CN103535363A - Pesticide insecticidal composition containing flubendiamide and teflubenzuron - Google Patents
Pesticide insecticidal composition containing flubendiamide and teflubenzuron Download PDFInfo
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- CN103535363A CN103535363A CN201310400411.5A CN201310400411A CN103535363A CN 103535363 A CN103535363 A CN 103535363A CN 201310400411 A CN201310400411 A CN 201310400411A CN 103535363 A CN103535363 A CN 103535363A
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- fipronil bisamide
- fluorobenzene urea
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Abstract
The invention relates to a pesticide insecticidal composition containing flubendiamide and teflubenzuro as well as use of the insecticidal composition in preventing or controlling pests. The pesticide insecticidal composition containing flubendiamide and teflubenzuro is characterized by containing active ingredients flubendiamide and teflubenzuro in a weight ratio of 50:1 to 1:50. According to the pesticide insecticidal composition containing flubendiamide and teflubenzuro disclosed by the invention, the flubendiamide and the teflubenzuro are combined and used for effectively preventing or controlling pests. Surprisingly, activity of the active compounds disclosed by the invention in controlling the pests in a combined manner is greatly higher than sum of performances of the independent active compounds, and the effect is truly synergistic effect instead of only combination of activities.
Description
Technical field
What the present invention relates to is a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea, and described Pesticidal combination is for preventing or control the purposes of pest.
Background technology
Although use chemical agent and be the most effectively means of controlling crop diseases and insect pests, use single chemical insecticide continuously for a long time high dose, easily cause the problems such as residual, the environmental pollution of medicament and resistance to resistanc pest development.Reasonably chemical insecticide is composite or be mixed and have expansion insecticidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay pest resistance and the positive feature such as drug-fast generation and development, pesticide compositional is to address the above problem one of effective method the most.Exploitation new product insecticide price is constantly soaring, and by contrast, exploitation is efficient with research, composite and the mixed insecticide of low toxicity, low-residual has small investment, the lead time is short, thereby is subject to domestic and international attention, and numerous and confused increasing develops dynamics.
Fipronil bisamide (flubendiamide), trade name ridge song.By Nihon Nihyaku Co., Ltd, researched and developed.Its chemical formula be the iodo-N'-of 3-(2-mesyl-1,1-dimethyl ethyl group-N-{4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl) ethyl]-0-tolyl phthalamide, structural formula is:
Fipronil bisamide is mainly used in vegetables, fruit tree, paddy rice, cotton control lepidoptera pest, by activating this brand-new mode of action Control pests of ryanodine receptor, these acceptors play key effect in muscle, the contraction of muscle cell needs calcium ion to be discharged into regularly in cytoplasm from calcium storehouse, ryanodine receptor, as ion channel selectively, regulates the release of calcium ion.Fipronil bisamide is combined with ryanodine receptor, causes the unconfined release of internal calcium ion, thereby stops the further contraction of muscle.With fipronil bisamide, process after insect, insect within a few minutes, present stop taking food, vigor disappears, and returns the poisoning symptoms such as Tuhe muscular paralysis, finally causes death.Because fipronil bisamide has unique chemical constitution and the novel mechanism of action, make its antagonism insect show excellent control effect.Produce without cross resistance with existing insecticide, be suitable for very much existing insecticide to produce the control of the insect of resistance, larva is had to very outstanding preventive effect, shortcoming is limited to adult control efficiency, there is no ovicidal action, interior suction conduction is not strong, and its price is comparatively expensive simultaneously, is unfavorable for that spread is used.
Fluorobenzene urea (Teflubenzuron), trade name agriculture dream spy, Teflubenzuron, special fluorine urea, be a kind of phenyl formoxyl ureas novel pesticide; there is stomach toxicity, action of contace poison, without systemic action, belong to low toxic pesticide; to fish and birds low toxicity, nontoxic to honeybee, to crop safety.The fluorobenzene urea mechanism of action is mainly to suppress chitin synthesis, after polypide contact, destroys the formation of insect chitin.Affect endepidermis and generate, while making insect decortication abnormal, can not cast off a skin smoothly lethal, but effect slowly.The Lepidoptera of the generation resistances such as organic phosphor, pyrethroid and coleopteran pest are had to special efficacy, should apply in ovum phase and low instar larvae phase, invalid to sucking pests such as leafhopper, plant hopper, aphids.Chemical name is 1-(3,5-bis-chloro-2,4-difluorophenyl)-3-(2,6-difluoro benzoyl) urea, and its chemical formula is:
The activity of described individually oriented compound is good; Yet they are not to meet the necessary satisfied high request of insecticide, miticide or nematocide institute while using at low rate of application or for independent insect.
Summary of the invention
The present invention seeks to as solving above-mentioned at least one problem or its at least one aspect, in particular for effectively controlling pest, through large number of biological test screen, the unexpected discovery of the inventor can prevent fipronil bisamide and the combination of fluorobenzene urea or control pest for effective.Surprisingly, the activity of the combination of reactive compound of the present invention control pest is much higher than independent active ingredient physical performance summation.This unexpected effect is real synergistic effect, and be not only active add and.
Therefore, an object of the present invention is to provide a kind of agricultural insecticide composition and use thereof containing fipronil bisamide, fluorobenzene urea.
A kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea is to take following technical scheme to realize:
An agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, is characterized in that: contain active component fipronil bisamide and fluorobenzene urea.
An agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, wherein the weight ratio of fipronil bisamide and fluorobenzene urea is that 50:1 is to 1:150.
An agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, wherein the weight ratio of fipronil bisamide and fluorobenzene urea is that 25:1 is to 1:100.
An agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, wherein the weight ratio of fipronil bisamide and fluorobenzene urea is that 10:1 is to 1:50.
An agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, wherein the weight ratio of fipronil bisamide and fluorobenzene urea is that 5:1 is to 1:25.
An agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, wherein the weight ratio of fipronil bisamide and fluorobenzene urea is that 1:1 is to 1:5.
An agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, is characterized in that the weight of described fipronil bisamide and fluorobenzene urea accounts for described composition 1%-90% by weight altogether.
An agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, is characterized in that described fipronil bisamide and fluorobenzene urea account for described composition 5%-80% by weight altogether.
An agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, is characterized in that described fipronil bisamide and fluorobenzene urea account for described composition 20%-50% by weight altogether.
Described a kind of agricultural insecticide composition, also comprises surfactant and/or extender containing fipronil bisamide and fluorobenzene urea.
The agricultural insecticide composition of described a kind of fipronil bisamide and fluorobenzene urea, formulation is missible oil, suspending agent, seed coat agent, water dispersible granules, wetting powder, suspension emulsion, extrudes granule, coated granule, aerosol, aqueous emulsion, microcapsule suspending agent.
An agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, wherein said composition also comprises one or more other active components.
On the other hand, the present invention also provides a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea for preventing or control the purposes of animal pest, and wherein animal pest is insect, acarid.
On the other hand, the present invention also provides a kind of prevention or has controlled the method for animal pest, a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea is acted on to the propagating materials of target useful plant, target animal insect or its environment, target useful plant.Described plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
Cover crop in case a method for animal pest invasion and attack comprise crop contacted with the agricultural insecticide composition that contains fipronil bisamide and fluorobenzene urea.
A method for prevention or control animal pest, comprises separately, uses successively or simultaneously fipronil bisamide, fluorobenzene urea.
Another object of the present invention is to provide a kind of for preventing or control the kit of animal pest, and it comprises fipronil bisamide and fluorobenzene urea.
A kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea is used for fipronil bisamide and the combination of fluorobenzene urea effectively prevention or controls pest.Surprisingly, the activity of the combination of reactive compound of the present invention control pest is much higher than independent active ingredient physical performance summation.Having effect is real synergistic effect, and be not only active add and.
Embodiment
The present invention finds: not only can bring the additive property for insecticidal spectrum to improve fipronil bisamide and the combination of fluorobenzene urea, but also realize amazing synergy.
Term used herein " synergy " refers to that the insecticidal effect of activating agent combination of the present invention or composition is greater than each activating agent effect sum, and in other words, its effect is superadditivity.
The invention provides a kind of fipronil bisamide and fluorobenzene urea of comprising as the agricultural insecticide composition of active component.
The invention provides a kind of fipronil bisamide and fluorobenzene urea of comprising as the agricultural insecticide composition of active component, wherein fipronil bisamide and fluorobenzene urea weight ratio be 50:1 to 1:150, preferably 25:1 is to 1:100, more preferably or 10:1 to 1:50, more preferably 5:1 is to 1:25, more preferably 1:1 to 1:5.
In the present composition, the total amount of active compound component can be selected according to material elements, to realize desired effect.Described factor for example, formulation, object to be administered, application process etc.Fipronil bisamide and fluorobenzene urea altogether account for described composition by weight 5% to 90%, preferably 10% to 80%, more preferably 20% to 50%.
Composition of the present invention optionally comprises acceptable surfactant or extender on agronomy.
According to the present invention, term " filler " refers to can be combined with reactive compound or for example combine, so that it is easier to be administered to the natural or synthetic organic or inorganic compound of object (plant, crop or careless class).Therefore, described carrier is preferably inertia, at least should be agronomically acceptablely.Described filler can be solid or liquid.
In the present invention, operable inactive filler can be both that solid can be also liquid, can be used as for example having that solid-filling agent used: the phyteral powdery type (particle of soybean meal, starch, grain dust, wood powder, bark powder, sawdust, walnut shell powder, wheat bran, cellulose powder, coconut husk, corncob and tobacco stem for example, extract residue after plant essence etc.), paper, sawdust, pulverize synthesized polymer body, clay class (such as kaolin, bentonite, acid china clay etc.), the talcum powder class of synthetic resin etc.Silica (for example diatomite, silica sand, mica, moisture silicic acid, calcium silicates), chemical fertilizer, the clay fertilizer of active carbon, natural mineral matter class (float stone, attapulgite and zeolite etc.), the inorganic mineral powder of firing diatomite, sand, plastics medium etc. (such as polyethylene, polypropylene, polyvinylidene chloride etc.), potassium chloride, calcium carbonate, calcium phosphate etc., ammonium sulfate, ammonium phosphate, urea, ammonium chloride etc., these materials can be used separately or two or more is mixed.
Can be used as can selecting of liquid filling agent use in following material, water for example, alcohol type (methyl alcohol for example, ethanol, isopropyl alcohol, butanols, ethylene glycol etc.), ketone (acetone for example, methyl ethyl ketone, isobutyrone, cyclohexanone etc.), ethers (ether for example, dioxanes, methylcellulose, oxolane etc.), aliphatic hydrocarbon class (kerosene for example, mineral wet goods), aromatic hydrocarbons class (benzene for example, toluene, dimethylbenzene, solvent naphtha, Fluhyzon, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, chlorobenzene, Deng), halogenated hydrocarbon class, amide-type, sulfone class, dimethyl sulfoxide (DMSO), mineral and vegetable oil, animal wet goods.
For making the emulsification of active ingredient compound, disperse, solubilization, and/or wetting can use surfactant for example can enumerate fatty alcohol-polyoxyethylene ether, polyoxyethylene alkylaryl ether, polyoxyethylene high-grade aliphatic ester, the phosphate of polyoxyethylene alcohol or phenol, the fatty acid ester of polyalcohol, naphthalene sulfonic acids polymer, lignosulfonates, a shape copolymer of macromolecule comb shape, butyl naphthalene sulfonate, alkylaryl sulfonates, alkyl sodium sulfosuccinate, grease, fatty alcohol and ethylene oxide condensate, the polyacrylate of alkyltaurate, protein hydrolysate.Suitable oligosaccharide thing or polymer, for example combination of the vinyl monomer based on independent, acrylic acid, polyoxyethylene and/or polyoxypropylene or itself and for example (polynary) alcohol or (polynary) amine.
For making the dispersion of active ingredient compound, stabilisation, adhering to, can use such as adjuvants such as xanthans, aluminium-magnesium silicate, gelatin, starch, methyl cellulose, polyvinyl alcohol, polyvinyl acetate and natural phospholipid (as cephalin and lecithin) and synthetic phospholipid, bentonite, sodium lignin sulfonates.
