CN103614229B - Environment-friendlymachine machine tool cutting fluid - Google Patents
Environment-friendlymachine machine tool cutting fluid Download PDFInfo
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- CN103614229B CN103614229B CN201310603646.4A CN201310603646A CN103614229B CN 103614229 B CN103614229 B CN 103614229B CN 201310603646 A CN201310603646 A CN 201310603646A CN 103614229 B CN103614229 B CN 103614229B
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Abstract
The invention discloses a kind of Environment-friendlymachine machine tool cutting fluid, described Environment-friendlymachine machine tool cutting fluid, be made up of by weight percentage following component: thiosemicarbazides 2 4%, ethyl n-butyrate. 0.02 0.04%, sodium carbonate 0.2 0.6%, antirust agent 0.4 0.8%, surplus is water.The Environment-friendlymachine machine tool cutting fluid of the present invention, can form protecting film on the metal surface, makes lathe from the corrosion of surrounding medium, it is adaptable to the machining of the metals such as steel, cast iron, rustless steel, copper aluminum and alloy thereof.
Description
Technical field
The present invention relates to a kind of cutting fluid, particularly relate to a kind of Environment-friendlymachine machine tool cutting fluid.
Background technology
Cutting fluid (cutting fluid, coolant), has another name called cuttings liquid.Be one be used in metal cut,
Cut, grind in the course of processing, be used for cooling down and lubricating the industrial type fluid of cutter and workpiece.Cut
Cut the important supplementary material that liquid is metal cutting process.
Summary of the invention
Environment-friendlymachine machine tool cutting fluid, is made up of by weight percentage following component: thiosemicarbazides 2-4%,
Ethyl n-butyrate. 0.02-0.04%, sodium carbonate 0.2-0.6%, antirust agent 0.4-0.8%, surplus is water.
By proportioning, whole components are mixed, be uniformly dissolved, can be prepared by.
Described antirust agent is mercaptopropyl trimethoxysilane, dodecenylsuccinic acid diglycollic amide
With the one in O-(N-butanimide)-1,1,3,3-tetramethylurea Tetrafluoroboric acid ester or its mixing
Thing.
Preferably, described antirust agent, it is made up of by weight following component: 10-30 part mercapto propyl group
Trimethoxy silane, 10-30 part dodecenylsuccinic acid diglycollic amide and 10-30 part O-(N-
Butanimide)-1,1,3,3-tetramethylurea Tetrafluoroboric acid ester.
Thiosemicarbazides, No. CAS: 79-19-6, this formula can be effectively improved stock-removing efficiency.
Ethyl n-butyrate., No. CAS: 105-54-4, it is possible to effectively reduce Metal Surface Roughness.Mercapto propyl group
Trimethoxy silane, No. CAS: 4420-74-0.O-(N-butanimide)-1,1,3,3-tetramethylurea
Tetrafluoroboric acid ester, No. CAS: 105832-38-0.Dodecenylsuccinic acid diglycollic amide, permissible
Following method is used to be prepared from: to be raw material with dodecenylsuccinic acid, methanol, diethanolamine,
Through two step synthetic method, under the conditions of 140 DEG C, dodecenylsuccinic acid, methanol, diethanolamine rub
Your ratio 1:2:2, the response time be 4h, Zhou Hai etc. " dodecenylsuccinic acid diglycollic amide
Synthesis and rustless property research thereof " (" Chemical Engineering Technology and exploitation " 02 phase in 2008) disclose this
Preparation method.
The Environment-friendlymachine machine tool cutting fluid of the present invention, can form protecting film on the metal surface, make lathe
Corrosion from surrounding medium, it is adaptable to the gold such as steel, cast iron, rustless steel, copper aluminum and alloy thereof
The machining belonged to.
Detailed description of the invention
Embodiment 1-4
As corresponding to table 1, embodiment 1-4 data weigh each raw material.Heat water to 60 DEG C, then
Thiosemicarbazides, ethyl n-butyrate., sodium carbonate and antirust agent are added to the water, are uniformly mixed,
Can be prepared by described Environment-friendlymachine machine tool cutting fluid.
