CN103608449B - Subsurface reactor system - Google Patents

Subsurface reactor system Download PDF

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Publication number
CN103608449B
CN103608449B CN201280028299.0A CN201280028299A CN103608449B CN 103608449 B CN103608449 B CN 103608449B CN 201280028299 A CN201280028299 A CN 201280028299A CN 103608449 B CN103608449 B CN 103608449B
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reactor according
heat
subsurface
reactor
conduit
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CN103608449A (en
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布兰顿·伊格莱西亚斯
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Tulane University
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Tulane University
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    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00—Bioreactors or fermenters specially adapted for specific uses
    • C12M21/12—Bioreactors or fermenters specially adapted for specific uses for producing fuels or solvents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24T—GEOTHERMAL COLLECTORS; GEOTHERMAL SYSTEMS
    • F24T10/00—Geothermal collectors
    • F24T10/10—Geothermal collectors with circulation of working fluids through underground channels, the working fluids not coming into direct contact with the ground
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/008—Controlling or regulating of liquefaction processes
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00—Constructional details, e.g. recesses, hinges
    • C12M23/02—Form or structure of the vessel
    • C12M23/06—Tubular
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00—Constructional details, e.g. recesses, hinges
    • C12M23/02—Form or structure of the vessel
    • C12M23/18—Open ponds; Greenhouse type or underground installations
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
    • C12M41/12—Means for regulation, monitoring, measurement or control, e.g. flow regulation of temperature
    • C12M41/18—Heat exchange systems, e.g. heat jackets or outer envelopes
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M43/00—Combinations of bioreactors or fermenters with other apparatus
    • C12M43/02—Bioreactors or fermenters combined with devices for liquid fuel extraction; Biorefineries
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M47/00—Means for after-treatment of the produced biomass or of the fermentation or metabolic products, e.g. storage of biomass
    • C12M47/06—Hydrolysis; Cell lysis; Extraction of intracellular or cell wall material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24T—GEOTHERMAL COLLECTORS; GEOTHERMAL SYSTEMS
    • F24T10/00—Geothermal collectors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24T—GEOTHERMAL COLLECTORS; GEOTHERMAL SYSTEMS
    • F24T10/00—Geothermal collectors
    • F24T10/30—Geothermal collectors using underground reservoirs for accumulating working fluids or intermediate fluids
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24T—GEOTHERMAL COLLECTORS; GEOTHERMAL SYSTEMS
    • F24T50/00—Geothermal systems
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
    • C12M41/40—Means for regulation, monitoring, measurement or control, e.g. flow regulation of pressure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/10—Geothermal energy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/59—Biological synthesis; Biological purification
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/30—Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/20—Waste processing or separation

Abstract

Subsurface reactor for manufacturing hydrocarbon and chemicals from organic material preferably includes thermal recovery unit。Some embodiments of the present invention include at least one pipe that biomass are injected underground and at least one the second pipe reacting artifact matter collecting on surface。Also disclose and can control temperature and pressure and collect other pipe of mineral and carbon dioxide。It is additionally provided with the method utilizing reactor。The method that further embodiment includes using reactor, for instance, algae manufacture the method for fuel and use mineral and carbon dioxide as the method for the food of the algae field of the biomass that will act as reactor。

Description

Subsurface reactor system
Inventor: IGLESIAS, Brandon, United States citizen, 2721St.CharlesAve.2B, NewOrleans, Louisiana, 70130, US。
Assignee: THEADMINISTRATORSOFTHETULANEEDUCATIONALFUND, Louisiana, US, non-profit company, address: 6823St.CharlesAve., Suite300, GibsonHall, NewOrleans, LA70118, US。
Related application
There is a requirement that the priority of the U.S. Provisional Patent Application the 61/602nd, 841 submitted in the U.S. Provisional Patent Application the 61/481st, 918 submitted on May 3rd, 2011 and on February 24th, 2012, these two sections of temporary patent applications are hereby incorporated herein by accordingly。
Statement about the research that federal government subsidizes
Inapplicable
CD is submitted to
Inapplicable
Background
Along with being continuously increased of world population, it is necessary to use more continuable energy processes to support more population。In order to extract oil with pump from ground, all parts of the world has drilled many oil wells, and these oil wells are once dry up and just going out of use。
Meanwhile, a completely self-contained development track gone on by bio-fuel, and wherein biomass are principal focal points to the conversion of alcohol-based fuel。
Due to the oil embargo of the Organization of Petroleum Exporting Countries (OrganizationofthePetroleumExportingCountries, OPEC), started algae from 1978 and diatom is studied much and develops。Before 1978, JackMyers and BesselKok has published works AlgalCulture " FromLaboratorytoPilotPlant ", and the Massachusetts Institute of Technology (MassachusettsInstituteofTechnology, MIT) is approximately in nineteen fifty and has carried out mass propgation project on roof (rooftop)。Country rechargeable energy laboratory (NationalRenewableEnergyLaboratory is subsidized when fuel develops Ministry of Energy (DOE) office (DepartmentofEnergy's (DOE) OfficeofFuelsDevelopment), NREL) former water biological species plan (AquaticSpeciesProgram, ASP) 16 years to define and to determine the commercial viability that algae is changed into energy time, research increases。1998ASP final report confirms that chlorella and diatom are the plants of most primitive form, thus most effective on cell division and growth because they will not as terrestrial plant in the basic structure of such as root, stem, leaf consumed energy。ASP is concluded that, due to the original nature of microalgae, it is contemplated that the oil yield in the per unit area soil of microalgae is 30 times of terrestrial oilseed crops。But, the focus of ASP report is being prepared in biodiesel from algae lipid, and not on synthetic crude。
1998ASP final report highlights owing to weather variations in temperature uncontrollable with in season causes impotentia to maintain the key issue in the unlimited algae pond that consistent high algal biomass growth rate causes。
It addition, it is pointed out, do not use the replacement algae industrial-scale production that unlimited algae pond is designed almost without prospect。
Further, owing to maintaining the difficulty of high yield organism, algae production cost is therefore recommended to analyze。According to nutraceutical availability, light intensity, temperature and CO2Determine algal biomass productivity ratio。The impact of light, nutrient and temperature is the property taken advantage of (multiplicative)。
Complete to indicate the calculating of the required temperature and pressure that reacts。Along with the reduction of relative dielectric constant, water is more is the effect playing solvent, and this is partly due to polarity and reduces。Use Arrhenius equation, have calculated that for variable temperature and constant pressure, or the dissociation constant of water of variable pressure and steady temperature。
Thermal spalling (thermalspallation) is the process applying at a relatively high heat flux to hard rock。Being called in the process of peeling in this area using superthermal fluid to dissolve rock, quick stress causes that surface particles departs from from rock。
It is incorporated by reference herein below with reference to document:
U.S. Patent No. 4,003,393 (it discloses soluble pipeline cleaner)。
US4,467,861、AU2011200090(Al)、US2011/092726、WO2009149519A1、US3,955,317、US5,958,761、FR2564855、EP1923460、EP1382576、US2005/064577、DE102006045872、US2004/033557、US2007/295505、US6,468,429、WO2011086358、GB2473865、DE102006045872、US2004/0033557、US2007/0295505、US4,937,052、US4,272,383、US7,866,385、US7,977,282。
ScottC.James and VarunBoriah, ModelingAlgaeGrowthinanOpen-ChannelRaceway。
UriKaplan, AdvancedOrganicRankineCyclesinBinaryGeothermalPowerPlant s, WorldEnergyCouncil, 2007。
YuanhuiZhang, HydrothermalLiquifactiontoConvertBiomassintoCrudeOil, the 10 chapter, BiofuelsfromAgriculturalWastesandByproducts, 2010。
YukihikoMatsumara et al., Biomassgasificationinnear-andsuper-criticalwater:Statusa ndProspects, BiomassandBioenergy, 2005。
UriKaplan, OrganicRankineCycleConfigurations, ProceedingsEuropeanGeothermalCongress, 2007。
NadavAmir, UtilizingOrganicRankineCycleTurbineSystemstoEfficientlyD riveFieldInjectionPumps, GRC2007AnnualMeeting, 2007。
ASMESteamTables.ThermodynamicandTransportPropertiesofSte am, The1967IFCformulationforindustrialuse. the 6th edition, ASME, 1993。
Benjamin, M.2002.WaterChemistry, the 1st edition, NewYork:McGrawHill。
AqueousSystemsatElevatedTemperaturesandPressures:Physica lChemistryinWater, SteamandHydrothermalSolutions, InternationalAssociationforthePropertiesofWaterandSteam, 2004。
Piezoelectricity:HistoryandNewThrusts, UltrasonicsSymposium, 1996。
AdiabaticProcesseshttp://hvperphysics.phy-astr.gsu.edu/hbase/thermo/adiab.html, GeorgiaStateUniversity。
Brief summary of the invention
Some embodiments of the present invention include subsoil water-ground thermal reactor that renewable oils feed is converted into fuel via temperature and pressure。The available produced coke of the embodiment of reactor and flue gas (offgas) produce electrically and thermally, utilize the water of the rich in mineral substances of produced carbon dioxide and heat to promote biomass growth。
Some embodiments use algae as biomass。Other embodiments are for having unlimited algae pond near the reactor of feed。Some embodiments provide the temperature to algae raceway pond to control by using heat energy utilization indirectly to flow out water。Further embodiment allows the recycle stream of reactor to provide nitrogen, phosphorus, potassium, carbon dioxide and the temperature raised in unlimited algae pond。The present invention includes the subsurface reactor being used in the fuel making process manufacturing fuel from organic material, and described reactor includes the first pipe that organic material injects underground；After collecting the reaction produced by subsurface reactor, the second of organic material manages；Extract the heat exchanger being ready to use in the heat that power is provided to the equipment used in fuel making process。
