CN103589203A - Seal primer and preparation method thereof - Google Patents
Seal primer and preparation method thereof Download PDFInfo
- Publication number
- CN103589203A CN103589203A CN201310466216.2A CN201310466216A CN103589203A CN 103589203 A CN103589203 A CN 103589203A CN 201310466216 A CN201310466216 A CN 201310466216A CN 103589203 A CN103589203 A CN 103589203A
- Authority
- CN
- China
- Prior art keywords
- parts
- hour
- add
- primer
- epoxy resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims description 8
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 13
- 239000003822 epoxy resin Substances 0.000 claims abstract description 8
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 8
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 claims abstract description 7
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012964 benzotriazole Substances 0.000 claims abstract description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 7
- 239000000194 fatty acid Substances 0.000 claims abstract description 7
- 229930195729 fatty acid Natural products 0.000 claims abstract description 7
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 7
- KOVKEDGZABFDPF-UHFFFAOYSA-N n-(triethoxysilylmethyl)aniline Chemical compound CCO[Si](OCC)(OCC)CNC1=CC=CC=C1 KOVKEDGZABFDPF-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920003180 amino resin Polymers 0.000 claims abstract description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 4
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000010977 jade Substances 0.000 claims description 6
- 239000002105 nanoparticle Substances 0.000 claims description 6
- 229920001522 polyglycol ester Polymers 0.000 claims description 6
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 claims description 3
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 3
- 229940037003 alum Drugs 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000011478 zinc gluconate Nutrition 0.000 claims description 3
- 239000011670 zinc gluconate Substances 0.000 claims description 3
- 229960000306 zinc gluconate Drugs 0.000 claims description 3
- 239000003973 paint Substances 0.000 abstract description 10
- 150000003839 salts Chemical class 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 244000028419 Styrax benzoin Species 0.000 abstract 1
- 235000000126 Styrax benzoin Nutrition 0.000 abstract 1
- 235000008411 Sumatra benzointree Nutrition 0.000 abstract 1
- 230000000845 anti-microbial effect Effects 0.000 abstract 1
- 229960002130 benzoin Drugs 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 abstract 1
- 235000019382 gum benzoic Nutrition 0.000 abstract 1
- 239000011325 microbead Substances 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 239000003513 alkali Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000010422 painting Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 206010020852 Hypertonia Diseases 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses a seal primer. The invention is characterized in that the primer is prepared from the following raw materials in parts by weight: 30-35 parts of ethyl methacrylate, 12-14 parts of butyl acrylate, 10-12 parts of hollow microbead, 0.4-0.8 part of cyclohexanone peroxide, 2.0-3.0 parts of benzotriazole, 2-3 parts of fatty acid polyethylene glycol ester, 45-50 parts of E-44 epoxy resin, 1-2 parts of anilinomethyl triethoxy silane, 3-4 parts of 1,6-hexanediol diacrylate, 1-2 parts of benzoin, 15-20 parts of amino resin, 5-10 parts of propylene glycol methyl ether acetate, 2-5 parts of polydimethylsiloxane and 3-4 parts of dispersing aid. The product can effectively resist alkalis and salts in the base layer from precipitation, has very high binding power with the elastic paint, and enhances the adhesive force between the base layer and the topcoat; the seal primer has the advantages of high water resistance, high moldproof and antimicrobial effects, high permeability and high adhesive force; and the seal primer can effectively prevent the finish coat from being corroded by soluble substances on the wall, thereby enhancing the quality of the topcoat.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of seal coat and preparation method thereof.
Background technology
Priming paint is the first layer of paint system, for improving the sticking power of finish paint, increase finish paint fullness ratio, alkali-resistivity is provided, anti-corrosion function etc. is provided, can guarantee the even absorption of finish paint simultaneously, make paint system performance best effect.Seal coat composition one is by hypertonicity epoxy resin liquid, and composition two is special curing agent, is applicable to the substrate surfaces such as concrete, timber, terrazzo, iron and steel and makes seal coat.Seal coat is attached directly in substrate, on it, be attached with middle painting, face painting, play a part to form a connecting link, good coat system does not have the interface of layer between layer and coating film, coating application requires can effectively interpenetrate between every procedure, whole coating becomes as a whole, seal coat is the first film being attached on base material, thereby the specification of quality of seal coat is very high, there are good water-fast, alkali resistance, saline and alkaline the oozing out of waterproof isolation, have good sticking power and ply adhesion.
