CN103539067A - Combined arc discharge plasma water decomposition hydrogen production method and hydrogen production system - Google Patents
Combined arc discharge plasma water decomposition hydrogen production method and hydrogen production system Download PDFInfo
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- CN103539067A CN103539067A CN201310339685.8A CN201310339685A CN103539067A CN 103539067 A CN103539067 A CN 103539067A CN 201310339685 A CN201310339685 A CN 201310339685A CN 103539067 A CN103539067 A CN 103539067A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Abstract
The invention relates to a combined arc discharge plasma water decomposition hydrogen production method and hydrogen production system. According to a comprehensive method for decomposing water molecules under catalysis of a catalyst heated by an evaporator and electrochemical catalysis of plasma, the hydrogen production system is composed of a water tank, a water quantity controller, a water evaporation catalyst, a temperature sensor, an intelligent central processor, a high-frequency high-voltage power supply and a combined arc discharge plasma catalyst. The hydrogen production system is characterized in that the water tank is connected with the water quantity controller, the water quantity controller is connected with an water evaporator, the water evaporator is connected with the intelligent processor, the intelligent processor is connected with the high-frequency high-voltage power supply and the temperature sensor, the high-frequency high-voltage power supply is connected with the combined arc discharge plasma catalyst, a water evaporation chamber and a catalyst chamber are arranged in the water evaporator, and granular nickel and manganese ferrite catalysts are arranged in the catalyst chamber.
Description
Technical field
The present invention relates to a kind of combined electrical arc discharging plasma solution water hydrogen production process and hydrogen generating system thereof, belong to hydrogen energy source, energy-conserving and emission-cutting technology field, be applicable to the technical fields such as automobile, motor vehicle, industrial machinery, agricultural machine energy-saving and emission-reduction and civil kitchen range and boiler energy-saving emission-reduction.
Background technology
Closely during the last ten years, plasma technique is very fast at industrial application development, for example: plasma igniting, plasma spraying, plasma heating, plasma-torch cutting, plasma body draw long-pending incineration, refuse to process etc.Plasma body is formed a kind of state under Kennelly heaviside layer or electric discharge phenomena (being commonly called as the 4th state), is accompanied by that electric discharge phenomena will generate that excited atom, excited ion, dissociation atom, free atomic group, atom or molion group's activity chemistry thing and they are collided with other chemicals and reacting of causing.In plasma generator, discharge process makes work gas molecule lose out-shell electron and forms ionic condition, produces high temperature, more than temperature can reach several ten thousand degree through mutually colliding, and the temperature of ion is only a little more than normal temperature, therefore the temperature in electric discharge approaches normal temperature.Although plasma technique has been applied to energy-conservation, the reduction of discharging field of automobile at present, but at present disclosed known technology for example the solution water hydrogen production efficiency of plate electrode formula, coaxial electrode formula low-temperature plasma generator is not high, volume is also very large, is unsuitable for the market requirement of small power, small volume, the hydrogen manufacturing of high-level efficiency solution water.
Summary of the invention
The present invention provides a kind of combined electrical arc discharging plasma solution water hydrogen production process and hydrogen generating system thereof now, described a kind of combined electrical arc discharging plasma solution water hydrogen production process: be to be designed with moisture evaporator room and nickel is installed in moisture evaporation catalyst converter, Mn ferrite particle is the catalyst chamber of catalyzer, utilize engine exhaust heat that liquid water is heated to be to steam-like, through nickel, after Mn ferrite is the catalysis of catalyzer, cracking rapidly in combined electrical arc discharging plasma catalyst converter, be decomposed into hydrogen molecule, oxygen molecule and hydrogen ion, oxonium ion, by pipeline again can low-temperature burning, combustion-supporting hydrogen, oxygen molecule and hydrogen, oxonium ion is sent into engine chamber burning and (or is sent into boiler furnace together with after air mixed, gas stove fire head burning) acting, thereby reached increase part of fuel and oxygen or Substitute For Partial fuel and increased oxygen, realizing engine increases substantially energy-conservation, reduce discharging the object of index.
A kind of combined electrical arc discharging plasma solution water hydrogen production process of the present invention and hydrogen generating system thereof: described hydrogen generating system is to consist of water tank, water quantity controller, moisture evaporation catalyst converter, temperature sensor, Intelligent central treater, high-frequency and high-voltage power supply and combined electrical arc discharging plasma catalyst converter.It is characterized in that: for water tank, silicone tube connection rate of water added controller, water quantity controller are connecting silicone tube connection combined electrical arc discharging plasma catalyst converter for moisture evaporation catalyst converter, moisture evaporation catalyst converter with silicone tube, Intelligent central treater is connecting high-voltage power supply and is being connected combined electrical arc discharging plasma catalyst converter with temperature sensor, high-voltage power supply, temperature sensor is arranged on moisture evaporation catalyst converter, in moisture vaporizer, be provided with moisture evaporator room and catalyst chamber, in catalyst chamber, be provided with particulate state nickel, Mn ferrite catalyzer.System is used 220 volts of AC power or automobile power source.
