CN103694535A - Processing method of high density composite pipe - Google Patents

Processing method of high density composite pipe Download PDF

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Publication number
CN103694535A
CN103694535A CN201310654028.2A CN201310654028A CN103694535A CN 103694535 A CN103694535 A CN 103694535A CN 201310654028 A CN201310654028 A CN 201310654028A CN 103694535 A CN103694535 A CN 103694535A
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Prior art keywords
high density
parts
temperature
density composite
density polyethylene
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CN201310654028.2A
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Chinese (zh)
Inventor
朱华明
陈德明
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Jiangsu Jinbo New Materials Technology Co Ltd
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Jiangsu Jinbo New Materials Technology Co Ltd
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Priority to CN201310654028.2A priority Critical patent/CN103694535A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911Cooling
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/9258Velocity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/9258Velocity
    • B29C2948/9259Angular velocity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92885Screw or gear
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92923Calibration, after-treatment or cooling zone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The invention relates to a high density composite pipe which is prepared by the following raw materials in parts by weight: 100 parts of high density polyethylene, 5-15 parts of nano calcium carbonate, 5-15 parts of filler, 1-5 parts of a lubricant and 1-5 parts of a solubilizer. The processing method comprises the following steps: putting the raw materials in parts by weight in a high speed mixer to primary mix for 3-5 minutes; uniformly mixing and stirring; extruding particles by the primarily mixed material in a twin-screw extruder, and controlling the temperature at 200-220 DEG C; putting the dried mixed material in a pipe extruder and extruding to obtain a high density polyethylene compound pipe; and cooling: cooling by water at 70-80 DEG C and setting. The processing method provided by the invention is convenient to operate, the strength of the high density polyethylene compound pipe is improved by applying assistants such as a bulking agent, and the comprehensive performances such as tensile strength can be remarkably improved. The raw materials are stirred at low speed and are prevented from being heated to lead to deterioration, so that the cost is saved to a certain degree.

