CN103624259B - Based on metal parts laser deposition restorative procedure and the device of the regulation and control of preset gradient temperature field - Google Patents
Based on metal parts laser deposition restorative procedure and the device of the regulation and control of preset gradient temperature field Download PDFInfo
- Publication number
- CN103624259B CN103624259B CN201310665362.8A CN201310665362A CN103624259B CN 103624259 B CN103624259 B CN 103624259B CN 201310665362 A CN201310665362 A CN 201310665362A CN 103624259 B CN103624259 B CN 103624259B
- Authority
- CN
- China
- Prior art keywords
- temperature
- district
- laser deposition
- reparation
- induction heater
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Heat Treatment Of Articles (AREA)
- Laser Beam Processing (AREA)
- General Induction Heating (AREA)
Abstract
Based on metal parts laser deposition restorative procedure and the device of the regulation and control of preset gradient temperature field, adopt induction heating apparatus closely to repair district to base material and add thermosetting high-temperature region, firing rate is fast, heating temperature range is large, thermal source is uniform and stable; Adopt multi-pipeline protective gas wind cooling, easy for installation, simple to operate, good stability; Protective gas adopts high-purity argon gas, and to reparation, district forms inert gas shielding atmosphere, prevents high-temperature oxydation during titanium alloy etc materials laser repairing; Adopt high-temperature flexible holder, simple installation, not yielding, ensure that in the pre-heat deposition repair process of base material, clamping is stable, safe and reliable; Adopt thermal infrared imager successively or given layer detect deposition repair layer temperature, in good time adjustment induction heater heating power, realize the regulation and control that base material closely repairs district's temperature and preset temperature gradient, the laser deposition reparation of disfiguring workpiece is completed after the match at gradient temperature, the thermograde of repairing inside workpiece can be reduced, reduce inside workpiece stress raisers, suppress workpiece deformation cracking.
Description
Technical field: the restorative procedure and the device that the present invention relates to a kind of metal parts, especially a kind of metal parts laser deposition restorative procedure based on the regulation and control of preset gradient temperature field and device.
Background technology: metal parts laser deposition recovery technique refers to: take laser as thermal source, take metal dust as raw material, based on the rapid prototyping principle manufactured that is layering, realize successively melting accumulation according to the scanning pattern of planning to the metal powder material of coaxial conveying by laser, repair the technology with the metal function part of 3D shape, be also referred to as Laser forming repair technology etc.; Technological process carrys out direct forming and manufactures the technology of metal function part and be called as laser deposition molding technology according to this, is also referred to as Laser Rapid Prototyping Technique; Metal parts laser deposition manufacturing technology can be referred to as.Because it has the feature of heat input energy-controllable and flexibility manufacture, make this technology be particularly suitable for precision, labyrinth the precious metal material parts such as titanium alloy, high temperature alloy reparation and directly manufacture, effectively can shorten new product development cycle, reduce development cost and development risk, receive the concern of domestic and international researcher and relevant manufactures in recent years gradually, and obtain Preliminary Applications in the reparation of aero titanium alloy parts and figuration manufacture field; Estimate within a period in future, the laser deposition manufacturing technology of metal parts will obtain develop rapidly and extensive use.
In metal parts laser deposition Study on manufacturing technology and through engineering approaches application, the workpiece deformation problem of Cracking in laser deposition manufacture process is that laser deposition manufacturing technology shapes up and the major obstacle of expansive approach; Particularly in metal parts laser repairing application, because workpiece to be repaired has been in mechanical machining phase or even finishing stage or the part of being on active service, allowance is little or do not have allowance, to prevent workpiece from ftractureing during reparation, workpiece deformation can not be there is, even if because very little deflection also will destroy the integrality of Workpiece structure; How to prevent the workpiece deformation laser repairing technology especially that ftractures from realizing of expansive approach key issue urgently to be resolved hurrily.Reason comprises many-sided many factors such as material, equipment, technique to cause this problem to occur, but its main cause is laser beam local heat, and deposition workpiece different parts heat transfer is different with radiation condition, cause Forming Workpiece local temperature Accumulation Phenomenon obviously different, cause the field distribution of Forming Workpiece internal temperature uneven, local produces stress concentration phenomenon, and then causes Forming Workpiece strain cracking.