Table 1: Environment-friendlymachine machine tool cutting fluid formula table unit: wt%
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Thiosemicarbazides | 3 | 3 | 3 | 3 |
| Ethyl n-butyrate. | 0.03 | 0.03 | 0.03 | 0.03 |
| Sodium carbonate | 0.4 | 0.4 | 0.4 | 0.4 |
| Mercaptopropyl trimethoxysilane | 0.2 | / | 0.3 | 0.3 |
| Dodecenylsuccinic acid diglycollic amide | 0.2 | 0.3 | / | 0.3 |
| O-(N-butanimide)-1,1,3,3-tetramethylurea Tetrafluoroboric acid ester | 0.2 | 0.3 | 0.3 | / |
| Water | Surplus | Surplus | Surplus | Surplus |
In each embodiment, each component sum is 100wt%.
Environment-friendlymachine machine tool cutting fluid to embodiment 1-4, tests, and test result is shown in Table 2.
Table 2: Environment-friendlymachine machine tool cutting fluid performance test table
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Method |
| One-level grey cast-iron corrosion testing, h | 65 | 61 | 57 | 58 | GB/T6144-85 |
| Red copper corrosion testing, h | 17 | 14 | 13 | 13 | GB/T6144-85 |
| Corrosion of aluminium alloy is tested, h | 7 | 6 | 6 | 6 | GB/T6144-85 |
Embodiment 1 is compared with embodiment 2-4, it is evident that: the present invention uses mercapto propyl group three
Methoxy silane, dodecenylsuccinic acid diglycollic amide and O-(N-butanimide)-1,1,3,3-
Tetramethylurea Tetrafluoroboric acid ester three compounds, antiseptic effect Synergistic.
Claims (1)
1. an Environment-friendlymachine machine tool cutting fluid, it is characterised in that by following component percentage by weight
Than composition: thiosemicarbazides 2 4%, ethyl n-butyrate. 0.02 0.04%, sodium carbonate 0.2 0.6%, anti-
Rust agent 0.4 0.8%, surplus is water；
Described antirust agent, is made up of by weight following component: 10 30 parts of mercapto propyl group trimethoxies
Base silane, 10 30 parts of dodecenylsuccinic acid diglycollic amides and 10 30 parts of O (N succinyls
Imines) 1,1,3,3 tetramethylurea Tetrafluoroboric acid esters.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310603646.4A CN103614229B (en) | 2013-11-25 | 2013-11-25 | Environment-friendlymachine machine tool cutting fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310603646.4A CN103614229B (en) | 2013-11-25 | 2013-11-25 | Environment-friendlymachine machine tool cutting fluid |
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| Publication Number | Publication Date |
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| CN103614229A CN103614229A (en) | 2014-03-05 |
| CN103614229B true CN103614229B (en) | 2016-10-19 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104120021A (en) * | 2014-06-30 | 2014-10-29 | 安徽铖友汽车零部件制造有限公司 | Environment-friendly cutting fluid suitable for multiple metals and preparation method thereof |
| CN107880997A (en) * | 2017-12-12 | 2018-04-06 | 佛山早稻田环保节能科技有限公司 | A kind of Environment-friendlymachine machine tool cutting fluid |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031196A (en) * | 2012-09-21 | 2013-04-10 | 上海韬鸿化工科技有限公司 | Emulsion type metal cutting fluid |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US8993494B2 (en) * | 2010-12-01 | 2015-03-31 | Empire Technology Development Llc | Compositions comprising reverse micelles and methods for their use |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031196A (en) * | 2012-09-21 | 2013-04-10 | 上海韬鸿化工科技有限公司 | Emulsion type metal cutting fluid |
Non-Patent Citations (2)
| Title |
|---|
| "3-巯丙基三甲氧基硅烷的合成";吴洪特等;《精细石油化工》;20110331;第28卷(第2期);第49-52页 * |
| "十二烯基丁二酸二乙醇酰胺的合成及其防锈性能研究";周海等;《化工技术与开发》;20080229;第37卷(第2期);第12-14、17页 * |
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Inventor after: Chen Ji Inventor before: Ding Yonghua |
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Effective date of registration: 20170523 Address after: Jiangdong Road 200137 Shanghai city Pudong New Area Lingqiao Industrial Zone 1726 Lane 149 Patentee after: Shanghai Petrofer Special Lubricant Co.,Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T157 Patentee before: Shanghai Yuemeng Environmental Protection Technology Co., Ltd. |