CN103694699A - Nylon 612 moulding composition as well as preparation method and application thereof - Google Patents
Nylon 612 moulding composition as well as preparation method and application thereof Download PDFInfo
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- CN103694699A CN103694699A CN201310478393.2A CN201310478393A CN103694699A CN 103694699 A CN103694699 A CN 103694699A CN 201310478393 A CN201310478393 A CN 201310478393A CN 103694699 A CN103694699 A CN 103694699A
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- 229920000572 Nylon 6/12 Polymers 0.000 title claims abstract description 116
- 239000000203 mixture Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000000465 moulding Methods 0.000 title abstract 4
- 239000011347 resin Substances 0.000 claims abstract description 28
- 229920005989 resin Polymers 0.000 claims abstract description 28
- 238000005469 granulation Methods 0.000 claims abstract description 18
- 230000003179 granulation Effects 0.000 claims abstract description 18
- 229920000098 polyolefin Polymers 0.000 claims abstract description 16
- 150000008065 acid anhydrides Chemical class 0.000 claims abstract description 9
- 239000000206 moulding compound Substances 0.000 claims description 79
- 230000003014 reinforcing effect Effects 0.000 claims description 35
- 239000003112 inhibitor Substances 0.000 claims description 21
- 230000003647 oxidation Effects 0.000 claims description 20
- 238000007254 oxidation reaction Methods 0.000 claims description 20
- 229920001903 high density polyethylene Polymers 0.000 claims description 19
- 239000004700 high-density polyethylene Substances 0.000 claims description 19
- 238000012360 testing method Methods 0.000 claims description 8
- 229920001684 low density polyethylene Polymers 0.000 claims description 5
- 239000004702 low-density polyethylene Substances 0.000 claims description 5
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 229920010741 Ultra High Molecular Weight Polyethylene (UHMWPE) Polymers 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 3
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 229920001897 terpolymer Polymers 0.000 claims description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 230000007123 defense Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 229920006124 polyolefin elastomer Polymers 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 19
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 18
- 238000011056 performance test Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 9
- -1 pentaerythritol ester Chemical class 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- 229920000305 Nylon 6,10 Polymers 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229910021595 Copper(I) iodide Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 description 2
- 235000013872 montan acid ester Nutrition 0.000 description 2
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 description 1
- CAPNUXMLPONECZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-2-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=C(O)C(C(C)(C)C)=C1 CAPNUXMLPONECZ-UHFFFAOYSA-N 0.000 description 1
- LLQHSBBZNDXTIV-UHFFFAOYSA-N 6-[5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-4,5-dihydro-1,2-oxazol-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC1CC(=NO1)C1=CC2=C(NC(O2)=O)C=C1 LLQHSBBZNDXTIV-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- ZRTHDHYYZUCESV-UHFFFAOYSA-N acetic acid;1,2-xylene Chemical group CC(O)=O.CC1=CC=CC=C1C ZRTHDHYYZUCESV-UHFFFAOYSA-N 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229960004839 potassium iodide Drugs 0.000 description 1
- 235000007715 potassium iodide Nutrition 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000000207 volumetry Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a nylon 612 moulding composition, which comprises following ingredients by weight: 70.0-85.0 parts of nylon 612 resins; 15.0-30.0 parts of toughening components; wherein, the toughening components comprises following components: (A) nonsaturated acid anhydride grafting polyolefin elastomers; (B) polyolefin; The weight ratio between the component (A) and the component (B) is 1:4-4:1; the preparation method comprises the following steps: uniformly mixing each component according to ratio using a high-speed mixing machine or a premixing machine; adding the mixture into an extruder; melting and extruding at 220-260 DEG C for granulation; preparing a nylon 612 moulding composition with high rigidity. The prepared nylon 612 moulding composition has the advantages of greatly improved toughness, less reduced rigidity and low cost, and the product can be applied in the fields of electronics and electric, electric tool, traffic transport, automobile, machinery, instrument, building, aviation spaceflight and national defense military industry.
Description
Technical field
The present invention relates to the processing modified technical field of polymer blending, be specifically related to a kind of nylon 612 moulding compound and its preparation method and application.
