CN103691289B - The processing method of molten sulfur pond tail gas in a kind of claus process - Google Patents
The processing method of molten sulfur pond tail gas in a kind of claus process Download PDFInfo
- Publication number
- CN103691289B CN103691289B CN201410026037.1A CN201410026037A CN103691289B CN 103691289 B CN103691289 B CN 103691289B CN 201410026037 A CN201410026037 A CN 201410026037A CN 103691289 B CN103691289 B CN 103691289B
- Authority
- CN
- China
- Prior art keywords
- subsider
- tail gas
- molten sulfur
- sulphur
- desulfurizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 title claims abstract description 67
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 42
- 239000011593 sulfur Substances 0.000 title claims abstract description 42
- 230000008569 process Effects 0.000 title claims abstract description 38
- 238000003672 processing method Methods 0.000 title claims abstract description 11
- 239000007789 gas Substances 0.000 claims abstract description 43
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 230000003009 desulfurizing effect Effects 0.000 claims abstract description 29
- 239000005864 Sulphur Substances 0.000 claims abstract description 24
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 15
- 230000008929 regeneration Effects 0.000 claims abstract description 15
- 238000011069 regeneration method Methods 0.000 claims abstract description 15
- 238000010521 absorption reaction Methods 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 238000010926 purge Methods 0.000 claims abstract description 9
- 239000002002 slurry Substances 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 230000000694 effects Effects 0.000 claims abstract description 5
- 239000000706 filtrate Substances 0.000 claims abstract description 4
- 230000001172 regenerating effect Effects 0.000 claims abstract description 4
- 239000007787 solid Substances 0.000 claims abstract description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 116
- 229910052742 iron Inorganic materials 0.000 claims description 47
- 239000003054 catalyst Substances 0.000 claims description 26
- 239000002738 chelating agent Substances 0.000 claims description 23
- 239000011734 sodium Substances 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 10
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 9
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 9
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 8
- 229910001447 ferric ion Inorganic materials 0.000 claims description 7
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 6
- 239000003223 protective agent Substances 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 5
- 230000000844 anti-bacterial effect Effects 0.000 claims description 5
- STNSYZSNIYTNMI-UHFFFAOYSA-N azane;[2-[bis(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]methylphosphonic acid Chemical compound N.OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O STNSYZSNIYTNMI-UHFFFAOYSA-N 0.000 claims description 5
- 239000003899 bactericide agent Substances 0.000 claims description 5
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 5
- AVTYONGGKAJVTE-OLXYHTOASA-L potassium L-tartrate Chemical compound [K+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O AVTYONGGKAJVTE-OLXYHTOASA-L 0.000 claims description 5
- 229940111695 potassium tartrate Drugs 0.000 claims description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- MSXHSNHNTORCAW-GGLLEASOSA-M sodium;(2s,3s,4s,5r,6s)-3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].O[C@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O MSXHSNHNTORCAW-GGLLEASOSA-M 0.000 claims description 5
- -1 DTPMPA Chemical compound 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 4
- 239000013522 chelant Substances 0.000 claims description 4
- PZZHMLOHNYWKIK-UHFFFAOYSA-N eddha Chemical compound C=1C=CC=C(O)C=1C(C(=O)O)NCCNC(C(O)=O)C1=CC=CC=C1O PZZHMLOHNYWKIK-UHFFFAOYSA-N 0.000 claims description 4
- 230000005484 gravity Effects 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000001472 potassium tartrate Substances 0.000 claims description 4
- 235000011005 potassium tartrates Nutrition 0.000 claims description 4
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- XIWFQDBQMCDYJT-UHFFFAOYSA-M benzyl-dimethyl-tridecylazanium;chloride Chemical group [Cl-].CCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XIWFQDBQMCDYJT-UHFFFAOYSA-M 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000003446 ligand Substances 0.000 claims description 2
- 150000003333 secondary alcohols Chemical class 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 150000003509 tertiary alcohols Chemical class 0.000 claims description 2
- 229940032912 zephiran Drugs 0.000 claims description 2
- 239000001476 sodium potassium tartrate Substances 0.000 claims 1