Description

A kind of working method of high density composite tubing
Technical field
The present invention relates to a kind of working method of tubing, particularly a kind of working method of high density composite tubing, belongs to the technical field that tubing is processed.
Background technology
Along with social development, the application of polyvinyl piping materials is more and more extensive.Polyvinyl piping materials mainly divides two large classes: high density polyethylene (low pressure polyethylene) and low density polyethylene (high-pressure polyethylene).Polyvinyl piping materials.Low Density Polyethylene (LDPE) has good snappiness.But resistance to compression compressive strength is lower, thus can only be for the tubing of low pressure minor diameter, and it is often made into coil pipe and for the occasion of rural water improvement and some non-life-time service.And high-density polyethylene material (HDPE) is owing to having good compressive property, thus be widely used in penstock field, but cost is higher.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of working method of high density composite tubing, can effectively increase the intensity of tubing and can effectively solve Cost Problems.
In order to achieve the above object, technical scheme of the present invention is achieved in that
This composite pipe raw material composition and ratio comprises:
Figure BDA0000431041430000011
In a preferred embodiment of the present invention, this high density composite raw material composition and ratio comprises:
Figure BDA0000431041430000021
In a preferred embodiment of the present invention, this high density composite raw material composition and ratio comprises:
Wherein, described solubilizing agent is a kind of in toxilic acid modified poly ethylene, ethylene-acrylic acid copolymer or ethylene-vinyl acetate copolymer; Described weighting agent is the wollastonite of needle-like; Described lubricant is one or more of paraffin, glycerine or stearic acid.
A preparation method for high density composite tubing, the method comprises the steps:
(1) press ratio of quality and the number of copies each component is dropped into just mixed 3-5min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 200-220 ℃;
(2) compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.
In a preferred embodiment of the present invention, each section of temperature of the described pipe extruder of step (2) is that one section of temperature is 90-100 ℃, and two sections of temperature are 170-180 ℃, and three sections of temperature are 175-185 ℃, and four sections of temperature are 190-200 ℃, and engine speed is 50r/min.
(3) cooling, with the water of temperature 70-80 ℃, carry out cooling, sizing.
The present invention is easy to operate, uses the auxiliary agents such as expanding material to improve the intensity of this composite pipe of high density polyethylene(HDPE), and the over-all properties such as tensile strength is significantly increased.And raw material is carried out to stirring at low speed, can avoid raw material heating, cause rottenly, saved to a certain extent cost.
Embodiment
Embodiment
A high density composite tubing, this composite pipe raw material composition and ratio comprises:
Figure BDA0000431041430000031
Wherein, described solubilizing agent is a kind of in toxilic acid modified poly ethylene, ethylene-acrylic acid copolymer or ethylene-vinyl acetate copolymer; Described weighting agent is the wollastonite of needle-like; Described lubricant is one or more of paraffin, glycerine or stearic acid.
A preparation method for high density composite tubing, the method comprises the steps:
(1) press ratio of quality and the number of copies each component is dropped into just mixed 3-5min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 200-220 ℃;
(2) compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.
In a preferred embodiment of the present invention, each section of temperature of the described pipe extruder of step (2) is that one section of temperature is 90-100 ℃, and two sections of temperature are 170-180 ℃, and three sections of temperature are 175-185 ℃, and four sections of temperature are 190-200 ℃, and engine speed is 50r/min.
(3) cooling, with the water of temperature 70-80 ℃, carry out cooling, sizing.
The present invention is further detailed explanation for knot preferred embodiment now.
Embodiment 1
100 parts of high density polyethylene(HDPE)s, 12 parts of nano-calcium carbonates, 10 parts of weighting agents, 3 parts of lubricants, 4 parts of solubilizing agent.
Press ratio of quality and the number of copies each component is dropped into just mixed 5min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 210 ℃; The compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.Each section of temperature of described pipe extruder is that one section of temperature is 100 ℃, and two sections of temperature are 180 ℃, and three sections of temperature are 180 ℃, and four sections of temperature are 190 ℃, and engine speed is 50r/min.Cooling, with the water of 80 ℃ of temperature, carry out cooling, sizing.
Embodiment 2
100 parts of high density polyethylene(HDPE)s, 10 parts of nano-calcium carbonates, 10 parts of weighting agents, 4 parts of lubricants, 3 parts of solubilizing agent.
Press ratio of quality and the number of copies each component is dropped into just mixed 4min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 205 ℃; The compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.Each section of temperature of described pipe extruder is that one section of temperature is 95 ℃, and two sections of temperature are 175 ℃, and three sections of temperature are 180 ℃, and four sections of temperature are 195 ℃, and engine speed is 50r/min.Cooling, with the water of 75 ℃ of temperature, carry out cooling, sizing.
100 parts of high density polyethylene(HDPE)s, 10 parts of nano-calcium carbonates, 10 parts of weighting agents, 4 parts of lubricants, 3 parts of solubilizing agent.
Press ratio of quality and the number of copies each component is dropped into just mixed 4min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 205 ℃; The compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.Each section of temperature of described pipe extruder is that one section of temperature is 95 ℃, and two sections of temperature are 175 ℃, and three sections of temperature are 180 ℃, and four sections of temperature are 195 ℃, and engine speed is 50r/min.Cooling, with the water of 75 ℃ of temperature, carry out cooling, sizing.
Embodiment 3
100 parts of high density polyethylene(HDPE)s, 12 parts of nano-calcium carbonates, 10 parts of weighting agents, 3 parts of lubricants, 3 parts of solubilizing agent.
Press ratio of quality and the number of copies each component is dropped into just mixed 4min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 200 ℃; The compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.Each section of temperature of described pipe extruder is that one section of temperature is 100 ℃, and two sections of temperature are 180 ℃, and three sections of temperature are 185 ℃, and four sections of temperature are 200 ℃, and engine speed is 50r/min.Cooling, with the water of 80 ℃ of temperature, carry out cooling, sizing.
Table 1 is the comprehensive physical performance of the poly-composite pipe goods of embodiment 1-3 middle-high density:
Embodiment Tensile strength (mpa) Shock strength (kj/m 2
1 29.6 18.4
2 29.1 18.0
3 29.2 18.1
The present invention is easy to operate, uses the auxiliary agents such as expanding material to improve the intensity of this composite pipe of high density polyethylene(HDPE), and the over-all properties such as tensile strength is significantly increased.And raw material is carried out to stirring at low speed, can avoid raw material heating, cause rottenly, saved to a certain extent cost.
Here description of the invention and application is illustrative, not wants that therefore, the present invention is not subject to the restriction of the present embodiment by scope restriction of the present invention in the above-described embodiments, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.

