CN103663737A - Material with algae removal and cleaning functions and preparation method of material - Google Patents
Material with algae removal and cleaning functions and preparation method of material Download PDFInfo
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- CN103663737A CN103663737A CN201210342212.9A CN201210342212A CN103663737A CN 103663737 A CN103663737 A CN 103663737A CN 201210342212 A CN201210342212 A CN 201210342212A CN 103663737 A CN103663737 A CN 103663737A
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- phosphorus
- selenium
- vanadium
- preparation
- cleaning
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- 241000195493 Cryptophyta Species 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 title claims abstract description 22
- 238000004140 cleaning Methods 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 32
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 32
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 23
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 23
- 239000011574 phosphorus Substances 0.000 claims abstract description 23
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 23
- 239000011669 selenium Substances 0.000 claims abstract description 23
- 229910052582 BN Inorganic materials 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 16
- 229910052755 nonmetal Inorganic materials 0.000 claims abstract description 14
- 230000006698 induction Effects 0.000 claims abstract description 13
- 239000000919 ceramic Substances 0.000 claims abstract description 12
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 11
- -1 metal compound boron nitride Chemical class 0.000 claims abstract description 6
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 6
- 150000003624 transition metals Chemical class 0.000 claims abstract description 6
- 239000013078 crystal Substances 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 6
- OXYOQBAZFDHPBM-UHFFFAOYSA-N [P].[Se] Chemical compound [P].[Se] OXYOQBAZFDHPBM-UHFFFAOYSA-N 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 238000004512 die casting Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 235000012054 meals Nutrition 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000003344 environmental pollutant Substances 0.000 abstract description 5
- 231100000719 pollutant Toxicity 0.000 abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000428 dust Substances 0.000 abstract description 4
- 230000001954 sterilising effect Effects 0.000 abstract description 4
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 4
- 239000012530 fluid Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 238000003723 Smelting Methods 0.000 abstract 1
- 230000003373 anti-fouling effect Effects 0.000 abstract 1
- 230000001580 bacterial effect Effects 0.000 abstract 1
- 230000033228 biological regulation Effects 0.000 abstract 1
- 239000010802 sludge Substances 0.000 abstract 1
- 241000894006 Bacteria Species 0.000 description 11
- 239000011538 cleaning material Substances 0.000 description 7
- 239000004519 grease Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- 230000018199 S phase Effects 0.000 description 4
- 230000001939 inductive effect Effects 0.000 description 4
- 239000008204 material by function Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000013517 stratification Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Lubricants (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a material with algae removal and cleaning functions and a preparation method of the material. The material is prepared from vanadium, selenium, phosphorus and boron nitride and comprises the following components in percentage by weight: 78-80% of transition metal vanadium, 17-19% of non-metal selenium and phosphorus, 0.5-1.0% of non-metal compound boron nitride, and the ratio of parts by weight of selenium to phosphorus is 5: 2+/-0.4; the material is prepared from smelting, strong magnetic field induction and ceramic infrared regulation. When in use, the original-away induction functional material disclosed by the invention is fixed on the outer side of equipment or pipeline with incrustation or oil dirt to be treated or is directly placed in water or oil to be treated; the application temperature range is minus 20 to 270 DEG C. Energy released by the induction material breaks macromolecular group structures of pollutants or attachments to dissolve the pollutants or attachments in fluid so as to achieve good effects of cleaning, anti-fouling, sterilization and algae removal. The material can be used for cleaning such pollutants or attachments as incrustation, oil dirt, bacterial sludge, carbon deposit and dust deposit, the cleaning efficiency is higher than 96%, no pollution is generated, and the investment cost and the operation cost are only 5-26% of those of the traditional process.
Description
Technical field:
The present invention relates to a kind of material with cleaning function, specifically a kind of can algae and clean functional materials of multiple pollutant, set thing and preparation method thereof.
Background technology
Oils, bacterium algae, incrustation scale and bacterium mud etc., the harm that equipment, pipeline are caused is very serious, and for a long time, people adopt the whole bag of tricks to be tackled:
When hot water pipeline, heat-exchange equipment, cooling water system are unified equipment generation incrustation scale and bacterium mud, conventionally adopt the method for matting and physical cleaning to remove.For this reason, usually need stop cleaning, and will consume a large amount of clean-out systems, thereby bring secondary pollution.And after cleaning, still can continue to produce the hurtful incrustation scale of equipment, bacterium mud.
When low pressure steam boiler produces incrustation scale, the method control incrustation scale that conventionally adopts softening water and dosing to process.Its shortcoming is that expense is high, resource consumption is large, secondary pollution is serious, and equipment operation failure is many, and life of equipment is short.