Summary of the invention: for the shortcoming of above-mentioned prior art, the object of the present invention is to provide a kind of metal parts laser deposition restorative procedure based on the regulation and control of preset gradient temperature field and device.
For achieving the above object, the technical solution used in the present invention is: based on the metal parts laser deposition prosthetic device of preset gradient temperature field regulation and control, comprise laser coaxial powder feeding head, flexible fixture, induction heater, cooling tube, workbench, thermal imaging system and induction heating apparatus.Flexible fixture is fixing on the table.Cooling tube is in the centre of flexible fixture, and is in workpiece lower end.Induction heater is in the periphery of cooling tube, and is fixed on disfiguring workpiece lower end.Laser coaxial powder feeding head and thermal imaging system are arranged on the top of disfiguring workpiece.Induction heater is connected with induction heating apparatus.
Based on the metal parts laser deposition restorative procedure of preset gradient temperature field regulation and control, its specific implementation step is as follows:
(1) restoring area of disfiguring workpiece is machined into the shapes such as the circle of regularization or rectangle, according to the induction heater repairing district's size design and manufacture correspondingly-sized, and is connected with induction heating apparatus.
(2) adopt flexible fixture to clamp disfiguring workpiece, fixture is repaired district at the lower surface of clamped base material and is closely repaired district and reserves additional space, guarantees that induction heater and cooling tube can be arranged on relevant position and realize high-temperature heating and sub-cooled.
(3) induction heater is positioned at corresponding lower surface place of nearly reparation district, form high-temperature district in nearly district of repairing, induction heating apparatus and disfiguring workpiece are with workbench movement jointly; Cooling tube is accessed below fixture and is fixed on base material and repair below district's correspondence, pass into inert protective gas quenching, below reparation district, form cooling zone.
(4) preset temperature distribution carries out laser deposition: before laser deposition reparation, by induction heater, base material is closely repaired district's preheating, preheat temperature can be regulated and controled by heater power output, below reparation district correspondence, adopt inert protective gas cooling tube to blow cooling, gas temperature is the temperature that liquid state turns gaseous state, can adjust gas flow according to actual conditions controls below room temperature by reparation district temperature, forms low temperature district; In laser deposition process by thermal infrared imager successively or which floor detects deposition repair layer temperature at interval, in good time adjustment induction heater heating power, complete the regulation and control that base material closely repairs district's temperature and preset temperature gradient, realize the laser deposition reparation of disfiguring workpiece with this understanding.
Tool of the present invention has the following advantages:
(1) adopt induction heating apparatus closely to repair district to base material and add thermosetting high-temperature region, firing rate is fast, heating temperature range is large, thermal source is uniform and stable; Induction heater and eddy-current heating source adopt and removably connect, and induction heater specification can manufacture and design according to reparation district geomery, and manufacturing process is simple, economical and practical, adapts to repair the changeable feature of district's geomery.
(2) multi-pipeline protective gas wind cooling is adopted, easy for installation, simple to operate, good stability; Protective gas adopts high-purity argon gas, and to reparation, district forms inert gas shielding atmosphere, prevents high-temperature oxydation during titanium alloy etc materials laser repairing.
(3) high-temperature flexible holder is adopted, simple installation, not yielding, ensure that in the pre-heat deposition repair process of base material, clamping is stable, safe and reliable.
(4) adopt thermal infrared imager successively or given layer detect deposition repair layer temperature, in good time adjustment induction heater heating power, realize the regulation and control that base material closely repairs district's temperature and preset temperature gradient, the laser deposition reparation of disfiguring workpiece is completed after the match at gradient temperature, the thermograde of repairing inside workpiece can be reduced, reduce inside workpiece stress raisers, suppress workpiece deformation cracking.
Accompanying drawing illustrates:
Fig. 1 is the structural representation of the metal parts laser deposition prosthetic device based on the regulation and control of preset gradient temperature field.
