CN103614264A - Quick detergent for roadside adlets - Google Patents
Quick detergent for roadside adlets Download PDFInfo
- Publication number
- CN103614264A CN103614264A CN201310649013.7A CN201310649013A CN103614264A CN 103614264 A CN103614264 A CN 103614264A CN 201310649013 A CN201310649013 A CN 201310649013A CN 103614264 A CN103614264 A CN 103614264A
- Authority
- CN
- China
- Prior art keywords
- parts
- adlets
- roadside
- small advertisement
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title abstract 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002608 ionic liquid Substances 0.000 claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims abstract description 6
- 239000000945 filler Substances 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000012747 synergistic agent Substances 0.000 claims description 8
- 239000013543 active substance Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
- 239000012459 cleaning agent Substances 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 5
- 230000006378 damage Effects 0.000 abstract description 7
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 9
- 238000003756 stirring Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000010907 mechanical stirring Methods 0.000 description 4
- 239000002516 radical scavenger Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 244000137852 Petrea volubilis Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 201000004681 Psoriasis Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940112822 chewing gum Drugs 0.000 description 1
- 235000015218 chewing gum Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- -1 salt compounds Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Abstract
The invention relates to a quick detergent for roadside adlets, which can quickly and efficiently remove roadside adlets on walls, bus stations and bulletin boards. The invention is characterized in that the detergent is prepared by mixing the following raw materials in parts by weight: 60-90 parts of solvent, 10-20 parts of surfactant, 5-10 parts of ionic liquid synergist, 6-8 parts of filler and 0.1-1 part of cetyl sodium sulfate. The solvent is a mixture of ethanol, ethyl acetate and deionized water in any ratio; and the surfactant is CH3O(CH3CH2CH2O)nCH2OCH3, wherein n=6-11. The detergent can quickly and efficiently remove roadside adlets on walls, bus stations and bulletin boards, is free of chemical components which are harmful to the environment and buildings, and can not do damage to the health of cleaning personnel and building surfaces.
Description
Technical field
The present invention relates to a kind of curbside small advertisement fast cleaning agent, it can remove wall, bus-stop and the curbside small advertisement above propaganda board fast and efficiently.
Background technology
Curbside small advertisement spreads unchecked, and is the large persistent ailment of one in city management always, has a strong impact on city image.Recruitment stevedore, rented house, specialty removal of home etc. small advertisement, has become the street of script neat and tidy into big flowery face.These small advertisements paste easily, but will it be known totally completely, are very difficult things.Advertisement before often is not also removed clean, after new small advertisement will stick.Such small advertisement has become the psoriasis in city, must try every possible means to be removed.
Small advertisement is difficult to remove, and has close relationship to a great extent with the glue of its use.Now widely used sizing agent mainly contains epoxy resin, acrylic acid or the like and urethane resin base adhesive.After these resin based adhesives solidify, the small advertisement scraps of paper used and metope can be bonded together firmly, form firmly chemical bond.Therefore, the core missions of cleaning small advertisement have just become how high-efficient cleaning is except the high molecular residue forming after these glue curing.
The main method of environmental sanitation and environmental protection department's removing curbside small advertisement is still polished at present: manually use sand paper, or rub with strength with the small-sized electric drill that storage battery drives; Or take scoop to rub back and forth.By small advertisement (being mainly polymer rubber and resin), friction high temperature cabonization is removed.Although removed like this small advertisement, can leave ugly vestige at building surface.
Up to the present, be not also specifically designed to patent, the bibliographical information of removing curbside small advertisement.For the small advertisement of removing curbside, some method and thinking still can use for reference how to remove ground chewing gum.
Chinese patent (patent No. ZL03111340.0) discloses a kind of gum and has removed liquid and blending process thereof, and it is comprised of turps, unsticking auxiliary agent and industrial essence, removes each composition weight umber ratio of liquid to be: turps 94 ?96; Unsticking auxiliary agent 0.5 ?5; Industry essence 0.3 ?0.5; First the raw pine fuel-economizing of said components, unsticking auxiliary agent and industrial essence are taken by weight, and then the raw material that takes parts by weight is rendered in stainless steel vessel and blent successively, again the blending liquid in container is stirred, finally it was fully mixed in standing 2 hours, then can bottles and make the agent of spraying type gum removing liquid bottle.Because turps is silvichemical, its source is limited.And turps is limited for the solubility property of natural rubber and resin, will cause it to remove small advertisement effect limited.
Given this, develop a kind of novel, efficient, eco-friendly small advertisement sanitising agent and just seem particularly urgent.
Will effectively remove small advertisement, its key is how to make it use, and is that the sizing agent having cured dissolves, softening, thereby peel off, comes off.This just requires not only will have the effective constituents such as tensio-active agent in its formula, also will have and can dissolve solvent or the synergistic agent having cured.