The optional spent glycol of antifreezing agent wherein, propane diols, glycerine, sorbierite.Deflocculant as suspension product can be used the adjuvant such as naphthalene sulfonic acids polymer, polymeric phosphate etc.As defoamer, can use silicone defoaming agent.For the mobility of improvement solid product, can use adjuvants such as paraffin, stearate, alkylphosphonate.
Operable colouring agent, inorganic pigment for example, as iron oxide, titanium oxide and Prussian blue; And organic pigment/dyestuff: alizarin dyes, azo dyes and metal phthalocyanine dyestuff; And trace element, for example molysite, manganese salt, boron salt, mantoquita, cobalt salt, molybdenum salt and zinc salt.
Optionally, also can comprise other annexing ingredient, for example protecting colloid, adhesive, thickener, thixotropic agent, bleeding agent, stabilizing agent, screening agent.
The formulation of described a kind of composition pesticide containing fipronil bisamide and fluorobenzene urea is: aerosol, suspending agent, micro-capsule granula, granula subtilis, concentrate can flow, ready to use solution agent, aqueous emulsion, oil emu, fine granule, oil dispersion powder, the miscible mobility concentrate of oil, the miscible liquid of oil, foaming agent, paste, suspending concentrate, suspension emulsion, solubility concentrates thing, soluble powder, granule, water dispersible granules, water-soluble granular and/or tablet, water solube powder, wetting powder, natural or synthetic material through reactive compound dipping, microcapsules in polymeric material and water-dispersible granule.
In preferred embodiments, described agricultural insecticide composition is suspending agent, water dispersible granules, wetting powder, suspension emulsion, missible oil, seed coat agent, wetting powder, extrudes granule, coated granule, aerosol, aqueous emulsion, microcapsule suspending agent.
Described preparation of the present invention can be mixed described reactive compound to prepare with conventional additives by known way.Described conventional additives is as conventional extender and solvent or thinner, emulsifier, dispersant and/or adhesive or fixative, wetting agent, waterproofing agent, if need, can also comprise drier and colouring agent, stabilizing agent, pigment, defoamer, preservative, thickener, water and other processing aid.
These compositions not only comprise and can be applicable to immediately pending object as spraying or dusting equipment by suitable equipment, but also be included in to be applied to, need the concentrated business composition that dilutes before object.
Composition of the present invention can be made the preparation that is suitable for using with the form of the composition of its active compound component, also can use with the form of the combination of the commodity preparation of its suitable dosage.
Composition of the present invention can also be co-administered with other active component, such as fungicide, bactericide, attractant, insecticide, miticide, nematocide, growth regulator, weed killer herbicide, safener, fertilizer or semiochemical etc. of described other active component.
On the other hand, the present invention also provides a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea for preventing or control the purposes of animal pest, preferred arthropods and nematode, particularly insect and spider guiding principle arthropods show to the good tolerance of plant, to the hypotoxicity of homoiothermy species and good Environmental compatibility simultaneously.To normal sensitivity, there is activity with kind resistance, there is to activity all or special developmental stage.Above-mentioned animal pest comprises:
From Isopoda, damp worm (Oniscus aselluse) for example, pillworm (Armadillidium vulgare), and spot pillworm (Porcellio scaber).
From Diplopoda, Blaniuus guttulatus for example.
From chilopoda, for example centipede (Geophilus carpophagus) and common house centipede dragonfly (Scutigera spp.).
From Symphyla, clean symphilid (Scutigerella immaculate) for example.
From Thysanoptera, silverfiss (Lepisma saccharina) for example.
From Collembola, Onychiurus arcticus (Onychiurus armatus) for example.
From orthoptera, house cricket found in a kitchen (Acheta domesticus) for example, Gryllotalpa spp (Gryllotalpa spp.), torrid zone migratory locusts (Locusta migratoria migratorioides), the negative locust of long volume belongs to (Melanoplus spp.), and desert locust (Schistocerca gregaria).
From Blattaria, oriental cockroach (Blatta orientalis) for example, American cockroach (Periplaneta Americana), leucophaea maderae (Leucophaea maderae), Groton bug (Blattella germanica).
From Dermaptera, European earwig (Forficula auricularia) for example.
From Isoptera, Reticulitermes for example.
From Anoplura, body louse (Pediculus humanus corporis) for example, blind lice belongs to, and long volume lice genus, Trichodectes, Damalinia.
From thrips, greenhouse Hercinothrips spp (Hercinothrips femoralis) for example, cotton thrips (Thrips tabaci), Thrips palmi and Frankliniella accidentalis.
From Heteroptera, for example Eurygasterspp belongs to, middle red cotton bug (Dysdercus intermedius), and beet is intended lace bug (Piesma quadrata), the smelly stinkbug in temperate zone (Cimex lectularius), red abdomen is hunted stinkbug (Rhodnius prolixus) and Triatoma.
From Homoptera, wild cabbage aleyrodid (Aleurodes brassicae) for example, Bemisia tabaci (Bemisia tabaci), Trialeurodes vaporariorum Westwood (Trialeurodes vaporariorum), cotten aphid (Aphis gossypii), cabbage aphid (Brevicoryne brassicae), the hidden knurl volume of tea deer aphid (Cryptomyzus ribis), black bean aphid (Brevicoryne brassicae), apple aphid (Aphispomi), apple aphid (Eriosoma lanigerum), mealy plum aphid (Hyalopterus arundinis), grape phylloxera (Phylloxera vastatrix), , Pemphigus, English grain aphid (Macrosiphum avenae), knurl volume Aphis, hops knurl volume aphid (Phorodon humuli), grain Rhopalosiphum spp (Rhopalosiphum padi), leafhopper belongs to, Euscelisbilobatus, rice leafhopper (Nephotettix cincticeps), brown apricot scale (Lecaniumcorni), olive helmet (Saissetia oleae), rice small brown rice planthopper (Laodelphaxstriatellus), brown back rice plant hopper (Nilaparvata lugens), California red scale (Aonidiel1a aurantii), sweet-scented oleander circle a red-spotted lizard (Aspidiotus hederae), mealybug belongs to and Psylla spp.