Summary of the invention
The object of this invention is to provide a kind of good penetrability, strong adhesion, Salt And Alkali Tolerance, water-fast Eng than priming paint and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of seal coat, raw material by following weight part is made: β-dimethyl-aminoethylmethacrylate 30-35, butyl acrylate 12-14, cenosphere 10-12, cyclohexanone peroxide 0.4-0.8, benzotriazole 2.0-3.0, fatty acid polyglycol ester 2-3, E-44 epoxy resin 45-50, anilinomethyl triethoxysilane 1-2,1,6 hexanediol diacrylate 3-4, st-yrax 1-2, aminoresin 15-20,1-Methoxy-2-propyl acetate 5-10, polydimethylsiloxane 2-5, dispersing auxiliary 3-4.
Described dispersing auxiliary makes by the following method: the weight part of its each feed composition is: diatomite 200-210, nano-sized carbon 4-5, jade powder 12-13, Zinc Gluconate 2-3, xitix 1-2, pentaerythritol triacrylate 1-2, Zirconium tetrafluoride 1-2, alum 3-4, polyoxyethylene octylphenol ether 1-2, Silane coupling agent KH550 1-2; Preparation method adds diatomite in 12-15% hydrochloric acid soln and soaks 3-4 hour, takes out, and with clear water, cleans, and calcines 3-4 hour with sending in calcining furnace at 530-550 ℃, cooling, merges and grinds to form 300-400 order powder with jade; Add Zirconium tetrafluoride, nano-sized carbon, polyoxyethylene octylphenol ether to continue grinding distribution 2-3 hour, then add other remaining component to be ground to fully to disperse to obtain 300-400 order powder, obtain.
Seal coat of the present invention, by following concrete steps, made:
(1) β-dimethyl-aminoethylmethacrylate, butyl acrylate, cenosphere, cyclohexanone peroxide are added in reactor and stirred, temperature of reaction is controlled at below 40-60 ℃, stirs 0.5-1 hour;
(2) in reactor, add benzotriazole, fatty acid polyglycol ester, E-44 epoxy resin, anilinomethyl triethoxysilane, 1,6 hexanediol diacrylate again, temperature of reaction is controlled at below 70-80 ℃, stirs 0.5-1 hour;
(3) finally add all the other remaining components, mix, stir, grind, obtain the slurry of 20-40 μ m, filter and get final product.
Product of the present invention can effectively be resisted separating out of alkali salt in basic unit, has extremely strong cohesive force with elastic coating, improves the sticking power of basic unit and face painting; Water-fast, antimildew and antibacterial, seepage force, strong adhesion; Outstanding closure, alkali burnout resistance, salting-out resistance, can effectively prevent that finish paint is corroded by body of wall soluble substance, the quality that raising face is coated with.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of seal coat, by following weight part (kilogram) raw material make: β-dimethyl-aminoethylmethacrylate 30, butyl acrylate 12, cenosphere 10, cyclohexanone peroxide 0.4, benzotriazole 2, fatty acid polyglycol ester 2, E-44 epoxy resin 45, anilinomethyl triethoxysilane 1,1,6 hexanediol diacrylate 3, st-yrax 1, aminoresin 15,1-Methoxy-2-propyl acetate 5, polydimethylsiloxane 2, dispersing auxiliary 3.
Described dispersing auxiliary makes by the following method: the weight part of its each feed composition (kilogram) be: diatomite 200, nano-sized carbon 4, jade powder 12, Zinc Gluconate 2, xitix 1, pentaerythritol triacrylate 1, Zirconium tetrafluoride 1, alum 3, polyoxyethylene octylphenol ether 1, Silane coupling agent KH550 1; Preparation method adds diatomite in 12-15% hydrochloric acid soln and soaks 3-4 hour, takes out, and with clear water, cleans, and calcines 3-4 hour with sending in calcining furnace at 530-550 ℃, cooling, merges and grinds to form 300-400 order powder with jade; Add Zirconium tetrafluoride, nano-sized carbon, polyoxyethylene octylphenol ether to continue grinding distribution 2-3 hour, then add other remaining component to be ground to fully to disperse to obtain 300-400 order powder, obtain.
