CN103667946B - A kind of tungstenic Heat-resistant alloy steel liner plate material and preparation method thereof - Google Patents
A kind of tungstenic Heat-resistant alloy steel liner plate material and preparation method thereof Download PDFInfo
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Abstract
A kind of tungstenic Heat-resistant alloy steel liner plate material, the chemical element composition that it contains and mass percent thereof are: carbon 0.2-0.4, silicon 0.9-1.2, manganese 3.7-4.2, chromium 3.2-3.4, molybdenum 0.12-0.16, tungsten 1.0-1.4, titanium 0.02-0.04, Be0.04-0.07, S≤0.04, P≤0.04, surplus are iron.Steel alloy of the present invention adds the elements such as tungsten, molybdenum, boron on the basis of middle low carbon steel, the steel alloy obtained not only has high hardness, excellent wear resistance, but also there is good toughness, red hard height, heat strong height, corrosion resistant advantage, relative to low carbon high alloy steel, cost is low.Refining agent of the present invention is used for Foundry Production, significantly improves yield rate, and the degree of porosity particularly in foundry goods reduces 1-2 degree, and can not produce pore at cast(ing) surface, trapped oxide also obviously reduces, and oxide inclusion is at about 2 grades.
Description
Technical field
The present invention relates to metal material field, particularly relate to a kind of tungstenic Heat-resistant alloy steel liner plate material and preparation method thereof.
Background technology
Lining material, through the development of more than 30 years, experienced by high violent steel, common spoken parts in traditional operas cast steel, ni-hard cast iron, high chromium white iron to the developmental stage of the middle-low alloy steel of modified high manganese steel and various Q-tempering technique.In practical application domestic at present, be still that high mangaenese steel rules all the land, in several main flow material, high mangaenese steel good toughness, but wear resistance and erosion resistance are also undesirable; Wear resistance of high-chromium iron is good, but toughness is poor again; Middle-low alloy steel fragility and erosion resistance are not up to standard.Need, from the more excellent lining material of the aspect such as starting material, technique research and development over-all properties, to enhance productivity, to reduce wear, reduce costs.
Summary of the invention
The object of the present invention is to provide a kind of tungstenic Heat-resistant alloy steel liner plate material and preparation method thereof, it is high that this alloy material has intensity, the advantage that wear resistance is good, heat is high by force.
Technical scheme of the present invention is as follows:
A kind of tungstenic Heat-resistant alloy steel liner plate material, is characterized in that: the chemical element composition that it contains and mass percent thereof are: carbon 0.2-0.4, silicon 0.9-1.2, manganese 3.7-4.2, chromium 3.2-3.4, molybdenum 0.12-0.16, tungsten 1.0-1.4, titanium 0.02-0.04, Be0.04-0.07, S≤0.04, P≤0.04, surplus are iron.
The production method of described tungstenic Heat-resistant alloy steel liner plate material, is characterized in that:
(1), the preparation pig iron and scrap iron are originated as ferrous substrate in 1:2-3 ratio, the pig iron is added drop in stove and melt, carry out desulfurization, deoxidation, employing refining agent initial refining, add alloying constituent and carry out alloying, then add scrap iron fusing, add refining agent secondary refining, detection adjust chemical element component content to qualified, casting, casting postheat treatment etc.;
(2) lot sequence, dropping into alloying element in alloying process in stove is: (1) silicon, manganese; (2) chromium, molybdenum, titanium; (3) other remaining components; The each batch of timed interval of dropping into element is 22-25 minute, stirs after feeding intake.
Described casting postheat treatment is: first by room temperature with 180-190 DEG C/h of ramp to 500-510 DEG C, insulation 60-70 minute, again with 180-190 DEG C/h of ramp to 700-710 DEG C, insulation 50-60 minute, again with 220-230 DEG C/h of ramp to 940-950 DEG C, insulation 3-4 hour; 600-610 DEG C is cooled to again with 160-170 DEG C/h of speed, then with 180-190 DEG C/h of ramp to 700-710 DEG C, then be cooled to 480-500 DEG C with 160-170 DEG C/h of speed, insulation 70-80 minute; 220-230 DEG C is cooled to again, insulation 2-3 hour with 160-170 DEG C/h of speed; Again with 180-190 DEG C/h of ramp to 340-350 DEG C, then be cooled to 200-210 DEG C with 160-170 DEG C/h of speed, then with 180-190 DEG C/h of ramp to 530-550 DEG C, insulation 2-3 hour, takes out air cooling and get final product.
