CN103665573B - A kind of polypropylene pipe and preparation method thereof - Google Patents

A kind of polypropylene pipe and preparation method thereof Download PDF

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Publication number
CN103665573B
CN103665573B CN201310648692.6A CN201310648692A CN103665573B CN 103665573 B CN103665573 B CN 103665573B CN 201310648692 A CN201310648692 A CN 201310648692A CN 103665573 B CN103665573 B CN 103665573B
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polypropylene pipe
nano
temperature
preparation
polypropylene
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CN103665573A (en
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朱华明
陈德明
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Jiangsu Jinbo New Materials Technology Co Ltd
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Jiangsu Jinbo New Materials Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895—Barrel or housing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92904—Die; Nozzle zone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/18—Applications used for pipes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of hardness polypropylene pipe good, on-deformable, its constituent is counted as follows by weight: copolymerization grade polypropylene 100 parts, melamine resin 26-54 part, nano ceramics powder liquid 18-32 part, toughener 5-12 part, plastic anti-aging agent 6-18 part, water 60-100 part, and provides its preparation method.

Description

A kind of polypropylene pipe and preparation method thereof
Technical field
The present invention relates to a kind of tubing, particularly to a kind of polypropylene pipe and preparation method thereof, Belong to pipe technology field.
Background technology
Poly-sustainable development is the target that Present Global is common, reduces the consumption of the energy, protection ring Border, it is to avoid hinder society's normal activity increasingly to come into one's own.Cost at plastic pipe work Expense and energy resource consumption are laid link and usually occupies critical role.The big portion of plastic tube outside building Dividing is buried laying and suspension bracket laying, and traditional suspension bracket is laid, adopted according to designed lines With mechanically or manually operation, suspension and support is installed at the scene, then in suspension and support, installs pipeline also Complete connecting test.
Suspension bracket laying technology proposes new requirement to tubing and material thereof, and suspension bracket is laid and is different from Tradition is laid, and its distinct issues are the problem on deformation of tubing, pipeline in laying due to suspension bracket Being supported by suspension and support, pipeline spot film accepts, the problem installed due to suspension and support, easily makes Pipeline discontinuity, thus be deformed, make pipeline receive damage and concentration may be born Point load.
Summary of the invention
The technical problem to be solved is to provide a kind of hardness good, no for above drawback Yielding polypropylene pipe, and its preparation method is provided.
For solving above-mentioned technical problem, the technical scheme is that
A kind of polypropylene pipe, its constituent is counted as follows by weight:
A kind of polypropylene pipe, it is preferred that its constituent is counted as follows by weight:
A kind of preparation method of polypropylene pipe tubing, its preparation method is as follows:
(1) by anti-ageing to copolymerization grade polypropylene, melamine resin, toughener, plastics Stirring in agent and water addition blender, mixing speed is 650-750 rev/min, stirring 6-10 minute；
(2) mixture in step (1) is added prepared granule in double screw extruder；
(3) granule prepared in step (2) is added poly-third extruded in single screw extrusion machine Alkene tubing germule, the temperature of extruder cylinder of single screw extruder is 125-155 DEG C, and the temperature of mould is 156-175 DEG C, die temperature is 135-145 DEG C；
(4) by nano ceramics powder liquid even application in tubing germule periphery, in temperature Carry out at 95-150 DEG C drying to obtain polypropylene pipe finished product.
Above-mentioned a kind of polypropylene pipe and preparation method thereof, wherein, described toughener is by nanometer One or both compositions in titanium dioxide, ABS resin, polyvinyl alcohol.
Above-mentioned a kind of polypropylene pipe and preparation method thereof, wherein, described nano-ceramic powder liquid The preparation method of body is: is added by nano-ceramic powder in aqueous epoxy resin emulsion, stirs, Its mixing speed is 550-650 rev/min, stirs 5-10 minute, nano-ceramic powder and aqueous The weight ratio of epoxy resin latex is 11-15:100.