Seal coat of the present invention, by following concrete steps, made:
(1) β-dimethyl-aminoethylmethacrylate, butyl acrylate, cenosphere, cyclohexanone peroxide are added in reactor and stirred, temperature of reaction is controlled at below 40-60 ℃, stirs 0.5-1 hour;
(2) in reactor, add benzotriazole, fatty acid polyglycol ester, E-44 epoxy resin, anilinomethyl triethoxysilane, 1,6 hexanediol diacrylate again, temperature of reaction is controlled at below 70-80 ℃, stirs 0.5-1 hour;
(3) finally add all the other remaining components, mix, stir, grind, obtain the slurry of 20-40 μ m, filter and get final product.
Product performance index of the present invention:
1, time of drying (25 ℃): surface drying 28min, does solid work 42h
2, snappiness mm≤1
3, hardness >=2H
4, high temperature resistant (130 ℃) >=490h
5, shock-resistance 50
6, salt spray resistance (120h level) >=3
7, water tolerance (29 ± 1 ℃ of 240h): non-foaming, do not come off
8, oil resistant (90# gasoline, 56h): non-foaming, do not come off
9, alkali resistance (GB/T9755-2001): by 48 hours
10, artificial weathering ageing resistance (GB/T9755-2001): by 1200 hours.
Claims (2)
1. a seal coat, it is characterized in that, raw material by following weight part is made: β-dimethyl-aminoethylmethacrylate 30-35, butyl acrylate 12-14, cenosphere 10-12, cyclohexanone peroxide 0.4-0.8, benzotriazole 2.0-3.0, fatty acid polyglycol ester 2-3, E-44 epoxy resin 45-50, anilinomethyl triethoxysilane 1-2,1,6 hexanediol diacrylate 3-4, st-yrax 1-2, aminoresin 15-20,1-Methoxy-2-propyl acetate 5-10, polydimethylsiloxane 2-5, dispersing auxiliary 3-4;
Described dispersing auxiliary makes by the following method: the weight part of its each feed composition is: diatomite 200-210, nano-sized carbon 4-5, jade powder 12-13, Zinc Gluconate 2-3, xitix 1-2, pentaerythritol triacrylate 1-2, Zirconium tetrafluoride 1-2, alum 3-4, polyoxyethylene octylphenol ether 1-2, Silane coupling agent KH550 1-2; Preparation method adds diatomite in 12-15% hydrochloric acid soln and soaks 3-4 hour, takes out, and with clear water, cleans, and calcines 3-4 hour with sending in calcining furnace at 530-550 ℃, cooling, merges and grinds to form 300-400 order powder with jade; Add Zirconium tetrafluoride, nano-sized carbon, polyoxyethylene octylphenol ether to continue grinding distribution 2-3 hour, then add other remaining component to be ground to fully to disperse to obtain 300-400 order powder, obtain.
2. seal coat according to claim 1, is characterized in that, by following concrete steps, is made:
(1) β-dimethyl-aminoethylmethacrylate, butyl acrylate, cenosphere, cyclohexanone peroxide are added in reactor and stirred, temperature of reaction is controlled at below 40-60 ℃, stirs 0.5-1 hour;
(2) in reactor, add benzotriazole, fatty acid polyglycol ester, E-44 epoxy resin, anilinomethyl triethoxysilane, 1,6 hexanediol diacrylate again, temperature of reaction is controlled at below 70-80 ℃, stirs 0.5-1 hour;
(3) finally add all the other remaining components, mix, stir, grind, obtain the slurry of 20-40 μ m, filter and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310466216.2A CN103589203A (en) | 2013-10-09 | 2013-10-09 | Seal primer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310466216.2A CN103589203A (en) | 2013-10-09 | 2013-10-09 | Seal primer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103589203A true CN103589203A (en) | 2014-02-19 |
Family
ID=50079536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310466216.2A Pending CN103589203A (en) | 2013-10-09 | 2013-10-09 | Seal primer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103589203A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106085083A (en) * | 2016-06-23 | 2016-11-09 | 苏州吉人高新材料股份有限公司 | A kind of aqueous composite paint of environmental protection and preparation method thereof |
| CN112778875A (en) * | 2020-12-31 | 2021-05-11 | 滁州圣好材料科技有限公司 | Water-based alkali-resistant primer for exterior wall and manufacturing method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101899248A (en) * | 2010-07-05 | 2010-12-01 | 江门市制漆厂有限公司 | Environment-friendly rust inhibiting primer |
