CN103694535A - Processing method of high density composite pipe - Google Patents
Processing method of high density composite pipe Download PDFInfo
- Publication number
- CN103694535A CN103694535A CN201310654028.2A CN201310654028A CN103694535A CN 103694535 A CN103694535 A CN 103694535A CN 201310654028 A CN201310654028 A CN 201310654028A CN 103694535 A CN103694535 A CN 103694535A
- Authority
- CN
- China
- Prior art keywords
- high density
- parts
- temperature
- density composite
- density polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92923—Calibration, after-treatment or cooling zone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The invention relates to a high density composite pipe which is prepared by the following raw materials in parts by weight: 100 parts of high density polyethylene, 5-15 parts of nano calcium carbonate, 5-15 parts of filler, 1-5 parts of a lubricant and 1-5 parts of a solubilizer. The processing method comprises the following steps: putting the raw materials in parts by weight in a high speed mixer to primary mix for 3-5 minutes; uniformly mixing and stirring; extruding particles by the primarily mixed material in a twin-screw extruder, and controlling the temperature at 200-220 DEG C; putting the dried mixed material in a pipe extruder and extruding to obtain a high density polyethylene compound pipe; and cooling: cooling by water at 70-80 DEG C and setting. The processing method provided by the invention is convenient to operate, the strength of the high density polyethylene compound pipe is improved by applying assistants such as a bulking agent, and the comprehensive performances such as tensile strength can be remarkably improved. The raw materials are stirred at low speed and are prevented from being heated to lead to deterioration, so that the cost is saved to a certain degree.
Description
Technical field
The present invention relates to a kind of working method of tubing, particularly a kind of working method of high density composite tubing, belongs to the technical field that tubing is processed.
Background technology
Along with social development, the application of polyvinyl piping materials is more and more extensive.Polyvinyl piping materials mainly divides two large classes: high density polyethylene (low pressure polyethylene) and low density polyethylene (high-pressure polyethylene).Polyvinyl piping materials.Low Density Polyethylene (LDPE) has good snappiness.But resistance to compression compressive strength is lower, thus can only be for the tubing of low pressure minor diameter, and it is often made into coil pipe and for the occasion of rural water improvement and some non-life-time service.And high-density polyethylene material (HDPE) is owing to having good compressive property, thus be widely used in penstock field, but cost is higher.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of working method of high density composite tubing, can effectively increase the intensity of tubing and can effectively solve Cost Problems.
In order to achieve the above object, technical scheme of the present invention is achieved in that
This composite pipe raw material composition and ratio comprises:
In a preferred embodiment of the present invention, this high density composite raw material composition and ratio comprises:
In a preferred embodiment of the present invention, this high density composite raw material composition and ratio comprises:
Wherein, described solubilizing agent is a kind of in toxilic acid modified poly ethylene, ethylene-acrylic acid copolymer or ethylene-vinyl acetate copolymer; Described weighting agent is the wollastonite of needle-like; Described lubricant is one or more of paraffin, glycerine or stearic acid.
A preparation method for high density composite tubing, the method comprises the steps:
(1) press ratio of quality and the number of copies each component is dropped into just mixed 3-5min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 200-220 ℃;
(2) compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.
In a preferred embodiment of the present invention, each section of temperature of the described pipe extruder of step (2) is that one section of temperature is 90-100 ℃, and two sections of temperature are 170-180 ℃, and three sections of temperature are 175-185 ℃, and four sections of temperature are 190-200 ℃, and engine speed is 50r/min.
(3) cooling, with the water of temperature 70-80 ℃, carry out cooling, sizing.
The present invention is easy to operate, uses the auxiliary agents such as expanding material to improve the intensity of this composite pipe of high density polyethylene(HDPE), and the over-all properties such as tensile strength is significantly increased.And raw material is carried out to stirring at low speed, can avoid raw material heating, cause rottenly, saved to a certain extent cost.
Embodiment
Embodiment
A high density composite tubing, this composite pipe raw material composition and ratio comprises:
Wherein, described solubilizing agent is a kind of in toxilic acid modified poly ethylene, ethylene-acrylic acid copolymer or ethylene-vinyl acetate copolymer; Described weighting agent is the wollastonite of needle-like; Described lubricant is one or more of paraffin, glycerine or stearic acid.