A kind of combined electrical arc discharging plasma solution water hydrogen production process of the present invention and hydrogen generating system thereof: be the chemical additive that is added with 1-10% hydrophilic molecules in water, they are dme and the methyl alcohol of 10-90% arbitrary proportion.
A kind of combined electrical arc discharging plasma solution water hydrogen production process of the present invention and hydrogen generating system thereof: the combined electrical arc discharging plasma catalyst converter of described hydrogen generating system, to be formed by least 2 pairs of above gliding arc discharge electrodes, high-temperature insulation shell, high-temperature insulation (pottery) support, air inlet port, production wells, gliding arc discharge electrode in pairs successively same level line arrange and to be arranged on insulation (pottery) support, every pair of gliding arc discharge electrode is connecting the high-voltage output end of high-voltage power supply successively in pairs.
The invention has the beneficial effects as follows:
1, combined electrical arc discharging plasma combines the advantage of thermal plasma and cold plasma, and electron density is large, gas processing amount is large, simple in structure, cost is low, strong operability, and energy transformation ratio is high.The present invention has initiated a kind of small power combined electrical arc discharging plasma solution water hydrogen production process and hydrogen generating system thereof, adopt the comprehensive technological scheme of decomposition and plasma combined electrical arc discharging catalytic device electrochemical decomposition water molecules hydrogen and oxygen production, utilize the high feature of plasma combined electrical arc discharge energy transformation ratio, greatly improved the efficiency of hydrogen and oxygen production.
2, when for automobile, the automatic hydrogen manufacturing of motor car engine, moisture evaporation catalyst converter can directly be sleeved on the exhaust pipe of engine, and installation only need match with the vapor pipe diameter of each vehicle.
3, when for transformation, production civil boiler or the automatic hydrogen manufacturing of Industrial Boiler, the steam can be directly boiler being produced directly send into chemical catalysis device and combined electrical arc discharging plasma catalyst converter be decomposed into rapidly the burner hearth of making a gift to someone after hydrogen, oxygen burn, combustion-supporting, can realize energy-conservation 15-30%.
4, when for hydrocarbon polymer hydrogen manufacturing such as methane, methyl alcohol, gasoline, diesel oil, can coordinate other purification facilities to raise the efficiency 15-30%.
5, when when transforming the hydrocarbon polymer civil kitchen range hydrogen manufacturing such as methyl alcohol, diesel oil, can in fuel, add the water of 20-50% and participate in hydrogen manufacturing burning, can be than existing Carbinol stove, the energy-conservation 20-40% of diesel range, also can, for the transformation innovation of Sweet natural gas, liquefied petroleum gas (LPG) domestic gas kitchen range, can realize energy-conservation 15-30%.
Accompanying drawing explanation
Below in conjunction with Figure of description, the present invention is elaborated:
Fig. 1 is the one-piece construction figure of a kind of combined electrical arc discharging plasma of the present invention solution water hydrogen production process and energy-saving hydrogen system thereof.
Fig. 2 is the structure iron of combined electrical arc discharging plasma catalyst converter of the present invention.
Fig. 3 is the structure iron of moisture evaporation of the present invention, catalyst converter.
Embodiment
Shown in Fig. 1: a kind of combined electrical arc discharging plasma solution water hydrogen production process of the present invention and hydrogen generating system thereof are to consist of water tank (1), water quantity controller (2), moisture evaporation catalyst converter (3), temperature sensor (4), intelligent controller (5), high-frequency and high-voltage power supply (6), combined electrical arc discharging plasma catalyst converter (7).It is characterized in that: water tank (1) connects water quantity controller (2) with silicone tube, water quantity controller (2) connects moisture evaporation catalyst converter (3) with silicone tube, on moisture evaporation catalyst converter (3), temperature sensor (4) is installed, intelligent controller (5) is connecting high-frequency and high-voltage power supply (6), water quantity controller (2) and temperature sensor (4), moisture evaporation catalyst converter (3) is connecting combined electrical arc discharging plasma catalyst converter (7) with silicone tube, and high-frequency and high-voltage power supply (6) is connecting combined electrical arc discharging plasma catalyst converter (7).
