CN103675125B - Test device for sampling efficiency of volatile organic compounds in air - Google Patents
Test device for sampling efficiency of volatile organic compounds in air Download PDFInfo
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Abstract
The invention belongs to the field of environmental monitoring and particularly relates to a test device for sampling efficiency of volatile organic compounds in air. The test device comprises a steel cylinder I, a plurality of steel cylinders II, a temperature and humidity control device, a dynamic uniform-mixing device and a plurality of sampling adsorption devices, wherein the steel cylinder I and the steel cylinders II are connected in parallel with one end of the temperature and humidity control device respectively; the other end of the temperature and humidity control device is connected in series with one end of the dynamic uniform-mixing device; the other end of the dynamic uniform-mixing device is connected in parallel with the sampling adsorption devices. The test device is simple in structure and does not need an air pump; the temperature and humidity of gas are controlled within a certain range or below a certain specific temperature or humidity through the temperature and humidity control device, and thus test results are accurate; the test device is wide in application range, can test the gas sampling efficiency of various sampling manners, also can accurately calculate the adsorption efficiency of adsorbents, and helps to choose appropriate adsorbents and sampling methods.
Description
Technical field
Technical field
The invention belongs to environmental monitoring technology field, be specifically related to a kind of volatile organic matter in air sampling efficiency proving installation.
Background technology
At present, have standard method of analysis to put into effect successively for the determination techniques of volatile organic matter in environmental protection industry (epi) air and waste gas, but method itself mainly emphasize analytical approach, and for standard, the method of sampling is also the most important thing, because the error of sampling is far longer than analytical error.Why these standards do not pay attention to the method for sampling, not because do not know the importance of the method for sampling, but suffer from sampling efficiency problem when not having suitable sampling testing efficiency device to go simulated field to sample, so these standards shirk the heavy work and choose the light have ignored the method for sampling.This is also that greatly volatile organic matter standard puts into effect few and major reason slowly in environmental protection industry (epi) air and waste gas.
And can complying with without environmental protection standard method of occurring of the mensuration of volatile organic matter in environmental protection industry (epi) air and waste gas, most method according to be Ministry of Health of the People's Republic of China's issue People's Republic of China's Occupational hygienic standard GBZ series of tasks place in the mensuration of volatile organic matter.Although this standard comparatively comprehensively and system, method itself is comparatively coarse, let alone considering sampling efficiency, and as the reference of environmental protection standard, it is also a unknown number that the reference of itself and effect have much.
The national standard analytical approach of organic poison in the current used air of workplace of China, the sampling of collecting sample with activated carbon tube increases just increasingly, the sampling that common are machine steam and compound thereof is sampled progressively by the solid adsorbent that absorption affinity is very strong by former absorbing liquid or syringe, as activated charcoal, silica gel etc. replace.According to document announcement, in the air that the U.S. OSHA and NIOSH promulgates organic vapor monitoring method in application of active carbon adsorbent sampler reached hundreds of more than, account for more than 60% of its whole monitoring method.Be enough to thus illustrate that activated charcoal is very wide in the application aspect as solid adsorbent.
At present, gather gaseous sample in air and generally adopt initiatively Sampling techniques, namely use air comprehensively sampling device (built-in motor, as the source of power, adds the speed that flow meter controls sampling) and sampling adsorbent to complete the collection of sample.Sampling adsorbent mainly contains activated charcoal, silica gel, resin and absorbing liquid etc.Although these are have best adsorption effect by the adsorbent selected theoretically, also tested mistake has good effect, but the process of sampling absorption is a complicated process, the effect quality of absorption is determined by several factors, comprises gas temperature humidity, sampling flow velocity, sampling time, the meteorological condition of sampling, the capacity of adsorbent, sampling interference and break through volume etc.Want the collection of simulating actual sample very difficult at present, and cost also high (with a room as source of the gas), substantially do not have a kind of method to realize.
