CN103700847A - Formula of polar plate lead plaster with high energy storage capacity, long service life and low temperature resistance - Google Patents
Formula of polar plate lead plaster with high energy storage capacity, long service life and low temperature resistance Download PDFInfo
- Publication number
- CN103700847A CN103700847A CN201310681326.0A CN201310681326A CN103700847A CN 103700847 A CN103700847 A CN 103700847A CN 201310681326 A CN201310681326 A CN 201310681326A CN 103700847 A CN103700847 A CN 103700847A
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- weight portion
- energy storage
- low temperature
- formula
- lead plaster
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/14—Electrodes for lead-acid accumulators
- H01M4/16—Processes of manufacture
- H01M4/20—Processes of manufacture of pasted electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/56—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of lead
- H01M4/57—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of lead of "grey lead", i.e. powders containing lead and lead oxide
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/582—Halogenides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses a formula of a polar plate lead plaster with high energy storage capacity, long service life and low temperature resistance, relating to the technical field of lead plasters of storage batteries. The polar plate lead plaster comprises the following components in parts by weight: 90-110 parts of lead powder, 0.5-0.7 part of precipitated barium sulphate, 0.2-0.3 part of sodium lignosulfonate, 0.2 part of carbon black, 0.05 part of chemical staples, 10-11 parts of sulfuric acid and 9-11 parts of pure water and is characterized by comprising 0.2-0.3 part of rare earth and 0.5-1 part of potassium bromide. According to the formula, the rare earth and the potassium bromide are added, so that the processed lead plaster is high in activity, rapid in charging and capable of improving the energy storage capacity and low temperature resistance of a storage battery.
Description
Technical field:
The present invention relates to storage battery has lead plaster technical field, specifically a kind of low temperature resistant pole plate lead paste formula of high energy storage long-life.
Background technology:
Lead plaster is the parent of plate active material, is that the lead powder by certain oxidizability and apparent density mixes with water and sulfuric acid the certain plastic pasty masses that has forming by mechanical agitation; The effect of lead plaster in lead-acid battery is mainly to provide for electrochemical reaction the material needing with reservoir.In prior art, the lead plaster that lead plaster is used on anodal and negative pole is different, a kind of for the lead plaster on negative pole at formula, has good energy storage effect, but charging is slower sometimes, and charging spended time is long, poor performance at low temperatures.
Summary of the invention:
Technical problem to be solved by this invention is to provide a kind of lead plaster activity processing high, the low temperature resistant pole plate lead paste formula of high energy storage long-life that charging rate is fast.
The object that will reach in order to realize the present invention, adopts following technical scheme:
A kind of low temperature resistant pole plate lead paste formula of high energy storage long-life, comprise the lead powder of 90～110 weight portions, the sodium lignosulfonate of the blanc fixe of 0.5～0.7 weight portion, 0.2～0.3 weight portion, the staple fibre of the carbon black of 0.2 weight portion, 0.05 weight portion, the pure water of the sulfuric acid of 10～11 weight portions and 9～11 weight portions it is characterized in that: add the rare earth of 0.2～0.3 weight portion and the KBr of 0.5～1 weight portion.
The preferred lead powder of technical scheme 100 weight portions, the sodium lignosulfonate of the blanc fixe of 0.6 weight portion, 0.25 weight portion, the staple fibre of the carbon black of 0.2 weight portion, 0.05 weight portion, the pure water of the sulfuric acid of 10.5 weight portions and 10 weight portions, and the KBr of the rare earth of 0.25 weight portion and 0.7 weight portion.
The density of described sulfuric acid is 1.4, and temperature remains on 25 ℃.
The present invention has added appropriate rare earth and KBr on the basis of traditional lead paste formula, these rare earths and KBr have played the effect of activating agent, can greatly increase the activity of lead plaster, can quick charge and electric discharge, and can also increase the whole energy storage of storage battery.
The invention has the beneficial effects as follows: the present invention fills a prescription simply, be convenient to make, the lead plaster activity processing is high, and charging rate is fast, and can increase energy storage and the resistance to low temperature of storage battery.
Embodiment:
For technological means, creation characteristic that the present invention is realized, reach object and effect is easy to understand, below in conjunction with instantiation, further set forth the present invention.
Embodiment mono-:
A kind of low temperature resistant pole plate lead paste formula of high energy storage long-life, comprise the lead powder of 90kg, the sodium lignosulfonate of the blanc fixe of 0.5kg, 0.2kg, the staple fibre of the carbon black of 0.2kg, 0.05kg, the pure water of the sulfuric acid of 10kg and 9kg, also comprises rare earth and the 0.5kg KBr of 0.2kg.The density of sulfuric acid is 1.4, and temperature remains on 25 ℃.
Embodiment bis-:
A kind of low temperature resistant pole plate lead paste formula of high energy storage long-life, the preferred lead powder of technical scheme 100kg, the sodium lignosulfonate of the blanc fixe of 0.6kg, 0.25kg, the staple fibre of the carbon black of 0.2kg, 0.05kg, the pure water of the sulfuric acid of 10.5kg and 10kg, and the rare earth of 0.25kg and 0.5kg KBr.The density of sulfuric acid is 1.4, and temperature remains on 25 ℃.
Embodiment tri-:
A kind of low temperature resistant pole plate lead paste formula of high energy storage long-life, comprise the lead powder of 110kg, the sodium lignosulfonate of the blanc fixe of 0.7kg, 0.3kg, the staple fibre of the carbon black of 0.2kg, 0.05kg, the pure water of the sulfuric acid of 11kg and 11kg, also comprises rare earth and the 1kg KBr of 0.3kg weight portion.The density of sulfuric acid is 1.4, and temperature remains on 25 ℃.
