CN103601857A - Preparation method of emulsion-type thickening agent - Google Patents
Preparation method of emulsion-type thickening agent Download PDFInfo
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- CN103601857A CN103601857A CN201310624167.0A CN201310624167A CN103601857A CN 103601857 A CN103601857 A CN 103601857A CN 201310624167 A CN201310624167 A CN 201310624167A CN 103601857 A CN103601857 A CN 103601857A
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Abstract
The invention relates to a preparation method of an emulsion-type thickening agent. The preparation method comprises the following steps of raw material pretreatment, initiator solution preparation, polymerization and other follow-up treatment processes. Compared with methods in the prior art, the preparation method utilizes a starved polymerization technology to prepare the emulsion-type thickening agent so that copolymer structure homogeneity is realized; the ammonia ester bond has hydrolysis resistance superior to that of an ester bond and the appropriate temperature and initiator are selected so that the obtained emulsion-type thickening agent has good thickening properties and stability; the emulsion-type thickening agent is a novel aqueous thickening agent and has characteristics of environmental friendliness, good safety and excellent performances; and the preparation method has simple processes and can be realized easily.
Description
Technical field
The present invention relates to field of fine chemical, particularly a kind of preparation method who mainly utilizes the emulsion-type thickening agent of urethane associating monomer modification.
Background technology
Due to increasingly sharpening of environmental issue, people's environmental consciousness also strengthens day by day, and the needed auxiliary agents of industry such as weaving, leather, packing, coating, ink are deionization water-based more and more.And in water-based system, mostly need water-based thickener to carry out thickening, the kind of thickening material is more in the market, there is inorganic thickening agent if wilkinite, attapulgite etc., natural organic thickening agent are if treated starch, modified-cellulose etc., organic synthesis thickening material are as emulsion-type thickening agent, polyurethane thickener etc., wherein, emulsion-type thickening agent because of its use simple, thickening effectiveness better, stable performance, price economy, in the thickening of water-based system, application is very extensive.
Summary of the invention
For existing research, the object of this invention is to provide the preparation method of the emulsion-type thickening agent of a kind of urethane associating monomer modification.Thickening material thickening effectiveness that the method obtains is good, storage-stable.
Polyreaction in the present invention is a random copolymerization reaction, and because thickening material is a kind of Additives Products, the consumption in application formula is very little, so the polymerization process of thickening material must have good homogeneity; Due to the problem that the reactive behavior of different monomers is different, the polymerization activity of the large monomer that particularly associates is poor, therefore have reactivity ratio, in order to guarantee that the macromolecular structure of product has good homogeneity, therefore take effects of hunger, control the polymerization velocity of the rate of addition≤monomer of monomer, the monomer that assurance adds can both participate in polyreaction in moment, and the survival rate of the product that so can not cause poor activity in polymerization system is more and more higher.
The object of the invention is to be achieved through the following technical solutions:
A preparation method for emulsion-type thickening agent, comprises the steps:
(1) pre-treatment of raw material: methacrylic acid, acrylate are added and mix in container A that to obtain mixing raw material standby, emulsifying agent A, associating monomer and deionized water are added in container B and be uniformly dissolved, add while stirring mixing raw material standby in container A, after adding, with the speed of 100rpm, stir 0.5～1 hour, make add in constant pressure funnel after emulsification mixing raw material in batches standby;
(2) preparation initiator solution: initiator is dissolved in a certain amount of deionized water, and then the speed with 250～300rpm stirs 0.5～1 hour on magnetic stirring apparatus, then adds in constant pressure funnel standby in batches;
(3) preparation aftertreatment fluid: initiator is dissolved in a certain amount of deionized water to the speed with 250～300rpm on magnetic stirring apparatus and stirs 0.5～1 hour, then add in constant pressure funnel standby;
(4) polyreaction: add a certain amount of deionized water in reaction vessel, add successively while stirring emulsifying agent B and initiator, and be warming up to 80～90 ℃, in 5～10 minutes backward reaction vessels, at the uniform velocity drip emulsification mixing raw material standby in the middle constant pressure funnel of step (1) and the initiator solution in step (2) simultaneously, and dropwised in 2.5-3 hour;
(5) after dropwising, insulation 30-60 minute;
(6) drip standby aftertreatment fluid in step (3), after adding, be cooled to below 40 ℃;
(7) detect qualified rear discharging;
Wherein, the ratio of quality and the number of copies between described methacrylic acid, acrylate and associating monomer is: 25～45:50～70:1～8.
