CN103692618A - Mold structure for polyimide material injection molding, and injection molding process - Google Patents

Mold structure for polyimide material injection molding, and injection molding process Download PDF

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Publication number
CN103692618A
CN103692618A CN201310562751.8A CN201310562751A CN103692618A CN 103692618 A CN103692618 A CN 103692618A CN 201310562751 A CN201310562751 A CN 201310562751A CN 103692618 A CN103692618 A CN 103692618A
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CN
China
Prior art keywords
injection molding
mold
metal insert
polyimide material
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310562751.8A
Other languages
Chinese (zh)
Inventor
赵小葳
薛树青
赵红华
韦亮亮
白春华
刘鹏
张搏
荣玲
梁林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QINHANG ELECTROMECHANICAL CO Ltd SHAANXI PROV
Shaanxi Aero Electric Co Ltd
Original Assignee
QINHANG ELECTROMECHANICAL CO Ltd SHAANXI PROV
Shaanxi Aero Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QINHANG ELECTROMECHANICAL CO Ltd SHAANXI PROV, Shaanxi Aero Electric Co Ltd filed Critical QINHANG ELECTROMECHANICAL CO Ltd SHAANXI PROV
Priority to CN201310562751.8A priority Critical patent/CN103692618A/en
Publication of CN103692618A publication Critical patent/CN103692618A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/72Heating or cooling
    • B29C45/73Heating or cooling of the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/38Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/27Sprue channels ; Runner channels or runner nozzles
    • B29C45/2701Details not specific to hot or cold runner channels
    • B29C45/2708Gates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/34Moulds having venting means

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

The present invention provides a mold structure for polyimide material injection molding, and an injection molding process. According to the present invention, the designed mold is provided with a heating device and a thermal insulation layer so as to ensure thermal efficiency and mold temperature stability; the material adopted in the mold molding portion must select a material with a low high-temperature thermal expansion coefficient, and the molding portion material hardness is more than HRC55 so as to easily achieve smooth demolding of the product; the demolding inclination of the mold cavity is greater than 0.5 DEG so as to ensure smooth demolding of the product and no scratch on the surface; each position corresponding to the metal insert or the hole is provided with a gas exhaust groove so as to meet the purpose of weld line eliminating; when the large size product is provided with the metal insert, the metal insert must be subjected to a chemical corrosion treatment or surface sand blowing cleaning, and be coated with the high temperature coupling agent such as A-151 and the like; and after being processed, the product is required to directly enter an oven with a temperature of 200+/-5 DEG C to carry out a stabilization treatment so as to prevent product crack generation.