Preferably, the present invention farther includes the converting heat of in the future automatic heat-exchanger and becomes energy thus provide the organic Rankine bottoming cycle of power to the equipment used in fuel making process。
Preferably, the equipment used in fuel making process is directly driven by the equipment extracting energy from heat exchanger。
Preferably, this equipment includes pump。
Preferably, this pump makes heat-exchange fluid circulate so that reaction zone maintains temperature required。
The present invention includes the subsurface reactor being used in the fuel making process manufacturing fuel from organic material, and described reactor includes the first pipe that organic material injects underground；After collecting the reaction produced by subsurface reactor, the second of organic material manages；And make heat-exchange fluid circulate in closed circuit so that reaction zone maintains temperature required pump。
Preferably, the present invention farther includes for extracting the heat exchanger being ready to use in the heat providing power to the equipment used in fuel making process。
Preferably, the present invention farther includes the converting heat of in the future automatic heat-exchanger and becomes energy thus provide the organic Rankine bottoming cycle of power to the equipment used in fuel making process。
Preferably, this equipment includes pump。
Preferably, the equipment used in fuel making process is directly driven by the equipment extracting energy from heat exchanger。
Optionally, organic material is biomass。
Preferably, biomass are algae。
Optionally, organic material is polymer。
Optionally, organic material is solid waste。
Optionally, organic material is reacted by liquefaction。
Optionally, organic material is reacted by thermal chemical reaction。
Optionally, organic material is reacted by water-heat process。
Preferably, the second pipe is in the first pipe。
Preferably, the bottom of the first pipe is Guan Bi, and the bottom of the second pipe is unlimited。
Preferably, the first pipe is deeper than the second pipe in underground。
Preferably, the present invention farther includes the sleeve pipe of encapsulating the first pipe and the second pipe。
Optionally, sleeve pipe and the first pipe are at least equally deep。
Optionally, sleeve pipe does not have the first pipe deep。
Preferably, the present invention farther includes the filter screen (screen) of the degree of depth down to the first pipe。
Preferably, sleeve pipe is insulator。
Preferably, this insulator is cement。
Preferably, the present invention farther include at least one heat-transfer matcrial can by the 3rd pipe of its pumping。
Preferably, heat-transfer matcrial is water。
Preferably, the present invention farther includes the oil of the product effluent of separate reactor, gas, water separator。
Optionally, separator is on the ground。
Optionally, separator is at subsurface。
Optionally, a part for described product is stored。
Optionally, a part for described product is used as to make the food of biomass growth。
Optionally, a part for described product is used for producing electricity。
Preferably, electricity is produced via heat exchange。
Optionally, at least the first pipe is bending。
Optionally, at least the first pipe is to tilt。
Optionally, at least the first pipe bifurcated。
The present invention includes the method performing high pressure, pyroreaction, and it includes, by the first conduit, organic material is transported to underground, wherein applies enough pressure and temperatures thus organic material is converted into fuel, hydrocarbon or chemicals to the organic material in reaction zone；Fuel, hydrocarbon or chemicals extracting will be come by the second conduit；Heat-exchange fluid is made to circulate in closed circuit so that reaction zone maintains temperature required。
Preferably, the present invention farther includes to use heat exchanger to extract and is ready to use in the heat providing power to the equipment used in conversion process。
Preferably, the equipment used in fuel making process is directly driven by the equipment extracting energy from heat exchanger。
Preferably, the present invention farther includes to use the converting heat of organic Rankine bottoming cycle automatic heat-exchanger in the future to become energy thus providing power to the equipment used in conversion process。
Preferably, this equipment includes pump。
The present invention includes the method performing high pressure, pyroreaction, comprising: organic material is transported to underground by the first conduit, wherein applies enough pressure and temperatures thus organic material is converted into fuel, hydrocarbon or chemicals to the organic material in reaction zone；Fuel, hydrocarbon or chemicals extracting will be come by the second conduit；Regulate heat exchanger and be ready to use in, for extracting, the heat that power is provided to the equipment used in conversion process。
Preferably, the present invention farther includes to make heat-exchange fluid circulate in closed circuit so that reaction zone maintains temperature required。
Preferably, the present invention farther includes to use the converting heat of organic Rankine bottoming cycle automatic heat-exchanger in the future to become energy thus providing power to the equipment used in conversion process。
Preferably, this equipment includes pump。
Preferably, the equipment used in fuel making process is directly driven by the equipment extracting energy from heat exchanger。
Preferably, pressure can be regulated by increasing or reduce the tubular reactor degree of depth。
Preferably, the present invention farther includes heat-transfer matcrial is transported to underground。
Optionally, the present invention farther includes to come the temperature of Heat Transfer Control material by regulating cycle rate。
Optionally, the present invention farther includes to carry out the temperature of Heat Transfer Control material by raising or reduce the temperature of organic material。
Preferably, the present invention further includes at and heat-transfer matcrial is transported to pressure break rock before underground。
Optionally, the present invention farther includes to be transported to heat exchanger heat-transfer matcrial from underground。
Optionally, the present invention farther includes to be transported to organic Rankine bottoming cycle heat-transfer matcrial from underground。
Preferably, the present invention farther includes to be separated into product oil, gas and group water solution。
Preferably, the present invention farther includes to transport group water solution for biomass growth。
Optionally, the present invention farther includes combustion product gases product and energy is used for dry heat exchanger。
Optionally, the present invention farther includes combustion product gases product and is used for producing electricity by energy。
Optionally, the present invention farther includes combustion product gases product and is used for producing mechanical energy by energy。
Optionally, the present invention farther includes combustion product gases product and is used for producing heat by energy。
Preferably, the present invention farther includes the part flowing out product transporting the second pipe to feed biomass。
Preferably, biomass are algae。
Preferably, a part for described outflow product comprises carbon dioxide。
Optionally, a part for described product the feed acting on still-process。
Optionally, a part for described product the feed acting on pyrolytic process。
Preferably, the present invention farther includes to make rock peel off。
Before present invention resides in shipment, bio oil/crude oil is carried out post-treatment, make ReactWell be separated into light ends, distillation fraction and heavy end。Stable by using underground geothermal density and ion isolation unit to realize oil, described underground geothermal density and ion isolation unit use underground heat, are bridged by BADIRE and the thermograde due to the detached dowel of underground within and drive Density Separation and ion isolation separating the piezoelectric bar producing voltage drop on fluid。Thus, this post uses geothermal energy to be used for heating and for ion isolation process。Use independent Density Separation not ' economical and effective ', because (currently the practice in yellow grease case carries out slower in winter in the restriction of time, and carry out comparatively fast in summer) but, ion isolation is also used for the separation process accelerating generally to be driven by the voltage applied。Ion isolation post uses voltage difference separating polar/ionic mixture (learning this point when preparing biodiesel)。Reversible piezoelectric produces temperature difference (this is reversible process: be also useful for generation voltage difference when component side is exposed in " DeltaT " temperature difference) when the voltage being applied in drives:
Use liquid alkali, alkaline-earth metal, transition metal, other metals, water, saline and other compounds various as heat-transfer fluid；
Use demineralization unit (DemineralizationUnit, DMIN) to take out mineral via cooling or magnetic b field and be used for resale (auxiliary income stream)；
By using working heat transfer fluids to be separated with geothermal reservoir fluid by the process fluid in tubular reactor。Purpose is by being limited in ips by geothermal fluid and reducing pigging maintenance, thus will minimize downtime。
Use such pipe cleaning objects such as wiper (petroleum industry term), it dissolves (due to water-heat process depolymerization) and and returns original state never in oil and gas when being injected in tubular reactor, but scavenging duct I.D. and O.D。
Some beneficial aspects of the present invention include:
Wiper close friend design makes the incrustation scale (scale) on the heat transfer stream side contacted with formation fluid (geothermal reservoir) easily remove；
A. wiper close friend design is that heat-transfer fluid flows in the internal diameter (I.D.) of pipe with the key difference of Previous designs。Wiper works when overhauling I.D. rather than O.D. of pipe the most efficiently。
Use demineralization unit (DMIN) to take out mineral via cooling or magnetic b field and be used for resale (auxiliary income stream)。
Working fluid that fin (fin) on heat-transfer pipe transfers heat to be included in sleeve pipe and serve as baffle plate to interrupt the eddy current that compounder systems (19) produces, this forces generation convection heat transfer' heat-transfer by convection in tubular reactor。Fin can also be positioned on tubular reactor。
