CN103589089A - Novel flame-retardant low-density foamed PVC (Polyvinyl Chloride) sole material - Google Patents
Novel flame-retardant low-density foamed PVC (Polyvinyl Chloride) sole material Download PDFInfo
- Publication number
- CN103589089A CN103589089A CN201310482625.1A CN201310482625A CN103589089A CN 103589089 A CN103589089 A CN 103589089A CN 201310482625 A CN201310482625 A CN 201310482625A CN 103589089 A CN103589089 A CN 103589089A
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- China
- Prior art keywords
- retardant
- fire retardant
- sole
- low
- shoe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 49
- 239000000463 material Substances 0.000 title claims abstract description 28
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 239000004800 polyvinyl chloride Substances 0.000 title abstract description 17
- 229920000915 polyvinyl chloride Polymers 0.000 title abstract description 16
- 239000000314 lubricant Substances 0.000 claims abstract description 8
- 239000002131 composite material Substances 0.000 claims abstract description 6
- 239000004014 plasticizer Substances 0.000 claims abstract description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 9
- 229910052796 boron Inorganic materials 0.000 claims description 9
- 239000003755 preservative agent Substances 0.000 claims description 9
- 229910052787 antimony Inorganic materials 0.000 claims description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 8
- 230000002335 preservative effect Effects 0.000 claims description 8
- 239000011159 matrix material Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical group [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 2
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical group [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 2
- 239000004088 foaming agent Substances 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- -1 polyethylene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 4
- 238000005187 foaming Methods 0.000 abstract description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000001746 injection moulding Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000008188 pellet Substances 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a novel flame-retardant low-density foamed PVC (Polyvinyl Chloride) sole material. The sole material is prepared from the following components in percentage by weight: 60-75% of PVC, 8-20% of DOP (Dioctyl-Phthalate), 5-15% of flame-retardant plasticizer, 5-20% of composite flame retardant, 0.5-2.0% of stabilizer, 0.8-1.5% of lubricant and 2.0-3.0% of foamer. Compared with the prior art, the sole material disclosed by the invention has the advantages of good flame-retardant effect, good foaming effect and low density.
Description
Technical field:
The present invention relates to footwear material technical field, be specifically related to a kind of PVC material for sole of shoe.
Background technology:
Polyvinyl chloride (PVC) material being widely used at home, because it is with low cost, PVC has irreplaceable status in footwear material field.But at present PVC footwear material exists density high, heavy wearing, and the problem such as flame retardant properties is poor.In special industries such as some fire-fightings, the flame retardant properties of PVC footwear material is had to requirements at the higher level.Existing this fire-retardant low-density foaming PVC footwear material in the market.
Summary of the invention:
The technical problem to be solved in the present invention is to provide the low-density foamed PVC material for sole of shoe of a kind of novel flame-retardant.
For achieving the above object, the low-density foamed PVC material for sole of shoe of a kind of novel flame-retardant of the present invention consists of following component by weight percentage:
As technique scheme preferably, described flame-retardant plasticizer is to be selected from Tritolyl Phosphate, triphenylphosphate, dialkyl group tetrachloro for one or more in phthalic ester or dialkyl group tetrabromophthalate.
As technique scheme preferably, described composite fire retardant is to be selected from containing antimony fire retardant, containing one or more in boron fire retardant preservative and metal matrix oxide solid fire retardant.
As technique scheme preferably, described composite fire retardant is containing antimony fire retardant, containing the mixture of boron fire retardant preservative and metal matrix oxide solid fire retardant.
As technique scheme preferably, described is 2: 1: 1 containing antimony fire retardant, containing the mass ratio of boron fire retardant preservative and metal matrix oxide solid fire retardant.
As technique scheme preferably, the described 10-20% that accounts for resin total amount containing boron fire retardant preservative.
As technique scheme preferably, described stablizer is calcium zinc class stablizer; Described lubricant is stearic acid and polyethylene wax polymer compounded lubricant; Described whipping agent is sodium bicarbonate and azo foaming agent.
Beneficial effect of the present invention is: its compared with prior art, this material for sole of shoe has good flame retardation effect, foaming effect is good, low density advantage.
Embodiment:
Embodiment 1
60 parts of PVC materials, DOP8 part, dialkyl group tetrachloro is for 10 parts, the compositional flame-retardant softening agent of phthalic ester and dialkyl group tetrabromophthalate, composite fire retardant (wherein containing 6 parts of boron fire retardant preservatives): 18 parts, and 0.5 part of stablizer, 1.5 parts of lubricants, under 80 ℃ of temperature condition, mix, finally add 2 parts of whipping agents to mix, then send into extruding pelletization in twin screw extruder, prilling temperature is 135 ℃, then that pellet is dry by injection moulding in injection moulding machine.Recording material LOI is 35%, and density is 0.75.
Embodiment 2
70 parts of PVC materials, DOP8 part, 5 parts of triphenylphosphates, contain 12 parts of antimony and metal matrix oxide compound fire retardants, 1.0 parts of stablizers, 1.0 parts of lubricants, under 80 ℃ of temperature condition, mix, finally add 3 parts of whipping agents to mix, then send into extruding pelletization in twin screw extruder, prilling temperature is 135 ℃, then that pellet is dry by injection moulding in injection moulding machine.Recording material LOI is 32%, and density is 0.68.