Described refining agent is made up of the raw material of following weight part: instrument comminuted steel shot 30-40, medical stone 1-2, Calcium Fluoride (Fluorspan) 3-4, magnesium oxide 6-7, iron(ic) chloride 1-2, feldspar in powder 2-3, Tremoliteor Tremoliteasbestos 5-6, magnesium sulfate 2-3, nano silicon 2-3, jade powder 3-4, montmorillonite 1-2, potassium silicofluoride 4-5; Each raw material mixes by preparation method, is heated to molten state, then, is poured into Quench in pure water, then is ground into 100-200 order powder; Gained powder is added and is equivalent to the silane resin acceptor kh-550 of powder weight 2-3%, the nano-carbon powder of 1-2%, after mixing, under 8-15Mpa, be pressed into base, then, at 900-950 DEG C, 3-4 hour is calcined, after cooling, be ground into 150-250 order powder again, obtain final product.
Beneficial effect of the present invention
Steel alloy of the present invention adds the elements such as tungsten, molybdenum, boron on the basis of middle low carbon steel, the steel alloy obtained not only has high hardness, excellent wear resistance, but also there is good toughness, red hard height, heat strong height, corrosion resistant advantage, relative to low carbon high alloy steel, cost is low.The present invention uses part scrap iron as raw material, and through secondary refining, conservative control casting postheat treatment temperature, throwing raw materials in batches, makes alloy quality more stable uniform, improves comprehensive mechanical property.Refining agent of the present invention is used for Foundry Production, significantly improves yield rate, and the degree of porosity particularly in foundry goods reduces 1-2 degree, and can not produce pore at cast(ing) surface, trapped oxide also obviously reduces, and oxide inclusion is at about 2 grades.
Embodiment
A kind of tungstenic Heat-resistant alloy steel liner plate material, the chemical element composition that it contains and mass percent thereof are: carbon 0.2-0.4, silicon 0.9-1.2, manganese 3.7-4.2, chromium 3.2-3.4, molybdenum 0.12-0.16, tungsten 1.0-1.4, titanium 0.02-0.04, Be0.04-0.07, S≤0.04, P≤0.04, surplus are iron.
The production method of described tungstenic Heat-resistant alloy steel liner plate material is:
(1), the preparation pig iron and scrap iron are originated as ferrous substrate in 1:2.5 ratio, the pig iron is added drop in stove and melt, carry out desulfurization, deoxidation, employing refining agent initial refining, add alloying constituent and carry out alloying, then add scrap iron fusing, add refining agent secondary refining, detection adjust chemical element component content to qualified, casting, casting postheat treatment etc.;
(2) lot sequence, dropping into alloying element in alloying process in stove is: (1) silicon, manganese; (2) chromium, molybdenum, titanium; (3) other remaining components; The each batch of timed interval of dropping into element is 24 minutes, stirs after feeding intake.
Described casting postheat treatment is: elder generation with 185 DEG C/h of ramp to 505 DEG C by room temperature, is incubated 65 minutes, then with 185 DEG C/h of ramp to 705 DEG C, is incubated 55 minutes, then with 225 DEG C/h of ramp to 945 DEG C, be incubated 3.5 hours; 605 DEG C are cooled to again with 165 DEG C/h of speed, then with 185 DEG C/h of ramp to 705 DEG C, then be cooled to 490 DEG C with 165 DEG C/h of speed, be incubated 75 minutes; Be cooled to 225 DEG C with 165 DEG C/h of speed again, be incubated 2.5 hours; Again with 185 DEG C/h of ramp to 345 DEG C, then be cooled to 205 DEG C with 165 DEG C/h of speed, then with 185 DEG C/h of ramp to 540 DEG C, be incubated 2.5 hours, take out air cooling and get final product.
Described refining agent is made up of the raw material of following weight part (kilogram): instrument comminuted steel shot 35, medical stone 1.5, Calcium Fluoride (Fluorspan) 3.5, magnesium oxide 6.5, iron(ic) chloride 1.5, feldspar in powder 2.5, Tremoliteor Tremoliteasbestos 5.5, magnesium sulfate 2.5, nano silicon 2.5, jade powder 3.5, montmorillonite 1.5, potassium silicofluoride 4.5; Each raw material mixes by preparation method, is heated to molten state, then, is poured into Quench in pure water, then is ground into 150 order powder; Gained powder is added and is equivalent to the silane resin acceptor kh-550 of powder weight 2.6%, the nano-carbon powder of 1.5%, after mixing, under 11Mpa, be pressed into base, then, calcine 3.6 hours at 940 DEG C, after cooling, then be ground into 190 order powder, obtain final product.