So that there is the blender/blade/propeller of convection heat transfer' heat-transfer by convection in tubular reactor in mixing capsule pipe working fluid；
Drive the gear-box treating to be provided the down-hole blender of power by ORC unit；
Geothermal reservoir fluid and pipe O.D. isolate available extremely low downtime and are removed from I.D. by incrustation scale, because this structure need not remove pipe fitting (if not some months, be also that several all nothings make a trip and downtime is overhauled in down-hole)；
Use the convection heat transfer' heat-transfer by convection of the velocity of rotation of (multiple) blender；
Bio oil is stable: bio oil processing in downstream will occur in top (topping) unit thus isolating light fraction, distillation and 6 heavier light wood material, it is then subjected to downstream oxygenate (oxygenate) and recovery of nutrient element procedure of processing, just leaves facility door afterwards and delivers for refine or petrochemistry。By little top end unit and recovery of nutrient element are incorporated in ReactWell base structure, can specifically adjust the selected cutting (selectcuts) of hydrocarbon, adapt it to the fluid catalytic cracker (FCC: " cat cracker (cat-crackers) ") in given refiner or petrochemistry complex and delayed coking unit, thus optimizing finished product ASTM specification, make valuable recovery of nutrient element in ReactWell facility reach maximum simultaneously。The key difference of the top end unit of ReactWell is that the use of Fossil fuel is separated (de-couple) by it, thus Fossil fuel is separated into selected light fraction, distillation and weight 6 oil tower bottom distillate。ReactWell uses underground heat ion isolation technology to complete oil fractional distillation, and this technology uses the loop circuit heat pipe of ground thermal drivers to utilize latent heat capillary flow and piezoelectric to drive Density Separation, thus producing voltage in response to geothermal temperature gradient and stress from hydraulic head。Thus, due to the temperature, capillarity, stress and the voltage gradient that are selected by underground heat, wick material, piezoelectric selects and gravity produces and maintains, there is liquid phase separation in underground。
In some cases, along with the passage of the power lifetime operatively descending reactor assembly, due to the permeability reduction being associated with incrustation scale and obstruction, underground heat and associated gradients are likely to be insufficient for reactor condition。Furthermore, it may be desired to run tubular reactor at relatively high temperatures。Thus, (make outflow CO by burning2Be recycled to algae pond), electric heater or Columnating type solar generating (CSP) tubular reactor inlet and working heat transfer fluids in advance be likely to be proved to be the effective solution of the pressure break again and well stimulation (simulation) postponing reservoir。
The advantage of embodiment of the present invention includes:
Cleaning/pigging equipment is used to remove incrustation scale/dirt；
Use operating heat exchange fluid heat reservori fluid isolator so that it is on tubular reactor, do not produce dirt；
Use (multiple) underground agitator forced convection heat transfer；
Use ground lower piezoelectric/hot particle that stress transmission is become heat；
Use underground catalytic agent；And
Use underground steam wither (vaporcollapse) produce latent heat。
Accompanying drawing is sketched
The following drawings forms the part of this specification, list at this in order that represent certain aspects of the invention further。It is better understood the present invention in conjunction with the description of specific embodiments provided herein by the one or more figure in these figure of reference。
Fig. 1. exemplarily thermal depolymerization tubular reactor。
Fig. 2. exemplarily descend reactor assembly。
Fig. 3. exemplarily descend reactor fluid stream。
Fig. 4. exemplary water-underground heat reactor process flow chart。
Fig. 5. exemplary water-underground heat reactor process flow chart。
Fig. 6. exemplarily hot tubular reactor。
Fig. 7. exemplarily hot tubular reactor。
Fig. 8. exemplarily hot tubular reactor。
Fig. 9. exemplarily hot tubular reactor。
Figure 10. exemplarily hot tubular reactor。
Figure 11. exemplarily hot tubular reactor, wherein it is absent from pump circulation pipe (pump-aroundtube), entrance and exit separately, and is absent from sleeve pipe。
Figure 12. the active heat transfer temperature curve in sleeve pipe。
Figure 13. stand the active heat transfer Temperature Distribution in the sleeve pipe of forced convertion。
Figure 14. tubular reactor is distributed。
Figure 15. stand the tubular reactor distribution of forced convertion。
Figure 16. with the diagram of the thermally heat reservori fluid of hot working fluid and reactor process fluid isolation。
Figure 17. there is the tubular reactor that geothermal reservoir flow sleeve injects。
Figure 18. there is the tubular reactor that externally heat reservori fluid injects。
Figure 19. there is the tubular reactor of the geothermal reservoir fluid of isolation。
Figure 20. there is the geothermal reservoir fluid of isolation and the tubular reactor of forced convertion。
Figure 21. use the tubular reactor of pressure heat/charged particle and catalyst。
Figure 22. the tubular reactor of the gas injection of use and geothermal reservoir fluid isolation。
Figure 23. the CFD model of sleeve pipe, tubular reactor and thermally transfer pipes。
Result of calculation. after the figure in U.S. Provisional Patent Application the 61/602,841st, appended form provides the result of calculation of the feasibility that embodiment of the present invention is described。
Detailed description of the invention
Exclusively hot tubular reactor (hydrolysis, depolymerization, decarboxylation, and thermal degradation)
The existence of downhole temperature and pressure causes and maintains water-ground thermal response and thermal depolymerization, and it produces the geothermal energy that can use in soil。Basement rock temperature along with change in depth is used as reference temperature driving force。The tubulose depolymerizing reactor section filling the water not standing forced circulation in sleeve pipe will be modeled。
Water-ground thermal reactor
Table 1: depolymerization variable interested
The water being loaded with algae from ground runway, unlimited pond or settling tank system is injected in closed circuit water-ground thermal reactor to down-hole。When the pressure and temperature of the down-hole water containing algae exceedes air and ambient temperature, algae and other organic matters stand hydrolysis and part thermal degradation thus forming carbon, CO2, flue gas, hydrocarbon and heat containing amino acid whose rich in mineral substances water。Tubular reactor is predominantly located in sleeve pipe, but extend to sleeve pipe externally enter open end region。Sleeve pipe contains hot water, and this hot water is static or is circulated by pump blood circulation, is under natural water pressure head or is pressed by the ground stood from rock stratum, simultaneously with ground power back balance。Exemplary figure 1 illustrates。
In one embodiment, when arriving deeper along with pipe, tubular reactor can bend thus allowing biomass close to bigger thermally hot rock to obtain the surface area increased。
Ground source heat is likely to press with being subject to or be not affected by。
In some embodiments, the degree of depth of subsurface reactor can in the scope of 33 feet-40,502 feet (10m-12,345m)。In some embodiments, tubular reactor outer tube can have 1 inch of diameter to 100 feet (25mm to 30m), in tubular reactor, pipe can have 1 inch of diameter to 100 feet (25mm to 30m), and sleeve pipe can have 1 inch of diameter to 100 feet (25mm to 30m)。Some embodiment can have bending or tipping tube, in order to the time in the reactor is longer。Tipping tube can have a series of gradient, moves to deeper along with it and becomes level more gradually。When exploring oil gas, exploitation and geothermal well can be used in the present invention, will suitably adjust the size of tubing used in this type of place so that it mates thereto。Such as, in the well of length about 5,000+ foot (1,524+m), pipe diameter will be likely about 12 to 120 inches (30-305cm)。
In some embodiments, it is understood that there may be more than one tubular reactor。
In some embodiments, the temperature needed for effecting reaction is likely larger than 100 DEG C, the highest 2,000 DEG C, and the pressure needed for effecting reaction is likely 14.7psig (203kPa) to 40,000psig (275,892kPa)。
According to the temperature and pressure scope in reactor, it may happen that heat of liquefaction is chemical or water-heat process in reactor when T and the P in water is within the scope of some:
100 DEG C to 374 DEG C (subcritical water) and 14.7psig (203kPa) to 30,000psig (206,944kPa)；
374 DEG C to 500+ DEG C (supercritical water) and 14.7psig (203kPa) to 30,000psig (206,944kPa)。
Some embodiments can use any kind of organic matter to manufacture product in reactor under associated temperature and pressure condition。In certain embodiments, polymer can be used for reacting in solvent (such as: water) in subsurface reactor as organic matter。
Some embodiments can use organic production chemicals, fuel or hydrocarbon, and this depends on the organic matter used。
In some embodiments, it is understood that there may be exclusively heat pipe part (tubular), this exclusively heat pipe part there is multiple pipe fitting, it has for obtaining the coiling tubing option of forced convection heat transfer increased in one or more underground heat ore deposits。Flow out geothermal fluid stream and can flow into organic Rankine bottoming cycle (orc)。Organic Rankine is made up of carburator/preheater, and described carburator/preheater uses from the heat and the evaporation work organic fluid that flow out underground heat tubular pump circulation of fluid。Work organic fluid (such as: normal butane) fluid steam drives turbine, and gas turbine exhaust steam can be carried out forced draft cooling, and hot-air is used for dry run, and water is cooled for the warm other for the offer of algae pond subsequently。Then the work organic fluid of condensation can be recirculated back to carburator for reheating。Turbine is connectable to injection pump and electromotor thus producing electricity。
The embodiment with tube-shaped heat pump cycle can provide the adjustable temperature to water-underground heat and depolymerizing reactor to control by the number of adjustment pump circulating hot water flow velocity and coiling tubing insert。The exemplary of this feature figure 3 illustrates。Some embodiments can use any heat-transfer fluid flow through reactor and adjust temperature。