Shown in Fig. 2: combined electrical arc discharging plasma catalyst converter of the present invention is to consist of high-temperature resistance plastice housing (8), arc-over electrode (9), high-temperature insulation (pottery) support (10), electrode scatterer (11), air inlet port (12), gas port (13), air guide chamber (14), hydrogen outlet (15), oxygen outlet (16).It is characterized in that: high-temperature insulation (pottery) support (10) is installed in the corresponding both sides of high-temperature resistance plastice housing (8), arc-over electrode (9) is installed on high-temperature insulation (pottery) support (10), electrode scatterer (11) is installed on arc-over electrode (9), in high-temperature resistance plastice housing (8), be provided with air inlet port (12), gas port (13), air guide chamber (14), at the other end of high-temperature resistance plastice housing (8), be provided with hydrogen outlet (15), oxygen outlet (16).
Shown in Fig. 3: the moisture evaporation catalyst converter (3) of hydrogen generating system of the present invention, to be formed by moisture evaporator room (3a) and chemical catalysis chamber (3b) that nickel, Mn ferrite catalyzer (17) be installed, the middle isolation of the stainless steel plate by porous, whole moisture evaporation, catalyst converter (3) are manufactured with stainless steel plate, below moisture evaporator room, be provided with prosopyle (18), above catalyst chamber, set out pore (19).
The working condition of this reality invention is such: for automobile, the automatic hydrogen manufacturing of motor car engine, be example; Now moisture evaporation catalyst converter directly suit be arranged on the exhaust pipe of engine, utilize engine exhaust heat heating water molecule, using main points is the installations that will match with the vapor pipe diameter of each vehicle of moisture evaporation catalyst converter.Starting engine, when engine do not reach normal temps, be the temperature of moisture evaporation catalyst converter (3) at the bottom of during in 105 degrees Celsius, temperature sensor (4) is failure to actuate.When the temperature that reaches normal temps, moisture evaporation catalyst converter (3) when engine reaches or surpasses 105 degrees Celsius, temperature sensor (4) sends signal to Intelligent central treater (5), and Intelligent central treater (5) is started working and controlled water quantity controller (2), high-frequency and high-voltage power supply (6), combined electrical arc discharging plasma catalyst converter (7) work.Water in water tank flows to moisture evaporation catalyst converter (3) under the control of water quantity controller (2), in moisture evaporation catalyst converter (3), be heated to form steam-like and become hydrogen partial and oxygen by nickel, Mn ferrite catalyzer (17) chemical catalysis, and then in combined electrical arc discharging plasma catalyst converter (7), continue decomposition, cracking hydrogen, oxygen, hydrogen ion, oxonium ion, through air guide chamber (14), from hydrogen outlet (15), oxygen outlet (16), be transported to engine cylinder and participate in burning workmanship, realize and improve the object that engine energy-saving reduces discharging index.
When for transforming the hydrocarbon polymer civil kitchen range hydrogen manufacturing such as the automatic hydrogen manufacturing of civil boiler or Industrial Boiler, transformation methyl alcohol and diesel oil and during for hydrocarbon polymer hydrogen manufacturing such as methane, methyl alcohol, gasoline, diesel oil, only need that hydrogen, oxygen, hydrogen ion, oxonium ion are sent into corresponding kitchen range or equipment burns or further hydrogen, oxygen are purified.
A kind of combined electrical arc discharging plasma solution water hydrogen production process of the present invention and hydrogen generating system thereof, combine the advantage of thermal plasma and cold plasma, electron density is large, gas processing amount is large, simple in structure, cost is low, strong operability, energy transformation ratio is high, it is a kind of small power combined electrical arc discharging plasma solution water hydrogen generating system, its working efficiency is than coaxial-type, dull and stereotyped dielectric barrier discharge formula plasma height, and volume is less, is conducive to install and use.More, owing to having adopted many groups compound electrode, can use the high-frequency and high-voltage power supply of smaller power, improve security and the practicality of equipment, reduce manufacturing cost.
A kind of combined electrical arc discharging plasma solution water hydrogen production process of the present invention and hydrogen generating system thereof, can determine in conjunction with practical use the output rating of system device, when for the automatic hydrogen manufacturing of motor car engine, the output rating of equipment can be determined according to engine displacement, for example: the output rating that the motor car engine of 1.6 liters can support equipment is 50-80 watt.When transforming the hydrocarbon polymer civil kitchen range hydrogen manufacturing such as methyl alcohol and diesel oil, can use output rating for the equipment of 50-180 watt.When using the equipment of 80-500 watt when transforming civilian or Industrial Boiler.
