103709968A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880988A (en) * | 2010-03-29 | 2010-11-10 | 深圳市高氏粘合剂制品有限公司 | Aqueous environment-friendly paper product laminating-imitation coating preparation and preparation technique thereof |
| CN101880512A (en) * | 2010-07-14 | 2010-11-10 | 浙江德尚化工科技有限公司 | Aqueous binding agent and preparation method thereof |
| CN102363933A (en) * | 2011-06-30 | 2012-02-29 | 上海乘鹰新材料有限公司 | Environmentally-friendly aqueous matte aluminized paper undercoating paint and preparation method as well as application thereof |
| CN103013383A (en) * | 2012-12-27 | 2013-04-03 | 广东达美新材料有限公司 | Aqueous pressure-sensitive adhesive and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105219162A (en) * | 2015-10-17 | 2016-01-06 | 广东翊翔民俗文化有限公司 | A kind of hot-melting type printing-ink of alumite thermoprinting foil and compound method thereof |
| CN107663434A (en) * | 2017-09-29 | 2018-02-06 | 上海睿途新材料科技有限公司 | A kind of composite glue of anti-rotation paper transfer loss of gloss phenomenon and its application |
| CN108753212A (en) * | 2018-07-24 | 2018-11-06 | 湖北华工图像技术开发有限公司 | The production method of aqueous compound adhesive and holographic positioning transfer paper |
| CN112500815A (en) * | 2020-11-23 | 2021-03-16 | 东莞海丽化学材料有限公司 | Water-based adhesive for vacuum aluminum-plated paper and preparation method thereof |
| CN114989777A (en) * | 2022-06-22 | 2022-09-02 | 湖北绿新环保包装科技有限公司 | Environment-friendly water-based transfer glue capable of improving firmness of paper |
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Application publication date: 20140409 |