Description

Polyimide material die for injection molding structure and injection molding technique
Technical field
The invention belongs to Design of Dies and moulding process, be specifically related to a kind of polyimide material die for injection molding structure and injection molding technique.
Background technology
Owing to thering is very stable fragrant heterocycle structure in polyimide molecule, make it embody the incomparable excellent electrical insulating property of other macromolecular materials, wearability, high temperature resistance radiation and Physical Mechanical.Meanwhile, as the exsertile tip materials of a kind of property, polyimides has been widely used in the fields such as electromechanics, electric, instrument, petrochemical industry, metering, and becomes one of indispensable materials in hard-core technology field such as global rocket, aerospace.
Polyimides (PI) is heat-resistant polymer, 500 ℃ of energy short-terms, keeps main physical property, can be for a long time uses approaching under 300 ℃ of conditions.In resistant to elevated temperatures engineering plastics, it is one of kind of most worthy.
If this material adopts compression molding, multiple pressure is made section bar, and the method for rear employing machining guarantees shape of product and dimensional requirement; If employing injection moulding, need mould straight forming, but because this material flowability is poor, forming materials temperature is high, therefore its mold structure, molding and processing technology are different from general injection material, at this, with regard to this material injection mould structure design feature and moulding process, study.
Summary of the invention
The technical problem solving
For fear of the deficiencies in the prior art part, the present invention proposes a kind of polyimide material die for injection molding structure and injection molding technique.
Technical scheme
A polyimide material die for injection molding structure, is characterized in that: at mold cavity place, heating rod hole is set, hot pin is provided with heating rod in hole; Surrounding at mould is provided with thermal insulation layer; The draft angle of mold cavity is greater than 0.5 °; Enter cast gate and adopt direct feeding manner, the depth dimensions that enters cast gate need reach 2/3 of cast gate place wall thickness; Air discharge duct is offered in position in each corresponding metal insert or hole.
The material hardness of mould molding part is more than HRC55.
Mold core, mold cavity surface must carry out chromium plating processing.
Mold core, mold cavity surface roughness are Ra0.1.
The degree of depth minimum of described air discharge duct is 0.5mm.
When the plastics wall thickness around metal insert or hole is less than 1mm, increase herein wall thickness 2~3mm.
Adopt above-mentioned mould structure to carry out the injection molding technique of polyimide material, it is characterized in that step is as follows:
Step 1: material is dried to processing according to material drying process condition;
Step 2: metal insert is carried out to preheating, and preheat temperature is identical with mold temperature or higher than 10 ℃ of mold temperatures;
Step 3: mold heated temperature are controlled to 200~230 ℃, then inject polyimide material;
Step 4: the product after moulding is directly put into the baking oven of 200 ± 5 ℃, wait stablizing after the processing time finishes, cooling with case.
In step 2, as metal insert appearance and size > Φ 80 * 100, during plastics wall thickness≤2mm, before moulding, chemical attack processing or the processing of surperficial blast clean surface are carried out in the surface of metal insert and plastic bonding, then apply resistant to elevated temperatures coupling agent.
Described coupling agent is A-151.
In step 3, when goods appearance and size is greater than about Φ 60 * 80, and wall thickness is while being less than 2mm, and mold temperature need be brought up to 260 ℃.
Beneficial effect
A kind of polyimide material die for injection molding structure and injection molding technique that the present invention proposes, the mould of design arranges heater and thermal insulation layer, guarantees the stability of the thermal efficiency and mold temperature; Mould molding part material therefor must be selected the material that high temperature thermal coefficient of expansion is little, and moulding section material hardness need, more than HRC55, be convenient to the smooth demoulding of product; The draft angle of mold cavity should be greater than 0.5 °, and assurance product is deviate from smoothly, and does not pull on surface; Air discharge duct is offered in position in each corresponding metal insert or hole, meets the object of eliminating weld mark.When large product band metal insert, metal insert must carry out chemical attack processing or surperficial blast and clean, and is coated with high temperature coupling agent as A-151 etc.; In addition, after product processing, need directly to enter in 200 ± 5 ℃ of baking ovens and stablize processing, prevent that product from cracking.
Accompanying drawing explanation
The part overall schematic of Fig. 1: embodiment 1, the thin part L of wall is less than 1mm;
Fig. 2: to the thin part of part integral wall of embodiment 1, L increases by 2~3mm
Fig. 3: the local enlarged diagram that the thin part L of the part integral wall of embodiment 1 is increased to 2~3mm
The part overall schematic of Fig. 4: embodiment 2.
The specific embodiment
Now in conjunction with the embodiments, the invention will be further described for accompanying drawing:
Polyimide material die for injection molding structure for the embodiment of the present invention 1, is characterized in that: at mold cavity place, heating rod hole is set, hot pin is provided with heating rod in hole; Surrounding at mould is provided with thermal insulation layer; The heater that mould arranges, its heating power should be able to meet 260 ℃ of temperature requirements.With heating rod, heat to improve mold temperature.In order to guarantee the stability of the thermal efficiency and mold temperature, need to be at surrounding's increase thermal insulation layer of mould.
The draft angle of mold cavity is greater than 0.5 °, and to guarantee that product deviates from smoothly, does not pull on surface.
Enter cast gate and adopt direct feeding manner, the depth dimensions that enters cast gate need reach 2/3 of cast gate place wall thickness; Air discharge duct is offered in position in each corresponding metal insert or hole, and degree of depth minimum is 0.5mm.To guarantee product appearance quality and to melt commissure intensity.
Because the metal insert of the present embodiment or hole plastics wall thickness are around when thinner, as be less than 1mm, adopting increases air discharge duct and cannot meet the object of eliminating weld mark, need increase wall thickness 2~3mm being less than 1mm part, see Fig. 3.
The material hardness of mould molding part is more than HRC55, and mold core, mold cavity surface must carry out chromium plating processing, and mold core, mold cavity surface roughness are Ra0.1.Because this material, in forming process, polycondensation reaction can occur, there is low molecular weight volatile deposits yields, to mould, can cause corrosion, surface roughness is Ra0.1, is convenient to the smooth demoulding of product.
Adopt mould structure to carry out the injection molding technique of polyimide material, it is characterized in that step is as follows:
Step 1: material is dried to processing according to material drying process condition;
Step 2: metal insert is carried out to preheating, and preheat temperature is identical with mold temperature or higher than 10 ℃ of mold temperatures;
Step 3: mold heated temperature are controlled to 200~230 ℃, then inject polyimide material; When goods appearance and size is greater than about Φ 60 * 80, and wall thickness is while being less than 2mm, and mold temperature need be brought up to 260 ℃.
Step 4: the product after moulding is directly put into the baking oven of 200 ± 5 ℃, wait stablizing after the processing time finishes, cooling with case.
For the about Φ 80 * 100 of metal insert appearance and size >, during plastics wall thickness≤2mm, in order to guarantee the bonding of metal insert and plastics, the crackle that minimizing causes because of material after-contraction or come off, before moulding, need the surface of metal insert and plastic bonding to carry out chemical attack processing or the processing of surperficial blast clean surface, the resistant to elevated temperatures coupling agent of rear coating is as A-151.