From Lepidoptera, pink bollworm (Pectinophora gossypiella) for example, loose looper (Bupalus piniarius), winter geometrid moth (Chemimatobia brumata), Lithoclletis blancardela, cherry ermine moth (Hyponomeuta padella), diamond-back moth (Plutella xylostel1a), tent caterpillar (Malacosoma neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrix thurberiella), tangerine leaf miner (Phyllocnis tiscitrella), Agrotis, root eating insect belongs to, brown Noctua, earias insulana (Eariasinsulana), Noctua, tomato moth (Mamestra brassicae), small noctuid (Panolis flammea), Noctua, cabbage looper (Trichoplusiani), codling moth (Carpocapsa pomonella), Pier, snout moth's larva belongs to Pyrausta nubilalis, Anagasta kuehniella (Ephestia kuehniella), rheum officinale snout moth's larva (Galleriamellonel1a), bag casemaking clothes moth (Tineola bisselliella), etting moth (Tineapell ionel1a), brown oecophorid (Hofmannophila pseudospretella), yellow tail leaf roller (Cacoecia podana), Capua reticulana, choristoneura fumigerana (Choristoneura fumiferana), grape codling moth (Clysia ambiguella) (Clysia ambiguel1a), tea yellow leaf curl moth (Homona magnanima), the green leaf roller of oak (Tortrix viridana), volume snout moth's larva belongs to, Oulema oryzae (Oulema oryzae).
From coleoptera, furniture death watch beetle (Anobium punctatum) for example, lesser grain borer (Rhizopertha dominica), Bruchidius obtectus, common bean weevil (Acanthoscelides obtectus), house longhorn beetle (Hylotrupes bajulus), the purple flea beetle (Agelastica alni) of alder, colorado potato beetle (Leptinotarsadecemlineata), horseradish ape chrysomelid (Phaedon cochleariae), chrysomelid genus, the blue flea beetle (Psylliodes chrysocephala) of rape, mexican bean ladybird (Epi1achna varivestis), hidden wing first belongs to, saw chest ostomatid (Oryzaephilus surinamensis), weevil belongs to, Sitophilus, vine black ear resembles (Otiorrhynchus sulcatus), banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil (Ceuthorrhynchusassimilis), alfalfa weevil (Hypera postica), khapra beetle belongs to, spot khapra beetle belongs to, Anthrenus, hair is moth-eaten to be belonged to, powder is moth-eaten to be belonged to, pollen beetle (Meligethes aeneus), Ptinus, golden yellow ptinid (Niptus hololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium, bloom first (Tenebrio molitor), click beetle belongs to, acupuncture needle Eimeria, angle cockchafer (Melolontha melolontha), chafer in June (Amphimallon solstitialis), brown New Zealand's rib wing angle cockchafer (Costelytra zealandica) and rice water resemble (Lissorhoptrus oryzophilus).
From Hymenoptera, for example Neodiprion spp belongs to, tenthredinidae, and field ant belongs to, MonomoriumMayr (Monomorium pharaonis) and Vespa.
From diptera, Aedes for example, spot Anopheles, Culex, drosophila yellow gorilla (Drosophila melanogaster), Musca, male servant fly belongs to, calliphora erythrocephala (Calliphoraerythrocephala), lucilia sericata belongs to, Carysomyia, cuterbrid belongs to, Gasterophilus, Hippobosca, chela fly belongs to, nose fly belongs to, Hypoderma, Pituophis, Tannia belongs to, Bibio hortulanus, Sweden's wheat stem chloropid fly (Oscinella frit), wheat fly belongs to, spinach leaf miner (Pegomyiahyoscyami), Mediterranean fruitfly (Ceratitis capitata), dacus oleae (Dacusoleae) and European daddy-longlegs (Tipula paludosa), Hylemyia, and Hippelates.
From Siphonaptera, for example Xenopsyllacheopis (Xenopsylla cheopis) and angle leaf lice mouse.
From arachnids, scorpion (Scorpio maurus) for example, black widow (Latrodectus mactans), Acarus siro (Acarus siro), Dermanyssus gallinae (Dermanyssys gallinae), tea deer goitre mite (Eriophyesribis), citrus rust mite (Phyllocoptruta oleivora), Boophilus, carrapato belongs to, Amblyomma, glass eye tick belongs to, and hard tick belongs to, Acarus tritici belongs to, ginger mite belongs to, and itch mite belongs to, the line genus of wriggling, Bryobia praetiosa (Bryobia praetiosa), two spotted spider mite belongs to, red autumnal leaves are wriggled genus, sharp tenthredinidae, short whisker Acarapis.
Parasitic plant nematode comprises that for example Pratylenchidae belongs to, similar similes thorne (Radopholus similis), fuller's teasel stem eelworm (Ditylenchus dipsaci), the nematode of partly puncturing (Tylenchulus semipenetrans), Heterodera, ball Heterodera, Meloidogyne, Aphelenchoides, minute hand Turbatrix, Xiphinema, and burr Turbatrix, remote spring dragonfly genus.
A kind of Pesticidal combination containing fipronil bisamide and fluorobenzene urea of the present invention is specially adapted to control " biting " insect, and these insects specifically comprise following insect:
From Lepidoptera, pink bollworm (Pectinophora gossypiella) for example, loose looper (Bupalus piniarius), winter geometrid moth (Cheimatobia brumata), Lithocolletis blancardel1a, cherry ermine moth (Hyponomeuta padella), diamond-back moth (Plutella xylostella), tent caterpillar (Malacosoma neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrix thurberlella), tangerine leaf miner (Phyllocnistiscitrella), Agrotis, root eating insect belongs to, brown Noctua, Egyptian complete just bored (Eariasinsulana), Noctua, tomato moth (Mamestra brassicae), small noctuid (Panolisflammea), Noctua, powder pattern moth (Trichoplusiani), codling moth (Carpocapsa pomonella), Pier, snout moth's larva belongs to, Pyrausta nubilalis, Anagasta kuehniella (Ephestia kuehniella), rheum officinale snout moth's larva (Gal1eriamellonella), bag casemaking clothes moth (Tineola bisselliella), etting moth (Tineapellionella), brown oecophorid (Hofmannophila pseudospretella), yellow tail leaf roller (Cacoecia podana), Capua reticulana, choristoneura fumigerana (Choristoneura fumiferana), grape is stayed moth-eaten moth (Clysia ambiguella), tea yellow leaf curl moth (Homona magnanima), the green leaf roller of oak (Tortrix viridana), volume snout moth's larva belongs to, Oulema oryzae (Oulema oryzae).