Preferably, described associating monomer is one or more the mixture in BA-15 (the large monomer of urethane of hydroxyethyl methylacrylate-IPDI-AEO-15), BA-25 (the large monomer of urethane of hydroxyethyl methylacrylate-IPDI-AEO-25), BA-40 (the large monomer of urethane of hydroxyethyl methylacrylate-IPDI-AEO-40) etc.
Preferably, described acrylate is one or more in ethyl propenoate and methyl acrylate, butyl acrylate and Isooctyl acrylate monomer.
Preferably, described emulsifying agent A is the mixture of NP-9, CO-436.
Preferably, described emulsifying agent B is the mixture of K-12, AES and NP-9.
Preferably, described initiator is the persulfuric acid salts such as ammonium persulphate, Sodium Persulfate, Potassium Persulphate.
Preferably, in step (1), the interpolation speed of mixing raw material described in container A is 10～30g/min.
Preferably, in step (2), the quality percentage composition of initiator described in initiator solution is 0.2%;
In step (3), the quality percentage composition of initiator described in aftertreatment fluid is 0.2%.
Preferably, in step (4), the ratio of quality and the number of copies of described emulsifying agent B and described initiator is 6～12:0.05～0.1.
Preferably, in step (4), the rate of addition of emulsification mixing raw material is 2.5～4.0g/min, and the rate of addition of initiator solution is 0.25～0.35ml/min.
Compared with prior art, thickening material prepared by the preparation method of emulsion-type thickening agent of the present invention adopts hungry polymerization technique, has solved the homogeneity of copolymer structure; Because ammonia ester bond has better anti-hydrolytic performance than ester bond, and by selecting suitable temperature and initiator, so the thickening material product obtaining has good thickening and stability; Thickening material prepared by the present invention is novel aqueous thickening material, has the features such as environmental protection, safety, excellent performance, the kind of domestic thickening material product that it is perfect; Manufacturing process of the present invention is simple, is easy to realize.
Embodiment
Embodiment 1:
Composition of raw materials: methacrylic acid: 100g, ethyl propenoate: 120g, butyl acrylate: 20g, Isooctyl acrylate monomer: 15g, deionized water: 250g+50g+25g+300g, ammonium persulphate: 0.1g+0.05g+0.05g, emulsifying agent A (NP-9:8g, CO-436:7g), BA-40:5g, BA-25:10g, emulsifying agent B (K-12:1g, NP-9:4g, AES:4g).All raw materials in the present invention are commercially available.
Preparation process is as follows:
1, the pre-treatment of raw material: by 100g methacrylic acid, 120g ethyl propenoate, 20g butyl acrylate, 15g Isooctyl acrylate monomer add in 500ml volumetric flask, mix standby; 8g NP-9,7gCO-436,5g BA-40,10g BD-25 and 250g deionized water are added in 1000ml four-hole boiling flask and be uniformly dissolved, add while stirring mixing raw material standby in 500ml volumetric flask, and added in 11 minutes, after adding, with the speed of 100rpm, stir 0.5 hour, make add in constant pressure funnel after emulsification mixing raw material in batches standby; In the present embodiment, the interpolation speed of mixing raw material described in container A is 10～30g/min;
2, preparation initiator solution: 0.1g ammonium persulphate is dissolved in 50g deionized water to the speed with 250rpm on magnetic stirring apparatus and stirs 0.5 hour, then add in constant pressure funnel standby in batches;
3, preparation aftertreatment fluid: 0.05g ammonium persulphate is dissolved in 25g deionized water to the speed with 250rpm on magnetic stirring apparatus and stirs 0.5 hour, then add in constant pressure funnel standby;
4, polyreaction: add 300g deionized water in 1000ml four-hole boiling flask, add successively while stirring 1g K-12,4g NP-9,4g AES, 0.05g ammonium persulphate, and be warming up to 85 ℃, in 6 minutes backward reaction vessels, at the uniform velocity drip emulsification mixing raw material standby in the middle constant pressure funnel of step (1) and the initiator solution in step (2) simultaneously, and dropwised at 2.6 hours; The ratio of quality and the number of copies of the B of emulsifying agent described in this step and described initiator is 9:0.05; The rate of addition of emulsification mixing raw material is 3.43g/min, and the rate of addition of initiator solution is 0.32ml/min;
5,, after dropwising, be incubated 30 minutes;
6, drip standby aftertreatment fluid in step (3), after adding, be cooled to below 40 ℃;
7, detect, outward appearance is white emulsion, and solid content is 29.7%, pH=4.0; Qualified, discharging obtains described thickening material.