The invention have the benefit that the water-tolerant of cymel material, can improve heat-resisting Property and mechanical strength, simultaneously can also improve hardness；Nano ceramics powder liquid can significantly improve Product hardness, hardness is the highest up to 6-8H, owing to its nanometer particle size is the most tiny, therefore Either which kind of solvent is all transparent, plastic anti-aging agent is nonflammable, not burn into storage steady Qualitative good, the compatibility of unsaturated-resin is good, has long-acting antioxygen, yellowing-resistant effect propety concurrently, Increase substantially the ageing resistace of product.The polypropylene pipe gone out by above manufacture of materials is with general Logical polypropylene pipe is compared, and in the case of other performances are constant, its heat distortion temperature can improve 35-40 DEG C, the rigidity of tubing is greatly improved, and its hardness can improve more than 2 times.
Detailed description of the invention
Below by way of specific embodiment, the detailed description of the invention of the present invention is made further details of Explanation.
Melamine resin of the present invention is purchased from the happy safe limited public affairs of chemical industry in Tianjin Development Zone Department；Described nano-ceramic powder is purchased from Shanghai Li Sheng International Trading Company Ltd；Described water-base epoxy Resin emulsion is purchased from Fujian Zhong Ke great achievement Chemical Industry Science Co., Ltd, and described plastic anti-aging agent is purchased In Qingdao Hua En Chemical Co., Ltd..
Example one:
A kind of preparation method of polypropylene pipe, its preparation method is as follows:
(1) toughener is prepared, by nano titanium oxide and ABS resin with the ratio of 1:1.5 Example mix homogeneously；
(2) by the copolymerization grade polypropylene that parts by weight are 100 parts, the tripolycyanamide first of 45 parts Urea formaldehyde, 10 parts of toughener, 12 parts of plastic anti-aging agents and 80 parts of water addition blenders stir Mixing uniformly, mixing speed is 650 revs/min, stirs 10 minutes；
(3) mixture in step (2) is added prepared granule in double screw extruder；
(4) granule prepared in step (3) is added poly-third extruded in single screw extrusion machine Alkene tubing germule, the temperature of extruder cylinder of single screw extruder is 135 DEG C, and the temperature of mould is 165 DEG C, die temperature is 145 DEG C；
(5) prepare nano ceramics powder liquid, nano-ceramic powder is added aqueous epoxy resins breast In liquid, stirring, its mixing speed is 550-650 rev/min, stirs 5-10 minute, Nano-ceramic powder is 15:100 with the weight ratio of aqueous epoxy resin emulsion；
(6) by nano ceramics powder liquid even application that parts by weight are 22 parts at tubing germule Periphery, carries out drying to obtain polypropylene pipe finished product at temperature 120 DEG C.
Example two:
A kind of preparation method of polypropylene pipe, its preparation method is as follows:
(1) toughener is prepared, by nano titanium oxide and polyvinyl alcohol with the ratio of 1.2:1 Mix homogeneously；
(2) by the copolymerization grade polypropylene that parts by weight are 100 parts, the tripolycyanamide first of 30 parts Urea formaldehyde, 8 parts of toughener, 10 parts of plastic anti-aging agents and 65 parts of water addition blenders stir Mixing uniformly, mixing speed is 650 revs/min, stirs 10 minutes；
(3) mixture in step (2) is added prepared granule in double screw extruder；
(4) granule prepared in step (3) is added poly-third extruded in single screw extrusion machine Alkene tubing germule, the temperature of extruder cylinder of single screw extruder is 135 DEG C, and the temperature of mould is 165 DEG C, die temperature is 145 DEG C；
(5) prepare nano ceramics powder liquid, nano-ceramic powder is added aqueous epoxy resins breast In liquid, stirring, its mixing speed is 550-650 rev/min, stirs 5-10 minute, Nano-ceramic powder is 15:100 with the weight ratio of aqueous epoxy resin emulsion；
(6) by nano ceramics powder liquid even application that parts by weight are 25 parts at tubing germule Periphery, carries out drying to obtain polypropylene pipe finished product at temperature 120 DEG C.
The water-tolerant of cymel material in sum, can improve thermostability and machinery is strong Degree, can also improve hardness simultaneously；Nano ceramics powder liquid can significantly improve product hardness, Hardness is the highest up to 6-8H, owing to its nanometer particle size is the most tiny, therefore either which kind of Solvent is all transparent, and plastic anti-aging agent is nonflammable, not burn into excellent storage stability, no The compatibility of saturated resin is good, has long-acting antioxygen, yellowing-resistant effect propety concurrently, significantly carries The ageing resistace of high product.The polypropylene pipe gone out by above manufacture of materials and plain polypropylene Tubing is compared, and in the case of other performances are constant, its heat distortion temperature can improve 35-40 DEG C, The rigidity of tubing is greatly improved, and its hardness can improve more than 2 times.
Here description of the invention and application is illustrative, is not wishing to limit the scope of the present invention In the above-described embodiments, therefore, the present invention is not limited system by the present embodiment, any employing etc. The technical scheme that effect replacement obtains is all in the scope of protection of the invention.

