CN103636632B - A kind of Pesticidal combination containing chlorine chlorfenapyr and Aphox - Google Patents
A kind of Pesticidal combination containing chlorine chlorfenapyr and Aphox Download PDFInfo
- Publication number
- CN103636632B CN103636632B CN201310629395.7A CN201310629395A CN103636632B CN 103636632 B CN103636632 B CN 103636632B CN 201310629395 A CN201310629395 A CN 201310629395A CN 103636632 B CN103636632 B CN 103636632B
- Authority
- CN
- China
- Prior art keywords
- aphox
- chlorine chlorfenapyr
- chlorfenapyr
- active ingredient
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 title claims abstract description 89
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 88
- 239000000460 chlorine Substances 0.000 title claims abstract description 88
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 88
- YFGYUFNIOHWBOB-UHFFFAOYSA-N pirimicarb Chemical compound CN(C)C(=O)OC1=NC(N(C)C)=NC(C)=C1C YFGYUFNIOHWBOB-UHFFFAOYSA-N 0.000 title claims abstract description 85
- 230000000361 pesticidal effect Effects 0.000 title claims description 12
- 239000000203 mixture Substances 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000003094 microcapsule Substances 0.000 claims abstract description 15
- 239000000725 suspension Substances 0.000 claims abstract description 15
- 239000004480 active ingredient Substances 0.000 claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 13
- 238000009736 wetting Methods 0.000 claims abstract description 13
- 239000000375 suspending agent Substances 0.000 claims abstract description 12
- 239000002917 insecticide Substances 0.000 claims abstract description 7
- 238000009472 formulation Methods 0.000 claims abstract description 5
- -1 alkylbenzene naphthalene sulfonate Chemical class 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000470 constituent Substances 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 8
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 5
- 210000000481 breast Anatomy 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- XXKHDSGLCLCFSC-UHFFFAOYSA-N 2,3-diphenylphenol Chemical compound C=1C=CC=CC=1C=1C(O)=CC=CC=1C1=CC=CC=C1 XXKHDSGLCLCFSC-UHFFFAOYSA-N 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 229920001732 Lignosulfonate Polymers 0.000 claims description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
- 239000002775 capsule Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000007859 condensation product Substances 0.000 claims description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000007884 disintegrant Substances 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000010985 leather Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000003002 pH adjusting agent Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 4
- 229920000053 polysorbate 80 Polymers 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- KKDONKAYVYTWGY-UHFFFAOYSA-M sodium;2-(methylamino)ethanesulfonate Chemical compound [Na+].CNCCS([O-])(=O)=O KKDONKAYVYTWGY-UHFFFAOYSA-M 0.000 claims description 4
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 claims description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 3
- 229920000084 Gum arabic Polymers 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 239000000205 acacia gum Substances 0.000 claims description 3
- 235000010489 acacia gum Nutrition 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- 229940077388 benzenesulfonate Drugs 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- GSNUFIFRDBKVIE-UHFFFAOYSA-N DMF Natural products CC1=CC=C(C)O1 GSNUFIFRDBKVIE-UHFFFAOYSA-N 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- 229960000583 acetic acid Drugs 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 229960000892 attapulgite Drugs 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 229920006184 cellulose methylcellulose Polymers 0.000 claims description 2
- 239000012362 glacial acetic acid Substances 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 229910052625 palygorskite Inorganic materials 0.000 claims description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 2
- 229920006324 polyoxymethylene Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical class CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 2
- 238000005498 polishing Methods 0.000 claims 5
- 241000978776 Senegalia senegal Species 0.000 claims 1
- 230000000749 insecticidal effect Effects 0.000 abstract description 14
- 241000176086 Sogatella furcifera Species 0.000 abstract description 9
- 241001124076 Aphididae Species 0.000 abstract description 7
- 241000607479 Yersinia pestis Species 0.000 abstract description 7
