A kind of preparation method of coiling type lithium battery
Technical field
The present invention relates to a kind of preparation method of coiling type lithium battery.
Background technology
Lithium ion battery, as chemical power source of new generation, has been applied to the various aspects of social life: expand to the fields such as energy storage, electric bicycle/motorcycle, electric automobile from 3C field.Along with the continuous increase of output, the accidents such as the lithium battery exposed all over the world blast, burning often have report: in January, 2013, U.S.'s Boeing 787 passenger plane lithium battery catches fire, and causes huge economic loss; 2007, the spontaneous combustion of Sony Notebook Battery caused large-tonnage product to recall ..., therefore the security performance of lithium battery promotes and always is and pays close attention to technical problem in industry.
Four large main materials of lithium battery are respectively: positive pole, negative pole, barrier film, electrolyte, its septation, as one of main material, is vital to the fail safe of lithium battery.When battery is under abnormal discharge and recharge or thermal runaway state, barrier film raises with temperature and deforms, and will melt to be bonded together micropore is disappeared when reaching its closed pore temperature, stops ion to pass through, timely cut-out internal current, prevents internal temperature of battery from sharply raising.But if now battery system is in thermal run away state, that is: battery temperature continues to be increased beyond diaphragm closed pore temperature, and after reaching broken film temperature, membrane ruptures, both positive and negative polarity large area directly contacts, cause battery to be short-circuited, under extreme case, can battery explosion be made.Therefore, for security consideration, battery diaphragm should possess relatively low closed pore temperature and higher broken film temperature.
At present, conventional its closed pore temperature of microporous polyolefin film and broken film temperature as shown in the table:
As can be seen from the table, conventional microporous polyolefin film closed pore temperature is lower, and excursion is relatively little, but the changing greatly of broken film temperature, there is very large parameter when battery thermal runaway in this, causes great potential safety hazard.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of preparation method of coiling type lithium battery.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is, a kind of preparation method of coiling type lithium battery, and coiling type lithium battery comprises positive plate and negative plate, comprises the following steps:
(1) nonwoven layer wrapped up completely by negative plate from negative plate head end, then nonwoven layer wrapped up completely by polyolefin micropore rete, the volume stem forming battery core to be spooled is divided;
(2) after dividing pre-wound at least 180 ° by volume stem, then positive plate is attached to the outside of polyolefin micropore rete, and is wound into annular from inside to outside, during ending, with nonwoven layer and polyolefin micropore rete around 360 °, end of reel end, high temperature gummed tape clings, and makes core.
The invention has the beneficial effects as follows:
Jointly be made up of the barrier film of lithium battery nonwoven layer and polyolefin micropore rete, Absorbable organic halogens improves more than the broken film temperature to 200 DEG C of barrier film, and then effect is better for the barrier film of coated with ceramic layer, so just effectively reduces cell safety hidden danger.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is further detailed explanation.
Fig. 1 is the structural representation of coiling type lithium battery embodiment of the present invention.
In figure, 1-negative plate, 2-nonwoven layer barrier film, 3-polyolefin micropore rete barrier film, 4-positive plate.
Embodiment
Step 1, lithium battery positive pole active substance and negative electrode active material to be bonded on metal foil respectively by binding agent, to make positive plate and negative plate, as the positive plate 4 in Fig. 1 and negative plate 1;
Step 2, by positive plate 4 and negative plate 1 winding become the battery structure shown in Fig. 1, detailed process is as follows:
1) material prepares: install positive plate, negative plate, polyolefin micropore rete barrier film 3, nonwoven layer barrier film 2 on the winder respectively, and terminal adhesive tape; Wherein polyolefin micropore rete is the monolayer polyethylene layer of double-coated ceramic layer; Also the double-coated of nonwoven layer barrier film 2 has ceramic layer;
2) core winding: negative plate 1, polyolefin micropore rete barrier film 3 and nonwoven layer barrier film 2 are sent to winding module, after first pre-roll at least 180 °, replant into positive plate 4, reel, windings is controlled by controller, by the alignment of rectify a deviation module controls barrier film and pole piece in winding process, after single core has reeled, respectively positive plate 4, negative plate 1, polyolefin micropore rete barrier film 3 and nonwoven layer barrier film 2 are cut off by cut-out module;
3) rubberizing discharging: completed the fixing termination of core by rubberizing module after, single core unloads and proceeds to subsequent processing by inversion module;
4) battery makes: the single core made loaded in battery container, carry out going between and fluid injection after seal welding, activation, complete battery and make.
Above-described embodiment of the present invention, does not form limiting the scope of the present invention.Any amendment done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within claims of the present invention.