Background technology
The excellent characteristics such as that nylon 612 resin has is wear-resisting, oil resistant, shock-resistant, antifatigue, corrosion-resistant, self-lubricating property is good, frictional coefficient is little.In addition, compare with PA66 with conventional PA6, it is low that nylon 612 resin has water-intake rate, the feature less to product size impact, and its application is more and more extensive.But there is dry state and the poor weakness of low temperature notched impact property in common nylon 612 resin, makes its Application Areas be subject to certain limitation.
At present, the increasing tougheness that improves nylon 612 resin is mainly to adopt elastomerics graft reaction group and nylon 612 resin alloy to carry out tenacity increased nylon.But elastomerics and nylon 612 resin alloy, when improving material increasing tougheness, also reduced the rigidity of material, the use field of having limited to a certain extent nylon 612 resin.
Summary of the invention
In order to overcome the deficiencies in the prior art and defect, primary and foremost purpose of the present invention is to provide a kind of toughened Nylon 6 12 moulding compounds of high rigidity.
Another object of the present invention is to provide the preparation method of toughened Nylon 6 12 moulding compounds of above-mentioned high rigidity.
The present invention is achieved by the following technical solution:
A nylon 612 moulding compound, by weight, comprises following component:
Nylon 612 resin: 70.0 ~ 85.0 parts;
Toughness reinforcing component: 15.0 ~ 30.0 parts;
Wherein, toughness reinforcing component comprises following component:
(A) unsaturated acid anhydride graft polyolefin elastomerics;
(B) polyolefine;
Wherein, (A) component is 1:4 ~ 4:1 with (B) weight ratio of component.
Preferably, a kind of nylon 612 moulding compound, by weight, comprises following component:
Nylon 612 resin: 70.0 ~ 80.0 parts;
Toughness reinforcing component: 15.0 ~ 30.0 parts;
Wherein, toughness reinforcing component comprises following component:
(A) unsaturated acid anhydride graft polyolefin elastomerics;
(B) polyolefine;
Wherein, (A) component is 2:3 ~ 3:2 with (B) weight ratio of component.
Described nylon 612 resin is 1.7 ~ 3.4 according to the relative viscosity of standard ISO 307 tests; The relative viscosity of nylon 612 resin is higher, and the toughness of nylon 612 moulding compound is corresponding higher, but the rising of nylon 612 resin relative viscosity, its processing characteristics also can decline; Take into account the balance of mechanical property and processing characteristics, be preferably relative viscosity and be 2.0 ~ 2.8 nylon 612 resin; The nylon 612 resin of relative viscosity 2.1 ~ 2.6 more preferably.
As nylon 612 resin of the present invention, meeting relative viscosity is that 1.7 ~ 3.4 PA612 resins that limit are all applicable, the compound that can enumerate as the example of nylon 612 resin of the present invention: Hiprolon 90(relative viscosity 2.2, Suzhou Han Pugao molecular material); GYEHVN(relative viscosity is 2.4, Shandong Guang Yin novel material company limited) etc.
Described toughness reinforcing component (A) is maleic anhydride graft terpolymer EP rubber (EPDM-g-MAH) and/or maleic anhydride grafted ethene-octene copolymer (POE-g-MAH); If no special instructions, the EPDM described in following the present invention is terpolymer EP rubber, and described POE is ethylene-octene copolymer.
In described toughness reinforcing component, (A) unsaturated acid of component or the percentage of grafting of unsaturated acid anhydride are 0.5% ~ 1.3%, and melt flow rate (MFR) is 0.5 ~ 6.0g/10min; Wherein, percentage of grafting adopts volumetry, with phenolphthalein, makes indicator, by acetic acid-xylene solution titration determination.Melt flow rate (MFR) is according to ASTM D1238 test, and test condition is at 190 ℃, to add load 2.16Kg.
Described toughness reinforcing component (B) is selected from one or more mixtures of ultrahigh molecular weight polyethylene(UHMWPE) (UHMWPE), high density polyethylene(HDPE) (HDPE), linear low density polyethylene (LLDPE), Low Density Polyethylene (LDPE); Be preferably one or more mixtures of HDPE, LLDPE, LDPE, more preferably HDPE.
