CN103642197A - Antibacterial, halogen-free and fire-retardant polyphenyl ether composite material - Google Patents
Antibacterial, halogen-free and fire-retardant polyphenyl ether composite material Download PDFInfo
- Publication number
- CN103642197A CN103642197A CN201310607771.2A CN201310607771A CN103642197A CN 103642197 A CN103642197 A CN 103642197A CN 201310607771 A CN201310607771 A CN 201310607771A CN 103642197 A CN103642197 A CN 103642197A
- Authority
- CN
- China
- Prior art keywords
- parts
- polyphenyl ether
- matrix material
- retardant polyphenyl
- antibacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an antibacterial, halogen-free, and fire-retardant polyphenyl ether composite material, and belongs to the technical field of polymer materials. The composite material is composed of the following raw materials in parts by weight: 61.3 to 72.5 parts of polyphenyl ether resin, 13.4 to 17.7 parts of polystyrene resin, 5 to 8 parts of powdered rubber, 8 to 13 parts of flexibilizer, 0.6 to 1.2 parts of antioxidant, 25 to 32 parts of phosphate, 1.1 to 1.7 parts of lubricant, 0.1 to 0.3 part of antibacterial agent, and 1.8 to 3.2 parts of carbon black. The antibacterial, halogen-free, and fire-retardant polyphenyl ether composite material has the following tested performance indexes: tensile strength of 16 to 24 MPa, elongation percentage of 230 to 320%, surface hardness of 45 to 55 D, and fire resistance of V-0 (UL-94-3.0mm), and has an excellent effect on inhibiting bacterial breeding.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of antibacterial halogen-free fire-retardant polyphenyl ether matrix material.
Background technology
Due to polyphenylene oxide, there is the strong points such as good temperature tolerance, crystallinity, erosion resistance, thereby be widely used in automobile, electronics, building, toy, office appliance etc.But polyphenylene oxide fusing point is high, add large, the processing difficulties of melt viscosity in man-hour, and the inclined to one side rigidity of pure polyphenylene oxide, snappiness is not enough, when the product of producing such as having the electrical equipment lever that elasticity requires, often cannot meet.And during for goods such as utensils, material fire-retardant required high, tradition is fire-retardant is by adding halogen-containing based flame retardant or antimony compounds, easily discharges toxic gas, harm health of people during these substance combustions.Meanwhile, utensil is during for the wet environment such as kitchen, because of bacterium procreation, mouldy have a strong impact on attractive in appearance.Therefore, develop and antibacterially there is realistic meaning with fire-retardant polyphenylene oxide composite material.
Summary of the invention
Task of the present invention is to provide a kind of and contributes to improve intensity, be conducive to improve flame retardant properties and be of value to the antibacterial halogen-free fire-retardant polyphenyl ether matrix material of bacteria growing inhibiting.
Task of the present invention completes like this, a kind of antibacterial halogen-free fire-retardant polyphenyl ether matrix material, and its raw material by following parts by weight forms:
In one embodiment of the invention, described polyphenylene oxide resin is 2,6 dimethyl 1.4 polyphenylene oxide resins.
In another embodiment of the present invention, described polystyrene resin is high impact polystyrene resin.
In yet another embodiment of the present invention, described powdered rubber is nanometer acrylonitrile-butadiene rubber powder.
In another embodiment of the present invention, described toughner is styrene-butadiene-styrene.
Of the present invention, also have in an embodiment, described oxidation inhibitor is 2,2 methylene radical-bis-(4-methyl-6-tert-butylphenols).
More of the present invention and in an embodiment, described phosphoric acid salt is hypo-aluminum orthophosphate.
In of the present invention and then an embodiment, described lubricant is organic silicone master batch.
Of the present invention again more and in an embodiment, described antiseptic-germicide is oxine ketone.
In again of the present invention and then an embodiment, described carbon black is that carbonarius is female.
Antibacterial halogen-free fire-retardant polyphenyl ether matrix material provided by the invention has following performance index after tested: tensile strength 16～24MPa, elongation 230～320%, surface hardness 45～55D, flame retardant resistance V-0 (UL-94-3.0mm), anti-bacteria reproductive effect is excellent.
Embodiment
Embodiment 1:
Embodiment 2:
Embodiment 3:
Embodiment 4:
The antibacterial halogen-free fire-retardant polyphenyl ether matrix material being obtained by above-described embodiment 1 to 4 has following technique effect after tested:
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Tensile strength MPa | 16 | 18 | 21 | 24 |
| Elongation at break % | 230 | 280 | 260 | 320 |
| Surface hardness | 45D | 47D | 52D | 55D |
| Flame retardant resistance (UL-94-3.0mm) | V-0 | V-0 | V-0 | V-0 |
Claims (10)
1. an antibacterial halogen-free fire-retardant polyphenyl ether matrix material, is characterized in that its raw material by following parts by weight forms:
61.3～72.5 parts of polyphenylene oxide resins;
13.4～17.7 parts of polystyrene resins;
5～8 parts of powdered rubbers;
8～13 parts of toughner;
0.6 ~ 1.2 part, oxidation inhibitor;
25 ~ 32 parts of phosphoric acid salt;
1.1 ~ 1.7 parts of lubricants;
0.1 ~ 0.3 part of antiseptic-germicide;
1.8 ~ 3.2 parts of carbon blacks.
2. antibacterial halogen-free fire-retardant polyphenyl ether matrix material according to claim 1, is characterized in that described polyphenylene oxide resin is 2,6 dimethyl 1.4 polyphenylene oxide resins.