Fig. 2 is the structural representation repairing district.
Fig. 3 is square induction heater and induction heating apparatus connection diagram.
Fig. 4 is circular induction heater and induction heating apparatus connection diagram.
Detailed description of the invention:
As shown in Figure 1: based on the metal parts laser deposition prosthetic device of preset gradient temperature field regulation and control, comprise laser coaxial powder feeding head 1, flexible fixture 4, induction heater 5, cooling tube 6, workbench 7, thermal imaging system 8 and induction heating apparatus 9.Flexible fixture 4 is fixing on the table 7.Cooling tube 6 is in the centre of flexible fixture 4.Induction heater 5 is in the periphery of cooling tube 6, and is fixed on disfiguring workpiece 3 lower end.Laser coaxial powder feeding head 1 and thermal imaging system 8 are arranged on the top of disfiguring workpiece 3.Induction heater 5 is connected with induction heating apparatus 9.
As shown in Figure 2: based on the metal parts laser deposition restorative procedure of preset gradient temperature field regulation and control, its specific implementation step is as follows:
(1) district's shape is repaired varied, first the reparation district 2 of disfiguring workpiece 3 is machined into the shape such as circle or rectangle of regularization, according to the induction heater 5 repairing district 2 size design manufacture correspondingly-sized, induction heater 5 is positioned at the corresponding lower surface in nearly reparation district 10, and induction heating apparatus 5 and disfiguring workpiece 3 are with workbench 7 movement jointly.
(2) effectively clamp for the flexible fixture that substrate sizes profile design manufacturing dimension to be repaired is adjustable, prevent from repairing workpiece deformation.Flexible fixture 4 is adopted effectively to clamp disfiguring workpiece 3, fixture is repaired district 2 at the lower surface of clamped base material and is closely repaired district 10 and reserves additional space, guarantees that induction heater 5 and cooling tube 6 can be arranged on relevant position and realize high-temperature heating and sub-cooled.
(3) induction heater 5 is positioned at nearly reparation corresponding lower surface place of district 10, form high-temperature district in nearly district 10 of repairing, induction heating apparatus and disfiguring workpiece 3 are with workbench 7 movement jointly; Cooling tube 6 will be entered access below flexible fixture 4 and be fixed on corresponding below, base material reparation district 2, and pass into inert protective gas quenching, below reparation district 2, form cooling zone 11.
(4) preset temperature distribution carries out laser deposition manufacture
Before laser deposition reparation, by induction heater 5, base material is closely repaired district 10 preheating; preheat temperature controllable is between 100-700 DEG C; adopt inert protective gas cooling tube 6 to blow cooling in corresponding below, reparation district 2, its temperature adjustable is between 0-20 DEG C.In laser deposition process by thermal infrared imager 8 successively (or interval which floor) detect deposition repair layer temperature, in good time adjustment induction heating apparatus 9 heating power, complete the regulation and control that base material closely repairs district 10 temperature and preset temperature gradient, realize the laser deposition reparation of disfiguring workpiece 3 with this understanding, the thermograde of repairing inside workpiece can be reduced, reduce inside workpiece stress raisers, suppress workpiece deformation cracking.
As shown in Figure 3 and Figure 4, according to different reparation district shapes, manufacture and design the induction heater 5 of correspondingly-sized, shape is square, circular etc.
Claims (4)
1., based on the metal parts laser deposition prosthetic device of preset gradient temperature field regulation and control, it is characterized in that: comprise laser coaxial powder feeding head, flexible fixture, induction heater, cooling tube, workbench, thermal imaging system and induction heating apparatus; Flexible fixture is fixing on the table, cooling tube is in the centre of flexible fixture, and be in workpiece lower end, induction heater is in the periphery of cooling tube, and being fixed on disfiguring workpiece lower end, laser coaxial powder feeding head and thermal imaging system are arranged on the top of disfiguring workpiece, and induction heater is connected with induction heating apparatus, induction heater is positioned at corresponding lower surface place of nearly reparation district, and cooling tube is fixed on disfiguring workpiece and repairs below district's correspondence.