From coleoptera, furniture death watch beetle (Anobium punctatum) for example, lesser grain borer (Rhizopertha dominica), Bruchidius obtectus, common bean weevil (Acanthoscelides obtectus), house longhorn beetle (Hylotrupes bajulus), the purple flea beetle (Agelastica alni) of alder, colorado potato beetle (Leptinotarsa decemlineata), horseradish ape chrysomelid (Phaedon cochleariae), chrysomelid genus, the blue flea beetle (Psylliodes chrysocephala) of rape, mexican bean ladybird (Epilachnavarivestis), hidden wing first belongs to, saw chest ostomatid (Oryzaephilus surinamensis), weevil belongs to, Sitophilus, during vine black ear beak (Otiorrhynchus sulcatus), banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil (Ceuthorrhynchus assimilis), alfalfa weevil (Hypera postica), khapra beetle belongs to, spot khapra beetle belongs to, Anthrenus, hair is moth-eaten to be belonged to, powder is moth-eaten to be belonged to, pollen beetle (Meligethes aeneus), Ptinus, golden yellow ptinid (Niptus hololeucus), wheat ptinid (Gibbium psylloides), Tribolium, bloom first (Tenebrio molitor), click beetle belongs to, acupuncture needle Eimeria, angle cockchafer (Melolontha melolontha), chafer in June (Amphimallon solstitialis), brown New Zealand's rib wing angle cockchafer (Costelytra zealandica) and rice water resemble (Lissorhoptrus oryzophilus).
A kind of Pesticidal combination containing fipronil bisamide and fluorobenzene urea of the present invention is also applicable to control " sucking " insect, and these insects specifically comprise following insect:
From Homoptera, wild cabbage aleyrodid (Aleurodes brassicae) for example, Bemisia tabaci (Bemisia tabaci), Trialeurodes vaporariorum Westwood (Trialeurodes vaporariorum), cotten aphid (Aphis gossypii), cabbage aphid (Brevicoryne brassicae), the hidden knurl volume of tea deer aphid (Cryptomyzus ribis), black bean aphid (Aphis fabae), apple aphid (Aphispomi), apple aphid (Eriosoma lanigerum), mealy plum aphid (Hyalopterusarundinis), grape phylloxera (Phylloxera vastatrix), goitre cotten aphid belongs to, English grain aphid (Macrosiphum avenae), knurl volume Aphis, hops knurl volume aphid (Phorodonhumuli), grain Rhopalosiphum spp (Rhopalosiphum padi), leafhopper belongs to, Euscelisbilobatus, rice leafhopper (Nephotettix cincticeps), brown apricot scale (Lecaniumcorni), olive helmet (Saissetia oleae), rice small brown rice planthopper (Laodel phaxstriatellus), brown back rice plant hopper (Nilaparvata lugens), California red scale (Aonidiella aurantii), sweet-scented oleander circle a red-spotted lizard (Aspidiotus hederae), mealybug belongs to and Psylla spp.
On the other hand, the present invention also provides a kind of prevention or has controlled the method for animal pest, a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea is acted on to the propagating materials of target useful plant, target animal insect or its environment, target useful plant.Described plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
Described common processing method as by pouring (dipping), drip irrigation, spraying, evaporation, atomization, broadcast sowing, the mode such as dusting, foaming, coating; Or as solvable pulvis, liquid agent, the slurry for seed or rice shoot processing; And by dry treatment, slurry processing, liquid handling.Also can use described compound by ultra low volume method, or described compound or composition itself are injected to soil.
Method of the present invention also provide with separately, reactive compound successively or described in simultaneous system combined administration.
It is common with favourable that Pesticidal combination of the present invention is used with following dosage conventionally:
-for leaf portion, process: 0.1-10000 g/ha, preferably 10-1000g/ha, more preferably 50-300g/ha; For dipping or for instiling and using, described dosage even also can reduce, particularly when using inert base as asbestos or perlite;
-for seed treatment: 2-200 g/100kg seed, preferably 3-150g/100kg seed;
-for soil treatment: 0.1-10000g/ha, preferred 1-5000g/ha.
Above-mentioned dosage is only general exemplary dose, and during actual using, those skilled in the art can, according to actual conditions and needs, especially adjust rate of application according to the character of pending plant or crop and insect pest situation.
Pesticidal combination of the present invention has good plant compatibility, be suitable for Control pests, particularly insect, acarid, nematode, and fungi, rodent, microorganism etc., it is preferably with the composition that acts on leaf processing, soil treatment and seed, rice shoot and process.
According to the present invention, can process the each several part of all plant and plant.Plant this be interpreted as representing all plants and plant population as desired with undesirable wild plant or crop (crop that comprises spontaneous growth).Crop can be the plant obtaining by conventional breeding and optimum seeking method; or the plant that the combination by biotechnology and genetic engineering method or these methods obtains, comprises genetically modified plants and comprises the plant cultivation kind that can or can not be protected by plant breeder's certificate.Plant each several part is interpreted as representing that all grounds and under ground portion and plant organ are as seedling, leaf, Hua Hegen, and the example that can mention is leaf, pin, stem, dry, flower, fruit body, fruit and seed and root, stem tuber and rhizome.The part of plant also comprises plant and vegetative propagation and the sexual propagation material after results, for example seedling, stem tuber, rhizome, transplant and seed.
As mentioned above, according to the present invention, can process all plants and part thereof.In preferred embodiments, those plant varieties and the part thereof having processed wild plant kind and plant cultivation kind or obtained as hybridization or protoplast fusion by conventional Biology Breeding method.In a more preferred embodiment, processed by genetic engineering (genetically modified plants and plant cultivation kind and the part thereof that obtain in conjunction with conventional method (Genetically Modified Organisms) if desired.
According to the present invention, particularly preferably be processing in all cases available on market or use in the plant of plant cultivation kind.
According to plant variety or plant cultivation kind, its position and growth conditions (soil, weather, vegetative period, food), according to processing of the present invention, also can produce to surpass to add with (" and work in coordination with ") effect.So, for example reduce consumption and/or widen activity profile and/or increase according to the activity of the spendable material of the present invention and composition, better plant growth, strengthen to the tolerance of high temperature or low temperature, strengthen to dry early, the tolerance of water or soil salt content, increase the performance of blooming, be easier to results, hasting of maturity, higher harvest yield, better quality and/or results product higher nutritive value, better the machinability of storage stability and/or results product all becomes possibility, this has exceeded the effect of actual desired.