Claims (10)

1. a polyimide material die for injection molding structure, is characterized in that: at mold cavity place, heating rod hole is set, hot pin is provided with heating rod in hole; Surrounding at mould is provided with thermal insulation layer; The draft angle of mold cavity is greater than 0.5 °; Enter cast gate and adopt direct feeding manner, the depth dimensions that enters cast gate need reach 2/3 of cast gate place wall thickness; Air discharge duct is offered in position in each corresponding metal insert or hole.
2. polyimide material die for injection molding structure according to claim 1, is characterized in that: the material hardness of mould molding part is more than HRC55.
3. according to polyimide material die for injection molding structure described in claim 1 or 2, it is characterized in that: mould molding inner surface must carry out chromium plating processing.
4. polyimide material die for injection molding structure according to claim 1, is characterized in that: the inside surface roughness of mould is Ra0.1.
5. polyimide material die for injection molding structure according to claim 1, is characterized in that: the degree of depth of described air discharge duct is minimum is 0.5mm.
6. polyimide material die for injection molding structure according to claim 1, is characterized in that: when metal insert or hole plastics wall thickness are around less than 1mm, increase herein wall thickness 2~3mm.
7. described in employing claim 1~6, any one mould structure carries out the injection molding technique of polyimide material, it is characterized in that step is as follows:
Step 1: material is dried to processing according to material drying process condition;
Step 2: metal insert is carried out to preheating, and preheat temperature is identical with mold temperature or higher than 10 ℃ of mold temperatures;
Step 3: mold heated temperature are controlled to 200~230 ℃, then inject polyimide material;
Step 4: the product after moulding is directly put into the baking oven of 200 ± 5 ℃, wait stablizing after the processing time finishes, cooling with case.
8. technique according to claim 7, it is characterized in that: in step 2, as metal insert appearance and size > Φ 80 * 100, during plastics wall thickness≤2mm, before moulding, chemical attack processing or the processing of surperficial blast clean surface are carried out in the surface of metal insert and plastic bonding, then apply resistant to elevated temperatures coupling agent.
9. technique according to claim 8, is characterized in that: described coupling agent is A-151.
10. technique according to claim 8, is characterized in that: in step 3, when goods appearance and size is greater than about Φ 60 * 80, and wall thickness is while being less than 2mm, and mold temperature need be brought up to 260 ℃.
CN201310562751.8A 2013-11-12 2013-11-12 Mold structure for polyimide material injection molding, and injection molding process Pending CN103692618A (en)

Priority Applications (1)

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CN201310562751.8A CN103692618A (en) 2013-11-12 2013-11-12 Mold structure for polyimide material injection molding, and injection molding process

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CN201310562751.8A CN103692618A (en) 2013-11-12 2013-11-12 Mold structure for polyimide material injection molding, and injection molding process

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CN103692618A true CN103692618A (en) 2014-04-02

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113320091A (en) * 2021-05-31 2021-08-31 福建泉州市嘉隆模具有限公司 Shoe mold convenient for demolding

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5840504B2 (en) * 1979-02-15 1983-09-06 旭化成株式会社 Injection molding method
CN1154086A (en) * 1994-06-22 1997-07-09 旭化成工业株式会社 Delustered injection molded product of synthetic resin and molding method for the same
CN101249714A (en) * 2008-04-02 2008-08-27 许南旭 Instant heating/cooling device for injection mold and mold temperature control method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5840504B2 (en) * 1979-02-15 1983-09-06 旭化成株式会社 Injection molding method
CN1154086A (en) * 1994-06-22 1997-07-09 旭化成工业株式会社 Delustered injection molded product of synthetic resin and molding method for the same
CN101249714A (en) * 2008-04-02 2008-08-27 许南旭 Instant heating/cooling device for injection mold and mold temperature control method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王澜: "《高分子材料》", 31 January 2009, article "聚亚酰胺", pages: 179 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113320091A (en) * 2021-05-31 2021-08-31 福建泉州市嘉隆模具有限公司 Shoe mold convenient for demolding
CN113320091B (en) * 2021-05-31 2023-08-22 福建泉州市嘉隆模具有限公司 Shoe mold convenient for demolding

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Application publication date: 20140402