Claims (4)
1. combined electrical arc discharging plasma solution water hydrogen production process and a hydrogen generating system thereof, described a kind of combined electrical arc discharging plasma solution water hydrogen production process: be to evaporate at moisture, in catalyst converter, be designed with moisture evaporator room and nickel is installed, Mn ferrite particle is the catalyst chamber of catalyzer, and liquid water is heated to be to steam-like, through nickel, after Mn ferrite is the catalysis of catalyzer, cracking rapidly in combined electrical arc discharging plasma catalyst converter, be decomposed into hydrogen molecule, oxygen molecule and hydrogen ion, oxonium ion, described hydrogen generating system is by water tank, water quantity controller, moisture evaporation catalyst converter, temperature sensor, Intelligent central treater, high-frequency and high-voltage power supply and combined electrical arc discharging plasma catalyst converter form, and it is characterized in that: water tank connects rate of water added controller with silicone tube, water quantity controller is connecting moisture vaporizer catalyst converter with silicone tube, moisture evaporation catalyst converter connects combined electrical arc discharging plasma catalyst converter with silicone tube, and Intelligent central treater is connecting high-frequency and high-voltage power supply and temperature sensor, high-frequency and high-voltage power supply is connecting combined electrical arc discharging plasma catalyst converter, and temperature sensor is arranged on moisture evaporation catalyst converter, in moisture evaporation catalyst converter, is provided with moisture evaporator room and catalyst chamber, is provided with particulate state nickel in catalyst chamber, Mn ferrite catalyzer.In water in water tank, be added with the chemical additive of 1-10% hydrophilic molecules, they are methyl alcohol and the dme of 10-90% ratio.
2. a combined electrical arc discharging plasma solution water hydrogen production process and hydrogen generating system thereof, the combined electrical arc discharging plasma catalyst converter of described hydrogen generating system, to be formed by least 2 pairs of above gliding arc discharge electrodes, high-temperature insulation shell, high-temperature insulation (pottery) support, air inlet port, production wells, gliding arc discharge electrode in pairs successively same level line arrange and to be arranged on insulation (pottery) support, every pair of gliding arc discharge electrode is connecting the high-voltage output end of high-voltage power supply successively in pairs.
3. a kind of combined electrical arc discharging plasma solution water hydrogen production process and hydrogen generating system thereof as described in claim 1 and 2, described combined electrical arc discharging plasma catalyst converter, by high-temperature resistance plastice housing (8), arc-over electrode (9), high-temperature insulation (pottery) support (10), electrode scatterer (11), air inlet port (12), gas port (13), air guide chamber (14), hydrogen outlet (15), oxygen outlet (16) forms, it is characterized in that, in the corresponding both sides of high-temperature resistance plastice housing (8), high-temperature insulation (pottery) support (10) is installed, arc-over electrode (9) is installed on high-temperature insulation (pottery) support (10), electrode scatterer (11) is installed on arc-over electrode (9), on high-temperature resistance plastice housing (8), be provided with air inlet port (12), gas port (13), air guide chamber (14), the other end at high-temperature resistance plastice housing (8) is provided with hydrogen outlet (15), oxygen outlet (16).
4. a kind of combined electrical arc discharging plasma solution water hydrogen production process and hydrogen generating system thereof as described in claim 1 and 2, the moisture evaporation catalyst converter (3) of described hydrogen generating system, to be formed by moisture evaporator room (3a) and chemical catalysis chamber (3b) that nickel, Mn ferrite catalyzer (17) be installed, the middle isolation of the stainless steel plate by porous, whole moisture evaporation catalyst converter (3) is manufactured with stainless steel plate, below moisture evaporator room, be provided with prosopyle (18), above catalyst chamber, be provided with production well (19).
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105819398A (en) * | 2015-09-30 | 2016-08-03 | 关梦杰 | Arc plasma hydrogen-energy steam generator |
| CN106256759A (en) * | 2015-06-18 | 2016-12-28 | 谢英英 | A kind of automatic hydrogen production process of automobile engine and environment protection energy-saving equipment thereof |
| CN108502847A (en) * | 2018-04-29 | 2018-09-07 | 杭州世路胜环保科技有限公司 | Integrated plasma device for producing hydrogen |
| CN112082153A (en) * | 2020-09-11 | 2020-12-15 | 李宝伟 | Plasma state hydrogen-oxygen atom generator and control method thereof |
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Patent Citations (5)
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106256759A (en) * | 2015-06-18 | 2016-12-28 | 谢英英 | A kind of automatic hydrogen production process of automobile engine and environment protection energy-saving equipment thereof |
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| CN108502847A (en) * | 2018-04-29 | 2018-09-07 | 杭州世路胜环保科技有限公司 | Integrated plasma device for producing hydrogen |
| CN112082153A (en) * | 2020-09-11 | 2020-12-15 | 李宝伟 | Plasma state hydrogen-oxygen atom generator and control method thereof |
| CN112082153B (en) * | 2020-09-11 | 2021-08-31 | 李宝伟 | Plasma state hydrogen-oxygen atom generator and control method thereof |
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Application publication date: 20140129 |