CN103693806B - Authigenic ferric salt chemical phosphorus removal-anaerobic ferrous oxidization biological denitrification integrated device - Google Patents
Authigenic ferric salt chemical phosphorus removal-anaerobic ferrous oxidization biological denitrification integrated device Download PDFInfo
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- CN103693806B CN103693806B CN201310650276.XA CN201310650276A CN103693806B CN 103693806 B CN103693806 B CN 103693806B CN 201310650276 A CN201310650276 A CN 201310650276A CN 103693806 B CN103693806 B CN 103693806B
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- 239000000126 substance Substances 0.000 title claims abstract description 52
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 34
- 150000003839 salts Chemical class 0.000 title abstract description 16
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract description 15
- 229910052698 phosphorus Inorganic materials 0.000 title abstract description 15
- 239000011574 phosphorus Substances 0.000 title abstract description 15
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title abstract description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 91
- 229910052742 iron Inorganic materials 0.000 claims abstract description 39
- 238000005189 flocculation Methods 0.000 claims abstract description 23
- 230000016615 flocculation Effects 0.000 claims abstract description 23
- 238000005191 phase separation Methods 0.000 claims abstract description 23
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 230000003311 flocculating effect Effects 0.000 claims abstract description 14
- 238000010992 reflux Methods 0.000 claims abstract description 14
- 238000000926 separation method Methods 0.000 claims abstract description 14
- 239000010802 sludge Substances 0.000 claims abstract description 11
- 238000001556 precipitation Methods 0.000 claims description 49
- 230000003647 oxidation Effects 0.000 claims description 30
- 230000002269 spontaneous effect Effects 0.000 claims description 17
- 238000000034 method Methods 0.000 abstract description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 16
- 239000002351 wastewater Substances 0.000 abstract description 13
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 8
- 239000011159 matrix material Substances 0.000 abstract description 7
- 239000002699 waste material Substances 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000007789 gas Substances 0.000 abstract description 3
- 239000013589 supplement Substances 0.000 abstract 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000012851 eutrophication Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- 244000062766 autotrophic organism Species 0.000 description 2
- 239000012295 chemical reaction liquid Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000001651 autotrophic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
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- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention discloses an authigenic ferric salt chemical phosphorus removal-anaerobic ferrous oxidization biological denitrification integrated device. The device is provided with a chemical flocculation settling area, a ferrous salt supplement area, a nitrogen and phosphorus removal area and a three-phase separation area from bottom to top, wherein the chemical flocculation settling area is provided with a solid-liquid separation phosphorus removal area and a slowly flocculating phosphorus removal area, the ferrous salt supplement area is provided with a zero-valent iron filling area, the nitrogen and phosphorus removal area is provided with a rapidly settling phosphorus removal area and a ferrous oxidization biological nitrogen removal area from inside to outside, the three-phase separation area is provided with a gas release area and a settling area, and the settling area is provided with a biological sludge discharge port, a reflux port, an overflow weir and a water outlet. According to the device, the matrix of the phosphorus removal process and the nitrogen removal process can be recycled; by using biological denitrificatio and authigenic ferric salt chemical phosphorus removal agent, the cost for removing phosphorus is lowered; zero-valent iron such as cheap iron residue/scrap iron is dissolved by acid ferric salt phosphorous removal reaction solution so as to provide ferrous salt matrix for biological denitrification, and the purpose of processing waste with waste is achieved; by using autotroph for denitrification, the problem of insufficient carbon source in biological denitrification of wastewater is effectively solved.
Description
Technical field
The present invention relates to denitrification dephosphorization apparatus, relate in particular to a kind of spontaneous high ferro chemical dephosphorization-anaerobism iron oxidation biological denitrificaion integrated apparatus.
