CN1035649A - The manufacture method of mineral water enriched material - Google Patents

The manufacture method of mineral water enriched material Download PDF

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Publication number
CN1035649A
CN1035649A CN 88105224 CN88105224A CN1035649A CN 1035649 A CN1035649 A CN 1035649A CN 88105224 CN88105224 CN 88105224 CN 88105224 A CN88105224 A CN 88105224A CN 1035649 A CN1035649 A CN 1035649A
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CN
China
Prior art keywords
enriched material
mineral water
water
mineral
hydrochloric acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 88105224
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Chinese (zh)
Inventor
曹钦臣
张保民
李巍然
赵广涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ocean University of Oingdao
Original Assignee
Ocean University of Oingdao
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ocean University of Oingdao filed Critical Ocean University of Oingdao
Priority to CN 88105224 priority Critical patent/CN1035649A/en
Publication of CN1035649A publication Critical patent/CN1035649A/en
Pending legal-status Critical Current

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Abstract

The present invention is a kind of method of being made the mineral water enriched material by the Laoshan medical stone.Wherein the ore with certain particle size mixes with the polymer solution in water of dilute hydrochloric acid or hydrochloric acid, behind the reaction certain hour, tells its supernatant liquor, concentrates with vacuum-evaporation after filtration and promptly obtains the mineral water enriched material.This enriched material can fully dissolve and not have precipitation promptly drinkable through dilution.Production method is simple, and is cheap, and product is convenient to transportation, and is wherein contained to people's beneficial trace elements A wide selection of colours and designs, the content height, and harmful element concentration is extremely low.

Description

The manufacture method of mineral water enriched material
The invention belongs to water-treatment technology field.
Utilization contains the natural mineral of multiple element, porousness mineral processing water particularly, absorption (comprising the mineral ion exchange) effect and Decomposition by mineral, can reduce deleterious composition in the water, stripping by mineral can make the trace element that increases in the water the human body beneficial, and this method is known already.Here foremost in the said natural mineral is exactly medical stone." medical stone " speech derives from Compendium of Material Medica one book that China Ming Dynasty medicine great master LI Shi-Zhen is shown, and the back is that the Japanese is used often.Refer to quartz porphyry in Japan, in fact it can comprise many natural porousness mineral, and hornblende andesite, quartzy diorite-porphyrite etc. are wherein just arranged more.Mentioning with trachyandesite in the J57-207592 patent is porousness mineral processing tap water, the effect that has absorption to remove objectionable impurities and chlorine.In the J61-1195 patent, mention the method for handling tap water and well water with quartzy diorite-porphyrite or hornblende andesite, comprising ore is immersed in the water, and use ultrasonic irradiation.The data of relevant treating water income effect is not provided in last patent, in one patent of back, has only SiO in the treated water yet 2With the data of residual chlorine content, PH and taste, but also not mentioned to human body beneficial's trace element.
The objective of the invention is to,, make every effort to utilize the most reasonable and effective treatment process and the mineral water that obtains to be of value to HUMAN HEALTH near the medical stone of Qingdao, finding (, mainly being biotite asperities andesitic porphyrite) hereinafter referred to as the Laoshan medical stone.
For this reason, the present invention adopts the Laoshan medical stone to handle distilled water and tap water etc., and has made the mineral water enriched material, and it contains the element more than 24 kinds, and wherein beneficial trace elements is dense, and the microelement concentration that is pernicious to people is very low.Concrete grammar is as follows:
1, the Laoshan medical stone with fragmentation is crushed to certain particle size with ball mill, for example the 120-200 order;
2, the certain density HCl aqueous solution of preparation and polymer solution in water; Acid concentration will be hanged down, and acid concentration is big, and iron stripping just are easy to produce precipitation more;
3, the above-mentioned acid solution a certain amount of above-mentioned chippy Laoshan medical stone and certain volume is mixed in a container, and is stirred every now and then, makes it fully react (time generally needs 6-8 hour);
When 4, treating that supernatant liquor is neutral (PH=6.5-7.0), tell supernatant liquor, and it is used filter paper filtering.The mineral precipitation that leaches can be handled once with acid solution again;
5, above-mentioned gained filtrate is carried out at a certain temperature vacuum-evaporation and concentrate, be concentrated to stoste about 1/100, be the mineral water enriched material.This product mainly is a liquid, also contains small amounts of solid matter.A large amount of crystal will occur during as further evaporation, we think that it is much better that the enriched material ratio is entirely crystal.
By the mineral water enriched material that the present invention makes, promptly drinkable with suitable quantity of water (for example in 1 gram enriched material, adding 2000ml water) dilution, meet the drinking water standard that United Nations's health organization is stipulated fully.During dilution, original solids dissolving does not produce new precipitation yet, and can keep PH neutrality.Make the mineral water enriched material by the present invention, method is simple, and beneficial trace elements is very fast by stripping in the ore, save time, and product price is cheap.Because healthy trace elements with household A wide selection of colours and designs in the enriched material, so drinking of said product is for because of lacking the multiple endemy that some beneficial element suffers from obvious curative effects being arranged.The mineral water that the concentration ratio of healthy trace elements with household is general in this product is high about 2000 times, helps carrying or transporting, and is convenient to family or tourism use.
Embodiment 1
In the beaker of 3000ml, add 1000 grams, 200 purpose Laoshan medical stones, adding concentration is 0.16% hydrochloric acid soln 2000ml, stirring makes its mixing, react 7 hours to supernatant liquor PH be 7.0, shift supernatant liquor, and use filter paper filtering, and analyze the content of some elements in the filtrate, the results are shown in table 1.Supernatant liquor is carried out vacuum-evaporation be concentrated into the supernatant liquid measure under 50 ℃
The content of some elements (ppm) in table 1 supernatant liquor
K?171.88 Na?280.00 Ca?1735 Mg?715.0 Mn?104.5 Fe?1532 Al?0.124 Zn?3.26 Sr?0.570 V?0.020 Co?0.069 Mo T SiO 264 (solubility) Se, 0.055 B, 0.105 Cu, 1.29 Cr, 0.066 Ni, 0.224 Ti 0.020 PO 4?0.01 Pb t Hg t As?0.47 Cd?0.06
* t represents trace in the table
1/100, get the mineral water enriched material, its analytical results is as shown in table 2.
Embodiment 2
Change hydrochloric acid soln among the embodiment 1 into acid concentration identical polymer solution in water, all the other are fully identical with embodiment 1, and the result is similar for gained.
T represents trace in the table