Embodiment 3
75 parts of PVC materials, DOP11 part, 5 parts of triphenylphosphates, containing 5 parts of antimony fire retardants, 0.5 part of stablizer, 1.5 parts of lubricants, under 80 ℃ of temperature condition, mix, finally add 2 parts of whipping agents to mix, then send into extruding pelletization in twin screw extruder, prilling temperature is 135 ℃, then that pellet is dry by injection moulding in injection moulding machine.Recording material LOI is 30%, and density is 0.70.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (7)
1. the low-density foamed PVC material for sole of shoe of novel flame-retardant, is characterized in that: following component, consist of by weight percentage:
2. the low-density foamed PVC material for sole of shoe of novel flame-retardant according to claim 1, is characterized in that: described flame-retardant plasticizer is to be selected from Tritolyl Phosphate, triphenylphosphate, dialkyl group tetrachloro for one or more in phthalic ester or dialkyl group tetrabromophthalate.
3. the low-density foamed PVC material for sole of shoe of novel flame-retardant according to claim 1, is characterized in that: described composite fire retardant is to be selected from containing antimony fire retardant, containing one or more in boron fire retardant preservative and metal matrix oxide solid fire retardant.
4. the low-density foamed PVC material for sole of shoe of novel flame-retardant according to claim 3, is characterized in that: described composite fire retardant is the mixture that contains antimony fire retardant, contains boron fire retardant preservative and metal matrix oxide solid fire retardant.
5. the low-density foamed PVC material for sole of shoe of novel flame-retardant according to claim 4,
It is characterized in that: described is 2: 1: 1 containing antimony fire retardant, containing the mass ratio of boron fire retardant preservative and metal matrix oxide solid fire retardant.
6. the low-density foamed PVC material for sole of shoe of novel flame-retardant according to claim 3, is characterized in that: the described 10-20% that accounts for resin total amount containing boron fire retardant preservative.
7. the low-density foamed PVC material for sole of shoe of novel flame-retardant according to claim 1, is characterized in that: described stablizer is calcium zinc class stablizer; Described lubricant is stearic acid and polyethylene wax polymer compounded lubricant; Described whipping agent is sodium bicarbonate and azo foaming agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310482625.1A CN103589089B (en) | 2013-10-15 | 2013-10-15 | A kind of fire-retardant low-density foaming PVC material for sole of shoe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310482625.1A CN103589089B (en) | 2013-10-15 | 2013-10-15 | A kind of fire-retardant low-density foaming PVC material for sole of shoe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103589089A true CN103589089A (en) | 2014-02-19 |
| CN103589089B CN103589089B (en) | 2016-09-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310482625.1A Active CN103589089B (en) | 2013-10-15 | 2013-10-15 | A kind of fire-retardant low-density foaming PVC material for sole of shoe |
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| Country | Link |
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| CN (1) | CN103589089B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289245A (en) * | 2013-06-21 | 2013-09-11 | 苏州市景荣科技有限公司 | Fire retardation HPVC foaming sole material |
| CN103289246A (en) * | 2013-06-21 | 2013-09-11 | 苏州市景荣科技有限公司 | Fire retardation PVC foaming sole material |
-
2013
- 2013-10-15 CN CN201310482625.1A patent/CN103589089B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289245A (en) * | 2013-06-21 | 2013-09-11 | 苏州市景荣科技有限公司 | Fire retardation HPVC foaming sole material |
| CN103289246A (en) * | 2013-06-21 | 2013-09-11 | 苏州市景荣科技有限公司 | Fire retardation PVC foaming sole material |
Non-Patent Citations (2)
| Title |
|---|
| 杨涛: "《聚氯乙烯配方设计与制品加工》", 30 June 2011, 北京：化学工业出版社，2011年6月北京第一版 * |
| 苑会林等: "软质PVC阻燃抑烟的研究", 《聚氯乙烯》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103589089B (en) | 2016-09-14 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yang Wuxian Inventor before: Huang Chao |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20160815 Address after: 809, room 209, building A, 325000 Wenchang Road, Wenzhou hi tech park, Zhejiang, China Applicant after: Wenzhou Honghe Paper Industry Co.,Ltd. Address before: 215000 Suzhou high tech Zone, Jiangsu, the British road, No. 88 Applicant before: SUZHOU JINGRO TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20181112 Address after: 313000 room 1020, science and Technology Pioneer Park, 666 Chaoyang Road, Nanxun Town, Nanxun District, Huzhou, Zhejiang. Patentee after: Huzhou You Yan Intellectual Property Service Co.,Ltd. Address before: 325000 room 809, building A, 209 Wenchang Road, hi tech park, Wenzhou, Zhejiang. Patentee before: Wenzhou Honghe Paper Industry Co.,Ltd. |
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Effective date of registration: 20190424 Address after: 522000 Renhui South Road, Xinan Section of Tianfu East Road, Jieyang Airport Economic Zone, Guangdong Province Patentee after: Jieyang Liangfengda Hardware Plastic Co.,Ltd. Address before: 313000 room 1020, science and Technology Pioneer Park, 666 Chaoyang Road, Nanxun Town, Nanxun District, Huzhou, Zhejiang. Patentee before: Huzhou You Yan Intellectual Property Service Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 522000 Renhui South Road, Xinan Section of Tianfu East Road, Jieyang Airport Economic Zone, Guangdong Province Patentee after: Guangdong liangfengda Industrial Co.,Ltd. Address before: 522000 Renhui South Road, Xinan Section of Tianfu East Road, Jieyang Airport Economic Zone, Guangdong Province Patentee before: Jieyang Liangfengda Hardware Plastic Co.,Ltd. |
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