In the present embodiment, finished product transformation efficiency is 99.7%, (wherein water thickening effectiveness condition determination is 25 ℃ to water thickening effectiveness 6900mPas, method, for add the thickening material sample in 10g the present embodiment in 190g water, then regulates pH=8～9 to measure viscosity afterwards with AMP-95).
Embodiment 2:
Composition of raw materials: methacrylic acid: 85g, ethyl propenoate: 145g, butyl acrylate: 15g, Isooctyl acrylate monomer: 10g, deionized water: 250g+50g+25g+300g, ammonium persulphate: 0.1g+0.05g+0.1g, emulsifying agent A (NP-9:6g, CO-436:6g), BA-40:8g, BA-15:6g, emulsifying agent B (K-12:1g, NP-9:4g, AES:4g)
Preparation process is as follows:
1, the pre-treatment of raw material: by 85g methacrylic acid, 145g ethyl propenoate, 15g butyl acrylate, 10g Isooctyl acrylate monomer add in 500ml volumetric flask, mix standby; 6g NP-9,6gCO-436,8g BA-40,6g BD-15 and 250g deionized water are added in 1000ml four-hole boiling flask and be uniformly dissolved, add while stirring mixing raw material standby in 500ml volumetric flask, and added in 10 minutes, after adding, with the speed of 100rpm, stir 0.5 hour, make add in constant pressure funnel after emulsification mixing raw material in batches standby; In the present embodiment, the interpolation speed of mixing raw material described in container A is 25.5g/min;
2, preparation initiator solution: 0.1g ammonium persulphate is dissolved in 50g deionized water to the speed with 250rpm on magnetic stirring apparatus and stirs 0.5 hour, then add in constant pressure funnel standby in batches;
3, preparation aftertreatment fluid: 0.1g ammonium persulphate is dissolved in 25g deionized water to the speed with 250rpm on magnetic stirring apparatus and stirs 0.5 hour, then add in constant pressure funnel standby;
4, polyreaction: add 300g deionized water in 1000ml four-hole boiling flask, add successively while stirring 1g K-12,2.5g NP-9,2.5g AES, 0.05g ammonium persulphate, and be warming up to 85 ℃, in 7 minutes backward reaction vessels, at the uniform velocity drip emulsification mixing raw material standby in the middle constant pressure funnel of step (1) and the initiator solution in step (2) simultaneously, and dropwised at 3 hours; The ratio of quality and the number of copies of the B of emulsifying agent described in this step and described initiator is 6:0.05; The rate of addition of emulsification mixing raw material is 2.95g/min, and the rate of addition of initiator solution is 0.27ml/min;
5,, after dropwising, be incubated 30 minutes;
6, drip standby aftertreatment fluid in step (3), after adding, be cooled to below 40 ℃;
7, detect, outward appearance is white emulsion, and solid content is 29.7%, pH=4.0; Qualified, discharging obtains described thickening material.
In the present embodiment, finished product transformation efficiency is 98.5%, (wherein water thickening effectiveness condition determination is 25 ℃ to water thickening effectiveness 8600mPas, method, for add the thickening material sample in 10g the present embodiment in 190g water, then regulates pH=8～9 to measure viscosity afterwards with AMP-95).