2., based on the metal parts laser deposition restorative procedure of preset gradient temperature field regulation and control, its specific implementation step is as follows:
(1) restoring area of disfiguring workpiece is machined into circle or the rectangular shape of regularization, according to the induction heater repairing district's size design manufacture correspondingly-sized, and is connected with induction heating apparatus;
(2) adopt flexible fixture to clamp disfiguring workpiece, fixture is repaired district at the lower surface of clamped disfiguring workpiece and is closely repaired district and reserves additional space, guarantees that induction heater and cooling tube can be arranged on relevant position and realize high-temperature heating and sub-cooled;
(3) induction heater is positioned at corresponding lower surface place of nearly reparation district, form high-temperature district in nearly district of repairing, induction heating apparatus and disfiguring workpiece are with workbench movement jointly; Cooling tube is accessed below fixture and is fixed on base material and repair below district's correspondence, pass into inert protective gas quenching, below reparation district, form cooling zone;
(4) preset temperature distribution carries out laser deposition: before laser deposition reparation, by induction heater, base material is closely repaired district's preheating, preheat temperature is regulated and controled by induction heating apparatus power output, below reparation district correspondence, adopt cooling tube to pass into inert protective gas blow cooling, gas temperature is the temperature that liquid state turns gaseous state, reparation district temperature controls below room temperature by adjustment gas flow, forms low temperature district; In laser deposition process by thermal infrared imager successively or which floor detects deposition repair layer temperature at interval, in good time adjustment induction heater heating power, complete the regulation and control that base material closely repairs district's temperature and preset temperature gradient, realize the laser deposition reparation of disfiguring workpiece with this understanding.
3. as claimed in claim 2 based on the metal parts laser deposition restorative procedure of preset gradient temperature field regulation and control, it is characterized in that: described preheat temperature regulation and control are between 100-700 DEG C.
4., as claimed in claim 2 based on the metal parts laser deposition restorative procedure of preset gradient temperature field regulation and control, it is characterized in that: described its temperature adjusting of low temperature district is between 0-20 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310665362.8A CN103624259B (en) | 2013-12-06 | 2013-12-06 | Based on metal parts laser deposition restorative procedure and the device of the regulation and control of preset gradient temperature field |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310665362.8A CN103624259B (en) | 2013-12-06 | 2013-12-06 | Based on metal parts laser deposition restorative procedure and the device of the regulation and control of preset gradient temperature field |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103624259A CN103624259A (en) | 2014-03-12 |
CN103624259B true CN103624259B (en) | 2015-11-04 |
Family
ID=50205907
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310665362.8A Expired - Fee Related CN103624259B (en) | 2013-12-06 | 2013-12-06 | Based on metal parts laser deposition restorative procedure and the device of the regulation and control of preset gradient temperature field |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103624259B (en) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104099610B (en) * | 2014-07-10 | 2016-04-27 | 西安交通大学 | The preparation method of coating unit and the thermal barrier coating based on this coating unit |
CN104164547B (en) * | 2014-07-22 | 2017-01-25 | 沈阳航空航天大学 | Local thermal treatment based destressing and shaping method and device for metal members after repairing |
EP3050666B2 (en) * | 2015-01-27 | 2022-08-10 | Ansaldo Energia IP UK Limited | Method of processing materials by applying a laser beam with adaptive shielding gas flow |