In some embodiments, temperature of reactor can regulate in the following way: increases or reduction pump rate of circulating flow, increases or reduce tubular reactor flow velocity, raises or reduces tubular reactor inlet temperature or rising or reduction pump circulation reinjects temperature。
Table 2: terrestrial heat pump circulation key variables
If pump circulation delivers enough heats via forced convertion, then temperature required in order to reach, slight depth is likely to enough for reactor。When being absent from tubular pump circulation, limited owing to conducting heat in tubular pump circulation, sleeve pipe and open end region, down-hole, therefore given geothermal energy resources are likely to need deeper drilling depth。
In some embodiments, pump circulation pipe can have 1 inch of diameter to 100 feet (25mm to 30m)。
Some embodiments can use heat exchanger to extract energy from the heat-transfer fluid of heat。The example of spendable heat-exchange apparatus includes Rankine, Carnot, Stirling, HeatRegenerativeCyclone, thermoelectricity (Peltier-Seebeck (peltier-seebeck) effect), Mesoscopic, Barton, Stoddard, Scuderi, BellColeman and Brayton。In other embodiment, incendivity flue gas product is thus being heated for the heat-transfer fluid in heat exchanger。Heat-transfer fluid can be used for drying, producing each side of electricity, reacting by heating device, or produces mechanical energy。
Other embodiment can use organic Rankine bottoming cycle direct-driven pump that heat-transfer fluid is sent into terrestrial heat pump blood circulation, provides power to the down-hole pump in tubular reactor and produces electricity。Further, when with during by electric or directly driving offer power forced ventilation system combination, the condensation section of organic Rankine bottoming cycle can be used to assist dry algal biomass or other organic materials。Further, the organic working fluids in condensation section can play the effect in warm algae pond。
The outflow water containing mineral, aminoacid and carbon of heat。
The product that flows out of tubular reactor can containing aseptic rich in mineral substances water, carbon and hydrocarbon/admixture of gas。Depolymerization, hydrolysis, deacidification and thermal degradation process result in hydrocarbon ils/gas/carbon/carbon dioxide mixture。Solid carbon and hydrocarbon are formed by the combination of the depolymerization of underground, hydrolysis, deacidification and thermal degradation。Some embodiments can include separating equipment with the standard oil/water/gas body of gas for separating hydrocarbon。
After separation, the outflow water of the rich in mineral substances of the tubular reactor of the heat of oil-free can return to open wide algae field track systems or other biological system。In some embodiments, total hot water returns volume and may be set to the 1/3 of runway water volume so that the 1/3 of runway water can be overturn by every day and process。
In some embodiments, the admixture of gas of separation and carbon dioxide can be burnt to produce electricity, heat and carbon dioxide。Be recycled back into algae pond or break tank (breaktank) at carbon dioxide before or after, can it be injected in tubular reactor effluent to down-hole to assist pumping and to be injected in effluent stream。
In some embodiments, the full-size of reactor is the function of the effluent flow velocity of water-underground heat depolymerizing reactor, temperature, content of mineral substances, amino acid content and carbonization, depends on geothermal energy resources, the tubular reactor degree of depth, pump cycle rate and direction。
The environmental variable affecting reactor can include ambient temperature, wind speed, cloud amount, evaporation rate, precipitation, relative humidity and atmospheric pressure。Critical process variables, except including algae the pool size such as degree of depth, width, length and circulating load (circulation), also includes reactor effluent flow velocity and temperature。
Table 3: algae runway and process variable
Water containing algae, biomass, waste material and polymer produce carbon dioxide in underground。
During deacidification step, pipe fitting can produce when underground exists water, heat, pressure, algae, biomass, waste material and polymer carbon dioxide。In some embodiments, carbon dioxide can in this process recirculation。
Hydrolysis and the thermal degradation of ground thermal drivers cause that the water containing algae, biomass, waste material and polymer produce hydrocarbon liquid/admixture of gas in underground。
When the water containing algae, biomass, waste water, waste material and polymer are subjected to higher than environment (300+ (149+ DEG C) and 300+psig (2 in underground, during pressure and temperature 170+kPA)), this material by being hydrolyzed, deacidification and degraded be thus forming the rich in mineral substances water of oil and gas and solid carbon, carbon dioxide and heat。In some embodiments, being then peeled off oil/gas/aqueous mixtures, water is recycled to algae pond, and oil and gas are transported to the downstream process unit generation for electricity, heat, chemicals, transport fuel and coke。Illustrate that the exemplary process diagram of this process illustrates in figures 4 and 5。Coke produces to occur via pyrolysis。
Table 4: water-ground thermal reactor stream
The benefit of existing industrial plants and algal culture is included renewable oils production, industrial wastewater consumption and uses CO2The growth property taken advantage of making large-scale algae field with the hot water of rich in mineral substances strengthens。
Table 5:ReactWellPFD
Figure 12 depicts the body temperature distribution of closed circuit working heat transfer fluids in sleeve pipe。Conduct heat and occurred by conduction, free convection and radiant heat transfer。Working heat transfer fluids (referring to 3 in Figure 19) in sleeve pipe is drawn in fig. 13。
Figure 13 depicts the body temperature distribution of closed circuit working heat transfer fluids in sleeve pipe。Conduct heat and occurred by conduction, free convection and radiant heat transfer。Working heat transfer fluids (referring to 3 in Figure 20) in sleeve pipe is drawn in fig. 13。
Figure 14 depicts the annularly flow space of the tubular reactor when being absent from forced convertion and central canal returns the tubular reactor Temperature Distribution of closed circuit process fluid in road (return)。Tubular reactor (referring to 19 in Figure 19) is immersed in working heat transfer fluids (referring to 3 in Figure 19)。Technological reaction thing enters reactor (referring to 15 in Figure 19), and this also illustrates in the bottom left hand district of this figure。Process fluid flows into underground by annular space (referring to 4 in Figure 19), then passes through central canal (referring to 5 in Figure 19) and returns。Temperature of reactor distribution can be regulated by regulating following a few person: inject the temperature of stream and flow velocity (in Figure 19 14), demineralization flow velocity (in Figure 19 13), organic Rankine bottoming cycle flow velocity (in Figure 19 16), piezoelectric particles concentration in working heat transfer fluids (referring to 21 in Figure 22) or tubular reactor (referring to 22 in Figure 22) and distribution, enter the concentration of the catalyst in tubular reactor and be distributed (referring to 23 in Figure 22), enter the gas flow rate (referring to 15 in Figure 22) in tubular reactor suction line, the inlet temperature (in Figure 19 15) of process fluid and the flow velocity (in Figure 19 15) of process fluid。
Figure 15 depicts the annularly flow space of the tubular reactor when there is forced convertion and central canal returns the tubular reactor Temperature Distribution of closed circuit process fluid in road。Tubular reactor (referring to 19 in Figure 19) is immersed in working heat transfer fluids (referring to 3 in Figure 19)。Technological reaction thing enters reactor (referring to 15 in Figure 19), and this also illustrates in the bottom left hand district of this figure。Process fluid flows into underground by annular space (referring to 4 in Figure 19), then passes through central canal (referring to 5 in Figure 19) and returns。Temperature of reactor distribution can be regulated by regulating following a few person: inject the temperature of stream and flow velocity (in Figure 19 14), demineralization flow velocity (in Figure 19 13), organic Rankine bottoming cycle flow velocity (in Figure 19 16), piezoelectric particles concentration in working heat transfer fluids (referring to 21 in Figure 22) or tubular reactor (referring to 22 in Figure 22) and distribution, enter the concentration of the catalyst in tubular reactor and be distributed (referring to 23 in Figure 22), enter the gas flow rate (referring to 15 in Figure 22) in tubular reactor suction line, the inlet temperature (in Figure 19 15) of process fluid, the flow velocity (in Figure 19 15) of process fluid and blender rod velocity of rotation (18.b in Figure 22) and blender rod impeller, propeller or blade surface geometry shape (18b in Figure 22)。
Figure 16 lists for by the incrustation scale of geothermal reservoir fluid, corrosion and the heat transfer mechanism in storing up the internal diameter being limited in thermally transfer pipes (referring to 7 in Figure 19) and fluid。It is by providing the pigging to bore to reduce maintenance downtime by the purpose of thermally heat reservori fluid (injection or be pre-existing in) with tubular reactor isolation。Pigging is such process, in this process, with the plastics/rubber object of friction edges/cutting knife (cutter) by by the pressure-driven of pipe, thus generally incrustation scale and other oxide/precipitums of the restriction heat transfer in bore and fluid flowing being washed。If pigging can not be performed, then will have to dismantle whole tubular reactor to remove incrustation scale。Thus, by underground heat working fluid is isolated in pipe and uses working heat transfer fluids (water, saline, hydrargyrum etc.) be delivered to tubular reactor by heat from the geothermal fluid of isolation, complete the feasible operation of subsurface reactor by substantially reducing maintenance downtime and cost。