Background technology
Body eutrophication is the important environmental problem that China faces.According to China's " national Environmental statistics communique " and " China Environmental State Bulletin ", within 2012, in 62 state control emphasis lakes (reservoir), eutrophic state water body accounts for 86.7%, and the main contamination index that causes body eutrophication is total nitrogen and total phosphorus.Therefore, denitrogenation of waste water dephosphorization has become the important channel of control body eutrophication.
Biological wastewater treatment technology is conventional wastewater processing technology.Waste water is through biological treatment (second-stage treatment), and COD concentration is substantially up to standard, but that concentration of nitrogen and phosphorus exceeds standard is still serious.For the low C:N:P of this class, than wastewater treatment, traditional wastewater biological denitrificaion (nitrated-denitrification) technique and biological phosphate-eliminating (aerobic suction phosphorus-anaerobic phosphorus release) technique is aobvious weak, and this is because these bioprocesss need electron donor, is conventionally provided by organism.Therefore, novel denitrification dephosphorization technique exploitation is extremely urgent.
Chemical precipitation method is a kind of important waste water dephosphorization technology.Ferric salt because of its dephosphorization efficiency by using high, the advantage such as stability is strong and being widely used.But, practical discovery, ferric salt dephosphorization technique also faces the shortcomings such as reagent cost is high, consumption is large.Therefore, relatively cheap ferric salt source is expanded very necessary.
Nitrate type anaerobism iron oxidation (Nitrate-dependent Anaerobic Ferrous Oxidation, NAFO) be the great discovery of environmental area and microorganism field, under anaerobic, some microorganisms can, taking ferrous salt as electron donor, be reduced to N by nitrate or nitrite
2, ferrous salt is oxidized to ferric salt (formula 1) simultaneously.Because NAFO is autotrophic organism reaction process, utilize this reaction to carry out denitrogenation of waste water, can effectively alleviate the problem of carbon source deficiency in wastewater biological denitrificaion.On the other hand, the Fe that NAFO denitrification process produces
3+can be waste water chemical dephosphorization ferric salt source is provided.
10FeCO
3 + 2NO
3 - + 24H
2O → 10Fe(OH)
3 + N
2 + 10HCO
3 - + 8H
+ (1)
Ferric salt, except solution after phosphorus reaction is acid, can dissolve the Zero-valent Iron (common industrial waste) such as cheap iron filings/scum to produce Fe
2+, for NAFO denitrification process provides matrix (electron donor).Finally realize spontaneous ferric salt chemical dephosphorization process and anaerobism iron oxidation biological denitrification process integrated.
From above-mentioned spontaneous ferric salt chemical dephosphorization-anaerobism iron oxidation biological denitrificaion integral process principle, this technique can realize the matrix recycle of dephosphorization process and denitrification process.By backflow NAFO reaction product, for chemical dephosphorization provides ferric salt precipitation agent, reduce dephosphorization cost; Dissolve the Zero-valent Iron such as cheap iron filings/scum by the acid-reaction liquid after ferric salt dephosphorization, for biological denitrificaion provides ferrous salt matrix, realize the treatment of wastes with processes of wastes against one another; By adopting NAFO denitrification of autotrophic organism, effectively solve the problem of carbon source deficiency in wastewater biological denitrificaion dephosphorization process.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of spontaneous high ferro chemical dephosphorization-anaerobism iron oxidation biological denitrificaion integrated apparatus is provided.