Break through volume (BTV) test is the characteristic index of activated carbon tube sampling, in order to definitely seek the calibrating gas sampling of impact and various variable concentrations that activated carbon tube can be applicable to on-the-spot different humidity temperature (as high concentration, high humility) time, BTV data are very important.Usually, BTV data depend on the adsorptive power of adsorbent itself and change with the change of field environmental condition.BTV is less, then more limit by the sampling time, can not react on-the-spot actual concentration, sampling representativeness is poor.Otherwise BTV is larger, the scene of centering, high concentration is not more by the restriction of time, and sample tests is representative strong, and can reflect the distribution situation of on-the-spot variable concentrations strictly according to the facts.The present invention can simulate the various requirement of break through volume experiment completely, and concentration can arbitrary disposition, the sampling time and sampling quantity enough, just can realize as long as on-the-spot environmental baseline humiture is once arranged gas and changing in the stainless steel cylinder of buffering.
At present, in environmental monitoring, when analog acquisition is carried out in the collecting efficiency test for volatile organic matter in air, large polybag or vent cabinet is often adopted to be equipped with the device of air sampler.There is larger shortcoming at present in these sampling apparatuses, as:
(1) build the system of combination, the running time is long, poor stability temporarily;
(2) volume of once sampling is fixed, the volume of large polybag or vent cabinet and sampling volume (in laboratory large polybag volume 10-20L, vent cabinet volume 100-200L), and sampling volume cannot be changed according to the actual requirements;
(3) large polybag or vent cabinet sampling, gas reduces formation negative pressure and does not consider, causes sampling rate uneven;
(4) large polybag or vent cabinet sampling, gas mixing operating difficulties;
(5) large polybag or vent cabinet temperature, humidity is difficult to control, and is difficult to reach simulated field sampling condition.Therefore need to improve for above-mentioned shortcoming, design a kind of efficiency test device better can simulating actual samples work, being convenient to staff has for the sample of actual acquisition and understands more accurately.
Summary of the invention
For solving the problems of the technologies described above, the invention provides the volatile organic matter in air sampling efficiency proving installation that a kind of structure is simple, easy to use;
The method of traditional sampling efficiency test solves usually in two ways, and one is large polybag or vent cabinet sampling, and this mode gas production volume cannot be simulated with actual conditions, and meteorologic parameter more cannot be mated, poor stability, and tool is not scientific.Two be directly add liquid standard specimen mode to adsorbent, this mode more cannot characterize the adsorptive power under adsorbent actual conditions, and also tool is scientific.And this device actual be the sampling usefulness really simulating adsorbent in actual samples situation, such as during sampling, the humidity of gas production gas is a very important parameter, by test adsorbent usefulness, when supposing more than 90% humidity, adsorbent usefulness obviously declines, and will avoid this high humility situation down-sampling during that actual samples, must to sample gas process, its temperature and humidity is made to remain in certain scope, to improve the accuracy of testing result.
Volatile organic matter in air sampling efficiency proving installation of the present invention is realized by following technical proposals:
Volatile organic matter in air sampling efficiency proving installation, this device comprises the steel cylinder I storing diluents, the steel cylinder II of multiple storage standards gas, temperature humidity control device, dynamic evenly mixing device, multiple sampling adsorbent equipment;
Steel cylinder I, steel cylinder II are in parallel with one end of temperature humidity control device respectively; The other end of temperature humidity control device is connected in series mutually with dynamic evenly mixing device, and the other end of dynamic evenly mixing device is parallel with multiple sampling adsorbent equipment;
All be connected by pipeline between above-mentioned steel cylinder I, steel cylinder II, temperature humidity control device, dynamically evenly mixing device, dynamically evenly mixing device with sampling adsorbent equipment;
All flowmeter is had between evenly mixing device and sampling adsorbent equipment between steel cylinder I and temperature humidity control device, between steel cylinder II and temperature humidity control device, between temperature humidity control device and dynamic evenly mixing device, dynamically;
Temperature humidity control device comprises stove case, the bottom having heaters of stove case, and humidifier is arranged at the top of stove case, and the puff prot of described humidifier is positioned at stove case inside, and the outer wall of stove case has fan; Humidifier adopts ultrasonic atomizing humidifier, and water vapour generation efficiency is high, and the time is short, by the amount regulating the uninterrupted of water to control water vapor generation, between humid control scope 0-95%;
The main body of above-mentioned dynamic evenly mixing device is the stainless steel cylinder that stainless steel is made, and its inside, through electro-polish polishing and deactivation process, prevents absorption and is easy to cleaning, prevents from addition seeing that the labile gas of light decomposes;
There is stirrer dynamic evenly mixing device inside, and the gas entering dynamic evenly mixing device is mixed again by stirrer therein, ensures that the gas of dynamic blending system reaches the requirement of needs.
