CN103694508A - Natural product and rubber synthetic sole as well as formula and manufacturing process thereof - Google Patents
Natural product and rubber synthetic sole as well as formula and manufacturing process thereof Download PDFInfo
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- CN103694508A CN103694508A CN201410010222.1A CN201410010222A CN103694508A CN 103694508 A CN103694508 A CN 103694508A CN 201410010222 A CN201410010222 A CN 201410010222A CN 103694508 A CN103694508 A CN 103694508A
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Abstract
The invention relates to a natural product and rubber synthetic sole as well as a formula and manufacturing process thereof. The process comprises the following steps: calculating the following components in parts by weight: low molecule polybutadiene, butylbenzene, natural rubber, natural particles, white carbon black, transparent rubber powder, nano-calcium, rubber oil, zinc oxide, stearic acid, an anti-aging agent, an anti-wear agent, an accelerant and a resin; mixing the previous materials, pouring the mixer into an internal mixer for mixing, wherein the internal mixing time is 6-8 minutes; controlling the temperature to be in a range from 120 to 135 DEG C; putting the materials subjected to internal mixing into a roller, adding color master and sulfur for color matching, and forming a rubber sheet; cutting the rubber sheet subjected to color matching into a small piece by using a stamping knife; putting the cut rubber sheet into a mold, pressurizing at a high temperature, controlling the temperature to be in a range from 160 to 180 DEG C, wherein the time is 5-6 minutes; and opening the mold after mold-opening cooling to obtain a complete sole. According to the process, the rubber sole is environment-friendly and is degraded. Meanwhile, the physical property of the original rubber sole is kept.
Description
Technical field
The present invention relates to Material Field, particularly a kind of natural goods, the synthetic sole of rubber and formula and manufacture craft.
Background technology
That rubber soles has advantages of is lightweight, good springiness, heat insulation vibration damping and comfort level good.But, rubber soles non-degradable and not environmental protection in the market.For this reason, the natural particle with approximately 30% replaces petroleum derivative material as industrial rubber etc., and the new type rubber sole of making, is keeping on the constant basis of former rubber soles physical property, environmental protection and degrading.This novel natural goods, the synthetic sole of rubber have greatly reduced the pollution that former rubber soles is brought to environment.
Summary of the invention
Object of the present invention, to the nondegradable weak point of existing rubber soles, provides a kind of environmental protection and the natural goods that can degrade, the synthetic sole of rubber and formula and manufacture craft.
It is as follows that the present invention is achieved in that natural goods, rubber synthesizes sole design parameter: hardness: 60 degree-65 degree; Proportion <1.165mg/MM3; Pulling force >97.44kg/cm3; Extend >500%; Tear >61.97kg/cm; Fastness to rubbing >200DIN; Folding endurance: under normal temperature, >6 is ten thousand times, subzero 15 degree >3 ten thousand times.
The formula of natural goods, the synthetic sole of rubber, calculates with weight ratio: 16.5 parts-20.5 parts of low molecular weight polycaprolactone butadienes, 2.5 parts-5.5 parts of butylbenzene, 3.5 parts-6.5 parts of natural gums, 9.8 parts-12.8 parts, natural particle, 9 parts-14 parts of white carbon blacks, 10.5 parts-15.5 parts of transparent rubber powders, 3 parts-6 parts of Namigai, 2 parts-6 parts of rubber oils, 2.0 parts-3.0 parts, zinc oxide, 10 parts-20 parts of stearic acid, 2.0 parts-3.0 parts, anti-aging agent, 2.0 parts-3.0 parts of anti-wear agents, 3 parts-5 parts of promotor, 3 parts-4 parts of resins;
Wherein, in every hundred parts of natural particles, contain 40 parts～55 parts of plant amylums, 10～15 parts of glycerine, 35～45 parts of polyethylene.
Described plant amylum is W-Gum, sweet potato starch, and wheat starch can also adopt other plant starch certainly; Described anti-aging agent is styrenated phenol; Anti-wear agent is for being two-(the silica-based propyl group of γ-triethoxy) tetrasulfide; Promotor is 2,2'-dithio-bis-benzothiazole; Resin is carbon nine resins.
The manufacture craft of natural goods, the synthetic sole of rubber, is characterized in that:
Step 1: by low molecular weight polycaprolactone butadiene, butylbenzene, natural gum, natural particle, white carbon black, transparent rubber powder, Namigai, oil, zinc oxide, stearic acid, anti-aging agent, anti-wear agent, promotor and resin are poured banburying in Banbury mixer into, the banburying time is 6-8 minute, and temperature is controlled within the scope of 120-135 ℃;
Step 2: the material that banburying is complete is put into roller, add look mother, sulphur toning, form film;
Step 3: by having adjusted the film of look, become small pieces with stamping knife stamping-out;
Step 4: the film cutting is put into mould, high-temperature pressurizing, temperature is controlled within the scope of 160～180 ℃, time 5-6 minute;
Step 5: die sinking after cooling, is opened mould, can obtain complete sole.
