CN103663645A - Flocculant for treating papermaking wastewater - Google Patents

Flocculant for treating papermaking wastewater Download PDF

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Publication number
CN103663645A
CN103663645A CN201310661614.XA CN201310661614A CN103663645A CN 103663645 A CN103663645 A CN 103663645A CN 201310661614 A CN201310661614 A CN 201310661614A CN 103663645 A CN103663645 A CN 103663645A
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China
Prior art keywords
flocculation agent
treatment
raw material
paper
flocculant
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Pending
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CN201310661614.XA
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Chinese (zh)
Inventor
牟军平
刘晓
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SHANDONG HWAYA ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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SHANDONG HWAYA ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Priority to CN201310661614.XA priority Critical patent/CN103663645A/en
Publication of CN103663645A publication Critical patent/CN103663645A/en
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Abstract

The invention belongs to the technical field of wastewater processing, and specifically relates to a flocculant for treating papermaking wastewater. The flocculant for treating papermaking wastewater is composed of the following raw materials: polymerized chlorinated ferric sulfate, starch-acrylamide grafted polymer, tannin, and bentonite, and has the advantages of good processing effect on papermaking wastewater, no containing of aluminum element, safety, and environment-friendliness.

Description

A kind of flocculation agent for the treatment of paper waste
Technical field
The invention belongs to the technical field of wastewater treatment, be specifically related to a kind of flocculation agent for the treatment of paper waste.
Background technology
Along with China people economic activity is day by day frequent, the pollution that caused water body by soil erosion, production and sanitary sewage is more and more serious, its pollutant component comprises lot of trace organic pollutant, heavy-metal pollution thing, the macromole natural organic matter that also contains higher concentration, single flocculation agent can not have been dealt with problems, and along with the enhancing of people's environmental consciousness, also more and more higher to the requirement of flocculation agent.Existing flocculation agent all contains aluminium element, and aluminium element has very big harm to human body.
It is raw material that paper industry is used timber, straw, reed, rag etc., through High Temperature High Pressure boiling, isolates Mierocrystalline cellulose, makes paper pulp.The non-cellulose of finally discharging in raw material in process of production, partly becomes black liquid.In black liquor, contain xylogen, Mierocrystalline cellulose, VFA etc., frowziness, contaminative is very strong.The paper waste that slurrying produces, pollutes the most serious.During pulp washing, discharge waste water and be chocolate, be called Heisui River, in Heisui River, Pollutant levels are very high, and BOD, up to 5-40g/L, contains a large amount of fibers, inorganic salt and pigment.The paper waste that bleaching process is discharged also contains a large amount of acid-base materials.The paper waste that paper machine is discharged, is called plain boiled water, the filler and the sizing material that wherein contain a large amount of fibers and add in process of production.
Summary of the invention
The object of the invention is to for the defect of above-mentioned existence and a kind of flocculation agent for the treatment of paper waste is provided, the treatment effect that this flocculation agent is directed to paper waste is good, does not contain aluminium element, Environmental Safety.
Technical scheme of the present invention is: a kind of flocculation agent for the treatment of paper waste, is comprised of the raw material of following weight part:
The described flocculation agent for the treatment of paper waste, is comprised of the raw material of following weight part:
Figure BDA0000433208840000012
The described flocculation agent for the treatment of paper waste, is comprised of the raw material of following weight part:
Figure BDA0000433208840000021
The described flocculation agent for the treatment of paper waste, is comprised of the raw material of following weight part:
Figure BDA0000433208840000022
The described flocculation agent for the treatment of paper waste, is comprised of the raw material of following weight part:
Figure BDA0000433208840000023
Beneficial effect of the present invention is: flocculation agent of the present invention has the characteristic of efficient and wide spectrum, and its pH scope that adapts to water quality is wide, and pH value all has good effect in 5~12 scopes, flocculate precipitate is tight, settling velocity is fast, easily clarifies layering, and in the water after processing, salinity is few.
Adopt flocculation agent Processing Paper Wastewater of the present invention, waste water total soluble matter concentration after processing is 17~20mg/L, and total suspended matter is 1.0~1.5mg/L, and BOD has reduced by 89.5%~93.15%, COD has reduced by 80%~85.5%, and pollutants removal rate is 89.55%~92.35%.
Embodiment
Below by specific embodiment, the present invention will be described in detail.
Embodiment 1
For the treatment of a flocculation agent for paper waste, by the raw material of following weight part, formed:
21 parts of poly-ferric sulfate chlorides
18 parts of Starch-acrylamide graftomer
8 parts of tannin
6 parts of wilkinites.
Flocculation agent Processing Paper Wastewater described in employing embodiment 1, the waste water total soluble matter concentration after processing is 20mg/L, and total suspended matter is 1.5mg/L, and BOD has reduced by 89.5%, COD and has reduced by 81.3%, and pollutants removal rate is 89.9%.
Embodiment 2
The described flocculation agent for the treatment of paper waste, is comprised of the raw material of following weight part:
Flocculation agent Processing Paper Wastewater described in employing embodiment 2, the waste water total soluble matter concentration after processing is 18.2mg/L,
Total suspended matter is 1.3mg/L, and BOD has reduced by 90.5%, COD and reduced by 81.3%, and pollutants removal rate is 89.9%.
Embodiment 3
The described flocculation agent for the treatment of paper waste, is comprised of the raw material of following weight part:
Figure BDA0000433208840000032
Flocculation agent Processing Paper Wastewater described in employing example 3, the waste water total soluble matter concentration after processing is 18.5mg/L, and total suspended matter is 1.2mg/L, and BOD has reduced by 91.4%, COD and has reduced by 83.4%, and pollutants removal rate is 91.5%.
Embodiment 4
The described flocculation agent for the treatment of paper waste, is characterized in that, the raw material of following weight part, consists of:
Figure BDA0000433208840000033
Flocculation agent Processing Paper Wastewater described in employing embodiment 4, the waste water total soluble matter concentration after processing is 19mg/L, and total suspended matter is 1.4mg/L, and BOD has reduced by 89.9%, COD and has reduced by 80.7%, and pollutants removal rate is 90.6%.
Embodiment 5
The described flocculation agent for the treatment of paper waste, is comprised of the raw material of following weight part:
Figure BDA0000433208840000034
Flocculation agent Processing Paper Wastewater described in employing embodiment 5, the waste water total soluble matter concentration after processing is 17.6mg/L, and total suspended matter is 1.18mg/L, and BOD has reduced by 92.95%, COD and has reduced by 84.6%, and pollutants removal rate is 92.1%.
Embodiment 6
For the treatment of a flocculation agent for paper waste, by the raw material of following weight part, formed:
Flocculation agent Processing Paper Wastewater described in employing embodiment 6, the waste water total soluble matter concentration after processing is 17mg/L, and total suspended matter is 1.0mg/L, and BOD has reduced by 93.15%, COD and has reduced by 85.5%, and pollutants removal rate is 92.35%.