Described nylon 612 moulding compound, also comprises the processing aid of 0 ~ 0.6 weight part, and described processing aid is selected from one or more mixtures of oxidation inhibitor, lubricant, nucleator.
Described oxidation inhibitor is selected from N, N '-1,6-dihexyl two (3,5-bis-(1,1-dimethyl ethyl)-4-hydroxyl) phenylpropyl alcohol acyl (general oxidation inhibitor 1098 by name), four (β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid) one or more mixtures in pentaerythritol ester (general antioxidant 1010 by name), three (2,4-di-tert-butyl-phenyl) phosphorous acid ester (general irgasfos 168 by name) or mantoquita composite antioxidant, are preferably oxidation inhibitor 1098.
Described mantoquita composite antioxidant is comprised of the potassiumiodide of 50 ~ 90wt% and the cuprous iodide of 10 ~ 50wt%, or is comprised of the Potassium Bromide of 50-90wt% and the cuprous iodide of 10-50wt%.
Described lubricant is selected from oxidized polyethlene wax, montanic acid wax, calcium stearate, aluminum stearate, silicone, N, N '-ethylene bis stearamide (EBS), N, one or more mixtures of N '-ethylene bis stearamide grafts (TAF); Be preferably montanic acid ester type waxes.
Described nucleator is selected from inorganic nucleator and/or organic nucleating agent.The grain diameter of described inorganic nucleator is less than 1 μ m.
Described nucleator is selected from one or more mixtures of talcum powder, polynite, calcium carbonate, Sodium Benzoate, sorbyl alcohol dibenzyl ester, carboxylic acid sodium salt; Preferably talc powder.
Described nylon 612 moulding compound further comprises: the typical additives such as anti-UV agent, static inhibitor, tinting material.But its addition is no more than the 0.5wt% of the weight summation of nylon 612 resin and toughness reinforcing component, avoid affecting because of the interpolation of these typical additives the rigidity of nylon 612 moulding compound.
A preparation method for above-mentioned nylon 612 moulding compound, comprises the steps:
Each component is mixed with high mixer or premixing machine by proportioning, join in forcing machine, at 220 ~ 260 ℃, melt extrude granulation, prepare the nylon 612 moulding compound of high rigidity.
Described nylon 612 moulding compound is in preparation method, due to (A) unsaturated acid anhydride graft polyolefin elastomerics and (B) polyolefinic acting in conjunction, the nylon 612 moulding compound preparing has higher melt strength, therefore, the nylon 612 moulding compound that the present invention prepares, except can be used for injection moulding, also can be used for extrusion moulding or blow molding.
The nylon 612 moulding compound of the high rigidity that the preparation method of described nylon 612 moulding compound obtains is in the purposes in electric, power tool, communications and transportation, automobile, machinery, instrument, building, aerospace and defence and military field.
Compared with prior art, beneficial effect is as follows in the present invention:
The nylon 612 moulding compound of gained of the present invention, by adding toughness reinforcing component (A) unsaturated acid anhydride graft polyolefin elastomerics and toughness reinforcing component (B) polyolefine to carry out toughness reinforcing in nylon 612 resin, and (A) component is 1:4 ~ 4:1 with (B) weight ratio of component, the toughness of the nylon 612 moulding compound preparing significantly improves, rigidity declines less, and cost is lower.
Embodiment
Below by embodiment, further illustrate the present invention, following examples are preferably embodiment of the present invention, but embodiments of the present invention are not subject to the restriction of following embodiment.
Now embodiment and comparative example starting material used are done to following explanation, but are not limited to these materials:
Nylon 612 resin, Hiprolon 90, and relative viscosity is 2.2, Suzhou Hanpu Polymer Material Co., Ltd.;
Nylon 612 resin, GYEHVN, relative viscosity is 2.4, Shandong Guang Yin novel material company limited;
POE-g-MAH, BONDYRAM 7103, and melt flow rate (MFR) is 1.5g/10min, and the percentage of grafting of MAH is 0.8%, Israel Polyram Ram-On Industries;
EPDM-g-MAH, BONDYRAM 7003, and melt flow rate (MFR) is 5.5g/10min, and the percentage of grafting of MAH is 0.8%, Israel Polyram Ram-On Industries;
HDPE, the trade mark is DMDA8008, Lanzhou Petrochemical Company;
LDPE, the trade mark is LB7500N, Korea S LG chemical company;
LLDPE, the trade mark is LL6101XR, Exxon Mobil company;
Montanic acid ester type waxes, Licowax E, German Clariant company;
Talcum powder, trade mark HTPUltra5, particle diameter is 0.5 μ m, Italian IMIFABI company.