The present invention has the following advantages: 1. utilize approximately 30% natural goods to substitute original petroleum derivative material as industrial rubber etc., as raw material, make rubber soles reach environmental protection, degraded.2. new type natural thing, the synthetic sole of rubber keep original rubber soles physical property.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment mono-
The manufacture craft of a kind of natural goods, the synthetic sole of rubber comprises the following steps:
Step 1: prepare 16.5 parts of low molecular weight polycaprolactone butadienes, butylbenzene 2.5, natural gum 3.5,9.8 parts, natural particle, 9 parts of white carbon blacks, 10.5 parts of transparent rubber powders, 3 parts of Namigai, 2 parts of rubber oils, 2.0 parts, zinc oxide, 10 parts of stearic acid, 2.0 parts of styrenated phenols, two-2.0 parts of (the silica-based propyl group of γ-triethoxy) tetrasulfides, 2,3 parts of 2'-dithio-bis-benzothiazoles, 3 parts of carbon nine resins; Wherein, in every hundred parts of natural particles, contain 55 parts of plant amylums, 35 parts of 10 parts of glycerine and polyethylene; Pour said components in Banbury mixer banburying, the banburying time is 6 minutes, and it is 120 ℃ that temperature is controlled.
Step 2: the material that banburying is complete is put into roller, add look mother, sulphur toning, form film.
Step 3: by having adjusted the film of look, become small pieces with stamping knife stamping-out.
Step 4: the film cutting is put into mould, high-temperature pressurizing, it is 160 ℃ that temperature is controlled, 5 minutes time.
Step 5: die sinking-after cooling, open mould, can obtain complete sole.
Embodiment bis-
The manufacture craft of a kind of natural goods, the synthetic sole of rubber comprises the following steps:
Step 1: prepare 17.5 parts of low molecular weight polycaprolactone butadienes, 3.5 parts of butylbenzene, 4.2 parts of natural gums, 10.8 parts, natural particle, 12 parts of white carbon blacks, 12.5 parts of transparent rubber powders, 5 parts of Namigai, 4 parts of rubber oils, 2.5 parts, zinc oxide, 15 parts of stearic acid, 2.5 parts of styrenated phenols, two-2.5 parts of (the silica-based propyl group of γ-triethoxy) tetrasulfides, 2,4 parts of 2'-dithio-bis-benzothiazoles, 3.5 parts of carbon nine resins; Wherein, in every hundred parts of natural particles, contain 45 parts of plant amylums, 43 parts of glycerine 12 and polyethylene; Pour said components in Banbury mixer banburying, the banburying time is 8 minutes, and it is 125 ℃ that temperature is controlled.
Step 2: the material that banburying is complete is put into roller, add look mother, sulphur toning, form film.
Step 3: by having adjusted the film of look, become small pieces with stamping knife stamping-out.
Step 4: the film cutting is put into mould, high-temperature pressurizing, it is 170 ℃ that temperature is controlled, 5.5 minutes time.
Step 5: die sinking-after cooling, open mould, can obtain complete sole.
Embodiment tri-
The manufacture craft of a kind of natural goods, the synthetic sole of rubber comprises the following steps:
Step 1: prepare 20.5 parts of low molecular weight polycaprolactone butadienes, 5.5 parts of butylbenzene, 6.5 parts of natural gums, 12.8 parts, natural particle, 14 parts of white carbon blacks, 15.5 parts of transparent rubber powders, 6 parts of Namigai, 6 parts of rubber oils, 3.0 parts, zinc oxide, 20 parts of stearic acid, 3.0 parts of styrenated phenols, two-3.0 parts of (the silica-based propyl group of γ-triethoxy) tetrasulfides, 2,5 parts of 2'-dithio-bis-benzothiazoles, 4 parts of carbon nine resins; Wherein, in every hundred parts of natural particles, contain 40 parts of plant amylums, 45 parts of glycerine 15 and polyethylene; Pour said components in Banbury mixer banburying, the banburying time is 10 minutes, and it is 130 ℃ that temperature is controlled.
Step 2: the material that banburying is complete is put into roller, add look mother, sulphur toning, form film.
Step 3: by having adjusted the film of look, become small pieces with stamping knife stamping-out.
Step 4: the film cutting is put into mould, high-temperature pressurizing, it is 180 ℃ that temperature is controlled, 6 minutes time.
Step 5: die sinking-after cooling, open mould, can obtain complete sole.
The synthetic sole design parameter of the natural goods that above-mentioned three kinds of embodiment make, rubber is as follows:
Hardness: 60 degree-65 degree; Proportion <1.165mg/MM3; Pulling force >97.44kg/cm3; Extend >500%; Tear >61.97kg/cm; Fastness to rubbing >200DIN; Folding endurance: under normal temperature, >6 is ten thousand times, subzero 15 degree >3 ten thousand times.
Claims (5)
1. natural goods, rubber synthesize a sole, it is characterized in that: its design parameter is as follows:
Hardness: 60 degree-65 degree; Proportion <1.165mg/MM
3; Pulling force >97.44kg/cm
3; Extend >500%; Tear >61.97kg/cm; Fastness to rubbing >200DIN; Folding endurance: under normal temperature, >6 is ten thousand times, subzero 15 degree >3 ten thousand times.