Claims (5)

1. for the treatment of a flocculation agent for paper waste, it is characterized in that, by the raw material of following weight part, formed:
Figure FDA0000433208830000011
2. according to claim 1 for the treatment of the flocculation agent of paper waste, it is characterized in that, by the raw material of following weight part, formed:
3. according to claim 1 for the treatment of the flocculation agent of paper waste, it is characterized in that, by the raw material of following weight part, formed:
Figure FDA0000433208830000013
4. according to claim 1 for the treatment of the flocculation agent of paper waste, it is characterized in that, by the raw material of following weight part, formed:
Figure FDA0000433208830000014
5. according to claim 1 for the treatment of the flocculation agent of paper waste, it is characterized in that, by the raw material of following weight part, formed:
Figure FDA0000433208830000021
CN201310661614.XA 2013-12-09 2013-12-09 Flocculant for treating papermaking wastewater Pending CN103663645A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310661614.XA CN103663645A (en) 2013-12-09 2013-12-09 Flocculant for treating papermaking wastewater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310661614.XA CN103663645A (en) 2013-12-09 2013-12-09 Flocculant for treating papermaking wastewater

Publications (1)

Publication Number Publication Date
CN103663645A true CN103663645A (en) 2014-03-26

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Country Status (1)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040774A (en) * 1988-08-26 1990-03-28 贵州省环境监测中心站 Polymerization ferric chloride purifying agent and method for making thereof
JPH10244278A (en) * 1997-03-05 1998-09-14 Kanegafuchi Chem Ind Co Ltd Method for aggregation-precipitation treatment of drainage of vinyl chloride resin polymerization
CN101746907A (en) * 2008-12-01 2010-06-23 中国石油化工股份有限公司 Silicon-containing wastewater treatment method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040774A (en) * 1988-08-26 1990-03-28 贵州省环境监测中心站 Polymerization ferric chloride purifying agent and method for making thereof
JPH10244278A (en) * 1997-03-05 1998-09-14 Kanegafuchi Chem Ind Co Ltd Method for aggregation-precipitation treatment of drainage of vinyl chloride resin polymerization
CN101746907A (en) * 2008-12-01 2010-06-23 中国石油化工股份有限公司 Silicon-containing wastewater treatment method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
赵燕等: "天然高分子水处理剂在燃料废水处理中的应用", 《皮革化工》, vol. 24, no. 6, 31 December 2007 (2007-12-31), pages 26 - 30 *

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Application publication date: 20140326