Pesticidal combination of the present invention is not only effective to plant insect, sanitary insect pest and store pest, and as also effective in hard tick, soft ticks, itch mite, lice shape Pu mite, fly (Ci Shi and lick formula), parasitic fly larva, lice, head louse, bird lice and flea to parazoon (vermin) aspect animal doctor.These parasites comprise:
Anoplura, Haematopinus for example, jaw lice belongs to, and lice belongs to, and Phtirus belongs to, and lice belongs to pipe;
Mallophaga and Amblycera and thin angle suborder, hair Trichodectes for example, Menopon belongs to, huge Linognathus, Trichodectes, Werneckiella belongs to, and Lepikentron belongs to, Damalinia, Trichodectes, Felicola;
Diptera and Nematocera and Brachycera, Aedes for example, Anopheles, Culex, Simulium, Eusimulium, owl midge, Lutzomyia belongs to, Bitting midge, Chrysops, knurl Gadfly, Atylotus, Gadfly, Chrysozona, Philipomyia belongs to, honeybee Hippobosca, Musca, Hydrotaea, chela fly belongs to, and horn fly belongs to, and fly does not belong to, Fannia, Glossina, Calliphora Lucilia, Carysomyia, Wohlfahrtia, Sarcophaga, Oestrus, Hypoderma, Gasterophilus, Hippobosca, Lipoptena belongs to, Melophagus;
Anoplura, for example lice belongs to, and the first lice of Cape jasmine belongs to, Xanthopsyllacheopis mouse, Ceratophyllus;
Heteroptera, Cimex for example, vertebra Reduvius, red abdomen is hunted Toona, wholecircle Toona;
Blattaria, oriental cockroach for example, American cockroach, Groton bug, blattaria belongs to;
Acarina and rear valve suborder and Mesostigmata, for example sharp port belongs to, Ornithodoros, residual beak tick belongs to, and hard tick belongs to, Amblyomma, Boophilus, Dermacentor, Haemophysalis belongs to, Hyalomma, Rh, Dermanyssus, stings sharp mite and belongs to, Pneumonyssus, Sternostoma, Varroa;
Spoke mite suborder (front valve suborder) and flour mite order (Astigmata), honeybee Tarsonemus for example, Cheyletiella, li mite belongs to fowl chela, Myobia, Psorergates, Demodex, Trombidium, yak mite belongs to, Tyroglyphus, Tyrophagus, Caloglyphus, under neck, mite belongs to, and wing mite belongs to, and scabies mite belongs to, Psoroptes, Notoedres, itch mite belongs to, and scab mite belongs to, lump mite belongs to, Cytoleichus, and epithelium mite belongs to.
Active compound composition of the present invention is also applicable to the agriculture livestock of control invasion and attack if ox, sheep, goat, horse, pig, donkey, camel, buffalo, rabbit, chicken, turkey, duck, goose, honeybee, other domestic animals are as dog, cat, the bird of raising in cages, sight, and reward fish and so-called experimental animal are as the arthropods of hamster, cavy, rat and mouse.By preventing and treating these arthropodss, should be able to reduce situation dead and reducing of the productivity (for meat, milk, wool, animal skin, egg, honey etc.), so the Pesticidal combination of the application of the invention can obtain more economical and simple livestock breeding.
Insecticidal combinations material of the present invention is in known manner for animal doctor aspect, by administration in the form intestines with for example tablet, capsule, potus, draught, granule, paste, bolus, feeding method, suppository, by such as injection (muscle is interior, subcutaneous, intravenous, peritonaeum are interior etc.), implant enteron aisle external administration, nose administration, with for example flood or soak, spray, pour, the form percutaneous dosing of spot printing, washing, dusting, and by the mechanograph containing reactive compound as necklace, ear tag, tail tag, limb girdle, halter rope, printer etc.
When rich etc. for ox, poultry, family, Pesticidal combination for example, can contain 1-80wt% reactive compound as preparation (pulvis, emulsion, flowable), directly or dilution 100-10000 use after doubly, or can be used as chemical immersion use.
In addition, found that Pesticidal combination of the present invention has effective insecticidal action to destroying the insect of industrial materials.
Propose as an example and preferably following insect, but be not limited to this:
Coleoptera is as North America house longhorn beetle (Hyloptrupes bajulus), green brave longicorn (Chlorophorus pilosis), furniture death watch beetle, report dead material death watch beetle (during Xestobiumrufovillosu, class wing death watch beetle (Ptilinus pecticornis), Dendrobium pertinex, pine bud branch death watch beetle (Ernobius mol1is), pine product death watch beetle (Priobiumcarpini), Lyctus brunneus Stephens (Lyctus brunneus), powder moth-eaten (Lyctus africanus), south powder moth-eaten (Lyctus planicollis), quercitron moth-eaten (Lyctus linearis), powder moth-eaten (Lyctus pubescens), chest powder moth-eaten (Trogoxylon aequale), minthea rugicollis (M i n t h e s r u g i c o l l i s), material bark beetle belongs to, wood strip bark beetle belongs to, coffee black long moth-eaten (Apa temonachus), Bostrychus capucins, brown different long wing moth-eaten (Heterobostrychusbrunneus), the long moth-eaten genus of sour jujube, bamboo pole powder long moth-eaten (Dinoderus minutus).
Dermaptera, blue black wood wasp (Sirex juvencus) for example, the large wood wasp of dragon spruce (Urocerusgigas), safely strengthens wood wasp (Urocerus gigas taignus), large wood wasp (Urocerus augur).
Termite, as kalotermitid (Kalotermes flavicollis), a fiber crops heap sand termite (Cryptotermes brevis), the Indian-Pakistani different termite of structural wood (Heterotermes indicola), American-European reticulitermes flavipe (Reticulitermes flavipes), reticulitermes flavipe (Reticulitermes santonensis), reticulitermes flavipe (Reticuli termeslucifugus), Darwin Australia termite (Mastotermes darwiniensis), the ancient termite (Zootermopsis nevadensis) in Nevada, Workers of Coptotermes formosanus Shiraki (Coptotermesformosanus).