2. the formula of a natural goods, the synthetic sole of rubber, it is characterized in that: with weight ratio, calculate 16.5 parts-20.5 parts of low molecular weight polycaprolactone butadienes, 2.5 parts-5.5 parts of butylbenzene, 3.5 parts-6.5 parts of natural gums, 9.8 parts-12.8 parts, natural particle, 9 parts-14 parts of white carbon blacks, 10.5 parts-15.5 parts of transparent rubber powders, 3 parts-6 parts of Namigai, 2 parts-6 parts of rubber oils, 2.0 parts-3.0 parts, zinc oxide, 10 parts-20 parts of stearic acid, 2.0 parts-3.0 parts, anti-aging agent, 2.0 parts-3.0 parts of anti-wear agents, 3 parts-5 parts of promotor, 3 parts-4 parts of resins;
Wherein, in every hundred parts of natural particles, contain 40 parts～55 parts of plant amylums, 10～15 parts of glycerine, 35～45 parts of polyethylene.
3. natural goods according to claim 2, rubber synthesize the formula of sole, it is characterized in that: with weight ratio, calculate, along 17.5 parts of fourths, 3.5 parts of butylbenzene, 4.2 parts of natural gums, 10.8 parts, natural particle, 12 parts of white carbon blacks, 12.5 parts of transparent rubber powders, 5 parts of Namigai, 4 parts of oil, 2.5 parts, zinc oxide, 15 parts of stearic acid, 2.5 parts, anti-aging agent, 2.5 parts of anti-wear agents, 4 parts of promotor, 3.5 parts of resins; Wherein, in every hundred parts of natural particles, contain 45 parts of plant amylums, 12 parts of glycerine, 43 parts of polyethylene.
4. according to the formula of the natural goods described in claim 2 or 3, the synthetic sole of rubber, it is characterized in that, described plant amylum is W-Gum, sweet potato starch, wheat starch; Described anti-aging agent is styrenated phenol; Anti-wear agent is two-(the silica-based propyl group of γ-triethoxy) tetrasulfide; Promotor is 2,2'-dithio-bis-benzothiazole; Resin is carbon nine resins.
5. the manufacture craft that natural goods, rubber synthesize sole, is characterized in that:
Step 1: by low molecular weight polycaprolactone butadiene, butylbenzene, natural gum, natural particle, white carbon black, transparent rubber powder, Namigai, oil, zinc oxide, stearic acid, anti-aging agent, anti-wear agent, promotor and resin are poured banburying in Banbury mixer into, the banburying time is 20-30 minute, and temperature is controlled within the scope of 210～225 ℃;
Step 2: the material that banburying is complete is put into roller, add look mother, sulphur toning, form film;
Step 3: by having adjusted the film of look, become small pieces with stamping knife stamping-out;
Step 4: the film cutting is put into mould, high-temperature pressurizing, temperature is controlled within the scope of 160～180 ℃, time 5-6 minute;
Step 5: die sinking after cooling, is opened mould, can obtain complete sole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410010222.1A CN103694508B (en) | 2014-01-09 | 2014-01-09 | Natural product and rubber synthetic sole as well as formula and manufacturing process thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410010222.1A CN103694508B (en) | 2014-01-09 | 2014-01-09 | Natural product and rubber synthetic sole as well as formula and manufacturing process thereof |
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| Publication Number | Publication Date |
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| CN103694508A true CN103694508A (en) | 2014-04-02 |
| CN103694508B CN103694508B (en) | 2015-04-29 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106065198A (en) * | 2016-07-11 | 2016-11-02 | 惠东县吉隆源发塑胶制品厂 | A kind of plastic shoes material goods using short fiber of plant as packing strengthening agent and its production and use |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH105005A (en) * | 1996-06-21 | 1998-01-13 | Koshin Gomme Kk | Antislip shoe sole |
| CN101061898A (en) * | 2006-04-28 | 2007-10-31 | 陈松和 | Method of producing plant amylum sole |
| CN101623139A (en) * | 2009-08-11 | 2010-01-13 | 陈聪贤 | Method for producing sole with plant waste fiber |
-
2014
- 2014-01-09 CN CN201410010222.1A patent/CN103694508B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH105005A (en) * | 1996-06-21 | 1998-01-13 | Koshin Gomme Kk | Antislip shoe sole |
| CN101061898A (en) * | 2006-04-28 | 2007-10-31 | 陈松和 | Method of producing plant amylum sole |
| CN101623139A (en) * | 2009-08-11 | 2010-01-13 | 陈聪贤 | Method for producing sole with plant waste fiber |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106065198A (en) * | 2016-07-11 | 2016-11-02 | 惠东县吉隆源发塑胶制品厂 | A kind of plastic shoes material goods using short fiber of plant as packing strengthening agent and its production and use |
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| Publication number | Publication date |
|---|---|
| CN103694508B (en) | 2015-04-29 |
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