A preparation method for high density composite tubing, the method comprises the steps:
(1) press ratio of quality and the number of copies each component is dropped into just mixed 3-5min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 200-220 ℃;
(2) compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.
In a preferred embodiment of the present invention, each section of temperature of the described pipe extruder of step (2) is that one section of temperature is 90-100 ℃, and two sections of temperature are 170-180 ℃, and three sections of temperature are 175-185 ℃, and four sections of temperature are 190-200 ℃, and engine speed is 50r/min.
(3) cooling, with the water of temperature 70-80 ℃, carry out cooling, sizing.
The present invention is further detailed explanation for knot preferred embodiment now.
Embodiment 1
100 parts of high density polyethylene(HDPE)s, 12 parts of nano-calcium carbonates, 10 parts of weighting agents, 3 parts of lubricants, 4 parts of solubilizing agent.
Press ratio of quality and the number of copies each component is dropped into just mixed 5min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 210 ℃; The compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.Each section of temperature of described pipe extruder is that one section of temperature is 100 ℃, and two sections of temperature are 180 ℃, and three sections of temperature are 180 ℃, and four sections of temperature are 190 ℃, and engine speed is 50r/min.Cooling, with the water of 80 ℃ of temperature, carry out cooling, sizing.
Embodiment 2
100 parts of high density polyethylene(HDPE)s, 10 parts of nano-calcium carbonates, 10 parts of weighting agents, 4 parts of lubricants, 3 parts of solubilizing agent.
Press ratio of quality and the number of copies each component is dropped into just mixed 4min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 205 ℃; The compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.Each section of temperature of described pipe extruder is that one section of temperature is 95 ℃, and two sections of temperature are 175 ℃, and three sections of temperature are 180 ℃, and four sections of temperature are 195 ℃, and engine speed is 50r/min.Cooling, with the water of 75 ℃ of temperature, carry out cooling, sizing.
100 parts of high density polyethylene(HDPE)s, 10 parts of nano-calcium carbonates, 10 parts of weighting agents, 4 parts of lubricants, 3 parts of solubilizing agent.
Press ratio of quality and the number of copies each component is dropped into just mixed 4min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 205 ℃; The compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.Each section of temperature of described pipe extruder is that one section of temperature is 95 ℃, and two sections of temperature are 175 ℃, and three sections of temperature are 180 ℃, and four sections of temperature are 195 ℃, and engine speed is 50r/min.Cooling, with the water of 75 ℃ of temperature, carry out cooling, sizing.
Embodiment 3
100 parts of high density polyethylene(HDPE)s, 12 parts of nano-calcium carbonates, 10 parts of weighting agents, 3 parts of lubricants, 3 parts of solubilizing agent.
Press ratio of quality and the number of copies each component is dropped into just mixed 4min in high-speed mixer, mixing and stirring, in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 200 ℃; The compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe.Each section of temperature of described pipe extruder is that one section of temperature is 100 ℃, and two sections of temperature are 180 ℃, and three sections of temperature are 185 ℃, and four sections of temperature are 200 ℃, and engine speed is 50r/min.Cooling, with the water of 80 ℃ of temperature, carry out cooling, sizing.
Table 1 is the comprehensive physical performance of the poly-composite pipe goods of embodiment 1-3 middle-high density:
Embodiment | Tensile strength (mpa) | Shock strength (kj/m 2) |
1 | 29.6 | 18.4 |
2 | 29.1 | 18.0 |
3 | 29.2 | 18.1 |
The present invention is easy to operate, uses the auxiliary agents such as expanding material to improve the intensity of this composite pipe of high density polyethylene(HDPE), and the over-all properties such as tensile strength is significantly increased.And raw material is carried out to stirring at low speed, can avoid raw material heating, cause rottenly, saved to a certain extent cost.
Here description of the invention and application is illustrative, not wants that therefore, the present invention is not subject to the restriction of the present embodiment by scope restriction of the present invention in the above-described embodiments, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.