US10343392B2 (en) * | 2015-08-27 | 2019-07-09 | General Electric Company | Powder-bed additive manufacturing devices and methods |
CN105716655B (en) * | 2016-02-03 | 2018-05-01 | 西北工业大学 | Temperature and deformation real-time synchronization measuring device and method in high energy beam increasing material manufacturing |
CN105671546B (en) * | 2016-02-25 | 2018-06-26 | 上海交通大学 | A kind of active cooling device and cooling means of laser repairing single crystal turbine blade |
AU2017347651A1 (en) * | 2016-10-17 | 2019-04-11 | Exxonmobil Research And Engineering Company | Laser metal deposition welding process, parts formed therefrom and their usage in oil, gas and petrochemical applications |
CN106915086B (en) * | 2017-03-09 | 2019-01-15 | 嘉兴敏惠汽车零部件有限公司 | A kind of 3D printing platform preventing alice |
CN107254570B (en) * | 2017-06-14 | 2018-11-23 | 沈阳航空航天大学 | Modularization fixture and its application method for induction heating local heat treatmet |
CN107442774A (en) * | 2017-07-26 | 2017-12-08 | 西安交通大学 | The method that sensing heating aids in alterant refining laser increasing material manufacturing titanium alloy crystal grain |
CN109518180B (en) * | 2018-10-09 | 2021-02-12 | 江苏大学 | Self-adaptive laser deposition repair device and method |
CN111172529A (en) * | 2018-11-13 | 2020-05-19 | 中国科学院沈阳自动化研究所 | Defect control method for cast aluminum alloy structural member in laser coaxial powder feeding repair process |
CN110548876B (en) * | 2019-10-14 | 2022-01-25 | 中国科学院重庆绿色智能技术研究院 | Powder-laying type remanufacturing device and method |
CN110640146B (en) * | 2019-10-28 | 2021-08-24 | 南京工程学院 | Modular material-increasing and material-decreasing composite repair method for defect area of part surface |
US11396063B2 (en) * | 2020-03-23 | 2022-07-26 | Rosemount Aerospace Inc. | Systems and methods for in process heating for direct energy deposition applications |
CN111843203A (en) * | 2020-06-22 | 2020-10-30 | 河海大学常州校区 | Gamma-TiAl intermetallic compound laser welding device with preheating device and method |
CN112548106B (en) * | 2021-02-26 | 2021-05-18 | 中国航发上海商用航空发动机制造有限责任公司 | Method for repairing ultrathin structure by additive manufacturing |
CN115283859B (en) * | 2022-08-15 | 2024-08-23 | 山东理工大学 | Laser drilling device and method based on built-in electric field of inert gas heating bin |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6262390B1 (en) * | 1998-12-14 | 2001-07-17 | International Business Machines Corporation | Repair process for aluminum nitride substrates |
CN200967119Y (en) * | 2006-11-14 | 2007-10-31 | 沈阳大陆激光技术有限公司 | Special laser processing machine for train wheel laser cladding |
CN201626977U (en) * | 2010-03-05 | 2010-11-10 | 南昌航空大学 | Device for rapidly preparing metal ceramic coatings by laser induction hybrid melt injection |
CN102179635A (en) * | 2011-04-26 | 2011-09-14 | 哈尔滨工业大学 | Processing method and device for carrying out microwave cutting on brittle material |
CN102259187A (en) * | 2011-04-01 | 2011-11-30 | 周明 | Method and device for manufacturing and repairing composite roll with high performance through laser spray forming |
US8247733B2 (en) * | 2009-01-12 | 2012-08-21 | Rolls-Royce Deutschland Ltd & Co Kg | Arrangement for the repair of the blades of BLISK drums by means of laser deposition welding |
CN102922149A (en) * | 2012-11-21 | 2013-02-13 | 沈阳航空航天大学 | Electromagnetic stirring device |
CN102922139A (en) * | 2012-11-26 | 2013-02-13 | 上海彩石激光科技有限公司 | Net shape repairing system |
CN103114286A (en) * | 2013-02-27 | 2013-05-22 | 沈阳航空航天大学 | Method for repairing titanium alloy by ultrasound-assisted laser |
CN203144513U (en) * | 2013-02-27 | 2013-08-21 | 沈阳航空航天大学 | Ultrasonic vibration coupling device for laser repairing |
-
2013
- 2013-12-06 CN CN201310665362.8A patent/CN103624259B/en not_active Expired - Fee Related
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6262390B1 (en) * | 1998-12-14 | 2001-07-17 | International Business Machines Corporation | Repair process for aluminum nitride substrates |
CN200967119Y (en) * | 2006-11-14 | 2007-10-31 | 沈阳大陆激光技术有限公司 | Special laser processing machine for train wheel laser cladding |
