CN103572078A - Refining method of aluminum alloy for heat exchangers - Google Patents

Refining method of aluminum alloy for heat exchangers Download PDF

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Publication number
CN103572078A
CN103572078A CN201310497511.4A CN201310497511A CN103572078A CN 103572078 A CN103572078 A CN 103572078A CN 201310497511 A CN201310497511 A CN 201310497511A CN 103572078 A CN103572078 A CN 103572078A
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aluminium
zirconium
aluminum alloy
tungsten
heat exchanger
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CN201310497511.4A
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姚富云
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Abstract

The invention relates to a refining method of an aluminum alloy material for heat exchangers. The aluminum alloy material comprises the following components in percentage by weight: manganese, copper, silicon, magnesium, zirconium, iron, titanium, tungsten, and the balance of aluminum inevitable impurities. The components are smelted and cast to obtain the aluminum alloy ingot. Compared with the existing aluminum alloy pipe, the aluminum alloy pipe provided by the invention has greatly higher strength, higher mechanical toughness and greatly improved corrosion resistance.

Description

A kind of heat exchanger aluminium alloy method for refining
Technical field
The invention belongs to field of aluminum alloys, specifically refer to a kind of heat exchanger aluminium alloy method for refining.
Background technology
Heat exchanger now mainly adopts standard aluminum alloy pipe, but the existing aluminium alloy pipe using can not meet light-weighted requirement, because in the situation that lightization quantizes, it is thinner that tube wall becomes, but existing aluminum alloy materials is after tube wall attenuation, physical strength reduces, and the resistance to corrosion of thin tubing is not enough to be adapted to heat exchanger field.
In order to improve the performance ,Xian various countries of aluminium alloy, all at the new aluminum alloy materials of exploitation, to adapt to, can manufacture the needs that thinner aluminium alloy pipe meets heat exchanger.In existing disclosed technical scheme, be all to contain optional in manganese, copper, silicon, magnesium or vanadium, chromium, titanium, and in some disclosed technology, require to contain zirconium or require not contain zirconium, or require in aluminum alloy materials, to contain ferro element, to reduce the hot crackability of copper.
But in metal field, the problem of existence is, even identical composition, but the subtle change of technique may will cause the greatest differences of the finished product performance, and this situation has been the common practise of this area.
Summary of the invention
The object of this invention is to provide a kind of raising intensity of aluminum alloy, and improve the aluminium alloy method for refining of corrosion resistance of aluminum alloy.
The present invention is achieved by the following technical solutions:
A kind of heat exchanger aluminium alloy method for refining, its material composition includes by weight percentage, 1.35% manganese, the copper of 0.6-1.2%, the silicon of 0.35-0.45%, the zirconium of the magnesium of 0.3-0.5%, 0.1-0.2%, the titanium of the iron of 0.3-0.6%, 0.1-0.15%, the tungsten of 0.05-0.075%, and surplus is aluminium and inevitable impurity;
First melting partinium adds half aluminium after partinium melts completely, after aluminium melts completely, adds all the other each components and remaining aluminium, carries out melting;
After removing the gred, aluminum alloy melt is put into and bred stove and carry out constant temperature and breed after 30 minutes and cast;
In when casting, adopt that at the uniform velocity constant temperature is cooling, speed of cooling is 5 ℃/sec-35 ℃/sec, while being cooled to 580 ℃-600 ℃, holding temperature is after 0.5-2 hour, 3 ℃/sec-8 ℃/sec at the uniform velocity constant temperature after being cooled to 150 ℃-180 ℃, naturally cool to normal temperature, obtain aluminum alloy ingot.
The weight ratio of described copper and iron is 2:1.
The weight ratio of described titanium and tungsten is 2:1.
When carrying out aluminium alloy smelting, tungsten adds in partinium mode, and in partinium, to account for weight percent be 10% to tungsten.
Zirconium adds in zirconium alloy mode, and wherein, zirconium accounts for 5% of zirconium alloy weight percent.
The aluminium alloy pipe that co-occurrence of the present invention is used is compared, and not only aspect intensity, is greatly improved, but also has improved mechanical tenacity, and have greatly improved aspect corrosion resistance nature.
Embodiment
Describe by the following examples technical scheme of the present invention in detail.
A kind of heat exchanger aluminium alloy method for refining, its composition includes by weight percentage, 1.35% manganese, the copper of 0.6-1.2%, the silicon of 0.35-0.45%, the zirconium of the magnesium of 0.3-0.5%, 0.1-0.2%, the titanium of the iron of 0.3-0.6%, 0.1-0.15%, the tungsten of 0.05-0.075%, and surplus is aluminium and inevitable impurity; The weight ratio of described copper and iron is 2:1; The weight ratio of described titanium and tungsten is 2:1.
When carrying out aluminium alloy smelting, tungsten adds in partinium mode, and in partinium, to account for weight percent be 10% to tungsten.
Zirconium adds in zirconium alloy mode, and wherein, zirconium accounts for 5% of zirconium alloy weight percent.
First melting partinium adds half aluminium after partinium melts completely, after aluminium melts completely, adds all the other each components and remaining aluminium, carries out melting.As for techniques such as slagging-off, be prior art, at this, do not describe.
After removing the gred, aluminum alloy melt is put into and bred stove and carry out constant temperature and breed after 30 minutes and cast.
In when casting, adopt that at the uniform velocity constant temperature is cooling, speed of cooling is 5 ℃/sec-35 ℃/sec, while being cooled to 580 ℃-600 ℃, holding temperature is after 0.5-2 hour, 3 ℃/sec-8 ℃/sec at the uniform velocity constant temperature after being cooled to 150 ℃-180 ℃, naturally cool to normal temperature, obtain aluminum alloy ingot.
Aluminum alloy ingot carries out the post-production of heat exchanger.
In various embodiments of the present invention, distinguishing is the difference of the material composition of each embodiment, and remaining condition is identical.
Embodiment 1
A kind of heat exchanger aluminum alloy materials, its composition includes by weight percentage, 1.35% manganese, 0.6% copper, 0.35% silicon, 0.3% magnesium, 0.1% zirconium, 0.3% iron, 0.1% titanium, 0.05% tungsten, and surplus is aluminium and inevitable impurity; The weight ratio of described copper and iron is 2:1; The weight ratio of described titanium and tungsten is 2:1.
Embodiment 2
A kind of heat exchanger aluminum alloy materials, its composition includes by weight percentage, 1.35% manganese, 1.2% copper, 0.45% silicon, 0.5% magnesium, 0.2% zirconium, 0.6% iron, 0.15% titanium, 0.075% tungsten, and surplus is aluminium and inevitable impurity; The weight ratio of described copper and iron is 2:1; The weight ratio of described titanium and tungsten is 2:1.
Embodiment 3
A kind of heat exchanger aluminum alloy materials, its composition includes by weight percentage, 1.35% manganese, 1.0% copper, 0.40% silicon, 0.35% magnesium, 0.15% zirconium, 0.5% iron, 0.12% titanium, 0.06% tungsten, and surplus is aluminium and inevitable impurity; The weight ratio of described copper and iron is 2:1; The weight ratio of described titanium and tungsten is 2:1.
Embodiment 4
A kind of heat exchanger aluminum alloy materials, its composition includes by weight percentage, 1.35% manganese, 0.8% copper, 0.42% silicon, 0.4% magnesium, 0.16% zirconium, 0.4% iron, 0.14% titanium, 0.07% tungsten, and surplus is aluminium and inevitable impurity; The weight ratio of described copper and iron is 2:1; The weight ratio of described titanium and tungsten is 2:1.