Claims (7)
1. a working method for high density composite tubing, is characterized in that this high density composite tubing raw material composition and ratio comprises:
100 parts of high density polyethylene(HDPE)s,
Nano-calcium carbonate 5-15 part,
Weighting agent 5-15 part,
Lubricant 1-5 part,
Solubilizing agent 1-5 part.
2. the working method of a kind of high density composite tubing as claimed in claim 1, is characterized in that this high density composite raw material composition and ratio comprises:
100 parts of high density polyethylene(HDPE)s,
Nano-calcium carbonate 10-15 part,
Weighting agent 8-15 part,
Lubricant 2-5 part,
Solubilizing agent 2-5 part.
3. the working method of a kind of high density composite tubing as claimed in claim 1, is characterized in that this high density composite raw material composition and ratio comprises:
100 parts of high density polyethylene(HDPE)s,
12 parts of nano-calcium carbonates,
10 parts of weighting agents,
3 parts of lubricants,
4 parts of solubilizing agent.
4. the working method of a kind of high density composite tubing as claimed in claim 1, is characterized in that described solubilizing agent is a kind of in toxilic acid modified poly ethylene, ethylene-acrylic acid copolymer or ethylene-vinyl acetate copolymer.
5. the working method of a kind of high density composite tubing as claimed in claim 1, is characterized in that the wollastonite that described weighting agent is needle-like.
6. the working method of a kind of high density composite tubing as claimed in claim 1, is characterized in that described lubricant is one or more of paraffin, glycerine or stearic acid.
7. a preparation method for high density composite tubing, the method comprises the steps:
(1) ratio of quality and the number of copies drops into just mixed 3-5min in high-speed mixer by each component, mixing and stirring, and in twin screw extruder, by the first mixed material extruding pelletization of process, temperature is controlled at 200-220 ℃;
(2) compound of having dried is put in pipe extruder, extruded to obtain high-density polyethylene compound pipe;
In a preferred embodiment of the present invention, each section of temperature of the described pipe extruder of step (2) is that one section of temperature is 90-100 ℃, and two sections of temperature are 170-180 ℃, and three sections of temperature are 175-185 ℃, and four sections of temperature are 190-200 ℃, and engine speed is 50r/min;
(3) cooling, with the water of temperature 70-80 ℃, carry out cooling, sizing.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310654028.2A CN103694535A (en) | 2013-12-05 | 2013-12-05 | Processing method of high density composite pipe |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310654028.2A CN103694535A (en) | 2013-12-05 | 2013-12-05 | Processing method of high density composite pipe |
Publications (1)
Publication Number | Publication Date |
---|---|
CN103694535A true CN103694535A (en) | 2014-04-02 |
Family
ID=50356211
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310654028.2A Pending CN103694535A (en) | 2013-12-05 | 2013-12-05 | Processing method of high density composite pipe |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103694535A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108384089A (en) * | 2018-02-09 | 2018-08-10 | 江苏理工学院 | A kind of modification high-density polyethylene material and preparation method thereof |
CN109061818A (en) * | 2018-08-23 | 2018-12-21 | 镇江荣诚管业有限公司 | A kind of production method of silicone pipes |
CN113845709A (en) * | 2021-09-02 | 2021-12-28 | 福建亚通新材料科技股份有限公司 | Anti-sagging modified high-density polyethylene water supply pipe and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1552761A (en) * | 2003-05-28 | 2004-12-08 | 新疆天业(集团)有限公司 | Nanometer material modified water delivering flexible pipe |
CN101514769A (en) * | 2009-01-06 | 2009-08-26 | 福建恒杰塑业新材料有限公司 | Non-digging PE-specialized service tube |
CN102775670A (en) * | 2012-08-22 | 2012-11-14 | 天津市滨海新区汉沽春光塑料厂 | Special high-elasticity low-temperature-resistant raw material for thread protector |
CN102942732A (en) * | 2012-11-30 | 2013-02-27 | 重庆美尔康塑胶有限公司 | Composite pipe and method for manufacturing same |