Spontaneous high ferro chemical dephosphorization-anaerobism iron oxidation biological denitrificaion integrated apparatus is provided with chemical flocculation precipitation district, ferrous salt additional area, denitrogenation dephosphorizing district and three-phase separation area from top to bottom successively; Chemical flocculation precipitation district is provided with solid-liquid separation dephosphorization district and the dephosphorization district of flocculating at a slow speed from bottom to top, bottom centre of solid-liquid separation dephosphorization district is provided with chemical sludge discharge outlet, solid-liquid separation dephosphorization district and the dephosphorization district of flocculating at a slow speed directly connect, and the central upper portion place of dephosphorization district of flocculating is at a slow speed provided with hydraucone; Top, chemical flocculation precipitation district is connected and connects with ferrous salt additional area by supporting plate, and ferrous salt additional area inside is provided with Zero-valent Iron fill area; Ferrous salt additional area top is connected with denitrogenation dephosphorizing district by post disc type up-flow water distributor, denitrogenation dephosphorizing district is provided with stage casing, rapid precipitation dephosphorization district and iron oxidation biological denitrificaion district from inside to outside successively, rapid precipitation dephosphorization district hypomere is positioned at chemical flocculation precipitation district, hypomere end, rapid precipitation dephosphorization district is provided with hydraucone, hydraucone below is provided with reflector, top, stage casing, rapid precipitation dephosphorization district is provided with from bottom to top successively into stype hydrophone and taper water-in, enter stype hydrophone and be connected with drug-feeding tube, taper water-in) be connected with water inlet pipe; Denitrogenation dephosphorizing district is oxidized top, biological denitrificaion district by iron and three-phase separation area connects, three-phase separation area is provided with rapid precipitation dephosphorization district epimere, outgas district and settling region from inside to outside successively, outgas district and settling region are separated by mud guard, three-phase separation area bottom is provided with biological sludge discharge outlet, and three-phase separation area top is provided with refluxing opening, overflow weir and water outlet.
Described hydraucone is positioned at 1/4 ~ 1/3 place, top, dephosphorization district of flocculating at a slow speed.The described stype hydrophone that enters is positioned at 1/4 ~ 1/3 place, top, stage casing, rapid precipitation dephosphorization district, and taper water-in is positioned at 1/5 ~ 1/4 place, top, stage casing, rapid precipitation dephosphorization district.Described stage casing, rapid precipitation dephosphorization district and iron oxidation biological denitrificaion district sectional area ratio are 1:20 ~ 40.The described dephosphorization of flocculation at a slow speed district and iron oxidation biological denitrificaion district height ratio are 1:5 ~ 10.Described refluxing opening is positioned at 1/3 ~ 1/2 place, top, settling region, and refluxing opening phegma flow and taper water-in flooding velocity ratio are 0.4 ~ 3.0.Described bottom, chemical flocculation precipitation district inclination alpha is 55 °, and reflector cone angle beta is 17 °, and three-phase separation area bottom tilt angle gamma is 50 °, and upper end, stage casing, rapid precipitation dephosphorization district inclination angle δ is 145 °, and mud guard bottom inclination angle ε is 140 °.
The present invention's beneficial effect is compared with prior art: 1) reactor is made up of chemical flocculation precipitation district, ferrous salt additional area, denitrogenation dephosphorizing district and four unit of three-phase separation area, and adjacent cells has complementary functions, compact construction, and floor space is little; 2) by structure ingehious design, realize the recycle of chemical dephosphorization process and biological denitrification process matrix, reduce additional pharmaceutical quantities; 3), by backflow anaerobism iron oxidation reaction product, for chemical dephosphorization provides ferric salt precipitation agent, reduce dephosphorization cost; 4) dissolve the Zero-valent Iron such as cheap iron filings/scum by the acid-reaction liquid after ferric salt dephosphorization, for biological denitrificaion provides ferrous salt matrix, the treatment of wastes with processes of wastes against one another; 5) associating autotrophic type biological denitrification process and chemical dephosphorization technique, in one, effectively solve the carbon resource shortage problem in wastewater biological denitrificaion dephosphorization process.