Ionic liquid, as its name suggests, is consisted of the salt compounds being at room temperature in a liquid state completely zwitterion.Different from traditional solid inorganic salt, the melting salt molecule existing with liquid state has designability, and different zwitterions can be combined into miscellaneous ionic liquid.By selecting different zwitterions, or directly introduce specific functional group and modify, the character to ionic liquid, as fusing point, viscosity, hydrophobicity are adjusted, meet different needs, design the ionic liquid that can there is excellent dissolution performance to natural rubber and resin and come.
Ionic liquid is because of the saturated vapor pressure obviously not recording, thereby use ionic liquid is than using traditional chemical solvents more to meet eco-friendly Green Development theory.
Ionic liquid has designability, by adjusting different zwitterions pair, can design kind difference, and the special ionic liquid that meets different needs comes.We are designed and can be shown novel ion liquid small advertisement matrix used to excellent dissolution performance by molecular computing and design, and this ionic liquid does not contain chlorion, and environmental friendliness can be for the removing of all kinds of small advertisements in city.
Summary of the invention
The invention provides a kind of curbside small advertisement fast cleaning agent, this clean-out system can be removed wall, bus-stop and the curbside small advertisement above propaganda board fast and efficiently, it does not contain environment and the harmful chemical composition of buildings, to cleaning worker health and building surface, can not damage.
The concrete technical scheme adopting of the present invention is:
A curbside small advertisement fast cleaning agent, is characterized in that, by the raw material of following weight part, is mixed:
Wherein, described solvent is ethanol, ethyl acetate and deionized water, and three is according to the mixture of arbitrary proportion;
Tensio-active agent is CH
3o(CH
3cH
2cH
2o) nCH
2oCH
3, n=6～11;
The structural formula of described ionic liquid synergistic agent is:
Preferably, described filler is nano-calcium carbonate or nano titanium oxide, or described filler is that nano-calcium carbonate and nano titanium oxide mix according to arbitrary proportion.
Ionic liquid synergistic agent of the present invention can strengthen its dissolving power to the residue that is difficult to remove.
Compared with prior art, beneficial effect of the present invention is:
1) the present invention utilizes the custom-designed ionic liquid solubility property outstanding to curbside small advertisement, all kinds of curbsides of removing small advertisement that can be rapidly and efficiently, and cheap, use suits large area to popularize;
2) the present invention does not relate to any poisonous and hazardous chemical, to operation environmental sanitation personnel and building surface, can not cause any secondary injury.
Embodiment
Below by concrete case study on implementation, will describe more comprehensively the present invention:
Embodiment 1
Mechanical stirring is being housed, in the four-hole 5000ml flask of prolong, thermometer, is adding successively ethanol 200g, ethyl acetate 50g, deionized water 1750g, tensio-active agent CH
3o(CH
3cH
2cH
2o)
8cH
2oCH
3, 300g, synergistic agent ionic liquid:
150g, heats up and stirs 60 minutes under 60 ℃ of conditions, after fully dissolving, removes heating.Then add nano-calcium carbonate 180g, Sodium palmityl sulfate 30g, stir, stand-by in tank filling.
During use, first that the small advertisement of dry solidification is wetting with scavenging agent of the present invention, fully dissolve, then with toothbrush, gently the softening residue dissolving is removed.Evaluation effect according to removing completely, part is residual, surface damage, be difficult to remove and be followed successively by: four ranks such as excellent, good, poor, non-constant.
Effect: excellent.
Embodiment 2
Mechanical stirring is being housed, in the four-hole mouth 5000ml flask of prolong, thermometer, is adding successively ethanol 150g, ethyl acetate 100g, deionized water 1600g, tensio-active agent CH
3o(CH
3cH
2cH
2o)
6cH
2oCH
3, 250g, synergistic agent ionic liquid:
150g, heats up and stirs 60 minutes under 60 ℃ of conditions, after fully dissolving, removes heating.Then add nano-calcium carbonate 200g, Sodium palmityl sulfate 35g, stir, stand-by in tank filling.
During use, first that the small advertisement of dry solidification is wetting with scavenging agent of the present invention, fully dissolve, then with toothbrush, gently the softening residue dissolving is removed.Evaluation effect according to removing completely, part is residual, surface damage, be difficult to remove and be followed successively by: four ranks such as excellent, good, poor, non-constant.
Effect: excellent.
Embodiment 3
Mechanical stirring is being housed, in the four-hole mouth 5000ml flask of prolong, thermometer, is adding successively ethyl acetate 200g, ethyl acetate 100g, deionized water 2000g, tensio-active agent CH
3o(CH
3cH
2cH
2o)
10cH
2oCH
3, 350g, synergistic agent ionic liquid:
200g, heats up and stirs 60 minutes under 60 ℃ of conditions, after fully dissolving, removes heating.Then add nano titanium oxide 180g, Sodium palmityl sulfate 40g, stir, stand-by in tank filling.