-
2013
- 2013-12-05 CN CN201310654028.2A patent/CN103694535A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1552761A (en) * | 2003-05-28 | 2004-12-08 | 新疆天业(集团)有限公司 | Nanometer material modified water delivering flexible pipe |
CN101514769A (en) * | 2009-01-06 | 2009-08-26 | 福建恒杰塑业新材料有限公司 | Non-digging PE-specialized service tube |
CN102775670A (en) * | 2012-08-22 | 2012-11-14 | 天津市滨海新区汉沽春光塑料厂 | Special high-elasticity low-temperature-resistant raw material for thread protector |
CN102942732A (en) * | 2012-11-30 | 2013-02-27 | 重庆美尔康塑胶有限公司 | Composite pipe and method for manufacturing same |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108384089A (en) * | 2018-02-09 | 2018-08-10 | 江苏理工学院 | A kind of modification high-density polyethylene material and preparation method thereof |
CN108384089B (en) * | 2018-02-09 | 2020-10-30 | 江苏理工学院 | Modified high-density polyethylene material and preparation method thereof |
CN109061818A (en) * | 2018-08-23 | 2018-12-21 | 镇江荣诚管业有限公司 | A kind of production method of silicone pipes |
CN109061818B (en) * | 2018-08-23 | 2023-11-07 | 镇江荣诚管业有限公司 | Manufacturing method of silicon core tube |
CN113845709A (en) * | 2021-09-02 | 2021-12-28 | 福建亚通新材料科技股份有限公司 | Anti-sagging modified high-density polyethylene water supply pipe and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN109438818B (en) | Special resin for cracking-resistant high-density polyethylene pipe and preparation method thereof | |
CN110951142B (en) | High-thermal-conductivity radiation crosslinked polyethylene pipe and preparation method and application thereof | |
CN103756088A (en) | High-temperature, temperature-resisting and wear-resisting polyethylene pipe | |
CN102996913B (en) | A kind of novel high-strength HDPE multiple tubes and its production method | |
CN103554629A (en) | TPO waterproof coiled material and production process thereof | |
CN105713315A (en) | Formula for synthesizing novel high-polymer fiber composite materials | |
CN104004271A (en) | Low-temperature-resistant polypropylene special material | |
CN102827448A (en) | Organosilane crosslinked polyethylene | |
CN108129734A (en) | A kind of combustion gas protection of pipe fire retardant thermal shrinkage tube through walls and preparation method thereof | |
CN103694535A (en) | Processing method of high density composite pipe | |
CN106349976B (en) | A kind of steel wire enhancing effective adhering resin of polyethylene hot water and preparation method thereof | |
CN104530545A (en) | PE cable material subjected to irradiation cross-linking at 125 DEG C for UL high-temperature electronic wire and preparation method of PE cable material | |
CN103554687B (en) | A kind of production method of environmental-protection flame-retardant polyolefine heat-shrink tube | |
CN102863677B (en) | Special modified recycled polyethylene material for pipes and pipe fittings and preparation method of special modified recycled polyethylene material | |
CN104945860A (en) | Halogen-free charging pile electric cable material and preparation method thereof | |
CN102382350A (en) | High density polyethylane bamboo plastic composite tubing and preparation method thereof | |
CN105017599A (en) | High-concentration carbon black master batch for polyethylene geomembrane | |
CN105778355A (en) | Low-density anti-impact modified polyvinyl chloride pipe and production process thereof | |
CN111004427B (en) | HDPE carrier carbon black master batch for PE pressure pipeline and preparation method thereof | |
CN102875934A (en) | Preparation method of high-strength PVC (polyvinyl chloride) threading pipe | |
CN106279997A (en) | A kind of low cost optical cable packing material and preparation method thereof | |
CN102766288A (en) | HDPE (High-Density Polyethylene) tubular product formula | |
CN115044148A (en) | Formula and preparation process of acrylate blended polyvinyl chloride pipe for water supply | |
CN106317669B (en) | A kind of PVC-M pipe composition and preparation method thereof | |
CN105273292A (en) | Linear low-density polyethylene auxiliary-agent master batch and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140402 |
|
RJ01 | Rejection of invention patent application after publication |