CN103554410A - Shoe pad warm in winter and cool in summer as well as preparation method thereof - Google Patents

Shoe pad warm in winter and cool in summer as well as preparation method thereof Download PDF

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Publication number
CN103554410A
CN103554410A CN201310490577.0A CN201310490577A CN103554410A CN 103554410 A CN103554410 A CN 103554410A CN 201310490577 A CN201310490577 A CN 201310490577A CN 103554410 A CN103554410 A CN 103554410A
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CN
China
Prior art keywords
parts
summer
winter
shoe
warm
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310490577.0A
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Chinese (zh)
Inventor
张连锋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QUANZHOU YUANLI SHOES MATERIAL Co Ltd
Original Assignee
QUANZHOU YUANLI SHOES MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QUANZHOU YUANLI SHOES MATERIAL Co Ltd filed Critical QUANZHOU YUANLI SHOES MATERIAL Co Ltd
Priority to CN201310490577.0A priority Critical patent/CN103554410A/en
Publication of CN103554410A publication Critical patent/CN103554410A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6505Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6511Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38 compounds of group C08G18/3203
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B17/00Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
    • A43B17/14Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined made of sponge, rubber, or plastic materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203Polyhydroxy compounds
    • C08G18/3206Polyhydroxy compounds aliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0083Foam properties prepared using water as the sole blowing agent

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to the technical field of shoe pads, and provides a shoe pad warm in winter and cool in summer, which has changeable temperature, can absorb moisture and discharge sweat effectively and is made of environment-friendly materials. The shoe pad warm in winter and cool in summer is prepared from the following raw materials in parts by weight: 17700-17800 parts of polymer polyol, 18900-19000 parts of isocyanic acid, 85-98 parts of amine catalysts, 550-560 parts of a hardening agent, 120-130 parts of 1-4 butanediol, 40-50 parts of silicon oil, 265-270 parts of water, 160-170 parts of antibiosis powder, 20-25 parts of black thick liquid, 3-5 parts of yellow thick liquid, 12-15 parts of blue thick liquid, 750-760 parts of rubber powder, 175-180 parts of floor wax and 5-20 parts of tourmaline. The invention also provides a method with a simple preparation process for preparing the shoe pad warm in winter and cool in summer.