- 235000011006 sodium potassium tartrate Nutrition 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 238000006477 desulfuration reaction Methods 0.000 abstract description 3
- 230000023556 desulfurization Effects 0.000 abstract description 3
- 238000012546 transfer Methods 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 239000003500 flue dust Substances 0.000 abstract description 2
- 239000012141 concentrate Substances 0.000 description 18
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 12
- 238000010790 dilution Methods 0.000 description 12
- 239000012895 dilution Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 5
- 235000018553 tannin Nutrition 0.000 description 5
- 229920001864 tannin Polymers 0.000 description 5
- 239000001648 tannin Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000536 complexating effect Effects 0.000 description 4
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 229910001448 ferrous ion Inorganic materials 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PTKWYSNDTXDBIZ-UHFFFAOYSA-N 9,10-dioxoanthracene-1,2-disulfonic acid Chemical compound C1=CC=C2C(=O)C3=C(S(O)(=O)=O)C(S(=O)(=O)O)=CC=C3C(=O)C2=C1 PTKWYSNDTXDBIZ-UHFFFAOYSA-N 0.000 description 1
- 208000005374 Poisoning Diseases 0.000 description 1
- OCBHHZMJRVXXQK-UHFFFAOYSA-M benzyl-dimethyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 OCBHHZMJRVXXQK-UHFFFAOYSA-M 0.000 description 1
- BWNMWDJZWBEKKJ-UHFFFAOYSA-M benzyl-docosyl-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 BWNMWDJZWBEKKJ-UHFFFAOYSA-M 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 208000029039 cyanide poisoning Diseases 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- PGQAXGHQYGXVDC-UHFFFAOYSA-N dodecyl(dimethyl)azanium;chloride Chemical class Cl.CCCCCCCCCCCCN(C)C PGQAXGHQYGXVDC-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000010512 thermal transition Effects 0.000 description 1
Landscapes
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
Description
Numbering | Molten sulfur pond concentration of hydrogen sulfide % | Fluid flow m 3/h | Desulfurization/regeneration temperature DEG C | Purified gas hydrogen sulfide content ppm |
1 | 0.015 | 3 | 45/45 | 0.0 |
2 | 0.032 | 3 | 45/45 | 0.1 |
3 | 0.067 | 3 | 45/45 | 0.1 |
4 | 0.138 | 3 | 45/45 | 0.0 |
5 | 0.179 | 3 | 45/45 | 0.1 |
6 | 0.230 | 3 | 45/45 | 0.0 |
Numbering | Process names | Dominant catalyst | Purified gas hydrogen sulfide content ppm |
1 | Tannin process | Tannin extract catalyst | 26 |
2 | Modified ADA method | Improvement anthraquinone disulphonate | 32 |
3 | FD method | Sulfosalicylic acid Complexing Iron | 49 |
4 | PDS method | PDS catalyst | 58 |
5 | LO-CAT method | Complexing Iron | 5 |
6 | OR-GREEN method | Complexing Iron | 17 |
7 | Novel chelating iron processes | Novel chelated iron | 0.1 |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410026037.1A CN103691289B (en) | 2014-01-21 | 2014-01-21 | The processing method of molten sulfur pond tail gas in a kind of claus process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410026037.1A CN103691289B (en) | 2014-01-21 | 2014-01-21 | The processing method of molten sulfur pond tail gas in a kind of claus process |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103691289A CN103691289A (en) | 2014-04-02 |
CN103691289B true CN103691289B (en) | 2015-11-18 |
Family
ID=50353050
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410026037.1A Active CN103691289B (en) | 2014-01-21 | 2014-01-21 | The processing method of molten sulfur pond tail gas in a kind of claus process |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103691289B (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104043326B (en) * | 2014-06-04 | 2016-08-17 | 北京化工大学 | The device of a kind of industrial gases hypergravity removing hydrogen sulfide and technique |
CN106731593A (en) * | 2016-08-03 | 2017-05-31 | 石家庄市滕泰环保设备有限公司 | Hydrogen sulfide removal system under aerobic conditions |
CN107500253A (en) * | 2017-09-08 | 2017-12-22 | 中冶焦耐(大连)工程技术有限公司 | A kind of claus tail-gas clean-up technique |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6610264B1 (en) * | 1992-04-15 | 2003-08-26 | Exxonmobil Oil Corporation | Process and system for desulfurizing a gas stream |
CN1960940A (en) * | 2004-03-03 | 2007-05-09 | 国际壳牌研究有限公司 | Process for the high recovery efficiency of sulfur from an acid gas stream |
CN101874968A (en) * | 2009-12-31 | 2010-11-03 | 中北大学 | Iron complex desulfurizer suitable for super-gravity desulfurization |
CN102151476A (en) * | 2011-03-29 | 2011-08-17 | 武汉国力通化工环保科技有限公司 | Method for removing hydrogen sulfide in gas phase through oxidization under high gravity field |
-
2014
- 2014-01-21 CN CN201410026037.1A patent/CN103691289B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6610264B1 (en) * | 1992-04-15 | 2003-08-26 | Exxonmobil Oil Corporation | Process and system for desulfurizing a gas stream |