Claims (3)

1, a kind of method of making the mineral water enriched material with the medical stone treating water, it is characterized in that used medical stone is a biotite asperities andesitic porphyrite, when making mineral water, it is mixed with the aqueous solution or the polymer solution in water of HCl, behind the reaction certain hour, tell supernatant liquor, filter, and its vacuum-evaporation is concentrated;
2, the method for manufacturing mineral water enriched material as claimed in claim 1 is characterized in that described concentration of hydrochloric acid solution is preferably 0.16%
3,, it is characterized in that the reaction times is (6~8) hour by the method for the described manufacturing mineral water of claim 1 enriched material.
CN 88105224 1988-03-11 1988-03-11 The manufacture method of mineral water enriched material Pending CN1035649A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 88105224 CN1035649A (en) 1988-03-11 1988-03-11 The manufacture method of mineral water enriched material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 88105224 CN1035649A (en) 1988-03-11 1988-03-11 The manufacture method of mineral water enriched material

Publications (1)

Publication Number Publication Date
CN1035649A true CN1035649A (en) 1989-09-20

Family

ID=4833438

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 88105224 Pending CN1035649A (en) 1988-03-11 1988-03-11 The manufacture method of mineral water enriched material

Country Status (1)

Country Link
CN (1) CN1035649A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102550603A (en) * 2010-12-29 2012-07-11 北京市松浦经贸发展公司 Extraction method of mineral concentrate for environmental restoration and application thereof
CN104229916A (en) * 2013-06-06 2014-12-24 济南大学 Method for adsorption of heavy metal lead ions by andesitic porphyrite mineral
WO2019024127A1 (en) * 2017-07-31 2019-02-07 席坚一 Functional mineral water and preparation method therefor

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102550603A (en) * 2010-12-29 2012-07-11 北京市松浦经贸发展公司 Extraction method of mineral concentrate for environmental restoration and application thereof
CN102550603B (en) * 2010-12-29 2014-03-05 北京市松浦经贸发展公司 Extraction method of mineral concentrate for environmental restoration and application thereof
CN104229916A (en) * 2013-06-06 2014-12-24 济南大学 Method for adsorption of heavy metal lead ions by andesitic porphyrite mineral
WO2019024127A1 (en) * 2017-07-31 2019-02-07 席坚一 Functional mineral water and preparation method therefor

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