Description

A kind of shoe-pad cool in summer and warm in winter and preparation method thereof
Technical field
The present invention relates to shoe-pad technical field, relate in particular to a kind of shoe-pad cool in summer and warm in winter and preparation method thereof.
Background technology
Shoe-pad is to be placed in the rebasing parts at the end in footwear.Its effect is to make footwear inner bottom part perfect clean, gets rid of pin sweat and moisture absorption, makes the interior end of footwear smooth smooth comfortable and easy to wear, and function ratio is more limited.Along with the raising of people's living standard, also more and more higher to the requirement of shoe-pad, the insole function on existing market is more single, can not meet people's demand.
Existing shoe-pad, be to adopt ethene-vinyl acetate copolymer (EVA) material mostly, its manufacture method is to be flat matrix band and a cloth cover gummed by one, and forms work in-process, again these work in-process are cut, obtain several shoe-pads and a clout.
Utilize the made shoe-pad of aforesaid method can produce lower column defects: this shoe-pad and cloth cover utilize glue coating and be bonded to one, and not only increase the cost of gluing, and contaminate environment likely in the processing procedure of glue coating, do not meet the demand of environmental protection.
Summary of the invention
Therefore, for above content, the invention provides the shoe-pad cool in summer and warm in winter of a kind of temperature-changeable, effective moisture absorbing and sweat releasing, material environment friendly, the method for the described shoe-pad cool in summer and warm in winter of the simple preparation of a kind of preparation technology is provided simultaneously.
For achieving the above object, the present invention is achieved by the following technical solutions: a kind of shoe-pad cool in summer and warm in winter, by each raw material of following weight part, made:
Polymer polyatomic alcohol: 17700~17800 parts
Carbimide: 18900~19000 parts
Amines catalyst: 85~98 parts
Stiffening agent: 550~560 parts
1-4 butyleneglycol: 120~130 parts
Silicone oil: 40~50 parts
Water: 265~270 parts
Antibiotic powder: 160~170 parts
Black slurry: 20~25 parts
Yellow slurry: 3~5 parts
Blue slurry: 12~15 parts
Rubber powder: 750~760 parts
Floor wax: 175~180 parts
Tourmaline: 5~20 parts.
Further improve and be: described Tourmaline size is 100~6000 orders.
Further improve and be: described stiffening agent is ethylene glycol.
A preparation method for shoe-pad cool in summer and warm in winter, comprises following processing step:
(1) mixing: 5~20 parts of 17700~17800 parts of polymer polyatomic alcohols, 18900~19000 parts of carbimides, 85~98 parts of amines catalysts, 550~560 parts of stiffening agents, 120~130 parts of 1-4 butyleneglycols, 40~50 parts of silicone oil, 265~270 parts, water, 160~170 parts, antibiotic powder, 20~25 parts of black slurry, 3~5 parts, yellow slurry, 12~15 parts, blue slurry, 750~760 parts of rubber powders, 175~180 parts of floor waxes, Tourmalines to be put into mixing roll mixing;
(2) moulding: the raw material after the mixing processing of step (1) is sent into in-mold molding;
(3) cut, the work in-process after moulding are cut, make shoe-pad cool in summer and warm in winter.
By adopting aforementioned techniques scheme, the invention has the beneficial effects as follows: shoe-pad cool in summer and warm in winter of the present invention, each raw material of following weight part is made: polymer polyatomic alcohol: 17700~17800 parts, carbimide: 18900~19000 parts, amines catalyst: 85~98 parts, stiffening agent: 550~560 parts, 1-4 butyleneglycol: 120~130 parts, silicone oil: 40~50 parts, water: 265~270 parts, antibiotic powder: 160~170 parts, black slurry: 20~25 parts, yellow slurry: 3~5 parts, blue slurry: 12~15 parts, rubber powder: 750~760 parts, floor wax: 175~180 parts, Tourmaline: 5~20 parts, the shoe-pad that adopts above-mentioned formula to make has temperature-changeable, the function of effective moisture absorbing and sweat releasing, the starting material environmental protection adopting, discarded do not use rear free from environmental pollution, in addition, preparation technology of the present invention is simple, easy to operate.
Embodiment
Below with reference to specific embodiment, describe embodiments of the present invention in detail, to the present invention, how utilisation technology means solve technical problem whereby, and the implementation procedure of reaching technique effect can fully understand and implement according to this.
If do not specialize, the conventional means that the technique means adopting in embodiment is well known to those skilled in the art, the reagent adopting and product are also and can business obtain.The source of agents useful for same, trade(brand)name and be necessary to list its moiety person are all indicated when occurring first.
Embodiment mono-
A shoe-pad, by each raw material of following weight part, made:
Polymer polyatomic alcohol: 17700 parts
Carbimide: 18900 parts
Amines catalyst: 85 parts
Ethylene glycol: 550 parts