- 238000001228 spectrum Methods 0.000 abstract description 7
- 235000013339 cereals Nutrition 0.000 abstract description 5
- 235000013311 vegetables Nutrition 0.000 abstract description 5
- 235000002637 Nicotiana tabacum Nutrition 0.000 abstract description 4
- 241000008892 Cnaphalocrocis patnalis Species 0.000 abstract description 3
- 241000255925 Diptera Species 0.000 abstract description 3
- 241000255967 Helicoverpa zea Species 0.000 abstract description 3
- 241000500437 Plutella xylostella Species 0.000 abstract description 3
- 241000985245 Spodoptera litura Species 0.000 abstract description 3
- 235000013399 edible fruits Nutrition 0.000 abstract description 3
- 241000258937 Hemiptera Species 0.000 abstract description 2
- 241000238631 Hexapoda Species 0.000 abstract description 2
- 241000255777 Lepidoptera Species 0.000 abstract description 2
- 230000007246 mechanism Effects 0.000 abstract description 2
- 241000208125 Nicotiana Species 0.000 abstract 2
- 238000002156 mixing Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000003814 drug Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000008346 aqueous phase Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 229920001807 Urea-formaldehyde Polymers 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000295 complement effect Effects 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 244000215068 Acacia senegal Species 0.000 description 2
- 244000061176 Nicotiana tabacum Species 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N 1H-pyrrole Natural products C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 1
- 125000006012 2-chloroethoxy group Chemical group 0.000 description 1
- 0 CCc1c(*F)[n](C=CCNCCC#C)c(-c2ccc(C)cc2)c1* Chemical compound CCc1c(*F)[n](C=CCNCCC#C)c(-c2ccc(C)cc2)c1* 0.000 description 1
- 208000019300 CLIPPERS Diseases 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000005923 Pirimicarb Substances 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 208000021930 chronic lymphocytic inflammation with pontine perivascular enhancement responsive to steroids Diseases 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
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- 238000002474 experimental method Methods 0.000 description 1
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
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- 230000035699 permeability Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of agricultural insecticide composition containing active ingredient chlorine chlorfenapyr and Aphox, wherein the weight ratio of active ingredient chlorine chlorfenapyr and active ingredient Aphox is 1 ~ 30 ︰ 1 ~ 30, and the gross weight of active ingredient accounts for 1% ~ 60% of composition total weight.Present composition formulation comprises wetting powder, water dispersible granules, suspending agent, aqueous emulsion, micro-capsule suspension.The present invention possesses chlorine chlorfenapyr and Aphox two kinds of insecticide double action mechanism, overcomes and delay the drug-fast generation of insect.Synergy is obvious, and dosage reduces, and cost reduces, and insecticidal spectrum increases.The various pests such as control diamond-back moth, prodenia litura, rice fulgorid, cotton bollworm, rice leaf roller can not only be used for, the aphid etc. on vegetables, tobacco, cereal crops can also be prevented and treated.Scope of using increases, and is applicable to the control of the multiple Lepidoptera of fruit tree, vegetables, grain, tobacco etc., Homoptera and Diptera pest.
Description
Technical field
The present invention relates to chlorine chlorfenapyr and Aphox is the Pesticidal combination of active ingredient.
Background technology
Chlorine chlorfenapyr, chemical name is the bromo-2-of 4-(4-chlorphenyl)-1-[(2-chloroethoxy) methyl]-5-trifluoromethyl pyrpole-3-formonitrile HCN, is the new pyrrole heterocycle compound with obvious insecticidal activity that Hunan Chemical Research Institute designs and synthesizes.
Its structural formula is:
Chlorine chlorfenapyr is the analog of novel pesticide chlorfenapyr.Its mechanism of action is by disturbing Intramitochondrial electrochemical gradient thus blocking oxide Phosphorylation events, have excellent to tag, stomach poison activity and comprehensive toxic action, its toxicity is low, and safety is good, without cross resistance.The various pests such as main control diamond-back moth, prodenia litura, rice fulgorid, cotton bollworm, rice leaf roller.But without stifling, systemic action, as eaten into carpophagous aphid, control is difficult to some crop pests.