Above-mentioned pipeline is copper pipe, and copper pipe is high-purity copper material, and inwall, through silanization treatment, ensures that the gas of test does not react with copper pipe, and the gas of test is not residual in copper pipe, and copper pipe quality softness is durable in use.
The fixed support for fixing dynamic evenly mixing device matched with dynamic evenly mixing device is had outside above-mentioned dynamic evenly mixing device, the top of described support and bottom are cross, also can be other shape, such as rice font, its object is to, the position of stainless steel cylinder is firmly fixed.
Dynamic evenly mixing device proof pressure is greater than 100psi.
Temperature humidity control device also comprises temperature sensor, humidity sensor; Display screen and microprocessor; Temperature sensor and humidity sensor lay respectively at the inside of stove case, and temperature sensor, humidity sensor, well heater, humidifier, display screen are connected with microprocessor respectively with fan.The temperature and humidity of temperature humidity control device inside is reacted to microprocessor by temperature sensor and humidity sensor, simultaneously displays temperature and humidity on a display screen, can be regulated and controled the gas temperature of its inside and humidity by this temperature humidity control device of microprocessor, run by well heater or humidifier or fan, to adjust the temperature and humidity of the gas in temperature humidity control device.
Microprocessor is also connected with flowmeter, to control the flow of every bar pipeline;
Also pressure relief valve is parallel with by pipeline with the other end of flow dynamics evenly mixing device.
Sampling adsorbent equipment can be adsorption tube or absorption bottle, and there are solid absorbent or liquid absorption liquid in sampling adsorbent equipment inside.
Fundamental purpose of the present invention be judge test gas when have multiple such as five kinds simulation interference gas, adsorbent now collecting efficiency.Five kinds of simulation interference gas can be selected arbitrarily wherein 1-5 kinds, and concentration range also can regulate arbitrarily.Many components flow gas distributing system gas out has an overall control valve, to control the general pressure of the calibrating gas obtained, and the excessive too small effect that calibration test system all can be caused to test.
Beneficial effect of the present invention is:
(1) have employed above-mentioned volatile organic matter in air sampling efficiency proving installation, its structure is simple, adopts without the need to air pump;
(2) have employed temperature humidity control device, the temperature and humidity of gas is made to control in some scopes or under a certain specific temperature or humidity, the temperature and humidity conditions of actual samples environment when simulating various spot sampling, finds the humiture environment of best sampling with optimal adsorption material.The result that detection is analyzed is more accurate.
(3) sample effect that can detect the gas of multiple sample mode applied widely, as being equipped with sampling pipe or the adsorption tube of different types of sorbing material, sorbing material can be solid adsorbent or liquid absorption liquid;
(4) adsorption of adsorbent can be calculated accurately;
(5) the optimal adsorption material of system of selection can be used for.
(6) can be used for configuring the calibrating gas of variable concentrations.
(7) under the interference gas condition of variable concentrations can be used for simulating, the adsorption of sorbing material.
(8) Best (the temperature and humidity scope of atmospheric sampling) of optimal adsorption material can be used for determining.
(9) break through volume of optimal adsorption material can be used for determining.