Brief description of the drawings
Fig. 1 is spontaneous high ferro chemical dephosphorization-anaerobism iron oxidation biological denitrificaion integrated apparatus section of structure;
Fig. 2 is spontaneous high ferro chemical dephosphorization-anaerobism iron oxidation biological denitrificaion integrated apparatus structure A-A sectional view;
In figure: chemical flocculation precipitation district I, ferrous salt additional area II, denitrogenation dephosphorizing reaction zone III, three-phase separation area IV; Chemical sludge discharge outlet 1, solid-liquid separation dephosphorization district 2, reflector 3, hydraucone 4, at a slow speed flocculate dephosphorization district 5, supporting plate 6, Zero-valent Iron fill area 7, post disc type up-flow water distributor 8, rapid precipitation dephosphorization district 9, iron oxidation biological denitrificaion district 10, drug-feeding tube 11, enter stype hydrophone 12, water inlet pipe 13, taper water-in 14, mud guard 15, outgas district 16, settling region 17, overflow weir 18, water outlet 19, refluxing opening 20, biological sludge discharge outlet 21.
Embodiment
As shown in Figure 1, 2, spontaneous high ferro chemical dephosphorization-anaerobism iron oxidation biological denitrificaion integrated apparatus is provided with chemical flocculation precipitation district I, ferrous salt additional area II, denitrogenation dephosphorizing district III and three-phase separation area IV from top to bottom successively, chemical flocculation precipitation district I is provided with solid-liquid separation dephosphorization district 2 and the dephosphorization district 5 of flocculating at a slow speed from bottom to top, 2 bottom centre of solid-liquid separation dephosphorization district are provided with chemical sludge discharge outlet 1, solid-liquid separation dephosphorization district 2 and the dephosphorization district 5 of flocculating at a slow speed directly connect, and the 5 central upper portion places of dephosphorization district of flocculating are at a slow speed provided with hydraucone 4, I top, chemical flocculation precipitation district is connected and connects with ferrous salt additional area II by supporting plate 6, and ferrous salt additional area II inside is provided with Zero-valent Iron fill area 7, ferrous salt additional area II top is connected with denitrogenation dephosphorizing district III by post disc type up-flow water distributor 8, denitrogenation dephosphorizing district III is provided with 9 stage casings, rapid precipitation dephosphorization district and iron oxidation biological denitrificaion district 10 from inside to outside successively, rapid precipitation dephosphorization district 9 hypomeres are positioned at chemical flocculation precipitation district I, 9 hypomere ends, rapid precipitation dephosphorization district are provided with hydraucone 4, hydraucone 4 belows are provided with reflector 3, 9 tops, stage casing, rapid precipitation dephosphorization district are provided with from bottom to top successively into stype hydrophone 12 and taper water-in 14, entering stype hydrophone 12 is connected with drug-feeding tube 11, taper water-in 14 is connected with water inlet pipe 13, denitrogenation dephosphorizing district III is oxidized 10 tops, biological denitrificaion district by iron and three-phase separation area IV connects, three-phase separation area IV is provided with rapid precipitation dephosphorization district 9 epimeres, outgas district 16 and settling region 17 from inside to outside successively, outgas district 16 and settling region 17 are separated by mud guard 15, three-phase separation area IV bottom is provided with biological sludge discharge outlet 21, and three-phase separation area IV top is provided with refluxing opening 20, overflow weir 18 and water outlet 19.
Described hydraucone 4 is positioned at 1/4 ~ 1/3 place, 5 top, dephosphorization district of flocculating at a slow speed.The described stype hydrophone 12 that enters is positioned at 1/4 ~ 1/3 place, 9 top, stage casing, rapid precipitation dephosphorization district, and taper water-in 14 is positioned at 1/5 ~ 1/4 place, 9 top, stage casing, rapid precipitation dephosphorization district.Described 9 stage casings, rapid precipitation dephosphorization district and iron oxidation biological denitrificaion district 10 sectional area ratios are 1:20 ~ 40.The described dephosphorization of flocculation at a slow speed district 5 is 1:5 ~ 10 with iron oxidation biological denitrificaion district 10 height ratio.Described refluxing opening 20 is positioned at 1/3 ~ 1/2 place, 17 top, settling region, and refluxing opening 20 phegma flows and taper water-in 14 flooding velocity ratios are 0.4 ~ 3.0.Described chemical flocculation precipitation district I bottom inclination alpha is 55 °, and reflector 3 cone angle beta are 17 °, and three-phase separation area IV bottom tilt angle gamma is 50 °, and rapid precipitation dephosphorization district 9 upper end, stage casing inclination angle δ are 145 °, and mud guard 18 inclination angle, bottom ε are 140 °.