Aphox (Pirimicarb) is the carbamates selectivity aphicide that the U.S. foretells the development of inside door company.This medicine sterling is colourless. the solid of odorless, can be dissolved in most of organic solvent.Under general condition deposit more stable, but meet strong acid, highly basic or easily decompose under ultraviolet illumination.Aphox have tag, fumigate, systemic action, permeability is woven with to vane group, can effectively prevents and treats aphid organic phosphor being had to resistance.Impose in soil and can be absorbed by crop root, to crop safety, there is quick-acting.This medicine can be used for cereal, fruit tree, vegetables, cigarette, beans and flowers etc.Also effective to Diptera pest.To crop safety, quick-acting is good, but persistence is not long.
The defect of existence is used alone in order to overcome chlorine chlorfenapyr, and expand insecticidal spectrum and the controlling object of chlorine chlorfenapyr, chlorine chlorfenapyr and Aphox are carried out compounded combination by spy, play chlorine chlorfenapyr and Aphox two kinds of insecticidal properties better, improve drug effect, expand insecticidal spectrum and use scope, reduce agriculture this and resistance generation.Have not yet to see the relevant report about chlorine chlorfenapyr and Aphox compounded combination.
Summary of the invention
The object of the invention is the defect being used alone existence in order to overcome chlorine chlorfenapyr, expand insecticidal spectrum and the controlling object of chlorine chlorfenapyr, the invention provides a kind of Pesticidal combination containing insecticidal active ingredient chlorine chlorfenapyr and insecticidal active ingredient Aphox, wherein the weight ratio of insecticidal active ingredient chlorine chlorfenapyr and insecticidal active ingredient Aphox is 1 ~ 30 ︰ 1 ~ 30, and the gross weight of insecticidal active ingredient accounts for 1% ~ 60% of composition total weight.
Pesticidal combination of the present invention, has into wetting powder, water dispersible granules, suspending agent, aqueous emulsion, micro-capsule suspension by the formulation of this area current techique processing.
When the present composition is wetting powder, each constituent content is:
The concrete procedure of processing of said composition wetting powder is: by above-mentioned formula by chlorine chlorfenapyr and Aphox and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mix after airslide disintegrating mill, the wetting powder of the present composition can be obtained.
When the present composition is for becoming water dispersible granules, each constituent content is:
The concrete procedure of processing of said composition water dispersible granules is: chlorine chlorfenapyr, Aphox and dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, the water dispersible granules containing chlorine chlorfenapyr and Aphox Pesticidal combination obtained of the present invention.
When the present composition is suspending agent, each constituent content is:
The concrete procedure of processing of said composition suspending agent is first mixed by auxiliary agent, mix through high speed shear, add chlorine chlorfenapyr and the former medicine of Aphox, ball milling 2-3 hour in ball mill, make diameter of particle all below 5 μm, the aqueous suspension formulations containing the Pesticidal combination of chlorine chlorfenapyr and Aphox obtained of the present invention.
When the present composition is aqueous emulsion, each constituent content is:
The concrete procedure of processing of this Pesticidal combination aqueous emulsion is for be added together former medicine chlorine chlorfenapyr and Aphox, solvent and emulsifier, it is made to be dissolved into uniform oil phase, other insecticides adjuvants such as part water, antifreezing agent are mixed into uniform aqueous phase, in a kettle. while high-speed stirred, oil phase is added in aqueous phase, slowly add water until arrive phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear 30min.The i.e. aqueous emulsion preparation containing the Pesticidal combination of chlorine chlorfenapyr and Aphox obtained of the present invention.