embodiment 1
After being mixed with high mixer, 90,4 parts of DMDA8008 of 80 parts of Hiprolon, 1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 16 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 56.2kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 1680MPa.
embodiment 2
After being mixed with high mixer, 90,8 parts of DMDA8008 of 80 parts of Hiprolon, 1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 12 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 64.7kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 1720MPa.
embodiment 3
After being mixed with high mixer, 90,10 parts of DMDA8008 of 80 parts of Hiprolon, 1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 10 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 70.8kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 1780MPa.
embodiment 4
After being mixed with high mixer, 90,12 parts of DMDA8008 of 80 parts of Hiprolon, 1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 8 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 65.5kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 1860MPa.
embodiment 5
After being mixed with high mixer, 90,16 parts of DMDA8008 of 80 parts of Hiprolon, 1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 4 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare NYLON610 moulding compound.
Described nylon 612 moulding compound performance test: it is 38.2kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 1920MPa.
embodiment 6
After being mixed with high mixer, 90,9 parts of DMDA8008 of 85 parts of Hiprolon, 1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 6 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 42.0kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 2060MPa.
embodiment 7
After being mixed with high mixer, 90,6 parts of DMDA8008 of 85 parts of Hiprolon, 1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 9 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 45.8kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 2140MPa.
embodiment 8
After being mixed with high mixer, 90,15 parts of DMDA8008 of 70 parts of Hiprolon, 1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 15 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 79.6kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 1380MPa.
embodiment 9
After being mixed with high mixer, 90,12 parts of DMDA8008 of 70 parts of Hiprolon, 1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 18 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 76.1kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 1340MPa.
embodiment 10 ~ 14
By the proportioning in table 3, take each component, preparation method is with embodiment 1, and described nylon 612 moulding compound the performance test results is in Table 3.
embodiment 15 ~ 17
By the proportioning in table 4, take each component, preparation method is with embodiment 1, and described nylon 612 moulding compound the performance test results is in Table 4.
comparative example 1
After being mixed with high mixer, 80 parts of Hiprolon90,1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 20 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 43.3kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 1630MPa.
comparative example 2
After being mixed with high mixer, 90,20 parts of DMDA8008 of 80 parts of Hiprolon, 1098,0.3 part of Licowax E of 0.1 part of oxidation inhibitor and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare NYLON610 moulding compound.
Described nylon 612 moulding compound performance test: it is 6.3kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 2130MPa.
comparative example 3
After being mixed with high mixer, 90,15 parts of DMDA8008 of 85 parts of Hiprolon, 1098,0.3 part of Licowax E of 0.1 part of oxidation inhibitor and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 6.2kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 2320MPa.
comparative example 4
After being mixed with high mixer, 1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 90,15 parts of BONDYRAM of 85 parts of Hiprolon and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 38.2 kJ/m that socle girder breach rushes intensity
2; Modulus in flexure 1810MPa.
comparative example 5
After being mixed with high mixer, 70 parts of Hiprolon90,1098,0.3 part of Licowax E of 7103,0.1 part of oxidation inhibitor of 30 parts of BONDYRAM and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 55.3kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 1260MPa.
comparative example 6
After being mixed with high mixer, 90,30 parts of DMDA8008 of 70 parts of Hiprolon, 1098,0.3 part of Licowax E of 0.1 part of oxidation inhibitor and 0.2 part of talcum powder add forcing machine, at 220-260 ℃, melt extrude granulation, prepare nylon 612 moulding compound.
Described nylon 612 moulding compound performance test: it is 6.0kJ/m that socle girder breach rushes intensity
2; Modulus in flexure is 1710MPa.
comparative example 7 ~ 10
By the proportioning in table 4, take each component, preparation method is with embodiment 1, and described nylon 612 moulding compound the performance test results is in Table 4.