1-4 butyleneglycol: 120 parts
Silicone oil: 40 parts
Water: 265 parts
Antibiotic powder: 160 parts
Black slurry: 20 parts
Yellow slurry: 3 parts
Blue slurry: 12 parts
Rubber powder: 750 parts
Floor wax: 175 parts
Size is 100~500 object Tourmalines: 5 parts.
Its preparation method, comprises following processing step:
(1) mixing: 17700 parts of polymer polyatomic alcohols, 18900 parts of carbimides, 85 parts of amines catalysts, 550 parts of ethylene glycol, 120 parts of 1-4 butyleneglycols, 40 parts of silicone oil, 265 parts, water, 160 parts, antibiotic powder, 20 parts of black slurry, 3 parts, yellow slurry, 12 parts, blue slurry, 750 parts of rubber powders, 175 parts of floor waxes, size to be that 5 parts of 100~500 object Tourmalines are put into mixing roll mixing;
(2) moulding: the raw material after the mixing processing of step (1) is sent into in-mold molding;
(3) cut, the work in-process after moulding are cut, make shoe-pad cool in summer and warm in winter.
Embodiment bis-
A shoe-pad, by each raw material of following weight part, made:
Polymer polyatomic alcohol: 17750 parts
Carbimide: 18950 parts
Amines catalyst: 90 parts
Ethylene glycol: 555 parts
1-4 butyleneglycol: 125 parts
Silicone oil: 45 parts
Water: 267 parts
Antibiotic powder: 165 parts
Black slurry: 22 parts
Yellow slurry: 4 parts
Blue slurry: 14 parts
Rubber powder: 755 parts
Floor wax: 178 parts
Size is 2000~3000 object Tourmalines: 12 parts.
A preparation method for shoe-pad cool in summer and warm in winter, comprises following processing step:
(1) mixing: 17750 parts of polymer polyatomic alcohols, 18950 parts of carbimides, 90 parts of amines catalysts, 555 parts of ethylene glycol, 125 parts of 1-4 butyleneglycols, 45 parts of silicone oil, 267 parts, water, 165 parts, antibiotic powder, 22 parts of black slurry, 4 parts, yellow slurry, 14 parts, blue slurry, 755 parts of rubber powders, 178 parts of floor waxes, size to be that 12 parts of 2000~3000 object Tourmalines are put into mixing roll mixing;
(2) moulding: the raw material after the mixing processing of step (1) is sent into in-mold molding;
(3) cut, the work in-process after moulding are cut, make shoe-pad cool in summer and warm in winter.
Embodiment tri-
A shoe-pad, by each raw material of following weight part, made:
Polymer polyatomic alcohol: 17800 parts
Carbimide: 19000 parts
Amines catalyst: 98 parts
Ethylene glycol: 560 parts
1-4 butyleneglycol: 130 parts
Silicone oil: 50 parts
Water: 270 parts
Antibiotic powder: 170 parts
Black slurry: 25 parts
Yellow slurry: 5 parts
Blue slurry: 15 parts
Rubber powder: 760 parts
Floor wax: 180 parts
Size is 4000~6000 object Tourmalines: 20 parts.
A preparation method for shoe-pad cool in summer and warm in winter, comprises following processing step:
(1) mixing: 20 parts of 17800 parts of polymer polyatomic alcohols, 19000 parts of carbimides, 98 parts of amines catalysts, 560 parts of stiffening agents, 130 parts of 1-4 butyleneglycols, 50 parts of silicone oil, 270 parts, water, 170 parts, antibiotic powder, 25 parts of black slurry, 5 parts, yellow slurry, 15 parts, blue slurry, 760 parts of rubber powders, 180 parts of floor waxes, Tourmalines to be put into mixing roll mixing;
(2) moulding: the raw material after the mixing processing of step (1) is sent into in-mold molding;
(3) cut, the work in-process after moulding are cut, make shoe-pad cool in summer and warm in winter.
Wherein, in the present invention, the component of described each raw material all can realize object of the present invention in following scope: polymer polyatomic alcohol: 17700~17800 parts, carbimide: 18900~19000 parts, amines catalyst: 85~98 parts, stiffening agent: 550~560 parts, 1-4 butyleneglycol: 120~130 parts, silicone oil: 40~50 parts, water: 265~270 parts, antibiotic powder: 160~170 parts, black slurry: 20~25 parts, yellow slurry: 3~5 parts, blue slurry: 12~15 parts, rubber powder: 750~760 parts, floor wax: 175~180 parts, Tourmaline: 5~20 parts.Described Tourmaline size all can realize object of the present invention at 100~6000 orders.
Shoe-pad cool in summer and warm in winter of the present invention, each raw material of following weight part is made: polymer polyatomic alcohol: 17700~17800 parts, carbimide: 18900~19000 parts, amines catalyst: 85~98 parts, stiffening agent: 550~560 parts, 1-4 butyleneglycol: 120~130 parts, silicone oil: 40~50 parts, water: 265~270 parts, antibiotic powder: 160~170 parts, black slurry: 20~25 parts, yellow slurry: 3~5 parts, blue slurry: 12~15 parts, rubber powder: 750~760 parts, floor wax: 175~180 parts, Tourmaline: 5~20 parts, the shoe-pad that adopts above-mentioned formula to make has temperature-changeable, the function of effective moisture absorbing and sweat releasing, the starting material environmental protection adopting, discarded do not use rear free from environmental pollution, in addition, preparation technology of the present invention is simple, easy to operate.
Above record, only, for utilizing the embodiment of this origination techniques content, modification, variation that any those skilled in the art use this creation to do, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.