When the present composition is micro-capsule suspension, constituent content is:
The processing method of this Pesticidal combination micro-capsule suspension has two kinds:
Method one: the preparation of (1) urea resin prepolymer: by formalin (mol ratio=1:1.5-2 of urea and the formaldehyde) mix and blend of urea and 37% mass percentage concentration, pH to 8.5 is regulated with triethylamine, be warming up to 70 DEG C, with 450 revs/min of stirring reactions 1 hour, obtain the urea resin prepolymer aqueous solution; (2) micro-capsule suspension preparation: under normal temperature, chlorine chlorfenapyr, Aphox are dissolved in solvent, dispersant, urea-formaldehyde resin aqueous solution, emulsifier is added under stirring condition, high speed homogenizing 5 minutes, reduce rotating speed to 450 rev/min after forming oil-in-water emulsion, regulate pH, react 1 hour under acid catalysis, to reaction end, adjust pH to neutral; Add thickener, stir and namely make micro-capsule suspension.
Method two: chlorine chlorfenapyr, Aphox are dissolved in solvent by (1), adds capsule leather material and stirs and obtain oil phase; (2) in water, add emulsifier for mixing and evenly obtain aqueous phase; (3) aqueous phase joins in oil phase, high speed homogenizing formation stabilized oil-in-water emulsion; (4) under 450 revs/min, add pH adjusting agent and participate in interface polymerization reaction, reaction temperature rises to 25 DEG C-70 DEG C, keeps solidifying encystation in 2-24 hour; (5) add dispersant, thickener, stir and namely make micro-capsule suspension.
Described emulsifier is one or more in alkylbenzene naphthalene sulfonate, alkylphenol polyoxyethylene phosphate, diphenyl phenol polyethenoxy polyethenoxy ether, styrenated phenol APEO, alkylphenol polyoxyethylene formaldehyde condensation products, diphenyl phenol polyethenoxy polyformaldehyde condensation product, castor oil ethylene oxide adduct, NNO, NP, agriculture breast 500, agriculture breast 600, Tween-80, polyvinyl alcohol.
Described dispersant is one or more in lignosulfonates, fatty acid amide N methyl taurine sodium salt, alkylphenol polyoxyethylene sulphate, polyoxyethylene polyoxypropylene block copolymer, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether.
Described wetting agent be selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, sodium alkyl benzene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder one or more.
Described disintegrant be selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate one or more.
Described filler be selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate one or more.
Described thickener is one in aluminium-magnesium silicate, xanthans, CMC, gum Arabic, polyvinylpyrrolidone or several.
Described antifreezing agent is selected from one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol.
Described defoamer is selected from silicone oil, aluminium-magnesium silicate, silicone compound, C
10-20saturated fat acid compounds, C
8-10one or more in aliphatic alcohols compound and polyoxyethylene glycerol ether.
Described capsule leather material is one or more in tolyl isocyanate, the many toluene diisocyanates of polymethylene, methyl diphenylene diisocyanate, Lauxite.
Described solvent is one or more in toluene, dimethylbenzene, ethanol, DMF, chloroform, cyclohexanone, acetone.
Described pH adjusting agent mainly contains one or more in hydrochloric acid, glacial acetic acid, citric acid, sodium hydroxide, ammoniacal liquor, ethylenediamine, triethanolamine, triethylamine.
The present invention has the following advantages:
(1) synergy is obvious: chlorine chlorfenapyr and the mutual mixture of Aphox do not produce conflict, and coordinate synergy, reduces dose, reduces costs.
(2) delaying drug resistance: possess two kinds of insecticide double action mechanism, overcome and delay the drug-fast generation of insect.
(3) insecticidal spectrum is expanded: the various pests such as control diamond-back moth, prodenia litura, rice fulgorid, cotton bollworm, rice leaf roller can not only be used for, the aphid etc. on vegetables, tobacco, cereal crops can also be prevented and treated.
(4) scope of using increases: the control being applicable to the multiple Lepidoptera of fruit tree, vegetables, grain, tobacco etc., Homoptera and Diptera pest.