3. antibacterial halogen-free fire-retardant polyphenyl ether matrix material according to claim 1, is characterized in that described polystyrene resin is high impact polystyrene resin.
4. antibacterial halogen-free fire-retardant polyphenyl ether matrix material according to claim 1, is characterized in that described powdered rubber is nanometer acrylonitrile-butadiene rubber powder.
5. antibacterial halogen-free fire-retardant polyphenyl ether matrix material according to claim 1, is characterized in that described toughner is styrene-butadiene-styrene.
6. antibacterial halogen-free fire-retardant polyphenyl ether matrix material according to claim 1, is characterized in that described oxidation inhibitor is 2,2 methylene radical-bis-(4-methyl-6-tert-butylphenols).
7. antibacterial halogen-free fire-retardant polyphenyl ether matrix material according to claim 1, is characterized in that described phosphoric acid salt is hypo-aluminum orthophosphate.
8. antibacterial halogen-free fire-retardant polyphenyl ether matrix material according to claim 1, is characterized in that described lubricant is organic silicone master batch.
9. antibacterial halogen-free fire-retardant polyphenyl ether matrix material according to claim 1, is characterized in that described antiseptic-germicide is oxine ketone.
10. antibacterial halogen-free fire-retardant polyphenyl ether matrix material according to claim 1, is characterized in that described carbon black is that carbonarius is female.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310607771.2A CN103642197A (en) | 2013-11-25 | 2013-11-25 | Antibacterial, halogen-free and fire-retardant polyphenyl ether composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310607771.2A CN103642197A (en) | 2013-11-25 | 2013-11-25 | Antibacterial, halogen-free and fire-retardant polyphenyl ether composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103642197A true CN103642197A (en) | 2014-03-19 |
Family
ID=50247491
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310607771.2A Pending CN103642197A (en) | 2013-11-25 | 2013-11-25 | Antibacterial, halogen-free and fire-retardant polyphenyl ether composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103642197A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107759913A (en) * | 2017-11-17 | 2018-03-06 | 皮光明 | High tenacity antibiotic plastic and its preparation technology |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130616A (en) * | 2007-09-28 | 2008-02-27 | 深圳市科聚新材料有限公司 | Low-smoke halogen-freeflame-proof polyphenylene oxide electric wire and cable material, and method for producing the same |
-
2013
- 2013-11-25 CN CN201310607771.2A patent/CN103642197A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130616A (en) * | 2007-09-28 | 2008-02-27 | 深圳市科聚新材料有限公司 | Low-smoke halogen-freeflame-proof polyphenylene oxide electric wire and cable material, and method for producing the same |
Non-Patent Citations (1)
| Title |
|---|
| 良友: "国内外抗菌材料应用技术和产业发展", 《精细化工原料及中间体》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107759913A (en) * | 2017-11-17 | 2018-03-06 | 皮光明 | High tenacity antibiotic plastic and its preparation technology |
| CN107759913B (en) * | 2017-11-17 | 2020-07-21 | 沈阳东源包装制品有限公司 | High-toughness antibacterial plastic and preparation process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104744875A (en) | Preparation method of antibacterial flame-retardant ABS material | |
| CN103030970B (en) | A kind of mildew-resistant halogen-free flameproof PET/PA6 alloy material and preparation method thereof | |
| CN106633915A (en) | Highly flame-retardant halogen-free environment-friendly silicone rubber and preparation method thereof | |
| CN103627129A (en) | Antibacterial dust-suppression halogen-free flam-retardant ABS and preparation technology thereof | |
| CN102675747A (en) | Formula of reinforcement and flame retardant polypropylene | |
| CN104327511A (en) | Low-smoke halogen-free flame retardant composition for silicone rubber and application thereof | |
| CN100582163C (en) | PC/ABS alloy | |
| CN104017264B (en) | The preparation of halogen-free low-smoke Cross-linked Polyethylene Composites | |
| CN103642197A (en) | Antibacterial, halogen-free and fire-retardant polyphenyl ether composite material | |
| CN104163987A (en) | Polytetrafluoroethylene modified polypropylene composite material | |
| CN101205328A (en) | Halogen-free flame-retardant polypropylene composition with excellent comprehensive properties and preparation thereof | |
| CN103642195A (en) | Preparation method of antibacterial, halogen-free, and fire-retardant polyphenyl ether composite material | |
| CN102167882B (en) | Benzoxazine-containing high-gloss halogen-free flame-retardant plastic and application thereof | |
| CN103102666A (en) | Flame retardant grade antibacterial office supply made of PC (polycarbonate)/ABS (acrylonitrile butadiene styrene) | |
| CN103951972B (en) | A kind of corrosion-resistant graphite nylon washer material | |
| CN110819092A (en) | High-hardness high-flame-retardant polycarbonate composite material | |
| CN103059427A (en) | Flame-retardant polystyrene resin | |
| CN105331111A (en) | Aromatic fireproof and oilproof rubber formula | |
| WO2017197659A1 (en) | Modified polyamide flame retardant plastic | |
| CN103937091A (en) | Flame retardation enhanced polypropylene composition and preparation method thereof | |
| CN104163980A (en) | Antibacterial halogen-free flame-retardant polypropylene composite material | |
| CN102675746B (en) | Formula of foam reinforced polypropylene | |
| CN103333475A (en) | Bactericidal polycarbonate fluorescent thin film | |
| CN107778748A (en) | A kind of modified plastics formula of nontoxic high luminosity | |
| CN103642196A (en) | Halogen-free, fire-retardant, and glass fiber strengthened polyphenyl ether alloy material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140319 |