Table 1
Table 2
Table 3
Table 4
The various embodiments described above all can make nylon 612 moulding compound.From embodiment 1-14, can find out that toughness reinforcing component accounts for 15-30 weight part, and the weight ratio of toughness reinforcing component (A) and toughness reinforcing component (B) is while being 1:4-4:1, the toughness of nylon 612 moulding compound increases, and keeps certain rigidity.From embodiment 2-4, embodiment 6-17, can find out, especially when the weight ratio of toughness reinforcing component (A) and toughness reinforcing component (B) is 2:3-3:2, when the toughness of material increases, keep relatively better rigidity, realized the rigidity-toughness balanced of elastomer toughened nylon 612.
The component concentration of the nylon 612 resin of embodiment 1-5 is constant, the weight ratio of nylon 612 resin and toughness reinforcing component is 80/20, along with the raising of HDPE content in toughness reinforcing component, the parameter socle girder notched Izod impact strength of exosyndrome material toughness first increases gradually as can be seen from Table 1, then declines; Along with the raising of HDPE content in toughness reinforcing component, the modulus in flexure of nylon 612 moulding compound increases, and the rigidity of nylon 612 moulding compound improves.Embodiment 1-5 and comparative example 1-2 contrast are known, POE-g-MAH and HDPE coordination plasticizing nylon 612, part HDPE replaces toughened Nylon 6 12 moulding compounds prepared by POE-g-MAH and has higher modulus in flexure than only take the nylon 612 moulding compound that POE-g-MAH prepared as toughner, than only take the NYLON610 moulding compound that HDPE prepared as toughner, has stronger toughness.
Embodiment 6-7 and comparative example 3-4 contrast in table 2, embodiment 8-9 and comparative example 5-6 contrast, can find out nylon 612 moulding compound prepared by HDPE and POE-g-MAH coordination plasticizing PA612, the nylon 612 moulding compound toughness reinforcing with POE-g-MAH only compared to be had higher socle girder breach and rushes intensity and modulus in flexure; Explanation is compared with POE-g-MAH toughened Nylon 6 12, uses HDPE and POE-g-MAH coordination plasticizing nylon 612, when increasing nylon 612 moulding compound toughness, the rigidity of nylon 612 moulding compound is also increased.
In table 3, in embodiment 10-14, toughness reinforcing component (B) polyolefine of employing different amounts and toughness reinforcing component (A) unsaturated acid graft polyolefin elastomerics carry out toughness reinforcing, when nylon 612 moulding compound toughness improves, also keep higher rigidity.
In table 4, in embodiment 15-17 and comparative example 7-10, the weight ratio of nylon 612 resin and toughness reinforcing component is 77/30, and other components are identical.In embodiment 15-17, the weight ratio of POE-g-MAH and HDPE is between 1:4-4:1, especially between 2:3-3:2; In comparative example 7-8, the weight ratio of POE-g-MAH and HDPE is greater than 4:1; In comparative example 9-10, the weight ratio of POE-g-MAH and HDPE is less than 1:4.Embodiment 15-17 and comparative example 7-8 contrast, and can find out the good toughness of the nylon 612 moulding compound in comparative example 7-8, but rigidity are poor; Embodiment 15-17 and comparative example 9-10 contrast, and can find out that the rigidity of the nylon 612 moulding compound in comparative example 9-10 keeps better, but toughening effect are poor.Therefore, from embodiment 15-17 contrast comparative example 7-10, can find out that the weight ratio of working as POE-g-MAH and HDPE is between 1:4-4:1, especially, between 2:3-3:2, nylon 612 moulding compound, in toughness reinforcing, is also keeping higher rigidity.
Nylon 612 moulding compound of the present invention, add toughness reinforcing component (A) unsaturated acid graft polyolefin elastomerics and toughness reinforcing component (B) polyolefin component to carry out toughness reinforcing, and (A) component is 1:4-4:1 with (B) weight ratio of component, in toughened Nylon 6 12, keep the rigidity of nylon 612 also relatively better.Especially when (A) component is when (B) weight ratio of component is 2:3-3:2, when toughened Nylon 6 12 has higher toughness, also keeping higher rigidity.
