CN103660397B - A kind of composite pipe - Google Patents

A kind of composite pipe Download PDF

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Publication number
CN103660397B
CN103660397B CN201310645172.XA CN201310645172A CN103660397B CN 103660397 B CN103660397 B CN 103660397B CN 201310645172 A CN201310645172 A CN 201310645172A CN 103660397 B CN103660397 B CN 103660397B
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China
Prior art keywords
parts
steel pipe
adhesive
molecular weight
high molecular
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CN201310645172.XA
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CN103660397A (en
Inventor
朱华明
陈德明
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Jiangsu Jinbo New Materials Technology Co Ltd
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Jiangsu Jinbo New Materials Technology Co Ltd
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Priority to CN201310645172.XA priority Critical patent/CN103660397B/en
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Abstract

The invention discloses a kind of composite pipe, comprise steel pipe, the coated ultra-high molecular weight polyethylene layer in described steel pipe periphery, adhesive layer is provided with between described steel pipe and described ultra-high molecular weight polyethylene layer, adhesive layer is formed by the adhesive applied, described adhesive is by rubber, butadiene-styrene rubber, Ludox, fire clay, pitch, rosin, silica, zinc oxide, water and diethylenetriamine, and the present invention has good UV resistant and nuclear radiation, pliability and excellent wear-resisting, durability.This adhesive compatibility is good, and normal temperature self-drying is nonpoisonous and tasteless, strong adhesion.

Description

A kind of composite pipe
Technical field
The present invention relates to a kind of composite pipe, belong to tubing technical field.
Background technology
Current numerous domestic conveying machinery industry carrying roller used has outside steel pipe, nylon tube, steel and covers the kind such as rubber tube, steel sleeve PE pipe, simple use steel pipe do carrying roller exist easily get rusty, frictional resistance is large and to defects such as conveyer belt serious wear; And using nylon tube to make carrying roller, production length within 500mm, once lengthen, can only can not carry larger load; Although it is better to cover rubber elasticity outside steel pipe, there is the defect that frictional resistance is large equally; And use steel pipe overcoat polyvinyl piping materials, although interference fit can be adopted to make to reduce gap between steel pipe and the polyethylene pipe of overcoat when assembling, but due to certain heat can be produced in running after friction, and polyethylene cannula external diameter after being heated expands, thus there is skidding, be subject to certain impact service life.In order to solve the adhesion problem, in prior art, adopt the method increasing adhesive, but due to tubing environment for use, there is larger corrosivity and especially in the north of cold, still come off after using a period of time.
Summary of the invention
The object of the invention is to overcome defect of the prior art, provide a kind of composite pipe, this this tubing has good weatherability, and cohesive is good.
The present invention is achieved by the following technical programs.
A kind of composite pipe, comprises steel pipe, the coated ultra-high molecular weight polyethylene layer in described steel pipe periphery, be provided with adhesive layer between described steel pipe and described ultra-high molecular weight polyethylene layer, adhesive layer is formed by the adhesive applied, wherein, described adhesive is made up of following ingredients, by weight:
Rubber 90-100 part
5 ~ 13 parts, butadiene-styrene rubber
Ludox 15-20 part
Fire clay 20 parts
Pitch 10 parts
Rosin 10 parts
Silica 5 ~ 30
Zinc oxide 5-10 part
Water 40-60 part
Diethylenetriamine 20-30 part.
Above-mentioned composite pipe, wherein, preferred following ingredients composition:
Rubber 100 parts
10 parts, butadiene-styrene rubber
Ludox 20 parts
Fire clay 20 parts
Pitch 10 parts
Rosin 10 parts
Silica 20 parts
5 parts, zinc oxide
60 parts, water
Diethylenetriamine 25 parts.
Beneficial effect of the present invention: the present invention has good UV resistant and nuclear radiation, pliability and excellent wear-resisting, durability.This adhesive compatibility is good, and normal temperature self-drying is nonpoisonous and tasteless, strong adhesion.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
A kind of composite pipe, comprise steel pipe, the coated ultra-high molecular weight polyethylene layer in described steel pipe periphery, adhesive layer is provided with between described steel pipe and described ultra-high molecular weight polyethylene layer, adhesive layer is formed by the adhesive applied, add and man-hour outer surface of steel tube is carried out derusting by sandblasting, by clean for outer surface of steel tube clean, dry 45 hours, evenly layer of adhesive is applied at outer surface of steel tube, then by the steel pipe of coated adhesive at room temperature dry 20-30 minute, again steel pipe is inserted in mould, open extruder at steel pipe outer cladding one deck ultra-high molecular weight polyethylene layer, each district heating-up temperature of extruder is followed successively by 165 DEG C, 170 DEG C, 170 DEG C, 175 DEG C, 180 DEG C, 190 DEG C, die temperature is 185-190 DEG C, extruder engine speed is 400r/min, cool finally by water tank, by weight, adhesive is made up of rubber 90 parts, 5 parts, butadiene-styrene rubber, Ludox 15 parts, fire clay 20 parts, pitch 10 parts, rosin 10 parts, silica 5 parts, 5 parts, zinc oxide, 40 parts, water and diethylenetriamine 20 parts.The thickness of ultra-high molecular weight polyethylene layer is 8mm.
6 hours surperficial rate of wear <0.17%
Peel strength >45MPa during room temperature
Peel strength >36MPa when 80 DEG C
Peel strength >34MPa when-120 DEG C
Cantilever beam impact strength>=20KJ/m 2
Embodiment two
A kind of composite pipe, comprise steel pipe, the coated ultra-high molecular weight polyethylene layer in described steel pipe periphery, adhesive layer is provided with between described steel pipe and described ultra-high molecular weight polyethylene layer, adhesive layer is formed by the adhesive applied, add and man-hour outer surface of steel tube is carried out derusting by sandblasting, by clean for outer surface of steel tube clean, dry 45 hours, evenly layer of adhesive is applied at outer surface of steel tube, then by the steel pipe of coated adhesive at room temperature dry 20-30 minute, again steel pipe is inserted in mould, open extruder at steel pipe outer cladding one deck ultra-high molecular weight polyethylene layer, each district heating-up temperature of extruder is followed successively by 165 DEG C, 170 DEG C, 170 DEG C, 175 DEG C, 180 DEG C, 190 DEG C, die temperature is 185-190 DEG C, extruder engine speed is 400r/min, cool finally by water tank, by weight, adhesive is by rubber 100 parts, 10 parts, butadiene-styrene rubber, Ludox 20 parts, fire clay 20 parts, pitch 10 parts, rosin 10 parts, silica 20 parts, 5 parts, zinc oxide, 60 parts, water, diethylenetriamine 25 parts.
Performance indications are as follows:
Peel strength >45MPa during room temperature
Peel strength >36MPa when 80 DEG C
Peel strength >34MPa when-120 DEG C
Here description of the invention and application is illustrative, not wants by scope restriction of the present invention in the above-described embodiments, and therefore, the present invention is not by the restriction of the present embodiment, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.