When pipeline road, oil transporting appliance, oil consumption equipment produce grease, oily wax, dust stratification and carbon distribution, conventionally adopt clean-out system to clean.Exist efficiency not high, clean the waste liquor contamination producing serious, difficult treatment is large and expense is high.What have cannot clean at all, can only solve problem by replacing.
Water system by bacterium algae pollution after, traditional method is to adopt chemicals treatment or thin up to change the methods such as water, filtration.Exist weak effect, secondary pollution is serious, expense is high problem.
Summary of the invention:
The object of the invention is to overcome the deficiency that prior art is removed the methods such as oils, bacterium algae, incrustation scale and bacterium mud; provide a kind of without medicament, without stop cleaning; sterilization algae removal, cleaning efficiency are high, and do not produce new functional materials of secondary pollution and preparation method thereof.
Of the present invention opening one's minds is:
The common feature that produces and exist according to bacterium, algae, incrustation scale, grease, bacterium mud, carbon distribution, dust stratification, make a kind of new functional materials having from former inducing function, this material has induction separating and cracking function, according to the energy of its release, destroy the macromolecular mass structure of pollutent, dirt settling, become subset, then loose, come off, be dissolved in fluid, reach the object of cleaning, antiscale, sterilization algae removal.
The present invention is achieved in that
The present invention's algae removal cleaning material, is by vanadium, selenium and phosphorus, and boron nitride, formulated.These raw-material purity all should be equal to or greater than 98.2%; The weight percent content of three's preparation is: transition metal vanadium 78-80%, nonmetal selenium phosphorus 17-19%, nonmetallic compound boron nitride 0.5-1.0%.
Weight part proportioning between described selenium, phosphorus is 5: 2 ± 0.4.
The preparation method of this algae removal cleaning function material is as follows:
1. by nonmetal selenium, phosphorus grinds, fineness is less than 250 orders, and the course of processing of powder process completes under the condition of be less than-26PASI vacuum tightness; (standby).
2. vanadium metal is placed on to heating and melting in intermediate frequency furnace, to boiling;
3. boron nitride is added in the vanadium liquid of melting, with tungsten bar, stir evenly;
4. when vanadium solution is cooled to 2400-2500 ℃, at 18T, (under the high-intensity magnetic field of A/M, vanadium solution is carried out the ordered arrangement of directional process-formation metallographic structure;
5. add selenium, phosphorus powder uniform stirring, guarantee that meal is evenly distributed; In the high-intensity magnetic field induction that is greater than 20T (A/M), the arrangement architecture of security deposit's phase constitution has directivity.
6. use die casting, and machine-shaping.
7. under the condition of 8-10T (A/M) strong magnetic field circumstance, temperature 1000-1300 ℃, with ceramic infrared, adjust internal crystal structure.
Describedly with ceramic infrared, adjust internal crystal structure, mean: in sealing atmosphere furnace, material is positioned on ceramic infrared hot plate; With temperature control, adjust temperature, control temperature 1000-1300 ℃.Principle with its microcosmic resonance induction, realizes the object of adjusting internal crystal structure.
During use, by the present invention from former induction functional materials, in the mode that bundlees or weld, be fixed on and need to process the equipment of incrustation scale, grease or pipeline outside, or be directly placed in pending water, in oil, use temperature scope-20 degree-+270 degree.The energy discharging according to this inductive material, destroys the macromolecular mass structure of pollutent, set thing, forms subset, produces induction separating and cracking, loose, come off, be dissolved in fluid, reaches the object of cleaning, antiscale, sterilization algae removal.
Beneficial effect of the present invention
1. saved the chemicals treatment of conventional art and shut down treating processes, pollution-free and secondary pollution.
2. not stop cleaning incrustation scale, grease, bacterium mud, carbon distribution, dust stratification, cleaning efficiency is more than 96%, and parent pollutant is changed into useful matter.。
3. save required expense in medicament production and transport, ability and the efficiency stopping to cause because of dirty bacterium algae are wasted, and synthesis energy saving surpasses more than 40%.
4. equipment and system failure rate are low, and life cycle (life-span) extends more than 2 times.
5. investment cost and working cost are the 5-26% of traditional technology.
Embodiment:
Narrate three embodiment below, the present invention will be further described.
Inductive material of 1 one kinds of algae removals of embodiment and preparation method thereof
The algae removal cleaning material of the present embodiment, is formulated by vanadium, selenium and phosphorus, boron nitride, and the weight percent content of three's preparation is: transition metal vanadium 80%, nonmetal selenium phosphorus 18%, nonmetallic compound boron nitride 0.8%.These raw-material purity are equal to or are greater than 98.2%.Weight part proportioning between nonmetal selenium, phosphorus is 5: 2.4.
