CN103667972B

CN103667972B - A kind of special type wear-resistant alloy material and preparation method thereof

Info

Publication number: CN103667972B
Application number: CN201310550328.6A
Authority: CN
Inventors: 梅百荣; 徐志勇
Original assignee: TONGLING ANDONG CAST STEEL CO Ltd
Current assignee: TONGLING ANDONG CAST STEEL CO Ltd
Priority date: 2013-11-08
Filing date: 2013-11-08
Publication date: 2016-04-27
Anticipated expiration: 2033-11-08
Also published as: CN103667972A

Abstract

A kind of special type wear-resistant alloy material, the chemical element composition that it contains and mass percent thereof are: carbon 0.1-0.3, silicon 0.3-0.5, boron 0.1-0.2, chromium 3.0-3.3, nickel 11.0-11.5, cobalt 3.3-3.5, Mo0.2-0.5, Cu0.6-0.8, Os0.01-0.03, Ir0.003-0.005, Ru0.004-0.006, Rh1.0-2.5, P≤0.030, S≤0.030, surplus are iron.The present invention is by using rare earth element and the combination of other raw metals, proportioning and production technique are rationally set, input order is rationally set, the alloy material formed has good comprehensive mechanical property, the feature such as especially there is intensity and hardness is high, wear resistance is fabulous, can the significant prolongation wear resisting part life-span, reduce the spoilage of machinery, add safety coefficient; And use part scrap iron as raw material, make the steady quality of alloy homogeneous; By adding refining agent, degree of porosity reduces 1-2 degree.

Description

A kind of special type wear-resistant alloy material and preparation method thereof

Technical field

The present invention relates to field of metal preparation, particularly relate to a kind of special type wear-resistant alloy material and preparation method thereof.

Background technology

The development of steel alloy has had the history of more than 100 year, up to the present, diversified steel alloy is industrially employed, mainly contain with Types Below: quenched and tempered steel, spring steel, tool steel, rapid steel, die steel, high, normal, basic carbon alloy steel etc., so far, although steel alloy technology is greatly developed, but, a lot of problem is still had to exist, as fastness to rubbing, hardness, rustless property, corrosion resistance nature, high and low temperature resistance, fragility, toughness, costs etc. can not be taken into account, the requirement of production can't be met in a lot of occasion, also require further improvement, to enhance productivity, reduce costs, improve security, for high-quality precision and sophisticated technology development provides safeguard, for social development provides power, task is also very arduous.

Summary of the invention

The object of the present invention is to provide a kind of special type wear-resistant alloy material and preparation method thereof, this alloy material has high wear resistance and hardness.

Technical scheme of the present invention is as follows:

A kind of special type wear-resistant alloy material, is characterized in that: the chemical element composition that it contains and mass percent thereof are: carbon 0.1-0.3, silicon 0.3-0.5, boron 0.1-0.2, chromium 3.0-3.3, nickel 11.0-11.5, cobalt 3.3-3.5, Mo0.2-0.5, Cu0.6-0.8, Os0.01-0.03, Ir0.003-0.005, Ru0.004-0.006, Rh1.0-2.5, P≤0.030, S≤0.030, surplus are iron.

The production method of described special type wear-resistant alloy material, is characterized in that:

(1), the pig iron and scrap iron are dropped in stove to melt in 1:2 ratio originate as ferrous substrate; Carry out desulfurization, deoxidation, alloying, the refining of employing refining agent, casting, casting postheat treatment etc.;

(2) lot sequence, dropping into alloying element in alloying process in stove is: (1) silicon, boron; (2) Cu, Os, Ir; (3) chromium, nickel, cobalt; (4) other remaining component; The each batch of timed interval of dropping into element is 8-10 minute, stirs after feeding intake.

Described casting postheat treatment is:

First by room temperature with 200-230 DEG C/h of ramp to 915-925 DEG C, insulation 3-4 hour; 620-630 DEG C is cooled to again, insulation 30-60 minute with 140-160 DEG C/h of speed; 320-340 DEG C is cooled to again, insulation 2-3 hour with 100-120 DEG C/h of speed; Again with again with 150-170 DEG C/h of ramp to 520-540 DEG C, insulation 2-3 hour, takes out air cooling and get final product.

Described refining agent is made up of the raw material of following weight part: instrument comminuted steel shot 3-4, clay 13-16, light calcium carbonate 2-3, silicon-dioxide 2-3, zinc oxide 1-2, wollastonite powder 3-4, magnesium hydroxide 10-12, diatomite 4-5, aluminium hydroxide 8-10, jade powder 3-4, montmorillonite 1-2, BaCO33-4, BaF ₂2-3; Each raw material mixes by preparation method, is heated to molten state, then, is poured into Quench in pure water, then is ground into 100-200 order powder; Gained powder is added and is equivalent to the silane resin acceptor kh-550 of powder weight 2-3%, the nano-carbon powder of 1-2%, after mixing, under 8-15Mpa, be pressed into base, then, at 900-950 DEG C, 3-4 hour is calcined, after cooling, be ground into 150-250 order powder again, obtain final product.