Claims (2)

1. a composite pipe, comprise steel pipe, the coated ultra-high molecular weight polyethylene layer in described steel pipe periphery, it is characterized in that, adhesive layer is provided with between described steel pipe and described ultra-high molecular weight polyethylene layer, adhesive layer is formed by the adhesive applied, add and man-hour outer surface of steel tube is carried out derusting by sandblasting, by clean for outer surface of steel tube clean, dry 45 hours, evenly layer of adhesive is applied at outer surface of steel tube, then by the steel pipe of coated adhesive at room temperature dry 20-30 minute, again steel pipe is inserted in mould, open extruder at steel pipe outer cladding one deck ultra-high molecular weight polyethylene layer, each district heating-up temperature of extruder is followed successively by 165 DEG C, 170 DEG C, 170 DEG C, 175 DEG C, 180 DEG C, 190 DEG C, die temperature is 185-190 DEG C, extruder engine speed is 400r/min, cool finally by water tank, by weight, adhesive is made up of rubber 90 parts, 5 parts, butadiene-styrene rubber, Ludox 15 parts, fire clay 20 parts, pitch 10 parts, rosin 10 parts, silica 5 parts, 5 parts, zinc oxide, 40 parts, water and diethylenetriamine 20 parts, and the thickness of ultra-high molecular weight polyethylene layer is 8mm.
2. a composite pipe, comprise steel pipe, the coated ultra-high molecular weight polyethylene layer in described steel pipe periphery, it is characterized in that, adhesive layer is provided with between described steel pipe and described ultra-high molecular weight polyethylene layer, adhesive layer is formed by the adhesive applied, add and man-hour outer surface of steel tube is carried out derusting by sandblasting, by clean for outer surface of steel tube clean, dry 45 hours, evenly layer of adhesive is applied at outer surface of steel tube, then by the steel pipe of coated adhesive at room temperature dry 20-30 minute, again steel pipe is inserted in mould, open extruder at steel pipe outer cladding one deck ultra-high molecular weight polyethylene layer, each district heating-up temperature of extruder is followed successively by 165 DEG C, 170 DEG C, 170 DEG C, 175 DEG C, 180 DEG C, 190 DEG C, die temperature is 185-190 DEG C, extruder engine speed is 400r/min, cool finally by water tank, by weight, adhesive is by rubber 100 parts, 10 parts, butadiene-styrene rubber, Ludox 20 parts, fire clay 20 parts, pitch 10 parts, rosin 10 parts, silica 20 parts, 5 parts, zinc oxide, 60 parts, water, diethylenetriamine 25 parts.
CN201310645172.XA 2013-12-05 2013-12-05 A kind of composite pipe Active CN103660397B (en)

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Application Number Priority Date Filing Date Title
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CN103660397B true CN103660397B (en) 2015-10-28

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108397608A (en) * 2018-03-01 2018-08-14 贵州黔峰管业有限公司 A kind of two-layer compound tubing and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103042069A (en) * 2012-12-28 2013-04-17 江苏金波新材料科技有限公司 Method for preparing composite pipe

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013185023A (en) * 2012-03-07 2013-09-19 Mitsubishi Plastics Inc Transparent double-sided pressure-sensitive adhesive sheet and image display using the same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103042069A (en) * 2012-12-28 2013-04-17 江苏金波新材料科技有限公司 Method for preparing composite pipe

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
尹卫平 等.橡胶胶黏剂.《精细化工产品及工艺》.华东理工大学出版社,2009, *

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