Thread tail order, as Taiwan silverfish (Lepisma saccharina).
Industrial materials are herein interpreted as representing that non-living material is as preferred polymers, adhesive, glue, paper and plate, leather, timber, timber-work and coating.Wish is protected its material that avoids insect infestations particularly preferably timber and timber fabricated product.
Available Pesticidal combination of the present invention or containing the timber of the mixture protection of said composition and timber fabricated product be interpreted as representation case as:
Construction timber, wooden frame, railroad tie, bridge member, breakwater, the wooden vehicles, box, pallet, container, phone mast, timber partition, wooden window and door, plywood, particle board, joinery, or be generally used for building construction or the joiner's timber-work of building.
Pesticidal combination can former state, with concentrate or conventional formulation, use as the form of pulvis, granule, solution, suspending agent, emulsion or paste.
Above-mentioned preparation can be prepared in a manner known way, for example, by by reactive compound, desiccant and the UV stabilizing agent with at least one solvent or thinner, emulsifier, dispersant and/or adhesive or fixative, waterproofing agent, while needing and the colouring agent while needing and pigment and other processing aids mix.
Pesticidal combination or concentrate for the protection of timber and timber-work contain the reactive compound of the present invention that concentration is 0.0001-95wt%, particularly 0.01-60wt%.
The consumption of composition or concentrate depends on kind and quantity and the medium of insect.Optimum amount in all cases can be determined by dispenser campaign, but the reactive compound of the materials'use 0.0001-20wt% protecting according to wish, preferred 0.001-10wt% is conventionally just enough.
Pesticidal combination of the present invention is also applicable to prevent and treat the animal pest of enclosure space, particularly insect, spider and acarid, and described enclosure space is as house, factory floor, office, cabin etc.They can be used for preventing and treating these insects in family expenses desinsection product, and they have activity to sensitivity and kind resistance with to all developmental stage.These insects comprise:
Scorpionida, for example, clamp scorpion (Buthus occitanus).
Acarina, for example adobe tick, stick up edge sharp-edged tick, Bryobia, Dermanyssus gallinae, the sweet mite of family's food, tampan tick, brown dog tick, trombiculid (Trombicula alfreddugesi), Neutrombicula autumnalis, dermatophagoides pteronyssinus, dust mite.
Araneida, for example cockle Zhu Ke，Yuan spider section.
Opiliones, for example, intend scorpion class (Pseudoscorpiones chelifer), Pseudoscorpiones cheiridium, Opiliones phalangium.
Isopoda, damp worm for example, pillworm.
Sufficient order doubly, for example, have a zebra land, mountain cricket Eimeria.
Lip foot order, for example Scolopendra.
Zygentoma order, for example comb silverfish genus, Taiwan silverfish, Lepismodes inquilinus.
Blattaria, for example oriental cockroach, Groton bug, Blatella (Bl a t t el1a asahinai), leucophaea maderae, angle abdomen Lian genus, wooden Lian genus, Australian cockroach, American cockroach, the large Lian of foxiness, Peroplaneta fluligginosa, long palpus blattaria.
Saltatoria, for example Shuai of family.
Dermaptera, for example European earwig.
Isoptera, for example kalotermitid belongs to, Reticulitermes.
Worm order, for example Lepinatus belongs to, powder is breathed heavily Eimeria.
Coleoptera, Anthrenus for example, fur is moth-eaten to be belonged to, and khapra beetle belongs to, a long lesser grain borer, hidden instep cuckoo Eimeria, Ptinus, lesser grain borer, grain weevil, rice weevil, corn weevil, Stegobium paniceum.
Diptera, Aedes aegypti for example, aedes albopictus, Aedes taeniorhynchus, Anopheles, calliphora erythrocephala, great number sarcophagid, Culex quinquefasciatus, northern house, Culex tarsalis, slow-witted fly belongs to, Fannia canicularis, housefly, Bai Ling belongs to, sarcophagid (Sarcophaga carnaria), Simulium, male servant chela fly, daddy-longlegs (Tipula paludosa).
Lepidoptera, lesser wax-moth for example, galleria mellonella waxmoth, the ancient phycitid of India, rain moth, bag rain moth, curtain rain moth.
Siphonaptera, the first lice of dog comb for example, Ctenocephalides felis felis, humanlice, chigo, Xanthopsyllacheopis.
Hymenoptera, for example, blazon hunchbacked ant, bright hair ant, and black wool ant, Lasius umbratus, MonomoriumMayr, Paravespula belongs to, Pavement Ant.
Anoplura, head louse for example, body louse, crab louse.
Heteroptera, cimex hemipterus for example, bed bug, phodnius prolixus, invades and harasses vertebra and hunts stinkbug.
Pesticidal combination of the present invention can be used as aerosol, spray product with no pressure for example pump spraying and atomizer spray, automatically mist formation system, fogger, foam, gel, have the evaporating plate that cellulose or polymer make evaporator product, liquid evaporator, gel and film evaporator, the evaporator that screw drives, do not consume energy or passive type vapo(u)rization system, catch moth paper, catch moth bag and insect-catching glue, as drawing agent or pulvis, for spraying bait formulation or the bait formulation position of use.
Any technical characterictic that it should be pointed out that any embodiment of the present invention or embodiment can be independently and any other embodiment combination with one another of the present invention.That is to say, one or more technical characterictics of any embodiment of the present invention all can reconfigure with any other technical characterictic.Technical characterictic reconfigures and the technical characterictic that forms is disclosed in herein thus, and it is documented in the same especially herein.
example of formulations
Embodiment 1:2% fipronil bisamide+10% fluorobenzene urea suspending agent
Fipronil bisamide 2%
Fluorobenzene urea 10%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Each components such as active component, dispersant, wetting agent and water are mixed according to the ratio of formula, after grinding and/or high speed shear, obtain 2% fipronil bisamide+10% fluorobenzene urea suspending agent.
Embodiment 2 20% fipronil bisamide+4% fluorobenzene urea wetting powders
Fipronil bisamide 20%
Fluorobenzene urea 4%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Active component, various auxiliary agent and filler etc. are mixed in the ratio composition of formula, after ultra-fine pulverizer disintegrating, obtain 20% fipronil bisamide+4% fluorobenzene urea wetting powder.