During use, first that the small advertisement of dry solidification is wetting with scavenging agent of the present invention, fully dissolve, then with toothbrush, gently the softening residue dissolving is removed.Evaluation effect according to removing completely, part is residual, surface damage, be difficult to remove and be followed successively by: four ranks such as excellent, good, poor, non-constant.
Effect: excellent.
Embodiment 4
Mechanical stirring is being housed, in the four-hole mouth 5000ml flask of prolong, thermometer, is adding successively ethanol 200g, ethyl acetate 100g, deionized water 1800g, tensio-active agent CH
3o(CH
3cH
2cH
2o)
11cH
2oCH
3, 300g, synergistic agent ionic liquid:
100g, heats up and stirs 60 minutes under 60 ℃ of conditions, after fully dissolving, removes heating.Then add nano-calcium carbonate 180g, Sodium palmityl sulfate 45g, stir, stand-by in tank filling.
During use, first that the small advertisement of dry solidification is wetting with scavenging agent of the present invention, fully dissolve, then with toothbrush, gently the softening residue dissolving is removed.Evaluation effect according to removing completely, part is residual, surface damage, be difficult to remove and be followed successively by: four ranks such as excellent, good, poor, non-constant.
Effect: excellent.
Claims (2)
1. a curbside small advertisement fast cleaning agent, is characterized in that, by the raw material of following weight part, is mixed:
Wherein, described solvent is ethanol, ethyl acetate and deionized water, and three is according to the mixture of arbitrary proportion;
Tensio-active agent is CH
3o(CH
3cH
2cH
2o) nCH
2oCH
3, n=6～11;
The structural formula of described ionic liquid synergistic agent is:
2. curbside according to claim 1 small advertisement fast cleaning agent, is characterized in that, described filler is nano-calcium carbonate or nano titanium oxide, or described filler is that nano-calcium carbonate and nano titanium oxide mix according to arbitrary proportion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310649013.7A CN103614264B (en) | 2013-12-04 | 2013-12-04 | Quick detergent for roadside adlets |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310649013.7A CN103614264B (en) | 2013-12-04 | 2013-12-04 | Quick detergent for roadside adlets |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103614264A true CN103614264A (en) | 2014-03-05 |
| CN103614264B CN103614264B (en) | 2015-06-24 |
Family
ID=50164984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310649013.7A Expired - Fee Related CN103614264B (en) | 2013-12-04 | 2013-12-04 | Quick detergent for roadside adlets |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103614264B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105154243A (en) * | 2015-09-15 | 2015-12-16 | 王颖 | Illegal small ad cleaning fluid |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102041189A (en) * | 2009-10-16 | 2011-05-04 | 刘华栋 | Environmentally-friendly abrasive cleaner for clearing away glue and paint advertisements in streets |
| CN102203232A (en) * | 2008-09-01 | 2011-09-28 | 恩维洛维斯科技有限公司 | Compositions and methods for the removal of chewing gum residues from substrates |
| CN102260599A (en) * | 2011-06-15 | 2011-11-30 | 于文 | Environment-friendly degumming agent |
-
2013
- 2013-12-04 CN CN201310649013.7A patent/CN103614264B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102203232A (en) * | 2008-09-01 | 2011-09-28 | 恩维洛维斯科技有限公司 | Compositions and methods for the removal of chewing gum residues from substrates |
| CN102041189A (en) * | 2009-10-16 | 2011-05-04 | 刘华栋 | Environmentally-friendly abrasive cleaner for clearing away glue and paint advertisements in streets |
| CN102260599A (en) * | 2011-06-15 | 2011-11-30 | 于文 | Environment-friendly degumming agent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105154243A (en) * | 2015-09-15 | 2015-12-16 | 王颖 | Illegal small ad cleaning fluid |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103614264B (en) | 2015-06-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: NINGBO BONDED ZONE ANDRIS MACHINERY CO., LTD. Free format text: FORMER OWNER: NINGBO SAINTER TECHNOLOGY SERVICE CO., LTD. Effective date: 20150513 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20150513 Address after: 315800 Zhejiang Province, Ningbo Free Trade Zone Foxconn 530-9 Trade Building Applicant after: NINGBO TAX-PROTECTED AREA ANDRIS MACHINERY CO., LTD. Address before: 315100 Yinzhou District, Ningbo, South Street, the first emerging industrial park Applicant before: NINGBO SAINTER TECHNOLOGY SERVICE CO., LTD. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161207 Address after: Wujiang District of Suzhou City, Jiangsu province 215228 Shengze Dongsheng Town Street No. 1-153 Patentee after: Suzhou Fengru Software Co., Ltd. Address before: 315800 Zhejiang Province, Ningbo Free Trade Zone Foxconn 530-9 Trade Building Patentee before: NINGBO TAX-PROTECTED AREA ANDRIS MACHINERY CO., LTD. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150624 Termination date: 20201204 |