Figure 17 lists the injection and reactor structure that are contained in sleeve pipe。The excellent equipment (in Figure 17 4) of continuous stirring maintains the high speed flow velocity along tubular reactor external diameter, incrustation scale and dirt is minimized thereby through the surface in continuous-cleaning convection heat transfer' heat-transfer by convection and aid (aids)。Geothermal reservoir fluid is injected (in Figure 17 3), under its access wall, enter in reservoir (in Figure 17 9), flow through the rock (in Figure 17 10) of pressure break and flow to organic Rankine unit (in Figure 17 2), described organic Rankine unit direct-driven pump and auxiliary equipment by recurrent canal (in Figure 17 8)。Geothermal reservoir fluid directly contacts the external diameter of tubular reactor, and can draw back via (in Figure 17 in 5 and 17 2) stream, for being reclaimed by the mineral of demineralization unit (DMIN)。Bottom hole temperature (BHT) can exceed that 200 DEG C and pressure are more than 500psig (3,549kPa)。
Figure 18 lists the structure with the reactor being contained in sleeve pipe being externally injected pipeline。The excellent equipment (in Figure 18 5) of continuous stirring maintains the high speed flow velocity along tubular reactor external diameter, incrustation scale and dirt is minimized thereby through the surface in continuous-cleaning convection heat transfer' heat-transfer by convection and aid。Geothermal reservoir fluid is injected (in Figure 18 14), under its access wall, enter in reservoir (in Figure 18 10), flow through the rock (in Figure 18 9) of pressure break and flow to organic Rankine unit (in Figure 18 16), described organic Rankine unit direct-driven pump and auxiliary equipment by recurrent canal (in Figure 18 11)。Geothermal reservoir fluid directly contacts the external diameter of tubular reactor, and can draw back via (in Figure 18 in 15 and 18 16) stream, for being reclaimed by the mineral of demineralization unit (DMIN)。Bottom hole temperature (BHT) can exceed that 200 DEG C and pressure are more than 500psig (3,549kPa)。
Figure 19 lists the structure of the reactor being contained in sleeve pipe, its have be externally injected pipeline (in Figure 19 14), be contained in sleeve pipe/internal geothermal reservoir fluid isolation and heat transfer pipeline (in Figure 19 13), be contained in sleeve pipe/at internal tubular reactor (in Figure 19 19), and externally heat reservori fluid return lines (in Figure 19 16)。Geothermal reservoir fluid is injected (in Figure 19 14), under its access wall, enter reservoir (in Figure 19 10), flow through the rock (in Figure 19 9) of pressure break and flow to organic Rankine unit (in Figure 19 16), described organic Rankine unit direct-driven pump and auxiliary equipment by recurrent canal (in Figure 19 11)。Geothermal reservoir fluid is not directly contacted with the external diameter of tubular reactor, but it is isolated in the internal diameter of the several hot heat-transfer pipe returning to earth's surface, to draw back via (in Figure 19 in 13 and 19 16) stream, for being reclaimed by the mineral of demineralization unit (DMIN)。Key difference between Figure 19 and previous Figure 17 and 18 is to use hot heat-transfer pipe (in Figure 19 7) thermally to isolate with reactor thus stoping generation incrustation scale/dirt on reactor wall by heat reservori fluid。(in Figure 19 7) main attainable benefit is so that and is prone to remove incrustation scale by internal diameter maintenance/pigging and increase heat transfer。Working heat transfer fluids (in Figure 19 3) is transferred heat in tubular reactor by moistening tubular reactor and hot heat transferring thermal pipe。Bottom hole temperature (BHT) can exceed that 200 DEG C and pressure are more than 500psig (3,549kPa)。
Figure 20 lists the structure of the reactor being contained in sleeve pipe, its have be externally injected pipeline (in Figure 20 14), be contained in sleeve pipe/internal geothermal reservoir fluid isolation and heat transfer pipeline (in Figure 20 13), be contained in sleeve pipe/at internal tubular reactor (in Figure 20 19), and externally heat reservori fluid return lines (in Figure 20 16)。Geothermal reservoir fluid is injected (in Figure 20 14), under its access wall, enter reservoir (in Figure 20 10), flow through the rock (in Figure 20 9) of pressure break and flow to organic Rankine unit (in Figure 20 16), described organic Rankine unit direct-driven pump and auxiliary equipment by recurrent canal (in Figure 20 11)。Geothermal reservoir fluid is not directly contacted with the external diameter of tubular reactor, but it is isolated in the internal diameter of the several hot heat-transfer pipe returning to earth's surface, to draw back via (in Figure 20 in 13 and 20 16) stream, for being reclaimed by the mineral of demineralization unit (DMIN)。The key difference of Figure 20 and previous Figure 17 and 18 is to use hot heat-transfer pipe (in Figure 20 7) thermally to isolate with reactor thus stoping generation incrustation scale/dirt on reactor wall by heat reservori fluid。The main attainable benefit of (in Figure 20 7) is so that and is prone to remove incrustation scale by internal diameter maintenance/pigging and increase heat transfer。Working heat transfer fluids (in Figure 20 3) is transferred heat in tubular reactor by moistening tubular reactor and hot heat transferring thermal pipe。Second key difference between Figure 20 and Figure 19 is to use to be provided in down-hole forced convertion thus increasing the rod of the continuous stirring of rate of heat transfer。Bottom hole temperature (BHT) can exceed that 200 DEG C and pressure are more than 500psig (3,549kPa)。
Figure 21 lists the structure of the reactor being contained in sleeve pipe, its have be externally injected pipeline (in Figure 21 14), be contained in sleeve pipe/internal geothermal reservoir fluid isolation and heat transfer pipeline (in Figure 21 13), be contained in sleeve pipe/at internal tubular reactor (in Figure 21 19), and externally heat reservori fluid return lines (in Figure 21 16)。Geothermal reservoir fluid is injected (in Figure 21 14), under its access wall, enter reservoir (in Figure 21 10), flow through the rock (in Figure 21 9) of pressure break and flow to organic Rankine unit (in Figure 21 16), described organic Rankine unit direct-driven pump and auxiliary equipment by recurrent canal (in Figure 21 11)。Geothermal reservoir fluid is not directly contacted with the external diameter of tubular reactor, but it is isolated in the internal diameter of the several hot heat-transfer pipe returning to earth's surface, to draw back via (in Figure 21 in 13 and 21 16) stream, for being reclaimed by the mineral of demineralization unit (DMIN)。The key difference of Figure 21 and previous Figure 20 is to use piezoelectric particles that the stress conversion produced by the gravity on the down-hole post acting on circulating heat transfer fluid is become electric current and heat。It addition, catalyst can at tubular reactor internal recycle together with piezoelectric particles。Bottom hole temperature (BHT) can exceed that 200 DEG C and pressure are more than 500psig (3,549kPa)。
Figure 22 lists the structure of the reactor being contained in sleeve pipe, its have be externally injected pipeline (in Figure 22 14), be contained in sleeve pipe/internal geothermal reservoir fluid isolation and heat transfer pipeline (in Figure 22 13), be contained in sleeve pipe/at internal tubular reactor (in Figure 22 19), and externally heat reservori fluid return lines (in Figure 22 16)。Geothermal reservoir fluid is injected (in Figure 22 14), under its access wall, enter reservoir (in Figure 22 10), flow through the rock (in Figure 22 9) of pressure break and flow to organic Rankine unit (in Figure 22 16), described organic Rankine unit direct-driven pump and auxiliary equipment by recurrent canal (in Figure 22 11)。Geothermal reservoir fluid is not directly contacted with the external diameter of tubular reactor, but it is isolated in the internal diameter of the several hot heat-transfer pipe returning to earth's surface, to draw back via (in Figure 22 in 13 and 22 16) stream, for being reclaimed by the mineral of demineralization unit (DMIN)。Key difference between Figure 22 and previous Figure 21 is the gas using and discharging latent heat through adiabatic compression in the tubular reactor isolated with geothermal reservoir and working heat transfer fluids。Bottom hole temperature (BHT) can exceed that 200 DEG C and pressure are more than 500psig (3,549kPa)。
Figure 23 highlights one or more tubular reactor and thermally heat pipe use in cement sleeve pipe。It is important to note that the sleeve pipe of cement serves as fabulous insulator because reducing heat loss completely。
Shown in Figure 22 7 one (multiple) hot heat-transfer pipe can carry out pigging with the lysotype wiper never returning original state。Plastics/rubber will depolymerization and As time goes on dissolve wiper in heat pipe part。Thus, once wiper is injected in ReactWell thermally heat pipe just never returns original state, because it dissolves due to high temperature and high pressure。
Embodiment
This document describes that embodiment and using method are as instructing those skilled in the art to use the basis of the present invention in any suitable manner。These embodiments disclosed herein are not construed to restrictive。
Embodiment 1
One embodiment of test system can include the reactor of bench top scale form, and this reactor is made up of larger-diameter pipe, and this pipe contains a pump circulation, oil/gas/water separator, a tubular reactor and auxiliary temperature and pressure sensing instruments。Right angle setting and bottom (bottom outlet) are placed in heater by this reactor。Heater is used for simulating geotemperature source。The circulation of effluent pump will be cooled down and be recirculated back to injection pump and be used for recirculation in pump closed circuit by condenser。Tubular reactor source case, by the water containing the organic material containing selection type, wherein may select and adds catalyst。The water being loaded with biomass is injected in the annular space of reactor by tubular reactor, and this is loaded with the water of biomass and reacts in down-hole and flow in the sample room with in-line analyzer。Pump cycle bleeder will use Back pressure control valve control。Tubular reactor discharge will use Back pressure control valve control。
Embodiment 2
One embodiment of test system is initially at stock (inventory) fixed amount deionized water (DI) in tubular reactor and pump circulation, starts the circulation on pump circulates。It is then turn on heater, starts condenser cooling fluid stream, and correspondingly regulate。Once as determined pump circulating temperature and pressure stability according to temperature and pressure detecting instrument/indicator, just start injection aqueous organic material in a tubular reactor。It is complete once aqueous organic material injects, it is known that the DI of amount will rinse tubular reactor。After flushing, the outflow DI of tubular reactor is recycled to starting in entrance。It is then turned off heater。Once the heat-transfer fluid temperature in pump blood circulation reaches ambient temperature, just disconnect tubular reactor injection pump。It is then turned off pump circulation injection pump and condenser cooling fluid。Before opening any chamber, vessel, reactor, pipeline (piping) or tubing (tubing), this desk-top equipment should be decompressed to environmental condition。