Claims (5)

1. a heat exchanger aluminium alloy method for refining, it is characterized in that: its material composition includes by weight percentage, 1.35% manganese, the copper of 0.6-1.2%, the silicon of 0.35-0.45%, the zirconium of the magnesium of 0.3-0.5%, 0.1-0.2%, the titanium of the iron of 0.3-0.6%, 0.1-0.15%, the tungsten of 0.05-0.075%, and surplus is aluminium and inevitable impurity;
First melting partinium adds half aluminium after partinium melts completely, after aluminium melts completely, adds all the other each components and remaining aluminium, carries out melting;
After removing the gred, aluminum alloy melt is put into and bred stove and carry out constant temperature and breed after 30 minutes and cast;
In when casting, adopt that at the uniform velocity constant temperature is cooling, speed of cooling is 5 ℃/sec-35 ℃/sec, while being cooled to 580 ℃-600 ℃, holding temperature is after 0.5-2 hour, 3 ℃/sec-8 ℃/sec at the uniform velocity constant temperature after being cooled to 150 ℃-180 ℃, naturally cool to normal temperature, obtain aluminum alloy ingot.
2. heat exchanger according to claim 1 aluminium alloy method for refining, is characterized in that: the weight ratio of described copper and iron is 2:1.
3. heat exchanger according to claim 1 aluminium alloy method for refining, is characterized in that: the weight ratio of described titanium and tungsten is 2:1.
4. heat exchanger according to claim 1 aluminium alloy method for refining, is characterized in that: when carrying out aluminium alloy smelting, tungsten adds in partinium mode, and in partinium, to account for weight percent be 10% to tungsten.
5. heat exchanger according to claim 1 aluminium alloy method for refining, is characterized in that: zirconium adds in zirconium alloy mode, and wherein, zirconium accounts for 5% of zirconium alloy weight percent.
CN201310497511.4A 2013-10-21 2013-10-21 Refining method of aluminum alloy for heat exchangers Pending CN103572078A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112397220A (en) * 2020-11-19 2021-02-23 安徽神华特种线缆有限公司 Aluminum alloy power cable

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10265882A (en) * 1997-03-25 1998-10-06 Mitsubishi Heavy Ind Ltd Aluminum alloy heat exchanger
JP2002241910A (en) * 2000-12-13 2002-08-28 Furukawa Electric Co Ltd:The Method for producing aluminum alloy fin material for brazing
CN1578844A (en) * 2001-10-05 2005-02-09 克里斯有限合伙公司 Aluminium alloy for making fin stock material
CN1690237A (en) * 2004-03-22 2005-11-02 赛帕导热股份公司 High strength long-life aluminium tube material with high sagging resistance
CN101358311A (en) * 2007-07-19 2009-02-04 古河Sky株式会社 Aluminum alloy brazing sheet having high-strength and production method therefore

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10265882A (en) * 1997-03-25 1998-10-06 Mitsubishi Heavy Ind Ltd Aluminum alloy heat exchanger
JP2002241910A (en) * 2000-12-13 2002-08-28 Furukawa Electric Co Ltd:The Method for producing aluminum alloy fin material for brazing
CN1578844A (en) * 2001-10-05 2005-02-09 克里斯有限合伙公司 Aluminium alloy for making fin stock material
CN1690237A (en) * 2004-03-22 2005-11-02 赛帕导热股份公司 High strength long-life aluminium tube material with high sagging resistance
CN101358311A (en) * 2007-07-19 2009-02-04 古河Sky株式会社 Aluminum alloy brazing sheet having high-strength and production method therefore

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
郭红: "提高汽车轮毂用铝合金的冲击韧性", 《中国优秀博硕士学位论文全文数据库(硕士)工程科技Ⅱ辑》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112397220A (en) * 2020-11-19 2021-02-23 安徽神华特种线缆有限公司 Aluminum alloy power cable

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Application publication date: 20140212