The mechanical property of tungstenic Heat-resistant alloy steel liner plate material of the present invention is: tensile strength 1324MPa, yield strength 914MPa, unit elongation 14%, relative reduction in area 35%, impact absorbing energy 54J, impelling strength 65J/cm2, hardness 259HB.
Claims (1)
1. a production method for tungstenic Heat-resistant alloy steel liner plate material, is characterized in that: the chemical element composition that tungstenic Heat-resistant alloy steel liner plate material contains and mass percent thereof are: carbon 0.2-0.4, silicon 0.9-1.2, manganese 3.7-4.2, chromium 3.2-3.4, molybdenum 0.12-0.16, tungsten 1.0-1.4, titanium 0.02-0.04, Be0.04-0.07, S≤0.04, P≤0.04, surplus are iron; The production method of described tungstenic Heat-resistant alloy steel liner plate material comprises following steps: (1), the preparation pig iron and scrap iron are originated as ferrous substrate in 1:2-3 ratio, the pig iron is added drop in stove and melt, carry out desulfurization, deoxidation, employing refining agent initial refining, add alloying constituent carry out alloying, then add scrap iron fusing, add refining agent secondary refining, detection and adjust chemical element component content to qualified, casting, casting postheat treatment; (2) lot sequence, dropping into alloying element in alloying process in stove is: (1) silicon, manganese; (2) chromium, molybdenum, titanium; (3) other remaining components; The each batch of timed interval of dropping into element is 22-25 minute, stirs after feeding intake; Described casting postheat treatment is: first by room temperature with 180-190 DEG C/h of ramp to 500-510 DEG C, insulation 60-70 minute, again with 180-190 DEG C/h of ramp to 700-710 DEG C, insulation 50-60 minute, again with 220-230 DEG C/h of ramp to 940-950 DEG C, insulation 3-4 hour; 600-610 DEG C is cooled to again with 160-170 DEG C/h of speed, then with 180-190 DEG C/h of ramp to 700-710 DEG C, then be cooled to 480-500 DEG C with 160-170 DEG C/h of speed, insulation 70-80 minute; 220-230 DEG C is cooled to again, insulation 2-3 hour with 160-170 DEG C/h of speed; Again with 180-190 DEG C/h of ramp to 340-350 DEG C, then be cooled to 200-210 DEG C with 160-170 DEG C/h of speed, then with 180-190 DEG C/h of ramp to 530-550 DEG C, insulation 2-3 hour, takes out air cooling and get final product; Described refining agent is made up of the raw material of following weight part: instrument comminuted steel shot 30-40, medical stone 1-2, Calcium Fluoride (Fluorspan) 3-4, magnesium oxide 6-7, iron(ic) chloride 1-2, feldspar in powder 2-3, Tremoliteor Tremoliteasbestos 5-6, magnesium sulfate 2-3, nano silicon 2-3, jade powder 3-4, montmorillonite 1-2, potassium silicofluoride 4-5; Each raw material mixes by preparation method, is heated to molten state, then, is poured into Quench in pure water, then is ground into 100-200 order powder; Gained powder is added and is equivalent to the silane resin acceptor kh-550 of powder weight 2-3%, the nano-carbon powder of 1-2%, after mixing, under 8-15MPa, be pressed into base, then, at 900-950 DEG C, 3-4 hour is calcined, after cooling, be ground into 150-250 order powder again, obtain final product.
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| CN201310582355.1A CN103667946B (en) | 2013-11-20 | 2013-11-20 | A kind of tungstenic Heat-resistant alloy steel liner plate material and preparation method thereof |
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| CN201310582355.1A CN103667946B (en) | 2013-11-20 | 2013-11-20 | A kind of tungstenic Heat-resistant alloy steel liner plate material and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101736206A (en) * | 2009-12-15 | 2010-06-16 | 山西百一机械设备制造有限公司 | Coking cart heat-resisting and wear-resisting lining plate and manufacturing method thereof |
| CN102892910A (en) * | 2010-05-10 | 2013-01-23 | 新日铁住金株式会社 | High-strength steel sheet and method for producing same |
| CN103057207A (en) * | 2013-01-29 | 2013-04-24 | 安徽工业大学 | Composite wear-resistant liner of sandwich structure |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101736206A (en) * | 2009-12-15 | 2010-06-16 | 山西百一机械设备制造有限公司 | Coking cart heat-resisting and wear-resisting lining plate and manufacturing method thereof |
| CN102892910A (en) * | 2010-05-10 | 2013-01-23 | 新日铁住金株式会社 | High-strength steel sheet and method for producing same |
| CN103057207A (en) * | 2013-01-29 | 2013-04-24 | 安徽工业大学 | Composite wear-resistant liner of sandwich structure |
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