Embodiment 3
One embodiment of test system is initially at stock's fixed amount deionized water (DI) in tubular reactor and pump circulation, starts the circulation on pump circulates。It is then turn on heater, starts condenser cooling fluid stream, and correspondingly regulate。Once as determined pump circulating temperature and pressure stability according to temperature and pressure detecting instrument/indicator, just start injection aqueous organic material in a tubular reactor。The outflow product of tubular reactor will be sent to oil/gas/water separator via fixed route。Water mixes by recirculation and with new organic feedstock and water。Oil and gas are analyzed。After determining that steady state test completes, it is known that the DI of amount will rinse tubular reactor。After flushing, start to make the outflow DI of tubular reactor to be recycled in entrance。It is then turned off heater。Once the heat-transfer fluid temperature in pump blood circulation reaches ambient temperature, just disconnect tubular reactor injection pump。It is then turned off pump circulation injection pump and condenser cooling fluid。Before opening any chamber, vessel, reactor, pipeline or tubing, this desk-top equipment should be decompressed to environmental condition。
Embodiment 4
One embodiment of test system include providing the heater of the exhaust temperature more than 400 DEG C, condensing unit, such as reactor described herein, oil/gas/water separator, the injection pump for pump closed circuit and the down-hole pump for the discharge of tubular reactor effluent, and relevant auxiliary temperature, pressure and flow detection instrument and instrument。This reactor is made up of larger-diameter pipe, and this pipe contains a pump circulation and a tubular reactor。This reactor right angle setting and bottom (bottom outlet) are placed in heater。Heater is used for simulating geotemperature source。Effluent pump cycles through condenser cooling and is recirculated back to injection pump, for recirculation in pump closed circuit。Tubular reactor source case contains the water of the organic material containing selection type, wherein optional interpolation catalyst。The water being loaded with biomass is injected in the annular space of reactor by tubular reactor, and this is loaded with the water of biomass and reacts in down-hole and flow in oil/water/gas separating device。The water separated will be recycled in storage tank。Oil will be sent to fuel reserve tank via fixed route。Gas will be stored, burn or be discharged in air。Pump cycle bleeder will use Back pressure control valve control。Tubular reactor discharge will use Back pressure control valve control。
Embodiment 5
One embodiment of test system is initially at stock's fixed amount deionized water (DI) in tubular reactor and pump circulation, starts the circulation on pump circulates。It is then turn on heater, starts condenser cooling fluid stream, and correspondingly regulate。Once as determined pump circulating temperature and pressure stability according to temperature and pressure detecting instrument/indicator, just start injection aqueous organic material in a tubular reactor。The outflow product of tubular reactor will be sent to oil/gas/water separator via fixed route。Water mixes by recirculation and with new organic feedstock and water。The oil separated will be sent in storage vessel via fixed route, and gas will be stored, and analyze and discharge。According to environmental legislation, gas is likely to need burning or incinerate before analysis。After completing steady state test, rinse tubular reactor with treated water。It is then turned off heater。Once the heat-transfer fluid temperature in pump blood circulation reaches ambient temperature, just disconnect tubular reactor injection pump。It is then turned off pump circulation injection pump and condenser cooling fluid。Before opening any chamber, vessel, reactor, pipeline or coiling tubing, this unit should be decompressed to environmental condition。
Embodiment 6
One embodiment of the invention has included siting analysis, at the exploratory well that subsurface boring is suitable, tubular reactor is pierced underground, sleeve pipe is installed, cementing, pressure break bottom rock, utilize hydrothermal make Rock in Well peel off thus increasing surface area, permeability and porosity, one (multiple) tubular pump circulation, for the packer (packer) of stable down-hole pipe fitting, (multiple) tubular reactor and relevant downhole detection instrument, pump and instrument。Then, organic Rankine bottoming cycle (ORC) unit is installed on the ground, make it upwards circulate pipe fitting with (multiple) ReactWell pump via pipe to connect, and upwards connect with (multiple) pump circulation injection pump and associated power equipment via pipeline。Then, (multiple) entrance of (multiple) tubular reactor is assembled in organic feedstock and other possible debirs streams of adjacent algae field。The effluent of one (multiple) tubular reactor will be delivered up to oil/gas/water separating equipment and vessel by pipe。
Embodiment 7
One embodiment of test system is initially at the treated water of stock's fixed amount in tubular reactor and pump circulation, use separately start pump startup circulation on pump circulates, and foot-operated start and force (forcing) pump blood circulation。Once temperature reaches organic Rankine bottoming cycle (ORC) target, just it is switched to direct Driver injection pump thus providing power to pump closed circuit and being delivered up by pipeline thus producing electricity。Enough condenser cooling fluid stream can be maintained, and correspondingly regulate。Cooling fluid can derive from (multiple) algae pond thus providing geothermal heating。Once as determined pump circulating temperature and pressure stability according to temperature and pressure detecting instrument/indicator, just start injection aqueous organic material in a tubular reactor。The outflow product of one (multiple) tubular reactor will be sent to oil/gas/water separator via fixed route。The water that flows out of the rich in mineral substances of heat by recirculation and mixes with the existing algae water in pond or vessel so that the algal grown property taken advantage of strengthens。The oil separated will be sent to storage vessel via fixed route。Gas (is mainly made up of carbon dioxide) will make the outflow aqueous carbonate being recycled in algae pond。When needs in (multiple) tubular reactor overhaul, first rinse it with treated water, then overhaul。When pump circulation needs to overhaul, rinse tubular reactor with treated water and make it keep online。By cut-out and overhaul organic Rankine bottoming cycle (ORC)。Tubular reactor effluent will be delivered up to cooler by pipeline, so that inside reactor maintains low temperature to stop the thermal stress owing to temperature Rapid Variable Design causes。If reactor is always done over again (totalrework), then the water that stock is treated in (multiple) tubular reactor, cuts off organic Rankine bottoming cycle (ORC) and makes it reduce pressure。Once temperature stabilization, just cut off tubular reactor pump and circulate and make it reduce pressure。Before opening any chamber, vessel, reactor, pipeline or coiling tubing, this unit should be decompressed to environmental condition and examine。
It should be noted that such as " preferably ", the term of " typically " and " generally " is not limited to the scope of the present invention for required protection or implies that some is characterized by that vital, required or even for the claimed present invention structure or function are important herein。On the contrary, these terms are only intended to replacement or the additional features of emphasizing can to use in specific embodiments of the present invention or not use。
There is provided herein the detailed description of one or more embodiment。However, it should be understood that the present invention can implement in a variety of forms。Therefore, specific details disclosed herein (even if being designated as preferred or favourable) is not construed to restrictive, and is used as the basis of claim and with acting on the representative basis instructing those skilled in the art to use the present invention in any appropriate manner。
Have described that many embodiments。It should be understood, however, that various amendment can be made when without departing from the spirit and scope of the present invention。Therefore, other embodiments include at this as the part of the present invention, and may be included in appended claims。Additionally, various embodiments described above does not imply that exclusive。Such as, " some " embodiments, " exemplary " embodiment, or " other " embodiment may be included in all or part of of " some ", " other " and " further " embodiments in the scope of the invention。
Embodiment 8
Geothermal fluid is initially injected in sleeve pipe to down-hole and injects in pipeline, be injected in the hot dry rock (HDR) of pressure break by one embodiment of the invention。This hot geothermal fluid then passes through the rock of pressure break and returns in the annular space injecting pipeline, sleeve pipe between reactor and sleeve pipe I.D., then flows to earth's surface and removes for mineral and enter pipeline by original annotation subsequently and reinject。Further, there is the second well and sleeve pipe, it provides power with the thermally heat reservori fluid flowed out to organic Rankine unit (ORC) so that this fluid remained heat before entering ORC circulation。The treated water of stock's fixed amount in the tubular pump blood circulation of reactor, uses startup pump startup circulation separately。After tubular pump blood circulation circulates, start geothermal fluid is injected down-hole。Once temperature reaches organic Rankine bottoming cycle (ORC) target, just it is switched to direct Driver injection pump thus providing power to pump closed circuit and being delivered up by pipeline thus producing electricity。The electricity produced may be from turbine and piezoelectricity/hot equipment。Correspondingly regulate ORC condenser cooling fluid stream。Cooling fluid can derive from for providing the fin fan (finfan) of geothermal heating or (multiple) algae pond。Once as determined pump circulating temperature and pressure stability by temperature and pressure detecting instrument/indicator, just begin at injection aqueous organic material in (multiple) tubular reactor。