CN103635566B - 一种卫生间环保无磷清洗剂 - Google Patents

一种卫生间环保无磷清洗剂 Download PDF

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CN103635566B
CN103635566B CN201280018794.3A CN201280018794A CN103635566B CN 103635566 B CN103635566 B CN 103635566B CN 201280018794 A CN201280018794 A CN 201280018794A CN 103635566 B CN103635566 B CN 103635566B
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李代虹
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0068—Deodorant compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

本发明公开了一种环保卫生间无磷清洗剂，组成为：C-12烷基苯磺酸6-10％、聚氧乙烯醚烷基酚3-7％、椰子油酸二乙醇酰胺3-7％、脂肪醇聚氧乙烯醚2-5.6％、苯甲酸钠0.5-1.5％、氢氧化钠2-6％、柠檬醛5-8.5%、皂角粉7-12.5%、烷基糖苷3-3.6%、甜菜碱5-8.5%、纳米二氧化钛1.5-4.6%、茶皂素2.8-4.1%和余量水组成；以上均为重量百分比；是一种无毒、不含ODS类物质、环保、高效的水基清洗剂，在自然环境（土壤、海水、河水）中可迅速降解为二氧化碳和水，有良好的生物降解性。

Description

一种卫生间环保无磷清洗剂
一、技术领域
本发明涉及一种卫生间环保无磷清洗剂。
二、背景技术
目前，卫生间清洗剂存在含有多种有毒化学成分、严重污染水体环境、损害人体健康等问题。目前卫生间清洗剂主要是靠酸来达到去污杀菌作用的，其中盐酸是卫生间清洗剂中最普遍使用的一种酸，而盐酸具有很强的刺激性气味，为了掩盖这种难闻的气味，多数产品都添加有香精等物质。但盐酸的刺激性气味很难掩盖、有毒，水污染十分严重。93107679.X专利涉及卫生间使用的杀菌型多功能卫生间清洗剂，它由盐酸15—30％，表面活性剂0.5—4％，缓蚀剂0.5—5％，杀菌剂0.5—3％构成的亮绿色透明液体，具有快速彻底清除铁锈、尿垢、水垢、油垢等各类有机、无机污垢的能力，并能在金属铁表面形成一层稳定的保护膜。
三、发明内容
本发明卫生间环保无磷清洗剂，是一种无毒、不含ODS类污染物质、环保、高效的水基清洗剂，在自然环境（土壤、海水、河水）中可迅速降解为二氧化碳和水，有良好的生物降解性；并且降解过程中对陆生、水生动植物无任何有害影响，不会对土壤、水体环境造成任何危害；不含磷，不会造成赤潮等环境破坏，符合国内环保法律和国际环保公约的要求。不含化学有毒有害物质，产品原料选自绿色植物，以及各种可降解表面活性剂、渗透剂、缓蚀剂，安全无毒，对人体无任何损害影响。对矿物性油脂（原油、机油、润滑脂）和动植物性油脂（豆油、猪油、人体分泌油脂）以及油脂与泥土、粉尘、颗粒物形成的顽固油垢均有极佳的溶解去除能力；具有去污力强，能彻底除去油脂污垢，低泡等优点，而且不腐蚀金属，适合各种广泛应用。
卫生间环保无磷清洗剂基本组成为：C-12烷基苯磺酸6-10％、聚氧乙烯醚烷基酚3-7％、椰子油酸二乙醇酰胺3-7％、脂肪醇聚氧乙烯醚2-5.6％、苯甲酸钠0.5-1.5％、氢氧化钠2-6％、柠檬醛5-8.5%、皂角粉7-12.5%、烷基糖苷3-3.6%、甜菜碱5-8.5%、纳米二氧化钛1.5-4.6%、茶皂素2.8-4.1%和余量水组成；以上均为重量百分比。以烷基糖苷为表面活性剂，以烷基糖苷、甜菜碱为替代磷助剂。
茶皂素又名茶皂甙,是由茶树种子中提取出来的一类醣甙化合物,是一种性能良好的天然表面活性剂,有较好的去污能力。
纳米二氧化钛的结构为二氧化钛晶体结构，纳米二氧化钛具有传统材料所不具备的特殊物理、化学特性，其化学稳定性高，无毒无污染，具有颗粒尺寸小、比表面积大、表面能高等特点，以及其特有的三大效应：表面效应、小尺寸效应和宏观量子隧道效应。二氧化钛晶体结构主要有三种：锐钛型、金红石型及板钛矿。子西莱纳米二氧化钛（光触媒）为锐钛型白色粉末状固态物，产品具有强大的光催化氧化还原能力，在紫外光、太阳光、日光灯的作用下纳米二氧化钛（光触媒）价带上的电子（eˉ）很容易被激发跃迁到导带，在价带上产生相应的空穴（h+）。随后h+和eˉ与吸附在纳米二氧化钛表面上的H2O、O2等发生作用，生成OHˉ、O2ˉ、OOHˉ等高活性集团，具有极强氧化作用的超氧离子自由基、羟基自由基、超氧羟基自由基，能将甲醛、苯、甲苯、二甲苯、氨、TVOC等多数有害有机物、污染物臭气、细菌、病毒等氧化分解成无害的CO2和H2O。
四、具体实施方式
一种卫生间环保无磷清洗剂：C-12烷基苯磺酸6.5％、聚氧乙烯醚烷基酚3.6％、椰子油酸二乙醇酰胺3.9％、脂肪醇聚氧乙烯醚2.15％、苯甲酸钠0.7％、氢氧化钠2.3％、柠檬醛7.2%、皂角粉9.1%、烷基糖苷3.2%、甜菜碱7.2%纳米二氧化钛2.3%、茶皂素3.8%和余量水组成；以上均为重量百分比。

Claims (1)

1.一种环保卫生间无磷清洗剂，其特征在于组成为：C-12烷基苯磺酸6-10％、聚氧乙烯醚烷基酚3-7％、椰子油酸二乙醇酰胺3-7％、脂肪醇聚氧乙烯醚2-5.6％、苯甲酸钠0.5-1.5％、氢氧化钠2-6％、柠檬醛5-8.5%、皂角粉7-12.5%、烷基糖苷3-3.6%、甜菜碱5-8.5%、纳米二氧化钛1.5-4.6%、茶皂素2.8-4.1%和余量水组成；以上均为重量百分比。
CN201280018794.3A 2012-09-25 2012-09-25 一种卫生间环保无磷清洗剂 Active CN103635566B (zh)

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CN104403578A (zh) * 2014-12-06 2015-03-11 韦良富 汽车清洁上光剂
CN105002006A (zh) * 2015-07-03 2015-10-28 陈明志 一种洁厕清洗剂
CN105349282A (zh) * 2015-11-20 2016-02-24 张玉奇 一种多功能天然洗护液
CN106221964A (zh) * 2016-07-21 2016-12-14 南京信息工程大学 一种环保清洗剂及其制备方法
CN107794533A (zh) * 2016-08-31 2018-03-13 天津市民兴科技发展有限公司 一种除油除锈清洗剂及其制备方法
CN106833936A (zh) * 2017-02-15 2017-06-13 中卫市创科知识产权投资有限公司 一种水性处理剂生产工艺
CN107474966A (zh) * 2017-08-21 2017-12-15 马鞍山中粮生物化学有限公司 一种下水道污垢清洁剂及其制备工艺

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