| CN102363687A (en) * | 2011-08-29 | 2012-02-29 | 大连市金州金河化工建材厂 | Seal coat |
| CN102408809A (en) * | 2011-08-29 | 2012-04-11 | 大连市金州金河化工建材厂 | High-efficiency primer sealer paint |
-
2013
- 2013-10-09 CN CN201310466216.2A patent/CN103589203A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101899248A (en) * | 2010-07-05 | 2010-12-01 | 江门市制漆厂有限公司 | Environment-friendly rust inhibiting primer |
| CN102363687A (en) * | 2011-08-29 | 2012-02-29 | 大连市金州金河化工建材厂 | Seal coat |
| CN102408809A (en) * | 2011-08-29 | 2012-04-11 | 大连市金州金河化工建材厂 | High-efficiency primer sealer paint |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106085083A (en) * | 2016-06-23 | 2016-11-09 | 苏州吉人高新材料股份有限公司 | A kind of aqueous composite paint of environmental protection and preparation method thereof |
| CN106085083B (en) * | 2016-06-23 | 2018-07-13 | 苏州吉人高新材料股份有限公司 | A kind of aqueous composite paint and preparation method thereof of environmental protection |
| CN112778875A (en) * | 2020-12-31 | 2021-05-11 | 滁州圣好材料科技有限公司 | Water-based alkali-resistant primer for exterior wall and manufacturing method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101974273B (en) | Exterior wall coating and preparation method thereof | |
| CN108003713B (en) | Water-based marking paint and preparation method and construction method thereof | |
| KR20140101861A (en) | Inorganic dry powder building coating and preparing method therefor | |
| CN109627890B (en) | Fluorine-silicon modified water-based marking paint | |
| CN104098996B (en) | A kind of nano compound polyurethane aircraft coating and preparation method thereof | |
| CN1821323A (en) | Water dispersion chromium-free single component silicon steel insulation paint and its preparing method | |
| CN105482027A (en) | Acrylic acid modified polysiloxane resin and application thereof to self-stratifying coating | |
| CN103555121B (en) | A kind of aqueous automobile chassis corrosion resistant coating and preparation method thereof | |
| CN103602114A (en) | Wear-resistant pressure-resistant epoxy paint and preparation method thereof | |
| CN109868015A (en) | A kind of organo-mineral complexing is aluminum paint, aqueous and preparation method thereof | |
| CN109504266A (en) | A kind of quick-drying no-solvent polyurethane paint and preparation method thereof modified based on bio-based polymers | |
| CN103602213A (en) | Anticorrosive luster primer and preparation method thereof | |
| CN101519547B (en) | Aqueous double-component atomic ash and application thereof | |
| CN103602116A (en) | High corrosion resistant epoxy paint with high solid content and preparation method thereof | |
| CN103589203A (en) | Seal primer and preparation method thereof | |
| CN101985530B (en) | Water-based inorganic iron oxide red antirust coating and preparation method thereof | |
| CN102796451B (en) | Long-effective corrosion, weather-proof, super quick drying paint and preparation method and application | |
| KR101799511B1 (en) | Steel painting composition with excellent weatherability and protection painting method for steel structures therewith | |
| KR101563291B1 (en) | Paint composition mixing rubber in epoxy resin | |
| CN103614049A (en) | Zinc-rich epoxy primer and preparation method thereof | |
| CN105273172A (en) | Water-based alkyd resin for coating manufacturing, and preparation method of water-based alkyd resin | |
| CN100417699C (en) | Green environmental protection polyisoprene in high elasticity | |
| CN106479343A (en) | A kind of preparation method of water paint | |
| CN104559598A (en) | Heat-resistant corrosion-resistant noise-reduction water-base paint and preparation method thereof | |
| KR100986711B1 (en) | Composition including ceramic and polymer resin for waterproof, anticorrosion, surface-protection of concrete and repair and reinforcement of civil engineering fabric eroded chemically in treatment facilities of sewage and wastewater and method for surface-protection using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140219 |