Accompanying drawing explanation
Fig. 1 is volatile organic matter in air sampling efficiency proving installation structural representation of the present invention;
Fig. 2 is the lateral plan of temperature humidity control device of the present invention;
Fig. 3 is electrical schematic diagram of the present invention;
Fig. 4 be of the present invention in the structural representation of dynamically evenly mixing device and support;
Fig. 5 is seven kinds of benzene homologues chromatograms;
In figure, 1-steel cylinder I, 2-steel cylinder II, 3-humidifier, 4-temperature humidity control device, 5-well heater, the dynamic evenly mixing device of 6-, 7-stirrer, 8-samples adsorbent equipment, 9-temperature sensor, 10-humidity sensor, 11-fan, 12-microprocessor, 13-display screen, 14-pressure relief valve, 15-flowmeter, 16-support.
Embodiment
Implement example by reference to the accompanying drawings and to be specifically further described the present invention, so that those skilled in the art understand the present invention.
Embodiment 1
Volatile organic matter in air is the most common, analyze maximum is benzene homologues, benzene homologues is generally benzene, toluene, ethylbenzene, P-xylene, m-xylene, o-xylene, isopropyl benzene, cinnamic general designation, it is the compound seen most in atmospheric environment and much pollution source gas, to health, all there is certain damaging effect, wherein benzene was confirmed as strong carcinogen in 1993 by the World Health Organization (WHO), can leukemogenesis and alpastic anemia also be generally acknowledged by medical circle.Therefore they are important pollutants of environment.Now for benzene in air system thing sampling testing efficiency, sampling efficiency proving installation of the present invention is adopted to test.
Volatile organic matter in air sampling efficiency proving installation of the present invention, comprises steel cylinder II 2, temperature humidity control device 4 that one stores steel cylinder I 1, six storage standards gases of diluents, dynamic evenly mixing device 6, six sampling adsorbent equipment 8;
Volatile organic matter in air sampling efficiency proving installation, this device comprises the steel cylinder I 1 storing diluents, the steel cylinder II 2 of multiple storage standards gas, temperature humidity control device 4, dynamic evenly mixing device 6, multiple sampling adsorbent equipment 8;
Steel cylinder I 1, steel cylinder II 2 are in parallel with one end of temperature humidity control device 4 respectively; The other end of temperature humidity control device 4 is connected in series mutually with dynamic evenly mixing device 6, and the other end of dynamic evenly mixing device 6 is parallel with multiple sampling adsorbent equipment 8;
All be connected by pipeline between above-mentioned steel cylinder I 1, steel cylinder II 2, temperature humidity control device 4, dynamically evenly mixing device 6, dynamically evenly mixing device 6 with sampling adsorbent equipment 8;
Flowmeter 15 is all had between evenly mixing device 6 and sampling adsorbent equipment 8 between steel cylinder I 1 and temperature humidity control device 4, between steel cylinder II 2 and temperature humidity control device 4, between temperature humidity control device 4 and dynamic evenly mixing device 6, dynamically;
Temperature humidity control device 4 comprises stove case, the bottom having heaters 5 of stove case, and humidifier 3 is arranged at the top of stove case, and the puff prot of described humidifier 3 is positioned at stove case inside, the outer wall of stove case has fan 11; Humidifier 3 adopts ultrasonic atomizing humidifier 3, and water vapour generation efficiency is high, and the time is short, by the amount regulating the uninterrupted of water to control water vapor generation, between humid control scope 0-95%;
The main body of above-mentioned dynamic evenly mixing device 6 is the stainless steel cylinder that stainless steel is made, and its inside, through electro-polish polishing and deactivation process, prevents absorption and is easy to cleaning, prevents from addition seeing that the labile gas of light decomposes;
There is stirrer 7 dynamic evenly mixing device 6 inside, and the gas entering dynamic evenly mixing device 6 is mixed again by stirrer 7 therein, ensures that the gas of dynamic blending system reaches the requirement of needs.
Above-mentioned pipeline is copper pipe, and copper pipe is high-purity copper material, and inwall, through silanization treatment, ensures that the gas of test does not react with copper pipe, and the gas of test is not residual in copper pipe, and copper pipe quality softness is durable in use.