Embodiment
Be elaborated the present invention below by embodiment, the percentage in embodiment is weight percentage, but the present invention is not limited thereto.
Embodiment 1:21% Aphox chlorine chlorfenapyr wetting powder
Aphox 1%, chlorine chlorfenapyr 20%, polyoxyethylene carboxylate 5%, lauryl sodium sulfate 5%, kaolin complement to 100%, mix laggard row air-flow crushing, obtained 21% Aphox chlorine chlorfenapyr wetting powder.
Embodiment 2:60% Aphox chlorine chlorfenapyr wetting powder
Aphox 30%, chlorine chlorfenapyr 30%, lignosulfonates 7%, spaonin powder 5%, bentonite complement to 100%, mix laggard row air-flow crushing, obtained 60% Aphox chlorine chlorfenapyr wetting powder.
Embodiment 3:2% Aphox chlorine chlorfenapyr wetting powder
Aphox 1%, chlorine chlorfenapyr 1%, alkylsulfonate 4%, Nekal BX 3%, diatomite complement to 100%, mix laggard row air-flow crushing, obtained 2% Aphox chlorine chlorfenapyr wetting powder.
Embodiment 4:40% Aphox chlorine chlorfenapyr water dispersible granules
Aphox 10%, chlorine chlorfenapyr 30%, alkylphenol polyoxyethylene 6%, lauryl sodium sulfate 4%, urea 5%, kaolin supply 100%, and mixing granulation obtains 40% Aphox chlorine chlorfenapyr water-dispersible granules.
Embodiment 5:60% Aphox chlorine chlorfenapyr water dispersible granules
Aphox 30%, chlorine chlorfenapyr 30%, fatty alcohol-polyoxyethylene ether 9%, sodium alkyl benzene sulfonate 5%, ammonium sulfate 2%, diatomite supply 100%, and mixing granulation obtains 60% Aphox chlorine chlorfenapyr water-dispersible granules.
Embodiment 6:2% Aphox chlorine chlorfenapyr water dispersible granules
Aphox 1%, chlorine chlorfenapyr 1%, fatty acid amide N methyl taurine sodium salt 3%, polyoxyethylene tri-styryl phosphenylic acid salt 3%, bentonite supply 100%, the 2% Aphox chlorine chlorfenapyr water-dispersible granules that mixing granulation is obtained.
Embodiment 7:25% Aphox chlorine chlorfenapyr suspending agent
Aphox 20%, chlorine chlorfenapyr 5%, alkylphenol polyoxyethylene 6%, aluminium-magnesium silicate 4%, ethylene glycol 1%, polyoxyethylene glycerol ether 0.5%, water supply 100%, obtained 25% Aphox chlorine chlorfenapyr suspending agent after mixing
Embodiment 8:60% Aphox chlorine chlorfenapyr suspending agent
Aphox 30%, chlorine chlorfenapyr 30%, lignosulfonates 10%, xanthans 3%, polyethylene glycol 2%, silicone oil 1%, water supply 100%, obtained 60% Aphox chlorine chlorfenapyr suspending agent after mixing.
Embodiment 9:2% Aphox chlorine chlorfenapyr suspending agent
Aphox 1%, chlorine chlorfenapyr 1%, fatty alcohol-polyoxyethylene ether 10%, polyvinylpyrrolidone 5%, propane diols 2%, C
8-10aliphatic alcohols compound 0.1%, water supply 100%, obtained 2% Aphox chlorine chlorfenapyr suspending agent after mixing
Embodiment 10:41% Aphox chlorine chlorfenapyr aqueous emulsion
Aphox 30%, chlorine chlorfenapyr 11%, agriculture breast 5008%, dimethylbenzene 6%, aluminium-magnesium silicate 4%, ethylene glycol 1%, polyoxyethylene glycerol ether 0.5%, water supply 100%, obtained 41% Aphox chlorine chlorfenapyr aqueous emulsion after mixing.