Claims (3)

1. a polypropylene pipe, is characterized by, its raw materials by weight portion meter is as follows:
The preparation method of polypropylene pipe is as follows:
(1) will stir in copolymerization grade polypropylene, melamine resin, toughener, plastic anti-aging agent and water addition blender, mixing speed is 650-750 rev/min, stirs 6-10 minute；
(2) mixture in step (1) is added prepared granule in double screw extruder；
(3) will extrude to obtain polypropylene pipe germule in the granule prepared in step (2) addition single screw extrusion machine, the temperature of extruder cylinder of single screw extruder is 125-155 DEG C, and the temperature of mould is 156-175 DEG C, and die temperature is 135-145 DEG C；
(4) by nano ceramics powder liquid even application in tubing germule periphery, carry out drying to obtain polypropylene pipe finished product at temperature 95-150 DEG C；The preparation method of described nano ceramics powder liquid is: added by nano-ceramic powder in aqueous epoxy resin emulsion, stir, its mixing speed is 550-650 rev/min, stirs 5-10 minute, and nano-ceramic powder is 11-15:100 with the weight ratio of aqueous epoxy resin emulsion.
2. a kind of polypropylene pipe as claimed in claim 1, is characterized by, it is preferred that its raw materials by weight portion meter is as follows:
3. a kind of polypropylene pipe as claimed in claim 1 or 2, is characterized by, described toughener is made up of one or both in nano titanium oxide, ABS resin, polyvinyl alcohol.
CN201310648692.6A 2013-12-04 2013-12-04 A kind of polypropylene pipe and preparation method thereof Expired - Fee Related CN103665573B (en)

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CN107805342A (en) * 2017-10-17 2018-03-16 盐城市瑞通塑胶有限公司 A kind of high heat-resistant impact MPP electric power protection pipes and preparation method thereof
CN109926015A (en) * 2017-12-19 2019-06-25 宜兴市江华环保科技有限公司 A kind of water process inclined tube filler
CN109081973A (en) * 2018-07-30 2018-12-25 界首市成龙塑业有限公司 A method of plastic grain is prepared using waste old
CN109265914A (en) * 2018-08-23 2019-01-25 安徽虹泰磁电有限公司 A kind of preparation method of ball mill cooling line material
CN109133411A (en) * 2018-08-23 2019-01-04 安徽虹泰磁电有限公司 A kind of preparation method of wastewater treatment dedicated pipeline material
CN109624256A (en) * 2018-10-22 2019-04-16 安徽杰航不锈钢装饰工程有限公司 A kind of processing method of the highorder accuracy schemes of high-strength light

Citations (5)

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Publication number Priority date Publication date Assignee Title
CN1374340A (en) * 2002-04-08 2002-10-16 刘建中 Plastic alloy
CN1490154A (en) * 2002-10-15 2004-04-21 刘建中 Plastic alloy composite pipe and producing method thereof
CN100999413A (en) * 2007-01-05 2007-07-18 北京博斯泰科技发展有限公司 Nanometer ceramic powder sizing agent composition and its preparation method
CN102775732A (en) * 2012-08-10 2012-11-14 昆山乔锐金属制品有限公司 Formula of composite high-performance nonmetal material
CN103160025A (en) * 2013-02-27 2013-06-19 广东聚石化学股份有限公司 High-glowing filament anti-soaking separate-out-free halogen-free inflaming retarding polypropylene materials and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1374340A (en) * 2002-04-08 2002-10-16 刘建中 Plastic alloy
CN1490154A (en) * 2002-10-15 2004-04-21 刘建中 Plastic alloy composite pipe and producing method thereof
CN100999413A (en) * 2007-01-05 2007-07-18 北京博斯泰科技发展有限公司 Nanometer ceramic powder sizing agent composition and its preparation method
CN102775732A (en) * 2012-08-10 2012-11-14 昆山乔锐金属制品有限公司 Formula of composite high-performance nonmetal material
CN103160025A (en) * 2013-02-27 2013-06-19 广东聚石化学股份有限公司 High-glowing filament anti-soaking separate-out-free halogen-free inflaming retarding polypropylene materials and preparation method thereof

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