The fixed support 16 for fixing dynamic evenly mixing device 6 matched with dynamic evenly mixing device 6 is had outside above-mentioned dynamic evenly mixing device 6, top and the bottom of described support 16 are cross, also can be other shape, such as rice font, its object is to, the position of stainless steel cylinder is firmly fixed.
Dynamic evenly mixing device 6 proof pressure is greater than 100psi.
Temperature humidity control device 4 also comprises temperature sensor 9, humidity sensor 10; Display screen 13 and microprocessor 12; Temperature sensor 9 and humidity sensor 10 lay respectively at the inside of stove case, and temperature sensor 9, humidity sensor 10, well heater 5, humidifier 3, display screen 13 are connected with microprocessor 12 respectively with fan 11.The temperature and humidity of temperature humidity control device 4 inside is reacted to microprocessor 12 by temperature sensor 9 and humidity sensor 10, displays temperature and humidity on display screen 13 simultaneously, can be regulated and controled the gas temperature of its inside and humidity by this temperature humidity control device 4 of microprocessor 12, run by well heater 5 or humidifier 3 or fan 11, to adjust the temperature and humidity of the gas in temperature humidity control device 4.
Microprocessor 12 is also connected with flowmeter 15, to control the flow of every bar pipeline;
Also pressure relief valve 14 is parallel with by pipeline with the other end of flow dynamics evenly mixing device 6.
Sampling adsorbent equipment 8 can be adsorption tube or absorption bottle, and there is solid absorbent activated charcoal sampling adsorbent equipment 8 inside.
In the process gathering benzene homologues, comprise following step:
Prepare the standard benzene homologues gas that concentration is 50.0mg/m3, the concentration of gas is used for calculating the organic absolute content of adsorbent, the pressure of the diluents in steel cylinder I 1 is greater than 5 MPas, control between 5-15 MPa, open dividing potential drop table to 0.2-1.0 MPa, the pressure of the calibrating gas in steel cylinder II 2 is greater than 5 MPas, control between 5-15 MPa, actual flow regulates according to the break through volume mass flowmeter 15 of sorbing material, calibrating gas is made to flow into bottom the stove case of temperature humidity control device 4, temperature and humidity in regulating stove case, temperature is adjusted to about 25 DEG C, humidity is 10%, the gas obtained is in the outlet outflow of stove box top, gas enters dynamic evenly mixing device 6 and mixes, gas after mixing enters sampling adsorbent equipment 8, charcoal absorption in adsorbent equipment, export again.
The range of the flowmeter 15 before sampling adsorbent equipment 8 is flow range 10-1000ml/min of spot sampling air sampler at ordinary times, the flow of design discharge meter 15 is 500mL/min, gather 60 minutes, calibrating gas flows through the adsorbent equipment that activated charcoal is housed with the speed of 500mL/min, gas production volume is calculated by sampling time and sampling flow velocity, by gas Chromatographic Determination, the size of the theoretical benzene homologues absolute magnitude multilevel iudge sampling efficiency that the concentration that quantified by external standard method calculates benzene homologues absolute magnitude that actual adsorbent collects and calibrating gas calculates.Because the gas in steel cylinder I 1, II is pressure gas, enough gas volumes can be ensured test, and the gaseous tension in steel cylinder I 1, II in 1 is also the power resources of gas, can ensure the amount of gas, can not form negative pressure.
Embodiment 2
Be with the difference of embodiment 1, in embodiment 2, the flow of design discharge meter 15 is 3000mL/min, gathers 10 minutes.
Embodiment 3
Be with the difference of embodiment 1, in embodiment 3, the flow of design discharge meter 15 is 500mL/min, gathers 200 minutes.
Embodiment 4
Be with the difference of embodiment 1, in embodiment 4, temperature is room temperature, and humidity is 80%, and flow and the acquisition time of design discharge meter 15 are constant.
Measure material: benzene, toluene, ethylbenzene, P-xylene, m-xylene, o-xylene, styrene.