Embodiment 11:60% Aphox chlorine chlorfenapyr aqueous emulsion
Aphox 30%, chlorine chlorfenapyr 30%, styrenated phenol APEO 10%, toluene 10%, xanthans 3%, polyethylene glycol 2%, silicone oil 1%, water supply 100%, 60% Aphox chlorine chlorfenapyr aqueous emulsion obtained after mixing.
Embodiment 12:2% Aphox chlorine chlorfenapyr aqueous emulsion
Aphox 1%, chlorine chlorfenapyr 1%, Tween-80 1%, DMF 10%, polyvinylpyrrolidone 5%, propane diols 2%, C
8-10aliphatic alcohols compound 0.1%, water supply 100%, obtained 2% Aphox chlorine chlorfenapyr water after mixing
Emulsion.
Embodiment 13:22% Aphox chlorine chlorfenapyr micro-capsule suspension
Aphox 2%, chlorine chlorfenapyr 20%, toluene 5%, Lauxite 3%, NP5%, sodium lignin sulfonate 3%, hydrochloric acid 2%, sodium hydroxide 1%, xanthans 5%, suitable quantity of water, namely make 22% Aphox chlorine chlorfenapyr micro-capsule suspension according to preparation method one.
Embodiment 14:60% Aphox chlorine chlorfenapyr micro-capsule suspension
Aphox 30%, chlorine chlorfenapyr 30%, dimethylbenzene 5%, toluene di-isocyanate(TDI) 10%, Tween-80 8%, alkylphenol polyoxyethylene 5%, ethylenediamine 1%, aluminium-magnesium silicate 2%, suitable quantity of water, namely make 60% Aphox chlorine chlorfenapyr micro-capsule suspension according to preparation method two.
Embodiment 15:2% Aphox chlorine chlorfenapyr micro-capsule suspension
Aphox 1%, chlorine chlorfenapyr 1%, N; dinethylformamide 1%, methyl diphenylene diisocyanate 0.5%, polyvinyl alcohol 2%, fatty acid amide N methyl taurine sodium salt 1%, triethanolamine 1%, gum Arabic 5%, suitable quantity of water, namely make 2% Aphox chlorine chlorfenapyr micro-capsule suspension according to preparation method two.
This experiment is the method adopting Toxicity Determination and field trial to combine.First by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC<80 is antagonism, 80≤CTC≤120 are summation action, CTC >=120 are synergistic effect, on this basis, then carry out field trial.
Table 1. Aphox, chlorine chlorfenapyr are to the Toxicity Determination of rice fulgorid
As shown in Table 1, Aphox and the LC50 of chlorine chlorfenapyr to rice fulgorid are respectively 5.68mg/L and 2.78mg/L.Aphox and chlorine chlorfenapyr proportioning are when 30:1 to 1:30, and co-toxicity coefficient CTC is all greater than 120, illustrate that Aphox and chlorine chlorfenapyr mixture in 30:1 to 1:30 scope all shows synergistic effect, and especially both synergistic effects when 1:1 are the most obvious.
The test of pesticide effectiveness of table 2 Aphox, chlorine chlorfenapyr and composite control rice fulgorid thereof
As can be seen from Table 2, Aphox and chlorine chlorfenapyr composite after effectively can prevent and treat rice fulgorid, the lasting period is also long, and control efficiency is all better than the preventive effect of single dose.In test scope of medication, Target crops is had no adverse effects.
The test of pesticide effectiveness of table 3 Aphox, chlorine chlorfenapyr and composite control apple yellow aphid thereof
As can be seen from Table 3, Aphox and chlorine chlorfenapyr composite after not only have good preventive effect to rice fulgorid, also have significant preventive effect to apple yellow aphid, the lasting period might as well, control efficiency is better than the preventive effect of single dose, and expands insecticidal spectrum.