CN1960940A (en) * | 2004-03-03 | 2007-05-09 | 国际壳牌研究有限公司 | Process for the high recovery efficiency of sulfur from an acid gas stream |
CN101874968A (en) * | 2009-12-31 | 2010-11-03 | 中北大学 | Iron complex desulfurizer suitable for super-gravity desulfurization |
CN102151476A (en) * | 2011-03-29 | 2011-08-17 | 武汉国力通化工环保科技有限公司 | Method for removing hydrogen sulfide in gas phase through oxidization under high gravity field |
Also Published As
Publication number | Publication date |
---|---|
CN103691289A (en) | 2014-04-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103752156B (en) | A kind of processing method of claus process tail gas | |
CN103599682A (en) | Method and special device for removing hydrogen sulfide by super-gravity liquid-phase redox | |
CN102151476B (en) | Method for removing hydrogen sulfide in gas phase through oxidization under high gravity field | |
CN105233649B (en) | A kind of Complexing Iron desulfurizing agent and its application method | |
CN103691289B (en) | The processing method of molten sulfur pond tail gas in a kind of claus process | |
EP2383030A1 (en) | Method for removing h2s from gaseous stream at normal temperature | |
CN102527214A (en) | Method for removing hydrogen sulfide from gas | |
CN104548898A (en) | Method and device for combining deep emission reduction of sulfur-containing tail gas | |
CN106669402A (en) | Gas field sulfur-containing waste gas treatment method | |
CN108704455A (en) | A kind of flue gas desulfurization denitration dust-removing technique | |
CN106268218A (en) | A kind of desulfurizing agent | |
CN107635645B (en) | Method and apparatus for desulfurizing a gas stream | |
CN106902625A (en) | A kind of hypergravity Claus tail gases desulphurization system device and application | |
CN107519762A (en) | A kind of clean type coke oven flue gas desulfurization denitration method and application | |
CN102658002A (en) | Method for absorbing and purifying hydrogen sulfide with EDTA (ethylene diamine tetraacetic acid) chelated iron copper compound system | |
CN103055834A (en) | Regeneration method for spent ferric oxide desulfurizer | |
CN111905549B (en) | Absorb H2S desulfurization solution, desulfurization system and desulfurization method | |
CN104787730A (en) | System and method for reducing sulfur dioxide emission concentration of sulfur recovery device and desulfurization agent | |
CN115463539A (en) | Complex iron desulfurizer and application thereof | |
CN111729474A (en) | Method for circulating flue gas desulfurization and sulfur dioxide recovery by using organic acid magnesium solution | |
CN116832873B (en) | Complex iron catalyst for removing hydrogen sulfide in industrial gas and preparation method thereof | |
CN205109370U (en) | Kiln is volatilized including sulphur tail gas desulfurization device to gyration | |
CN109603487B (en) | Stabilizer of iron chelate catalyst in liquid-phase oxidation desulfurization process and desulfurizer containing stabilizer | |
CN204320059U (en) | A kind of for combining the device that the sulfur-containing tail gas degree of depth reduces discharging | |
CN103432878B (en) | The method of hypergravity complexing ferrous smoke-gas wet desulfurization denitration demercuration arsenic integration |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information |
Inventor after: Zeng Xiangpeng Inventor after: Cao Yuhu Inventor after: Hou Yifan Inventor after: Lv Mingfang Inventor before: Zeng Xiangpeng Inventor before: Zhu Yuanbiao Inventor before: Cao Yuhu Inventor before: Hou Yifan Inventor before: Jiang Airu Inventor before: Lv Mingfang |
|
COR | Change of bibliographic data | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP02 | Change in the address of a patent holder |
Address after: 264006 No. 3-12 Kaifeng Road, Yantai Development Zone, Shandong Province, No. 1-2 Patentee after: YANTAIF SUNRISE ENVIRONMENTAL PROTECTION SCIENCE & TECHNOLOGY CO., LTD. Address before: 264000 4th Floor, Tonghe Group, No. 9 Binglun West Road, Zhifu District, Yantai City, Shandong Province Patentee before: YANTAIF SUNRISE ENVIRONMENTAL PROTECTION SCIENCE & TECHNOLOGY CO., LTD. |
|
CP02 | Change in the address of a patent holder | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Processing method of liquid sulfur pool tail gas in claus process Effective date of registration: 20190415 Granted publication date: 20151118 Pledgee: Yantai financing Company Limited by Guarantee Pledgor: YANTAIF SUNRISE ENVIRONMENTAL PROTECTION SCIENCE & TECHNOLOGY CO., LTD. Registration number: 2019980000068 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200422 Granted publication date: 20151118 Pledgee: Yantai financing Company Limited by Guarantee Pledgor: YANTAI SUNRISE ENVIRONMENTAL PROTECTION SCIENCE & TECHNOLOGY Co.,Ltd. Registration number: 2019980000068 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right |