GC conditions:
Chromatographic column: AT-WAX 30m*320 μm of * 0.5 μm of injector temperature: 180 DEG C of detecting device (FID) temperature: 300 DEG C of column temperatures: 65 DEG C of post flow: 2.0ml/min;
Typical curve and instrument detection limit
Compound concentration is followed successively by the benzene homologues class standard of physical solution (this is reference concentration sequence) of 2.0mg/L, 5.0mg/L, 10.0mg/L, 20.0mg/L, 50 mg/L and 100 mg/L.
In this concentration range, the related coefficient of 8 kinds of components is all greater than 0.999.With signal to noise ratio (S/N ratio) for calculating the instrument detection limit of each material, acquired results sees the following form.
The linear equation of 7 kinds of benzene homologues class materials
The concentration of four kinds of embodiment Plays gases is all 50.0mg/m3, and the testing time in each embodiment is 6 times, and use gas chromatographic analysis after collecting calibrating gas standard method of analysis the solvent analysis in each embodiment, the data obtained are as follows:
Embodiment 1
Embodiment 2
Embodiment 3
Embodiment 4
Data result shows:
Seven kinds of benzene homologues, six image data relative standard deviations of embodiment 1 are 1.13%-3.07%, seven kinds of benzene homologues, six the image data relative standard deviations implementing example 2 are 1.96%-5.46%, seven kinds of benzene homologues, six the image data relative standard deviations implementing example 3 are 1.80%-3.52%, all meet or be better than other device.
Embodiment 1 compares with embodiment 2, the gas volume gathered be all 30L, and the benzene homologues absolute magnitude that two kinds of methods collect in theory is the same, but reaches 3L/min because of the gas flow rate of embodiment 2, adsorbent can not be effectively very fast absorption, so embodiment 2 is poorer than embodiment 1 adsorption efficiency.Two kinds of embodiments show that this device can test the optimal adsorption speed of adsorbent.
Embodiment 1 compares with embodiment 3, the gas volume that embodiment 1 gathers is 30L, the gas volume that embodiment 3 gathers is 100L, the benzene homologues absolute magnitude example 3 that two kinds of methods collect in theory is 3.3 times of example 1, but actual acquisition to benzene homologues absolute magnitude example 3 are about 2 times of example 1, this situation shows that embodiment 3 adsorbent reaches state of saturation when collecting certain benzene homologues, now adsorbent is without adsorption, and two kinds of embodiments show that this device can test the optimal adsorption amount of adsorbent.
Embodiment 1 compares with embodiment 4, room temperature is consistent, the gas volume gathered is 30L, gas production adsorbent unsaturation, gas recovery velocity is consistent, but seven kinds of benzene homologues, six the image data relative standard deviations implementing example 4 are 11.63%-27.84%, deviation is comparatively large, this is because affect the humidity of an important indicator gas of adsorbent usefulness.When the humidity of gas is larger, the adsorption of adsorbent obviously declines.
Two kinds of embodiments show that device of the present invention can test the optimal adsorption condition of adsorbent.
Certain volatile organic matter in air sampling efficiency proving installation of the present invention is not merely applicable to the benzene homologues in above cited air, is also applicable to other volatile organic matter.
Claims (9)
1. volatile organic matter in air sampling efficiency proving installation, is characterized in that, described device comprises the steel cylinder I storing diluents, the steel cylinder II of multiple storage standards gas, temperature humidity control device, dynamic evenly mixing device, multiple sampling adsorbent equipment;
Described steel cylinder I, steel cylinder II are in parallel with one end of temperature humidity control device respectively; The other end of described temperature humidity control device is connected in series mutually with dynamic evenly mixing device, and the other end of dynamic evenly mixing device is parallel with multiple sampling adsorbent equipment;
All be connected by pipeline between above-mentioned steel cylinder I, steel cylinder II, temperature humidity control device, dynamically evenly mixing device with sampling adsorbent equipment;
All flowmeter is had between evenly mixing device and sampling adsorbent equipment between steel cylinder I and temperature humidity control device, between steel cylinder II and temperature humidity control device, between temperature humidity control device and dynamic evenly mixing device, dynamically;
Described temperature humidity control device comprises stove case, the bottom having heaters of described stove case, and humidifier is arranged at the top of stove case, and the puff prot of humidifier is positioned at stove case inside, and the outer wall of stove case has fan.