In sum, the present invention contains the Pesticidal combination of Aphox and chlorine chlorfenapyr, has good control efficiency to rice fulgorid and apple yellow aphid.Complex preparation not only increases preventive effect, and expands insecticidal spectrum, and in production reality, tool is of great significance.
Claims (3)
1. an agricultural insecticide composition, it is characterized in that containing active ingredient chlorine chlorfenapyr and active ingredient Aphox, the weight ratio of chlorine chlorfenapyr and Aphox is 1 ~ 30 ︰ 1 ~ 30, the gross weight of active ingredient accounts for 1% ~ 60% of composition total weight, and Pesticidal combination formulation comprises wetting powder, water dispersible granules, suspending agent, aqueous emulsion, micro-capsule suspension.
2. a kind of agricultural insecticide composition according to claim 1, when it is characterized in that said composition formulation is wetting powder, each constituent content is:
Chlorine chlorfenapyr 1-30%
Aphox 1-30%
Dispersant 3-10%
Wetting agent 3-10%
Filler polishing to 100%
When said composition is water dispersible granules, each constituent content is:
Chlorine chlorfenapyr 1-30%
Aphox 1-30%
Dispersant 3-10%
Wetting agent 3-10%
Disintegrant 2-5%
Filler polishing to 100%
When said composition is suspending agent, each constituent content is:
Chlorine chlorfenapyr 1-30%
Aphox 1-30%
Dispersant 3-10%
Antifreezing agent 0.5-4%
Thickener 0.1-2%
Defoamer 0.1-1%
Water polishing to 100%
When said composition is aqueous emulsion, each constituent content is:
Chlorine chlorfenapyr 1-30%
Aphox 1-30%
Emulsifier 2-10%
Solvent 3-10%
Thickener 0.1-5%
Antifreezing agent 0.5-2%
Defoamer 0.1-1%
Water polishing to 100%
When said composition is micro-capsule suspension, constituent content is:
Chlorine chlorfenapyr 1-30%
Aphox 1-30%
Capsule leather material 0.5-10%
Solvent 1-5%
Dispersant 1-8%
Emulsifier 2-8%
Thickener 2-5%
PH adjusting agent 0-3%
Water polishing to 100%.
3. a kind of agricultural insecticide composition according to claim 2, is characterized in that:
Described emulsifier is one or more in alkylbenzene naphthalene sulfonate, alkylphenol polyoxyethylene phosphate, diphenyl phenol polyethenoxy polyethenoxy ether, styrenated phenol APEO, alkylphenol polyoxyethylene formaldehyde condensation products, diphenyl phenol polyethenoxy polyformaldehyde condensation product, castor oil ethylene oxide adduct, NNO, NP, agriculture breast 500, agriculture breast 600, Tween-80, polyvinyl alcohol;
Described dispersant is one or more in lignosulfonates, fatty acid amide N methyl taurine sodium salt, alkylphenol polyoxyethylene sulphate, polyoxyethylene polyoxypropylene block copolymer, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether;
Described wetting agent be selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, sodium alkyl benzene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder one or more;
Described disintegrant be selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate one or more;
Described filler be selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate one or more;
Described thickener is one in aluminium-magnesium silicate, xanthans, CMC, gum Arabic, polyvinylpyrrolidone or several;
Described antifreezing agent is selected from one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol;
Described defoamer is selected from silicone oil, aluminium-magnesium silicate, silicone compound, C
10-20saturated fat acid compounds, C
8-10one or more in aliphatic alcohols compound and polyoxyethylene glycerol ether;
Described capsule leather material is one or more in tolyl isocyanate, the many toluene diisocyanates of polymethylene, methyl diphenylene diisocyanate, Lauxite;
Described solvent is one or more in toluene, dimethylbenzene, ethanol, DMF, chloroform, cyclohexanone, acetone;
Described pH adjusting agent mainly contains one or more in hydrochloric acid, glacial acetic acid, citric acid, sodium hydroxide, ammoniacal liquor, ethylenediamine, triethanolamine, triethylamine.
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