Embodiment 3:
Composition of raw materials: methacrylic acid: 95g, ethyl propenoate: 135g, butyl acrylate: 10g, Isooctyl acrylate monomer: 15g, deionized water: 250g+50g+25g+300g, ammonium persulphate: 0.1g+0.1g+0.05g, emulsifying agent A (NP-9:5g, CO-436:7g), BA-40:15g, emulsifying agent B (K-12:1g, NP-9:4g, AES:4g)
Preparation process is as follows:
1, the pre-treatment of raw material: by 95g methacrylic acid, 135g ethyl propenoate, 10g butyl acrylate, 15g Isooctyl acrylate monomer add in 500ml volumetric flask, mix standby; 5g NP-9,7gCO-436,15g BA-40 and 250g deionized water are added in 1000ml four-hole boiling flask and be uniformly dissolved, add while stirring mixing raw material standby in 500ml volumetric flask, and added in 10 minutes, after adding, with the speed of 100rpm, stir 0.5 hour, make add in constant pressure funnel after emulsification mixing raw material in batches standby; In the present embodiment, the interpolation speed of mixing raw material described in container A is 25.5g/min;
2, preparation initiator solution: 0.1g ammonium persulphate is dissolved in 50g deionized water to the speed with 250rpm on magnetic stirring apparatus and stirs 0.8 hour, then add in constant pressure funnel standby in batches;
3, preparation aftertreatment fluid: 0.05g ammonium persulphate is dissolved in 25g deionized water to the speed with 250rpm on magnetic stirring apparatus and stirs 0.5 hour, then add in constant pressure funnel standby;
4, polyreaction: add 300g deionized water in 1000ml four-hole boiling flask, add successively while stirring 2g K-12,5g NP-9,5g AES, 0.1g ammonium persulphate, and be warming up to 85 ℃, in 6 minutes backward reaction vessels, at the uniform velocity drip emulsification mixing raw material standby in the middle constant pressure funnel of step (1) and the initiator solution in step (2) simultaneously, and dropwised at 2.75 hours; The ratio of quality and the number of copies of the B of emulsifying agent described in this step and described initiator is 12:0.05; The rate of addition of emulsification mixing raw material is 3.22g/min, and the rate of addition of initiator solution is 0.30ml/min;
5,, after dropwising, be incubated 50 minutes;
6, drip standby aftertreatment fluid in step (3), after adding, be cooled to below 40 ℃;
7, detect, outward appearance is white emulsion, and solid content is 29.7%, pH=4.0; Qualified, discharging obtains described thickening material.
In the present embodiment, finished product transformation efficiency is 99.2%, (wherein water thickening effectiveness condition determination is that temperature is 25 ℃ to water thickening effectiveness 10300mPas, method, for add the thickening material sample in 10g the present embodiment in 190g water, then regulates pH=8～9 to measure viscosity afterwards with AMP-95).
The above embodiments are just in order better to explain the present invention, and it should not be construed limitation of the present invention.Those skilled in the art is according to equivalents of the present invention or be equal to the technical scheme that replacement forms, within all dropping on rights protection scope of the present invention.
Claims (10)
1. a preparation method for emulsion-type thickening agent, is characterized in that: comprise the steps:
(1) pre-treatment of raw material: methacrylic acid, acrylate are added and mix in container A that to obtain mixing raw material standby, emulsifying agent A, associating monomer and deionized water are added in container B and be uniformly dissolved, add while stirring mixing raw material standby in container A, after adding, with the speed of 100rpm, stir 0.5～1 hour, make add in constant pressure funnel after emulsification mixing raw material in batches standby;
(2) preparation initiator solution: initiator is dissolved in a certain amount of deionized water, and then the speed with 250～300rpm stirs 0.5～1 hour on magnetic stirring apparatus, then adds in constant pressure funnel standby in batches;
(3) preparation aftertreatment fluid: initiator is dissolved in a certain amount of deionized water to the speed with 250～300rpm on magnetic stirring apparatus and stirs 0.5～1 hour, then add in constant pressure funnel standby;
(4) polyreaction: add a certain amount of deionized water in reaction vessel, add successively while stirring emulsifying agent B and initiator, and be warming up to 80～90 ℃, in 5～10 minutes backward reaction vessels, at the uniform velocity drip emulsification mixing raw material standby in the middle constant pressure funnel of step (1) and the initiator solution in step (2) simultaneously, and dropwised in 2.5-3 hour;
(5) after dropwising, insulation 30-60 minute;
(6) drip standby aftertreatment fluid in step (3), after adding, be cooled to below 40 ℃;
(7) detect qualified rear discharging;
Wherein, the ratio of quality and the number of copies between described methacrylic acid, acrylate and associating monomer is: 25～45:50～70:1～8.