2. a kind of volatile organic matter in air sampling efficiency proving installation as claimed in claim 1, is characterized in that, the main body of described dynamic evenly mixing device is stainless steel cylinder.
3. a kind of volatile organic matter in air sampling efficiency proving installation as claimed in claim 1 or 2, is characterized in that, there is stirrer described dynamic evenly mixing device inside.
4. a kind of volatile organic matter in air sampling efficiency proving installation as claimed in claim 1, it is characterized in that, described pipeline is copper pipe.
5. a kind of volatile organic matter in air sampling efficiency proving installation as claimed in claim 1, it is characterized in that, have outside described dynamic evenly mixing device match with dynamic evenly mixing device and for the fixed support of fixing dynamic evenly mixing device, the top of described support and bottom are cross.
6. a kind of volatile organic matter in air sampling efficiency proving installation as claimed in claim 1, is characterized in that, described dynamic evenly mixing device proof pressure is greater than 100psi.
7. a kind of volatile organic matter in air sampling efficiency proving installation as claimed in claim 1, it is characterized in that, described temperature humidity control device also comprises temperature sensor, humidity sensor; Display screen and microprocessor; Described temperature sensor and humidity sensor lay respectively at the inside of stove case, and described temperature sensor, humidity sensor, well heater, humidifier, display screen are connected with microprocessor respectively with fan; Described microprocessor is also connected with flowmeter.
8. a kind of volatile organic matter in air sampling efficiency proving installation as claimed in claim 1, it is characterized in that, the other end of flow dynamics evenly mixing device is also parallel with pressure relief valve by pipeline.
9. a kind of volatile organic matter in air sampling efficiency proving installation as claimed in claim 1, is characterized in that having adsorbent or adsorption liquid in described sampling adsorbent equipment.
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| CN106482988A (en) * | 2016-12-13 | 2017-03-08 | 北京大学 | A kind of Portable high-flow air sampler |
| CN108693261A (en) * | 2018-04-12 | 2018-10-23 | 广州市赛特检测有限公司 | A kind of detection method and sampling apparatus of Indoor Air Benzene and total volatile organic compounds |
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| CN101493383A (en) * | 2009-02-20 | 2009-07-29 | 广州市纤维产品检测院 | Volatile substance generating and acquiring system |
| CN201561960U (en) * | 2009-12-15 | 2010-08-25 | 环境保护部南京环境科学研究所 | Device for detecting agricultural chemical volatility |
| JP2013195280A (en) * | 2012-03-21 | 2013-09-30 | Sumitomo Metal Mining Co Ltd | Collector, analyzer and analytical method using the same |
| CN203643409U (en) * | 2013-11-27 | 2014-06-11 | 江苏省环境监测中心 | Tester for testing sampling efficiency of volatile organic compound in air |
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| US7247278B2 (en) * | 2000-08-28 | 2007-07-24 | Burge Scott R | Automated ground water monitoring and analysis system |
| CN101493383A (en) * | 2009-02-20 | 2009-07-29 | 广州市纤维产品检测院 | Volatile substance generating and acquiring system |
| CN201561960U (en) * | 2009-12-15 | 2010-08-25 | 环境保护部南京环境科学研究所 | Device for detecting agricultural chemical volatility |
| JP2013195280A (en) * | 2012-03-21 | 2013-09-30 | Sumitomo Metal Mining Co Ltd | Collector, analyzer and analytical method using the same |
| CN203643409U (en) * | 2013-11-27 | 2014-06-11 | 江苏省环境监测中心 | Tester for testing sampling efficiency of volatile organic compound in air |
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