The preparation method of this cleaning material is as follows:
1. by selenium, phosphorus grinds, fineness is less than 250 orders, and the course of processing of powder process completes under the condition of be less than-26PASI vacuum tightness; Standby.
2. vanadium is placed on to heating and melting in intermediate frequency furnace, to boiling;
3. boron nitride is added in the vanadium liquid of melting, with tungsten bar, stir evenly;
4. when vanadium solution cooling is at 2400 ℃, at 18T, (under the high-intensity magnetic field of A/M, vanadium solution is carried out the ordered arrangement of directional process-formation metallographic structure;
5. add selenium, phosphorus powder uniform stirring, guarantee that meal is evenly distributed; Be greater than 20T (in the high-intensity magnetic field induction of A/M, the directivity of the arrangement architecture of security deposit's phase constitution.
6. use die casting, and machine-shaping.
Under 7.9T (A/M) strong magnetic field circumstance, 1200 ℃ of hot conditionss, with ceramic infrared, adjust internal crystal structure.
Describedly with ceramic infrared, adjust internal crystal structure; mean: in punching, have in the sealing High Temperature Furnaces Heating Apparatus of shielding gas, be positioned over ceramic infrared hot plate top, with temperature control unit, adjust temperature 1000-1300 ℃; principle with its microcosmic resonance induction, realizes the object of adjusting internal crystal structure.
2 one kinds of embodiment clean inductive material of grease and preparation method thereof
The algae removal cleaning material of the present embodiment, is by vanadium, selenium and phosphorus, boron nitride, formulated.The weight percent content of three's preparation is: transition metal vanadium 78%, nonmetal selenium phosphorus 19%, nonmetallic compound boron nitride 0.5%.These raw-material purity all should be equal to or greater than 98.2%.Weight part proportioning between nonmetal selenium, phosphorus is 5: 1.6.
The preparation method of this cleaning material is as follows:
1. by nonmetal selenium, phosphorus grinds, fineness is less than 250 orders, and the course of processing of powder process completes under the condition of be less than-26PASI vacuum tightness; Standby.
2. vanadium metal is placed on to heating and melting in intermediate frequency furnace, to boiling;
3. boron nitride is added in the vanadium liquid of people's melting, with tungsten bar, stir evenly;
4. when vanadium solution cooling is at 2500 ℃, at 18T, (under the high-intensity magnetic field of A/M, vanadium solution is carried out the ordered arrangement of directional process-formation metallographic structure;
5. add selenium, phosphorus powder uniform stirring, guarantee that meal is evenly distributed; Be greater than 20T (in the high-intensity magnetic field induction of A/M, the directivity of the arrangement architecture of security deposit's phase constitution.
6. use die casting, and machine-shaping.
7. under 8T (A/M) strong magnetic field circumstance, 1300 ℃ of hot conditionss, with ceramic infrared, adjust internal crystal structure.
3 one kinds of embodiment clean material of grease and preparation method thereof
The algae removal cleaning material of the present embodiment, is by vanadium, selenium and phosphorus, and boron nitride, formulated, the weight percent content of three's preparation is: transition metal vanadium 79%, nonmetal selenium phosphorus 17%, nonmetallic compound boron nitride 1.0%.These raw-material purity all should be equal to or greater than 98.2%.Weight part proportioning between nonmetal selenium, phosphorus is 5: 2.
The preparation method of this cleaning material is as follows:
1. by nonmetal selenium, phosphorus grinds, fineness is less than 250 orders, and the course of processing of powder process completes under the condition of be less than-26PASI vacuum tightness; Standby.
2. vanadium metal is placed on to heating and melting in intermediate frequency furnace, to boiling;
3. boron nitride is added in the vanadium liquid of people's melting, with tungsten bar, stir evenly;
4. when vanadium solution cooling is at 2400-2500 ℃, at 18T, (under the high-intensity magnetic field of A/M, vanadium solution is carried out the ordered arrangement of directional process-formation metallographic structure;
5. add selenium, phosphorus powder uniform stirring, guarantee that meal is evenly distributed; Be greater than 20T (in the high-intensity magnetic field induction of A/M, the directivity of the arrangement architecture of security deposit's phase constitution.
6. use die casting, and machine-shaping.
7. under 10T (A/M) strong magnetic field circumstance, 1000 ℃ of hot conditionss, with ceramic infrared, adjust internal crystal structure.