The outflow product of one (multiple) tubular reactor will be sent to oil/gas/water separator via fixed route, the downstream bio oil using the ion isolation that the voltage difference applied by (rod) under ORC electricity or piezoelectricity/thermally drives stablize unit and will be separated light fraction and heavy distillat and also the chance of offer operation downstream catalytic further。The water that flows out of the rich in mineral substances of heat by recirculation and mixes with the existing algae water in pond or vessel so that the algal grown property taken advantage of strengthens。The oil separated will be sent to storage vessel via fixed route。Gas (is mainly made up of burned carbon dioxide and methane), produced CO2For making the outflow aqueous carbonate being recycled in algae pond。When needs in (multiple) tubular reactor overhaul, first rinse it with treated water, then overhaul。When ascending pipe or flow out thermally heat reservori fluid hose need to overhaul time, rinse tubular reactor with treated water and make it keep online。Cut off and isolate organic Rankine bottoming cycle (ORC)。Tubular reactor effluent will be delivered up to cooler slowly through pipeline, so that inside reactor maintains low temperature to stop the thermal stress owing to temperature Rapid Variable Design causes。If reactor is always done over again, the water that stock is treated in (multiple) tubular reactor, cuts off and isolates organic Rankine bottoming cycle (ORC) and make it reduce pressure。Once temperature stabilization, just cut off tubular reactor pump and circulate and make it reduce pressure。Opening any chamber, lift pipe, make a trip (makingtrips), before removal vessel, reactor, pipeline or coiling tubing, this unit should be decompressed to environmental condition and examine。
Embodiment 9
Geothermal fluid is initially injected in sleeve pipe to down-hole and injects in pipeline, be injected in the hot dry rock (HDR) of pressure break by one embodiment of the invention。Then the rock flowing through pressure break is returned in the annular space injecting pipeline, sleeve pipe between reactor and sleeve pipe I.D. by this hot geothermal fluid, then flows to earth's surface and removes for mineral and enter pipeline by original annotation subsequently and reinject。Further, there is the second well and sleeve pipe, it will provide power with the thermally heat reservori fluid flowed out to organic Rankine unit (ORC) so that this fluid remained heat before entering ORC circulation。The treated water of stock's fixed amount in the tubular pump blood circulation of reactor, uses startup pump startup circulation separately。After tubular pump blood circulation circulates, start geothermal fluid is injected down-hole。Once temperature reaches organic Rankine bottoming cycle (ORC) target, just it is switched to direct Driver injection pump thus providing power to pump closed circuit and being delivered up by pipeline thus producing electricity。The electricity produced may be from turbine and piezoelectricity/hot equipment。Correspondingly regulate ORC condenser cooling fluid stream。Cooling fluid can derive from for providing the fin fan of geothermal heating or (multiple) algae pond。Once as determined pump circulating temperature and pressure stability by temperature and pressure detecting instrument/indicator, just begin at injection aqueous organic material in (multiple) tubular reactor。The outflow product of one (multiple) tubular reactor will be sent to oil/gas/water separator via fixed route, the downstream bio oil using the ion isolation that the voltage difference applied by (rod) under ORC electricity or piezoelectricity/thermally drives stablize unit and will be separated light fraction and heavy distillat and also the chance of offer operation downstream catalytic further。The water that flows out of the rich in mineral substances of heat by recirculation and mixes with the existing algae water in pond or vessel so that the algal grown property taken advantage of strengthens。The oil separated will be sent to storage vessel via fixed route。Gas (is mainly made up of burned carbon dioxide and methane), produced CO2For making the outflow aqueous carbonate being recycled in algae pond。When needs in (multiple) tubular reactor overhaul, first rinse it with treated water, then overhaul。When ascending pipe or flow out thermally heat reservori fluid hose need to overhaul time, rinse tubular reactor with treated water and make it keep online。Cut off and isolate organic Rankine bottoming cycle (ORC)。Tubular reactor effluent will be delivered up to cooler slowly through pipeline, so that inside reactor maintains low temperature to stop the thermal stress owing to temperature Rapid Variable Design causes。If reactor is always done over again, the water that stock is treated in (multiple) tubular reactor, cuts off and isolates organic Rankine bottoming cycle (ORC) and make it reduce pressure。Once temperature stabilization, just cut off tubular reactor pump and circulate and make it reduce pressure。Opening any chamber, lift pipe, make a trip (makingtrips), before removal vessel, reactor, pipeline or coiling tubing, this unit should be decompressed to environmental condition and examine。
Embodiment 10
One embodiment of the invention is initially in sleeve pipe stock's heat-transfer fluid, and this heat-transfer fluid is not exposed to described hot dry rock or process。Then, water is injected into outside sleeve pipe to down-hole and injects in pipeline, be injected in the hot dry rock (HDR) of pressure break。Then this water will flow through the rock of pressure break and enter sleeve pipe, flow through heat pipe internal diameter and flow to earth's surface for mineral removing and enter pipeline by original annotation subsequently and reinject。Further, there is the 3rd drilling well, it will provide power to organic Rankine unit (ORC)。Then the treated water of stock's fixed amount in reactor and pump circulate, the circulation on pump circulates of the use startup pump startup separately, and foot-operated startup and force (forcing) pump blood circulation。Once temperature reaches organic Rankine bottoming cycle (ORC) target, just it is switched to direct Driver injection pump thus providing power to pump closed circuit and being delivered up by pipeline thus producing electricity。Enough condenser cooling fluid stream can be maintained, and correspondingly regulate。Cooling fluid can derive from (multiple) algae pond for providing geothermal heating。Once as determined pump circulating temperature and pressure stability by temperature and pressure detecting instrument/indicator, just begin at injection aqueous organic material in (multiple) tubular reactor。The outflow product of one (multiple) tubular reactor will be sent to oil/gas/water separator via fixed route。The water that flows out of the rich in mineral substances of heat by recirculation and mixes with the existing algae water in pond or vessel so that the algal grown property taken advantage of strengthens。The oil separated will be sent to storage vessel via fixed route。Gas (is mainly made up of carbon dioxide) will make the outflow aqueous carbonate being recycled in algae pond。When needs in (multiple) tubular reactor overhaul, first rinse it with treated water, then overhaul。When pump circulation needs to overhaul, rinse tubular reactor with treated water and make it keep online。Cut off organic Rankine bottoming cycle (ORC) and overhaul。Tubular reactor effluent will be delivered up to cooler by pipeline, so that inside reactor maintains low temperature to stop the thermal stress owing to temperature Rapid Variable Design causes。If reactor is always done over again, the water that stock is treated in (multiple) tubular reactor, cuts off organic Rankine bottoming cycle (ORC) and makes it reduce pressure。Once temperature stabilization, just cut off tubular reactor pump and circulate and make it reduce pressure。Before opening any chamber, vessel, reactor, pipeline or coiling tubing, this unit should be decompressed to environmental condition and examine。
Embodiment 11
One embodiment of the invention is initially in sleeve pipe stock's heat-transfer fluid, and this heat-transfer fluid is not exposed to described hot dry rock or process。Then, water is injected into outside sleeve pipe to down-hole and injects in pipeline, be injected in the hot dry rock (HDR) of pressure break。Then the rock flowing through pressure break is entered sleeve pipe by this water, and stream is removed to earth's surface for mineral and entered pipeline by original annotation subsequently and reinjects。Further, there is the 3rd drilling well, it will provide power to organic Rankine unit (ORC)。Then the treated water of stock's fixed amount in reactor and pump circulate, uses the startup pump startup separated circulation on pump circulates, starts stirring rod stirring, and ride startup and force (forcing) pump blood circulation。Once temperature reaches organic Rankine bottoming cycle (ORC) target, just it is switched to direct Driver injection pump thus providing power to pump closed circuit and being delivered up by pipeline thus producing electricity。Enough condenser cooling fluid stream can be maintained, and correspondingly regulate。Cooling fluid can derive from (multiple) algae pond for providing geothermal heating。Once as determined pump circulating temperature and pressure stability by temperature and pressure detecting instrument/indicator, just begin at injection aqueous organic material in (multiple) tubular reactor。The outflow product of one (multiple) tubular reactor will be sent to oil/gas/water separator via fixed route。The water that flows out of the rich in mineral substances of heat by recirculation and mixes with the existing algae water in pond or vessel so that the algal grown property taken advantage of strengthens。The oil separated will be sent to storage vessel via fixed route。Gas (is mainly made up of carbon dioxide) will make the outflow aqueous carbonate being recycled in algae pond。When needs in (multiple) tubular reactor overhaul, first rinse it with treated water, then overhaul。When pump circulation needs to overhaul, rinse tubular reactor with treated water and make it keep online。Cut off organic Rankine bottoming cycle (ORC) and overhaul。Tubular reactor effluent will be delivered up to cooler by pipeline, so that inside reactor maintains low temperature to stop the thermal stress owing to temperature Rapid Variable Design causes。If reactor is always done over again, the water that stock is treated in (multiple) tubular reactor, cuts off organic Rankine bottoming cycle (ORC) and makes it reduce pressure。Once temperature stabilization, just cut off the circulation of tubular reactor pump, disconnect stirring rod and reduce pressure。Before opening any chamber, vessel, reactor, pipeline or coiling tubing, this unit should be decompressed to environmental condition and examine。