Properties testing method:
Socle girder notched Izod impact strength: test by ISO180/1A, sample is of a size of 80 * 10 * 4mm
3, A type breach; Modulus in flexure: test by ISO178, sample is of a size of 80 * 10 * 4mm
3, test speed is 2mm/min.
Claims (9)
1. a nylon 612 moulding compound, is characterized in that, by weight, comprises following component:
Nylon 612 resin: 70.0 ~ 85.0 parts;
Toughness reinforcing component: 15.0 ~ 30.0 parts;
Wherein, toughness reinforcing component comprises following component:
(A) unsaturated acid anhydride graft polyolefin elastomerics;
(B) polyolefine;
Wherein, (A) component is 1:4 ~ 4:1 with (B) weight ratio of component.
2. nylon 612 moulding compound according to claim 1, is characterized in that, by weight, comprises following component:
Nylon 612 resin: 70.0 ~ 80.0 parts;
Toughness reinforcing component: 15.0 ~ 30.0 parts;
Wherein, toughness reinforcing component comprises following component:
(A) unsaturated acid anhydride graft polyolefin elastomerics;
(B) polyolefine;
Wherein, (A) component is 2:3 ~ 3:2 with (B) weight ratio of component.
3. nylon 612 moulding compound according to claim 1 and 2, is characterized in that, described nylon 612 resin is 1.7 ~ 3.4 according to the relative viscosity of standard ISO 307 tests, is preferably 2.0 ~ 2.8.
4. nylon 612 moulding compound according to claim 1 and 2, is characterized in that, described toughness reinforcing component (A) is maleic anhydride graft terpolymer EP rubber (EPDM-g-MAH) and/or maleic anhydride grafted ethene-octene copolymer (POE-g-MAH).
5. nylon 612 moulding compound according to claim 4, is characterized in that, the unsaturated acid of described toughness reinforcing component (A) or the percentage of grafting of unsaturated acid anhydride are 0.5% ~ 1.3%, and melt flow rate (MFR) is 0.5 ~ 6.0g/10min.
6. nylon 612 moulding compound according to claim 1 and 2, is characterized in that, described toughness reinforcing component (B) is selected from one or more mixtures of ultrahigh molecular weight polyethylene(UHMWPE), high density polyethylene(HDPE), linear low density polyethylene, Low Density Polyethylene.
7. nylon 612 moulding compound according to claim 1 and 2, is characterized in that, also comprises the processing aid of 0 ~ 0.6 weight part, and described processing aid is selected from one or more mixtures of oxidation inhibitor, lubricant, nucleator.
8. a preparation method for the nylon 612 moulding compound described in claim 1 or 2, is characterized in that, comprises the steps:
Each component is mixed with high mixer or premixing machine by proportioning, join in forcing machine, at 220 ~ 260 ℃, melt extrude granulation, prepare the nylon 612 moulding compound of high rigidity.
9. the nylon 612 moulding compound of the high rigidity that the preparation method of nylon 612 moulding compound as claimed in claim 8 obtains is in the purposes in electric, power tool, communications and transportation, automobile, machinery, instrument, building, aerospace and defence and military field.
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| CN106928624A (en) * | 2017-03-09 | 2017-07-07 | 山东省科学院能源研究所 | A kind of nucleocapsid nylon toughener and preparation method and application based on extruder technique |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1161356A (en) * | 1996-01-31 | 1997-10-08 | 埃尔夫阿托化学有限公司 | Compositions based on polyamides and on polyolefins which are flexurally very flexible |
| CN102942786A (en) * | 2012-10-24 | 2013-02-27 | 金发科技股份有限公司 | Nylon composition, preparation method and applications thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1161356A (en) * | 1996-01-31 | 1997-10-08 | 埃尔夫阿托化学有限公司 | Compositions based on polyamides and on polyolefins which are flexurally very flexible |
| CN102942786A (en) * | 2012-10-24 | 2013-02-27 | 金发科技股份有限公司 | Nylon composition, preparation method and applications thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106928624A (en) * | 2017-03-09 | 2017-07-07 | 山东省科学院能源研究所 | A kind of nucleocapsid nylon toughener and preparation method and application based on extruder technique |
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