Spontaneous high ferro chemical dephosphorization-anaerobism iron oxidation biological denitrificaion integrated apparatus can be made of PVC plate and steel plate, its working process is as follows: containing the waste water of nitre nitrogen/nitrite nitrogen and phosphorus, and refluxed through refluxing opening 20 by settling region 17 be rich in ferric salt solution together by water inlet pipe 13 access to plant rapid precipitation dephosphorization districts 9, mixed solution flow velocity after taper water-in 14 is improved, downwards with through drug-feeding tube 11 with enter adding medicine outside the part of stype hydrophone 12 accesss to plant and fully mix, carry out rapid chemical dephosphorization process; Solidliquid mixture after rapid chemical dephosphorization flows downward, enter by the hydraucone 4 being connected with 9 bottoms, rapid precipitation dephosphorization district the dephosphorization district 5 of flocculating at a slow speed, carry out chemical flocculation dephosphorization process at a slow speed in this region, reacted solid enters solid-liquid separation dephosphorization district 2 downwards and carries out solid-liquid separation, solid matter is discharged by chemical sludge discharge outlet 1, reacted liquid (being acid) upwards enters the Zero-valent Iron fill area 7 of ferrous salt additional area II through supporting plate 6, the Zero-valent Iron material dissolves such as iron filings/scum that inside is filled are ferrous iron; Enter iron oxidation biological denitrificaion district 10 containing ferrous waste water through post disc type up-flow water distributor 8 and carry out biological denitrificaion; Reacted solid-liquid-gas mixture enters three-phase separation area IV through 10 tops, biological denitrificaion district, wherein, gas enters atmosphere through outgas district 16, solidliquid mixture carries out solid-liquid separation through settling region 17, liquid is discharged reactor by overflow weir 18 and water outlet 19, solid is discharged reactor by top biological sludge discharge outlet 21, and in settling region 17, settled solution part refluxes through refluxing opening 20.
Claims (7)
1. spontaneous high ferro chemical dephosphorization-anaerobism iron oxidation biological denitrificaion integrated apparatus, is characterized in that: device is provided with chemical flocculation precipitation district (I), ferrous salt additional area (II), denitrogenation dephosphorizing district (III) and three-phase separation area (IV) from top to bottom successively, chemical flocculation precipitation district (I) is provided with solid-liquid separation dephosphorization district (2) and the dephosphorization district (5) of flocculating at a slow speed from bottom to top, bottom centre of solid-liquid separation dephosphorization district (2) is provided with chemical sludge discharge outlet (1), solid-liquid separation dephosphorization district (2) and the dephosphorization district (5) of flocculating at a slow speed directly connect, and the central upper portion place of dephosphorization district (5) of flocculating is at a slow speed provided with hydraucone (4), top, chemical flocculation precipitation district (I) is connected and connects with ferrous salt additional area (II) by supporting plate (6), and ferrous salt additional area (II) inside is provided with Zero-valent Iron fill area (7), ferrous salt additional area (II) top is connected with denitrogenation dephosphorizing district (III) by post disc type up-flow water distributor (8), denitrogenation dephosphorizing district (III) is provided with (9) stage casing, rapid precipitation dephosphorization district and iron oxidation biological denitrificaion district (10) from inside to outside successively, rapid precipitation dephosphorization district (9) hypomere is positioned at chemical flocculation precipitation district (I), hypomere end, rapid precipitation dephosphorization district (9) is provided with hydraucone (4), hydraucone (4) below is provided with reflector (3), top, stage casing, rapid precipitation dephosphorization district (9) is provided with from bottom to top successively into stype hydrophone (12) and taper water-in (14), entering stype hydrophone (12) is connected with drug-feeding tube (11), taper water-in (14) is connected with water inlet pipe (13), denitrogenation dephosphorizing district (III) is oxidized (10) top, biological denitrificaion district by iron and three-phase separation area (IV) connects, three-phase separation area (IV) is provided with rapid precipitation dephosphorization district (9) epimere, outgas district (16) and settling region (17) from inside to outside successively, separate by mud guard (15) outgas district (16) and settling region (17), three-phase separation area (IV) bottom is provided with biological sludge discharge outlet (21), and three-phase separation area (IV) top is provided with refluxing opening (20), overflow weir (18) and water outlet (19).