More than show and described basic principle of the present invention and principal character and advantage of the present invention.The technical staff of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification, describes just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (3)
1. one kind high low temperature resistant pole plate lead paste formula of energy storage long-life, comprise the lead powder of 90～110 weight portions, the sodium lignosulfonate of the blanc fixe of 0.5～0.7 weight portion, 0.2～0.3 weight portion, the staple fibre of the carbon black of 0.2 weight portion, 0.05 weight portion, the pure water of the sulfuric acid of 10～11 weight portions and 9～11 weight portions it is characterized in that: also comprise the rare earth of 0.2～0.3 weight portion and the KBr of 0.5～1 weight portion.
2. a kind of low temperature resistant pole plate lead paste formula of high energy storage long-life according to claim 1, it is characterized in that: the preferred lead powder of technical scheme 100 weight portions, the sodium lignosulfonate of the blanc fixe of 0.6 weight portion, 0.25 weight portion, the staple fibre of the carbon black of 0.2 weight portion, 0.05 weight portion, the pure water of the sulfuric acid of 10.5 weight portions and 10 weight portions, and the KBr of the rare earth of 0.25 weight portion and 0.75 weight portion.
3. a kind of low temperature resistant pole plate lead paste formula of high energy storage long-life according to claim 1 and 2, is characterized in that: the density of described sulfuric acid is 1.4, and temperature remains on 25 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310681326.0A CN103700847A (en) | 2013-11-30 | 2013-11-30 | Formula of polar plate lead plaster with high energy storage capacity, long service life and low temperature resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310681326.0A CN103700847A (en) | 2013-11-30 | 2013-11-30 | Formula of polar plate lead plaster with high energy storage capacity, long service life and low temperature resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103700847A true CN103700847A (en) | 2014-04-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310681326.0A Pending CN103700847A (en) | 2013-11-30 | 2013-11-30 | Formula of polar plate lead plaster with high energy storage capacity, long service life and low temperature resistance |
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| CN (1) | CN103700847A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105024046A (en) * | 2015-07-31 | 2015-11-04 | 湘潭大学 | Preparation method of lead-carbon battery cathode |
| CN105428731A (en) * | 2015-12-11 | 2016-03-23 | 贵州宏宇金属电源科技有限公司 | Long-life super storage battery with quick charge acceptance |
| CN107317027A (en) * | 2017-05-22 | 2017-11-03 | 安徽轰达电源有限公司 | A kind of lead-acid accumulator anode diachylon added with 4BS crystal seeds |
| CN112652765A (en) * | 2020-12-21 | 2021-04-13 | 超威电源集团有限公司 | Negative electrode lead paste of lead-acid storage battery, preparation method of negative electrode lead paste and negative plate |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62208568A (en) * | 1986-03-07 | 1987-09-12 | Japan Storage Battery Co Ltd | Paste type lead-acid battery |
| CN101651206A (en) * | 2009-07-08 | 2010-02-17 | 张天任 | Storage battery diachylum formula for electric vehicle and preparation method thereof |
| CN102738467A (en) * | 2012-06-25 | 2012-10-17 | 天能集团江苏科技有限公司 | Lead-carbon battery anode lead paste for hybrid vehicle, and its preparation method |
| CN102956893A (en) * | 2012-11-01 | 2013-03-06 | 浙江天能能源科技有限公司 | Low-temperature nickel-hydrogen battery and preparation method thereof |
| CN103035923A (en) * | 2012-12-18 | 2013-04-10 | 超威电源有限公司 | Low-temperature-resistant storage battery internally formed lead plaster |
-
2013
- 2013-11-30 CN CN201310681326.0A patent/CN103700847A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62208568A (en) * | 1986-03-07 | 1987-09-12 | Japan Storage Battery Co Ltd | Paste type lead-acid battery |
| CN101651206A (en) * | 2009-07-08 | 2010-02-17 | 张天任 | Storage battery diachylum formula for electric vehicle and preparation method thereof |
| CN102738467A (en) * | 2012-06-25 | 2012-10-17 | 天能集团江苏科技有限公司 | Lead-carbon battery anode lead paste for hybrid vehicle, and its preparation method |
| CN102956893A (en) * | 2012-11-01 | 2013-03-06 | 浙江天能能源科技有限公司 | Low-temperature nickel-hydrogen battery and preparation method thereof |
| CN103035923A (en) * | 2012-12-18 | 2013-04-10 | 超威电源有限公司 | Low-temperature-resistant storage battery internally formed lead plaster |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105024046A (en) * | 2015-07-31 | 2015-11-04 | 湘潭大学 | Preparation method of lead-carbon battery cathode |
| CN105024046B (en) * | 2015-07-31 | 2017-11-14 | 湘潭大学 | A kind of preparation method of lead carbon battery negative pole |
| CN105428731A (en) * | 2015-12-11 | 2016-03-23 | 贵州宏宇金属电源科技有限公司 | Long-life super storage battery with quick charge acceptance |
| CN107317027A (en) * | 2017-05-22 | 2017-11-03 | 安徽轰达电源有限公司 | A kind of lead-acid accumulator anode diachylon added with 4BS crystal seeds |
| CN112652765A (en) * | 2020-12-21 | 2021-04-13 | 超威电源集团有限公司 | Negative electrode lead paste of lead-acid storage battery, preparation method of negative electrode lead paste and negative plate |
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Application publication date: 20140402 |