2. the preparation method of emulsion-type thickening agent according to claim 1, it is characterized in that, described associating monomer is one or more the mixture in BA-15 (the large monomer of urethane of hydroxyethyl methylacrylate-IPDI-AEO-15), BA-25 (the large monomer of urethane of hydroxyethyl methylacrylate-IPDI-AEO-25), BA-40 (the large monomer of urethane of hydroxyethyl methylacrylate-IPDI-AEO-40) etc.
3. the preparation method of emulsion-type thickening agent according to claim 1, is characterized in that, described acrylate is one or more in ethyl propenoate and methyl acrylate, butyl acrylate and Isooctyl acrylate monomer.
4. the preparation method of emulsion-type thickening agent according to claim 1, is characterized in that, described emulsifying agent A is the mixture of NP-9, CO-436.
5. the preparation method of emulsion-type thickening agent according to claim 1, is characterized in that, described emulsifying agent B is the mixture of K-12, AES and NP-9.
6. the preparation method of emulsion-type thickening agent according to claim 1, is characterized in that, described initiator is the persulfuric acid salts such as ammonium persulphate, Sodium Persulfate, Potassium Persulphate.
7. according to the preparation method of the emulsion-type thickening agent described in claim 1 to 6 any one, it is characterized in that, in step (1), the interpolation speed of mixing raw material described in container A is 10～30g/min.
8. according to the preparation method of the emulsion-type thickening agent described in claim 1 to 6 any one, it is characterized in that, in step (2), the quality percentage composition of initiator described in initiator solution is 0.2%;
In step (3), the quality percentage composition of initiator described in aftertreatment fluid is 0.2%.
9. according to the preparation method of the emulsion-type thickening agent described in claim 1 to 6 any one, it is characterized in that, in step (4), the ratio of quality and the number of copies of described emulsifying agent B and described initiator is 6～12:0.05～0.1.
10. the preparation method of emulsion-type thickening agent according to claim 1, is characterized in that, in step (4), the rate of addition of emulsification mixing raw material is 2.5～4.0g/min, and the rate of addition of initiator solution is 0.25～0.35ml/min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877455A (en) * | 2014-02-27 | 2015-09-02 | 真彩文具股份有限公司 | A low-viscosity antibacterial gel-ink thickening agent and a preparing method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120802A (en) * | 2010-11-19 | 2011-07-13 | 苏州博纳化学科技有限公司 | Preparation method of polyurethane macromonomer modified emulsion-type thickening agent |
| CN102120792A (en) * | 2010-11-19 | 2011-07-13 | 苏州博纳化学科技有限公司 | Preparation method of maleic anhydride-(meth)acrylic acid dispersant |
| CN102399351A (en) * | 2010-11-19 | 2012-04-04 | 苏州博纳化学科技有限公司 | Preparation method of emulsion-type thickening agent |
| CN103204968A (en) * | 2013-04-03 | 2013-07-17 | 中山职业技术学院 | High performance alkali swelling thickener and preparation method thereof |
-
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- 2013-11-22 CN CN201310624167.0A patent/CN103601857A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120802A (en) * | 2010-11-19 | 2011-07-13 | 苏州博纳化学科技有限公司 | Preparation method of polyurethane macromonomer modified emulsion-type thickening agent |
| CN102120792A (en) * | 2010-11-19 | 2011-07-13 | 苏州博纳化学科技有限公司 | Preparation method of maleic anhydride-(meth)acrylic acid dispersant |
| CN102399351A (en) * | 2010-11-19 | 2012-04-04 | 苏州博纳化学科技有限公司 | Preparation method of emulsion-type thickening agent |
| CN103204968A (en) * | 2013-04-03 | 2013-07-17 | 中山职业技术学院 | High performance alkali swelling thickener and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877455A (en) * | 2014-02-27 | 2015-09-02 | 真彩文具股份有限公司 | A low-viscosity antibacterial gel-ink thickening agent and a preparing method thereof |
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Application publication date: 20140226 |