2. the spontaneous high ferro chemical dephosphorization-anaerobism of one according to claim 1 iron oxidation biological denitrificaion integrated apparatus, is characterized in that: described hydraucone (4) is positioned at 1/4 ~ 1/3 place, top of dephosphorization district (5) of flocculating at a slow speed.
3. the spontaneous high ferro chemical dephosphorization-anaerobism of one according to claim 1 iron oxidation biological denitrificaion integrated apparatus, it is characterized in that: the described stype hydrophone (12) that enters is positioned at 1/4 ~ 1/3 place, top, stage casing of rapid precipitation dephosphorization district (9), and taper water-in (14) is positioned at 1/5 ~ 1/4 place, top, stage casing of rapid precipitation dephosphorization district (9).
4. the spontaneous high ferro chemical dephosphorization-anaerobism of one according to claim 1 iron oxidation biological denitrificaion integrated apparatus, is characterized in that: described (9) stage casing, rapid precipitation dephosphorization district and iron oxidation biological denitrificaion district (10) sectional area ratio are 1:20 ~ 40.
5. the spontaneous high ferro chemical dephosphorization-anaerobism of one according to claim 1 iron oxidation biological denitrificaion integrated apparatus, is characterized in that: the described dephosphorization of flocculation at a slow speed district (5) is 1:5 ~ 10 with iron oxidation biological denitrificaion district (10) height ratio.
6. the spontaneous high ferro chemical dephosphorization-anaerobism of one according to claim 1 iron oxidation biological denitrificaion integrated apparatus, it is characterized in that: described refluxing opening (20) is positioned at 1/3 ~ 1/2 place, top, settling region (17), refluxing opening (20) phegma flow and taper water-in (14) flooding velocity ratio are 0.4 ~ 3.0.
7. the spontaneous high ferro chemical dephosphorization-anaerobism of one according to claim 1 iron oxidation biological denitrificaion integrated apparatus, it is characterized in that: described bottom, chemical flocculation precipitation district (I) inclination alpha is 55 °, reflector (3) cone angle beta is 17 °, three-phase separation area (IV) bottom tilt angle gamma is 50 °, rapid precipitation dephosphorization district (9) upper end, stage casing inclination angle δ is 145 °, and mud guard (18) inclination angle, bottom ε is 140 °.
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CN103193360B (en) * | 2012-01-09 | 2014-05-14 | 济南大学 | Nitrogen and phosphorus removal integrated biological aerated filter water purification system and water purification method thereof |
CN102659207B (en) * | 2012-04-26 | 2015-02-04 | 南京道科环境科技有限公司 | Clarification, denitrification and dephosphorization integrated high efficiency equipment |
CN102795744A (en) * | 2012-08-10 | 2012-11-28 | 杭州净洋环保科技有限公司 | Integrated life sewage nitrogen and phosphorus removal apparatus |
CN103420480B (en) * | 2013-08-07 | 2015-11-11 | 浙江大学 | A kind of anaerobism molysite biological denitrification process |
CN203602456U (en) * | 2013-12-06 | 2014-05-21 | 浙江大学 | self-produced high-iron chemical dephosphorization-anaerobic iron oxidization biological denitrification integrated device |
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2013
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