Embodiment 12
One embodiment of the invention is initially in sleeve pipe stock's heat-transfer fluid, and this heat-transfer fluid is not exposed to described hot dry rock or process, and containing pressure heat/piezoelectric particles thus produce electric current and heat when being subject to hydraulic coupling。Then, injecting water into down-hole, this water is entered in sleeve pipe by the rock of pressure break, and arrives earth's surface and remove for mineral and enter pipeline by original annotation subsequently and reinject。Further, there is the 3rd drilling well, it will provide power to organic Rankine unit (ORC)。Then the treated water of stock's fixed amount in reactor and pump circulate, uses the startup pump startup separated circulation on pump circulates, starts stirring rod stirring, and ride startup and force (forcing) pump blood circulation。Once temperature reaches organic Rankine bottoming cycle (ORC) target, just it is switched to direct Driver injection pump thus providing power to pump closed circuit and being delivered up by pipeline thus producing electricity。Enough condenser cooling fluid stream can be maintained, and correspondingly regulate。Cooling fluid can derive from (multiple) algae pond for providing geothermal heating。Once as determined pump circulating temperature and pressure stability by temperature and pressure detecting instrument/indicator, just begin at injection aqueous organic material in (multiple) tubular reactor。The outflow product of one (multiple) tubular reactor will be sent to oil/gas/water separator via fixed route。The water that flows out of the rich in mineral substances of heat by recirculation and mixes with the existing algae water in pond or vessel so that the algal grown property taken advantage of strengthens。The oil separated will be sent to storage vessel via fixed route。Before shipping bio oil/crude oil is carried out post-treatment, make ReactWell be separated into light ends, distillation fraction and heavy end。Stable by using underground geothermal density and ion isolation unit to realize oil, described underground geothermal density and ion isolation unit use underground heat, are bridged by BADIRE and the thermograde due to the detached dowel of underground within and drive Density Separation and ion isolation separating the piezoelectric bar producing voltage drop on fluid。Thus, this post uses geothermal energy to be used for heating and for ion isolation process。Use independent Density Separation not " economical and effective ", because (currently the practice in yellow grease case carries out slower in winter in the restriction of time, and carry out comparatively fast in summer) but, ion isolation is also used for the separation process accelerating generally to be driven by the voltage applied。Gas (is mainly made up of carbon dioxide) will make the outflow aqueous carbonate being recycled in algae pond。When needs in (multiple) tubular reactor overhaul, first rinse it with treated water, then overhaul。When pump circulation needs to overhaul, rinse tubular reactor with treated water and make it keep online。Cut off organic Rankine bottoming cycle (ORC) and overhaul。Tubular reactor effluent will be delivered up to cooler by pipeline, so that inside reactor maintains low temperature to stop the thermal stress owing to temperature Rapid Variable Design causes。If reactor is always done over again, the water that stock is treated in (multiple) tubular reactor, cuts off organic Rankine bottoming cycle (ORC) and makes it reduce pressure。Once temperature stabilization, just cut off the circulation of tubular reactor pump, disconnect stirring rod and reduce pressure。Before opening any chamber, vessel, reactor, pipeline or coiling tubing, this unit should be decompressed to environmental condition and examine。
Embodiment 13
One embodiment of the invention is initially in sleeve pipe stock's heat-transfer fluid, and this heat-transfer fluid is not exposed to described hot dry rock or process, and containing pressure heat/piezoelectric particles thus produce electric current and heat when being subject to hydraulic coupling。Then, injecting water into down-hole, this water is entered in sleeve pipe by the rock of pressure break, and arrives earth's surface and remove for mineral and enter pipeline by original annotation subsequently and reinject。Further, there is the 3rd drilling well, it will provide power to organic Rankine unit (ORC)。Then the treated water of stock's fixed amount in reactor and pump circulate, uses the startup pump startup separated circulation on pump circulates, starts stirring rod stirring, and ride startup and force (forcing) pump blood circulation。Once temperature reaches organic Rankine bottoming cycle (ORC) target, just it is switched to direct Driver injection pump thus providing power to pump closed circuit and being delivered up by pipeline thus producing electricity。Enough condenser cooling fluid stream can be maintained, and correspondingly regulate。Cooling fluid can derive from (multiple) algae pond for providing geothermal heating。Once as determined pump circulating temperature and pressure stability by temperature and pressure detecting instrument/indicator, just begin at injection aqueous organic material in (multiple) tubular reactor。The outflow product of one (multiple) tubular reactor will be sent to oil/gas/water separator via fixed route。The water that flows out of the rich in mineral substances of heat by recirculation and mixes with the existing algae water in pond or vessel so that the algal grown property taken advantage of strengthens。The oil separated will be sent to storage vessel via fixed route。Gas (is mainly made up of carbon dioxide) will make the outflow aqueous carbonate being recycled in algae pond。When needs in (multiple) tubular reactor overhaul, first rinse it with treated water, then overhaul。When pump circulation needs to overhaul, rinse tubular reactor with treated water and make it keep online。Cut off organic Rankine bottoming cycle (ORC) and overhaul。Tubular reactor effluent will be delivered up to cooler by pipeline, so that inside reactor maintains low temperature to stop the thermal stress owing to temperature Rapid Variable Design causes。If reactor is always done over again, the water that stock is treated in (multiple) tubular reactor, cuts off organic Rankine bottoming cycle (ORC) and makes it reduce pressure。Once temperature stabilization, just cut off the circulation of tubular reactor pump, disconnect stirring rod and reduce pressure。Before opening any chamber, vessel, reactor, pipeline or coiling tubing, this unit should be decompressed to environmental condition and examine。

Claims (33)

1. it is used in the closed circuit subsurface reactor the fuel making process manufacturing fuel from organic material, comprising:
Organic material is injected the first conduit of underground；
Second conduit of organic material after the reaction that collection is produced by described subsurface reactor；
Extract the heat exchanger being ready to use in the heat that power is provided to the equipment used in described fuel making process。
2. reactor according to claim 1, it farther includes the converting heat from described heat exchanger is become energy thus provide the organic Rankine bottoming cycle of power to the equipment used in described fuel making process。
3. reactor according to claim 1, the equipment used in wherein said fuel making process is directly driven by the equipment extracting energy from described heat exchanger。
4. reactor according to claim 1, wherein said equipment includes pump。
5. reactor according to claim 4, wherein said pump makes heat-exchange fluid circulate so that reaction zone maintains temperature required。
6. subsurface reactor according to claim 1, wherein said organic material is biomass。
7. subsurface reactor according to claim 6, wherein said biomass are algae。
8. subsurface reactor according to claim 1, wherein said organic material is polymer。
9. subsurface reactor according to claim 1, wherein said organic material is solid waste。
10. subsurface reactor according to claim 1, wherein said organic material is reacted by liquefaction。
11. subsurface reactor according to claim 1, wherein said organic material is reacted by thermal chemical reaction。
12. subsurface reactor according to claim 1, wherein said organic material is reacted by water-heat process。
13. subsurface reactor according to claim 1, wherein said second conduit is in described first conduit。
14. subsurface reactor according to claim 13, the bottom of wherein said first conduit is Guan Bi, and the bottom of described second conduit is unlimited。
15. subsurface reactor according to claim 13, wherein said first conduit is deeper than described second conduit in underground。
16. subsurface reactor according to claim 13, its sleeve pipe farther including to encapsulate described first conduit and described second conduit。
17. subsurface reactor according to claim 16, wherein said sleeve pipe is at least equally deep with described first conduit。
18. subsurface reactor according to claim 16, wherein said sleeve pipe does not have described first conduit deep。
19. subsurface reactor according to claim 18, it farther includes the filter screen of the degree of depth down to described first conduit。
20. subsurface reactor according to claim 17, wherein said sleeve pipe is insulator。
21. subsurface reactor according to claim 20, wherein said insulator is cement。
22. subsurface reactor according to claim 16, it farther includes at least one heat-transfer matcrial can pass through the 3rd conduit of its pumping。
23. subsurface reactor according to claim 22, wherein said heat-transfer matcrial is water。
24. subsurface reactor according to claim 23, it farther includes to separate the oil of the product effluent of described reactor, gas, water separator。
25. subsurface reactor according to claim 24, wherein said separator is on the ground。
26. subsurface reactor according to claim 24, wherein said separator is at subsurface。
27. subsurface reactor according to claim 24, a part for wherein said product is stored。
28. subsurface reactor according to claim 24, a part for wherein said product is used as to make the food of biomass growth。
29. subsurface reactor according to claim 24, a part for wherein said product is used for producing electricity。
30. subsurface reactor according to claim 22, wherein produce electricity via heat exchange。
31. subsurface reactor according to claim 1, the first conduit described at least a part of which is bending。
32. subsurface reactor according to claim 1, the first conduit described at least a part of which is to tilt。
33. subsurface reactor according to claim 32, the first conduit bifurcated described at least a part of which。
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