Beneficial effect of the present invention

The present invention is by using rare earth element and other material combination, proportioning and production technique are rationally set, input order is rationally set, the alloy material formed has good comprehensive mechanical property, the feature such as especially there is intensity and hardness is high, wear resistance is fabulous, can the significant prolongation wear resisting part life-span, reduce the spoilage of machinery, add safety coefficient; And use part scrap iron as raw material, make the steady quality of alloy homogeneous.Refining agent of the present invention is used for Foundry Production, significantly improves yield rate, and the degree of porosity particularly in foundry goods reduces 1-2 degree, and be controlled effectively, can not produce pore at cast(ing) surface, trapped oxide also obviously reduces, and oxide inclusion is at about 2 grades.

Embodiment

A kind of special type wear-resistant alloy material, the chemical element composition that it contains and mass percent thereof are: carbon 0.1-0.3, silicon 0.3-0.5, boron 0.1-0.2, chromium 3.0-3.3, nickel 11.0-11.5, cobalt 3.3-3.5, Mo0.2-0.5, Cu0.6-0.8, Os0.01-0.03, Ir0.003-0.005, Ru0.004-0.006, Rh1.0-2.5, P≤0.030, S≤0.030, surplus are iron.

The production method of described special type wear-resistant alloy material is:

(2) lot sequence, dropping into alloying element in alloying process in stove is: (1) silicon, boron; (2) Cu, Os, Ir; (3) chromium, nickel, cobalt; (4) other remaining component; The each batch of timed interval of dropping into element is 9 minutes, stirs after feeding intake.

Described casting postheat treatment is: elder generation with 210 DEG C/h of ramp to 920 DEG C, is incubated 3.5 hours by room temperature; Be cooled to 625 DEG C with 150 DEG C/h of speed again, be incubated 46 minutes; Be cooled to 330 DEG C with 110 DEG C/h of speed again, be incubated 2.5 hours; Again with again with 160 DEG C/h of ramp to 530 DEG C, be incubated 2.4 hours, take out air cooling.

Described refining agent is made up of the raw material of following weight part (kilogram): instrument comminuted steel shot 4, clay 13, light calcium carbonate 2, silicon-dioxide 3, zinc oxide 1, wollastonite powder 4, magnesium hydroxide 12, diatomite 4, aluminium hydroxide 8, jade powder 3, montmorillonite 2, BaCO33, BaF ₂2; Each raw material mixes by preparation method, is heated to molten state, then, is poured into Quench in pure water, then is ground into 100-200 order powder; Gained powder is added and is equivalent to the silane resin acceptor kh-550 of powder weight 2-3%, the nano-carbon powder of 1-2%, after mixing, under 8-15Mpa, be pressed into base, then, at 900-950 DEG C, 3-4 hour is calcined, after cooling, be ground into 150-250 order powder again, obtain final product.

The mechanical property of special type wear-resistant alloy material of the present invention is: tensile strength 1056MPa, yield strength 840MPa, unit elongation 14%, relative reduction in area 27%, impact absorbing energy 53J, impelling strength 64J/cm2, hardness 295HB.

Claims

1. a special type wear-resistant alloy material, is characterized in that: the chemical element composition that it contains and mass percent thereof are: carbon 0.1-0.3, silicon 0.3-0.5, boron 0.1-0.2, chromium 3.0-3.3, nickel 11.0-11.5, cobalt 3.3-3.5, Mo0.2-0.5, Cu0.6-0.8, Os0.01-0.03, Ir0.003-0.005, Ru0.004-0.006, Rh1.0-2.5, P≤0.030, S≤0.030, surplus are iron;

The production method of described special type wear-resistant alloy material is as follows:

(1), the pig iron and scrap iron are dropped in stove to melt in 1:2 ratio originate as ferrous substrate; Carry out desulfurization, deoxidation, alloying, the refining of employing refining agent, casting, casting postheat treatment;

(2) lot sequence, dropping into alloying element in alloying process in stove is: (1) silicon, boron; (2) Cu, Os, Ir; (3) chromium, nickel, cobalt; (4) other remaining component; The each batch of timed interval of dropping into element is 8-10 minute, stirs after feeding intake;

Described casting postheat treatment is: first by room temperature with 200-230 DEG C/h of ramp to 915-925 DEG C, insulation 3-4 hour; 620-630 DEG C is cooled to again, insulation 30-60 minute with 140-160 DEG C/h of speed; 320-340 DEG C is cooled to again, insulation 2-3 hour with 100-120 DEG C/h of speed; Again with 150-170 DEG C/h of ramp to 520-540 DEG C, insulation 2-3 hour, takes out air cooling and get final product;

Described refining agent is made up of the raw material of following weight part: instrument comminuted steel shot 3-4, clay 13-16, light calcium carbonate 2-3, silicon-dioxide 2-3, zinc oxide 1-2, wollastonite powder 3-4, magnesium hydroxide 10-12, diatomite 4-5, aluminium hydroxide 8-10, jade powder 3-4, montmorillonite 1-2, BaCO ₃3-4, BaF ₂2-3; Each raw material mixes by preparation method, is heated to molten state, then, is poured into Quench in pure water, then is ground into 100-200 order powder; Gained powder is added and is equivalent to the silane resin acceptor kh-550 of powder weight 2-3%, the nano-carbon powder of 1-2%, after mixing, under 8-15MPa, be pressed into base, then, at 900-950 DEG C, 3-4 hour is calcined, after cooling, be ground into 150-250 order powder again, obtain final product.