Claims (4)

1. a shoe-pad cool in summer and warm in winter, is characterized in that, by each raw material of following weight part, is made:
Polymer polyatomic alcohol: 17700~17800 parts
Carbimide: 18900~19000 parts
Amines catalyst: 85~98 parts
Stiffening agent: 550~560 parts
1-4 butyleneglycol: 120~130 parts
Silicone oil: 40~50 parts
Water: 265~270 parts
Antibiotic powder: 160~170 parts
Black slurry: 20~25 parts
Yellow slurry: 3~5 parts
Blue slurry: 12~15 parts
Rubber powder: 750~760 parts
Floor wax: 175~180 parts
Tourmaline: 5~20 parts.
2. shoe-pad cool in summer and warm in winter according to claim 1, is characterized in that: described Tourmaline size is 100~6000 orders.
3. shoe-pad cool in summer and warm in winter according to claim 1, is characterized in that: described stiffening agent is ethylene glycol.
4. a preparation method for shoe-pad cool in summer and warm in winter, is characterized in that, comprises following processing step:
(1) mixing: 5~20 parts of 17700~17800 parts of polymer polyatomic alcohols, 18900~19000 parts of carbimides, 85~98 parts of amines catalysts, 550~560 parts of stiffening agents, 120~130 parts of 1-4 butyleneglycols, 40~50 parts of silicone oil, 265~270 parts, water, 160~170 parts, antibiotic powder, 20~25 parts of black slurry, 3~5 parts, yellow slurry, 12~15 parts, blue slurry, 750~760 parts of rubber powders, 175~180 parts of floor waxes, Tourmalines to be put into mixing roll mixing;
(2) moulding: the raw material after the mixing processing of step (1) is sent into in-mold molding;
(3) cut, the work in-process after moulding are cut, make shoe-pad cool in summer and warm in winter.
CN201310490577.0A 2013-10-19 2013-10-19 Shoe pad warm in winter and cool in summer as well as preparation method thereof Pending CN103554410A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310490577.0A CN103554410A (en) 2013-10-19 2013-10-19 Shoe pad warm in winter and cool in summer as well as preparation method thereof

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Application Number Priority Date Filing Date Title
CN201310490577.0A CN103554410A (en) 2013-10-19 2013-10-19 Shoe pad warm in winter and cool in summer as well as preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106589905A (en) * 2016-12-21 2017-04-26 王春晓 Mattress warm in winter and cool in summer

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101591420A (en) * 2008-05-27 2009-12-02 上海合达聚合物科技有限公司 A kind of plastic-blasting polyurethane composition, its preparation method and application thereof
CN102551268A (en) * 2011-11-10 2012-07-11 杨红光 Silica gel health-care shoe and making method thereof as well as silica gel insole and making method thereof
CN102617903A (en) * 2011-01-26 2012-08-01 王绪珍 Negative ion shoe material and manufacturing method thereof
CN103030782A (en) * 2012-12-05 2013-04-10 江苏恒康家居科技股份有限公司 Slow-rebound memory sponge insole material
CN103045153A (en) * 2012-11-20 2013-04-17 陈晴 Acid liquor corrosion resistant dual-component polyurethane adhesive as well as preparation method and application thereof
CN103319685A (en) * 2013-05-08 2013-09-25 杭州康诚汽车附件有限公司 Self-skinning polyurethane foam plastic and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101591420A (en) * 2008-05-27 2009-12-02 上海合达聚合物科技有限公司 A kind of plastic-blasting polyurethane composition, its preparation method and application thereof
CN102617903A (en) * 2011-01-26 2012-08-01 王绪珍 Negative ion shoe material and manufacturing method thereof
CN102551268A (en) * 2011-11-10 2012-07-11 杨红光 Silica gel health-care shoe and making method thereof as well as silica gel insole and making method thereof
CN103045153A (en) * 2012-11-20 2013-04-17 陈晴 Acid liquor corrosion resistant dual-component polyurethane adhesive as well as preparation method and application thereof
CN103030782A (en) * 2012-12-05 2013-04-10 江苏恒康家居科技股份有限公司 Slow-rebound memory sponge insole material
CN103319685A (en) * 2013-05-08 2013-09-25 杭州康诚汽车附件有限公司 Self-skinning polyurethane foam plastic and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106589905A (en) * 2016-12-21 2017-04-26 王春晓 Mattress warm in winter and cool in summer

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Application publication date: 20140205