US8247733B2 (en) * | 2009-01-12 | 2012-08-21 | Rolls-Royce Deutschland Ltd & Co Kg | Arrangement for the repair of the blades of BLISK drums by means of laser deposition welding |
CN201626977U (en) * | 2010-03-05 | 2010-11-10 | 南昌航空大学 | Device for rapidly preparing metal ceramic coatings by laser induction hybrid melt injection |
CN102259187A (en) * | 2011-04-01 | 2011-11-30 | 周明 | Method and device for manufacturing and repairing composite roll with high performance through laser spray forming |
CN102179635A (en) * | 2011-04-26 | 2011-09-14 | 哈尔滨工业大学 | Processing method and device for carrying out microwave cutting on brittle material |
CN102922149A (en) * | 2012-11-21 | 2013-02-13 | 沈阳航空航天大学 | Electromagnetic stirring device |
CN102922139A (en) * | 2012-11-26 | 2013-02-13 | 上海彩石激光科技有限公司 | Net shape repairing system |
CN103114286A (en) * | 2013-02-27 | 2013-05-22 | 沈阳航空航天大学 | Method for repairing titanium alloy by ultrasound-assisted laser |
CN203144513U (en) * | 2013-02-27 | 2013-08-21 | 沈阳航空航天大学 | Ultrasonic vibration coupling device for laser repairing |
Also Published As
Publication number | Publication date |
---|---|
CN103624259A (en) | 2014-03-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103624259B (en) | Based on metal parts laser deposition restorative procedure and the device of the regulation and control of preset gradient temperature field | |
CN105499569B (en) | A kind of temperature field active control system and its control method for high energy beam increasing material manufacturing | |
CN104959604B (en) | A kind of controlled high energy beam selective melting method and apparatus of shaped region thermograde | |
CN103068516A (en) | Method for manufacturing a component by selective laser melting | |
EP2806711B1 (en) | Incremental sheet forming for fabrication of cold sprayed smart susceptor | |
EP2119530A1 (en) | Preheating Using a Laser Beam | |
CN105256311B (en) | A kind of method of sensing heating control Laser Direct Deposition high temperature alloy oriented growth | |
CN205414406U (en) | A temperature field initiative regulation and control system for high energy beam vibration material disk | |
CN110539080A (en) | double-mechanical-arm laser-plasma composite milling material-increasing and material-decreasing manufacturing equipment and method | |
CN107385434A (en) | A kind of laser melting coating system and method for increasing material processing for cylinder | |
CN109317793A (en) | A kind of plasma-arc fuse increasing material manufacturing device and method | |
CN104164547B (en) | Local thermal treatment based destressing and shaping method and device for metal members after repairing | |
Zhang et al. | Numerical study of thermal history in laser aided direct metal deposition process | |
CN103170777A (en) | Metal pipe butt-joint circumferential seam heating device | |
US10710304B2 (en) | Apparatus for producing a three-dimensional work piece with process temperature control | |
KR102284632B1 (en) | Large scale metal forming | |
CN104313299B (en) | Large gear ring heat treatment deformation multiple spot stress compensation device and equalising means thereof | |
CN107695137A (en) | Straightening method and fixture are deformed after a kind of annular flame tube high temperature enamel paint | |
CN104878330A (en) | Method for optimizing repaired tissue of large workpiece based on local heat treatment realized by induction heating | |
CN104264149A (en) | Method for preheating and slow cooling in laser cladding process by using uniform elliptic light beam | |
CN112548581A (en) | Substrate-formed part preheating device and method of material increase and decrease manufacturing equipment | |
CN105887079A (en) | Method for fast and emergently repairing failure parts through laser forming in field environment | |
CN104889570A (en) | Quick forming device and method based on femtosecond laser and ion beam composite technology | |
Pinkerton et al. | The development of temperature fields and powder flow during laser direct metal deposition wall growth | |
CN211866829U (en) | Welding device for heat-resistant steel base of slow cooling wheel |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151104 Termination date: 20181206 |
|
CF01 | Termination of patent right due to non-payment of annual fee |