Claims (3)
1. the material that has algae removal and cleaning function, is characterized in that: by vanadium, and selenium and phosphorus, boron nitride is formulated; These raw-material purity are equal to or are greater than 98.2%; The weight percent content of three preparation is, transition metal vanadium 78-80%, nonmetal selenium phosphorus 17-19%, nonmetallic compound boron nitride 0.5-1.0%;
Weight part proportioning between described selenium, phosphorus is 5: 2 ± 0.4.
2. the preparation method who has the material of algae removal and cleaning function, is characterized in that, method, step are as follows:
1) by nonmetal selenium, phosphorus grinds, fineness is less than 250 orders; In the course of processing of powder process, be to carry out under the condition of be less than-26PASI vacuum;
2) vanadium metal is placed on to heating and melting in intermediate frequency furnace, to boiling;
3) boron nitride is added in the vanadium liquid of melting, with tungsten bar, stir evenly;
4), when vanadium solution temperature drops to 2400-2500 ℃, under the high-intensity magnetic field of 18T (A/M), vanadium solution is carried out to directional process, to form the ordered arrangement of metallographic structure;
5) add selenium, phosphorus powder, uniform stirring, so that meal is evenly distributed; In the high-intensity magnetic field induction that is greater than 20T (A/M), so that the arrangement architecture of metallographic structure has directivity;
6) with die casting, and machine-shaping;
7) under 8-10T (A/M) strong magnetic field circumstance, 1000-1300 ℃ hot conditions, with ceramic infrared, adjust internal crystal structure.
3. there is according to claim 2 the preparation method of the material of algae removal and cleaning function, it is characterized in that: describedly with ceramic infrared, adjust internal crystal structure, mean: in sealing atmosphere furnace, material is positioned on ceramic infrared hot plate; By temperature control unit, control temperature 1000-1300 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210342212.9A CN103663737A (en) | 2012-09-17 | 2012-09-17 | Material with algae removal and cleaning functions and preparation method of material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210342212.9A CN103663737A (en) | 2012-09-17 | 2012-09-17 | Material with algae removal and cleaning functions and preparation method of material |
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| Publication Number | Publication Date |
|---|---|
| CN103663737A true CN103663737A (en) | 2014-03-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210342212.9A Pending CN103663737A (en) | 2012-09-17 | 2012-09-17 | Material with algae removal and cleaning functions and preparation method of material |
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| Country | Link |
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| CN (1) | CN103663737A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104759248A (en) * | 2015-04-17 | 2015-07-08 | 重庆师范大学 | Microporous boron vanadate compound with adsorption performance and preparation method of microporous boron vanadate compound |
| CN105880222A (en) * | 2014-11-15 | 2016-08-24 | 赵坚强 | Novel environmentally-friendly processor made from high-energy-state material and capable of scale inhibition, rust removal and catalysis |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001239297A (en) * | 2000-03-02 | 2001-09-04 | Chuyu Shoji Kk | System for recovering/recycling cleaning water and its operating method |
| CN1730692A (en) * | 2005-08-09 | 2006-02-08 | 河北工业大学 | A functional alloy material and its preparation method and application |
| RU2422372C2 (en) * | 2009-08-17 | 2011-06-27 | Анатолий Степанович Черабаев | Method of producing water soluble process fluids |
| CN102362044A (en) * | 2009-02-17 | 2012-02-22 | 埃克森美孚研究工程公司 | Coated oil and gas well production devices |
-
2012
- 2012-09-17 CN CN201210342212.9A patent/CN103663737A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001239297A (en) * | 2000-03-02 | 2001-09-04 | Chuyu Shoji Kk | System for recovering/recycling cleaning water and its operating method |
| CN1730692A (en) * | 2005-08-09 | 2006-02-08 | 河北工业大学 | A functional alloy material and its preparation method and application |
| CN102362044A (en) * | 2009-02-17 | 2012-02-22 | 埃克森美孚研究工程公司 | Coated oil and gas well production devices |
| RU2422372C2 (en) * | 2009-08-17 | 2011-06-27 | Анатолий Степанович Черабаев | Method of producing water soluble process fluids |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105880222A (en) * | 2014-11-15 | 2016-08-24 | 赵坚强 | Novel environmentally-friendly processor made from high-energy-state material and capable of scale inhibition, rust removal and catalysis |
| CN104759248A (en) * | 2015-04-17 | 2015-07-08 | 重庆师范大学 | Microporous boron vanadate compound with adsorption performance and preparation method of microporous boron vanadate compound |
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Application publication date: 20140326 |