Claims (7)

1. a working method for high density composite tubing, is characterized in that this high density composite tubing raw material composition and ratio comprises:
100 parts of high density polyethylene(HDPE)s,
Nano-calcium carbonate 5-15 part,
Weighting agent 5-15 part,
Lubricant 1-5 part,
Solubilizing agent 1-5 part.
2. the working method of a kind of high density composite tubing as claimed in claim 1, is characterized in that this high density composite raw material composition and ratio comprises:
100 parts of high density polyethylene(HDPE)s,
Nano-calcium carbonate 10-15 part,
Weighting agent 8-15 part,
Lubricant 2-5 part,
Solubilizing agent 2-5 part.
3. the working method of a kind of high density composite tubing as claimed in claim 1, is characterized in that this high density composite raw material composition and ratio comprises:
100 parts of high density polyethylene(HDPE)s,
12 parts of nano-calcium carbonates,
10 parts of weighting agents,
3 parts of lubricants,
4 parts of solubilizing agent.
4. the working method of a kind of high density composite tubing as claimed in claim 1, is characterized in that described solubilizing agent is a kind of in toxilic acid modified poly ethylene, ethylene-acrylic acid copolymer or ethylene-vinyl acetate copolymer.
5. the working method of a kind of high density composite tubing as claimed in claim 1, is characterized in that the wollastonite that described weighting agent is needle-like.
6. the working method of a kind of high density composite tubing as claimed in claim 1, is characterized in that described lubricant is one or more of paraffin, glycerine or stearic acid.
7. a preparation method for high density composite tubing, the method comprises the steps:
(1) ratio of quality and the number of copies drops into just mixed 3-5min in high-speed mixer by each component, mixing and stirring, and in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 200-220 ℃;
(2) compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe;
In a preferred embodiment of the present invention, each section of temperature of the described pipe extruder of step (2) is that one section of temperature is 90-100 ℃, and two sections of temperature are 170-180 ℃, and three sections of temperature are 175-185 ℃, and four sections of temperature are 190-200 ℃, and engine speed is 50r/min;
(3) cooling, with the water of temperature 70-80 ℃, carry out cooling, sizing.
CN201310654028.2A 2013-12-05 2013-12-05 Processing method of high density composite pipe Pending CN103694535A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108384089A (en) * 2018-02-09 2018-08-10 江苏理工学院 A kind of modification high-density polyethylene material and preparation method thereof
CN109061818A (en) * 2018-08-23 2018-12-21 镇江荣诚管业有限公司 A kind of production method of silicone pipes
CN113845709A (en) * 2021-09-02 2021-12-28 福建亚通新材料科技股份有限公司 Anti-sagging modified high-density polyethylene water supply pipe and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1552761A (en) * 2003-05-28 2004-12-08 新疆天业(集团)有限公司 Nanometer material modified water delivering flexible pipe
CN101514769A (en) * 2009-01-06 2009-08-26 福建恒杰塑业新材料有限公司 Non-digging PE-specialized service tube
CN102775670A (en) * 2012-08-22 2012-11-14 天津市滨海新区汉沽春光塑料厂 Special high-elasticity low-temperature-resistant raw material for thread protector
CN102942732A (en) * 2012-11-30 2013-02-27 重庆美尔康塑胶有限公司 Composite pipe and method for manufacturing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1552761A (en) * 2003-05-28 2004-12-08 新疆天业(集团)有限公司 Nanometer material modified water delivering flexible pipe
CN101514769A (en) * 2009-01-06 2009-08-26 福建恒杰塑业新材料有限公司 Non-digging PE-specialized service tube
CN102775670A (en) * 2012-08-22 2012-11-14 天津市滨海新区汉沽春光塑料厂 Special high-elasticity low-temperature-resistant raw material for thread protector
CN102942732A (en) * 2012-11-30 2013-02-27 重庆美尔康塑胶有限公司 Composite pipe and method for manufacturing same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108384089A (en) * 2018-02-09 2018-08-10 江苏理工学院 A kind of modification high-density polyethylene material and preparation method thereof
CN108384089B (en) * 2018-02-09 2020-10-30 江苏理工学院 Modified high-density polyethylene material and preparation method thereof
CN109061818A (en) * 2018-08-23 2018-12-21 镇江荣诚管业有限公司 A kind of production method of silicone pipes
CN109061818B (en) * 2018-08-23 2023-11-07 镇江荣诚管业有限公司 Manufacturing method of silicon core tube
CN113845709A (en) * 2021-09-02 2021-12-28 福建亚通新材料科技股份有限公司 Anti-sagging modified high-density polyethylene water supply pipe and preparation method thereof

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