Embodiment 3 0.2% fipronil bisamide+30% fluorobenzene urea aqueous emulsions
Fipronil bisamide 0.2%
Fluorobenzene urea 30%
1-METHYLPYRROLIDONE 15%
Calcium dodecyl benzene sulfonate 5%
Agriculture breast 600# 5%
Water complements to 100%
Former medicine, solvent, emulsifier are added together, make to be dissolved into even oil phase; Water-soluble component and water mixing are made to water; Under high-speed stirred, oil phase is mixed with water, make 0.2% fipronil bisamide+30% fluorobenzene urea aqueous emulsion.
Embodiment 4 3.5% fipronil bisamide+1.5% fluorobenzene urea water dispersible granules
Fipronil bisamide 3.5%
Fluorobenzene urea 1.5%
Sodium lignin sulfonate 4%
Lauryl sodium sulfate 5%
Urea 5%
Kaolin complements to 100%
Active component, dispersant, wetting agent, disintegrant and filler are mixed in the ratio of formula, through air-flow crushing, become wetting powder, then add a certain amount of water mixing extruding to make material.After drying screening, obtain 3.5% fipronil bisamide+1.5% fluorobenzene urea water dispersible granules.
Embodiment 5 10% fipronil bisamide+0.2% fluorobenzene urea suspending agents
Fipronil bisamide 10%
Fluorobenzene urea 0.2%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Each components such as active component, dispersant, wetting agent and water are mixed in the ratio of formula, after grinding and/or high speed shear, obtain 10% fipronil bisamide+0.2% fluorobenzene urea suspending agent.
Embodiment 6 7.5% fipronil bisamide+2.5% fluorobenzene urea suspending agents
Fipronil bisamide 7.5%
Fluorobenzene urea 2.5%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Each components such as active component, dispersant, wetting agent and water are mixed in the ratio of formula, after grinding and/or high speed shear, obtain 7.5% fipronil bisamide+2.5% fluorobenzene urea suspending agent.
Embodiment 7 1% fipronil bisamide+10% fluorobenzene urea wetting powders
Fipronil bisamide 1%
Fluorobenzene urea 10%
Lauryl sodium sulfate 10%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Embodiment 8 10% fipronil bisamide+1% fluorobenzene urea suspending agents
Fipronil bisamide 10%
Fluorobenzene urea 1%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, be prepared into suspending agent.
Embodiment 9 30% fipronil bisamide+20% fluorobenzene urea aqueous emulsions
Oil phase:
Fipronil bisamide 30%
Fluorobenzene urea 20%
Methyl oleate 38%
Polystyrene 3.7%
Water:
Xanthans 0.07%
The sodium salt 1% of the naphthalene sulfonic acids-formaldehyde condensation products of sulfonation
Bactericide 0.2%
Water complements to 100%
Fipronil bisamide and fluorobenzene urea are dissolved in methyl oleate, add polystyrene to obtain oil phase; According to the component in formula, mix and obtain water; Under agitation add water to obtain aqueous emulsion oil phase.
Embodiment 10 25% fipronil bisamide+1% fluorobenzene urea wetting powders
Fipronil bisamide 25%
Fluorobenzene urea 1%
Sodium lignin sulfonate 4%
NaLS 2%
The silicic acid 1% of high degree of dispersion
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Embodiment 11 1% fipronil bisamide+25% fluorobenzene urea coated granules
Fipronil bisamide 1%
Fluorobenzene urea 25%
Polyethylene glycol 3%
The silicic acid 1% of high degree of dispersion
Calcium carbonate complements to 100%
In blender, levigate active component is evenly applied on the carrier being soaked by polyethylene glycol.Can obtain dustless coated granule in this way.
Embodiment 12 30% fipronil bisamide+60% fluorobenzene urea wetting powders
Fipronil bisamide 30%
Fluorobenzene urea 60%
Lauryl sodium sulfate 1%
Sodium lignin sulfonate 1%
White carbon 1%
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Embodiment 13 20% fipronil bisamide+40% fluorobenzene ureas are extruded granule
Fipronil bisamide 20%
Fluorobenzene urea 40%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 2%
Kaolin complements to 100%
Active component is mixed with auxiliary agent and grind, mixture water-wet.This mixture is extruded, then dry in air stream.
Embodiment 14 1% fipronil bisamide+50% fluorobenzene urea suspending agents
Fipronil bisamide 1%
Fluorobenzene urea 50%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, be prepared into suspending agent.
Embodiment 15 10% fipronil bisamide+20% fluorobenzene urea ZC
Atlox 4913 4%
Citric acid 0.05%
Catalyzer 0.1%
Water 13%
Fipronil bisamide 10%
PAPI 1.35%
Solvesso 200 10%
Atlox4913 16%
Dispersant LFH 0.3%
Defoamer 0.16%
Urea 8.4%
Fluorobenzene urea 20%
Water complements to 100%
By PAPI, the oil phase that fluorobenzene urea and Solvesso 100 form adds in the aqueous solution containing Atlox4913, forms emulsion.Then heat and be incubated 50
ounder C, add catalyst reaction 2 hours.After cooling, obtain the microcapsules of fluorobenzene urea.
Atlox 4913, dispersant LFH, and defoamer, urea, fipronil bisamide and water mix in proportion, and through sand milling, are prepared into suspending agent.
The microcapsules of the fluorobenzene urea obtaining is added in the aqueous suspension agent of fipronil bisamide, stir and obtain 10% fipronil bisamide+20% fluorobenzene urea ZC.
Embodiment 16 5% fipronil bisamide+15% fluorobenzene urea suspended emulsions
Fipronil bisamide 5%
Fluorobenzene urea 15%
Solvesso 200 30%
Ethoxylated castor oil 4%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Fluorobenzene urea is dissolved in Solvesso 200, adds ethoxylated castor oil, obtain the missible oil of fluorobenzene urea;
By fipronil bisamide, fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium, above-mentioned each component mixes in proportion, and through sand milling, is prepared into suspending agent.
The oil phase of fluorine-containing phenylurea is joined in the suspending agent containing fipronil bisamide, obtain suspended emulsion.
Embodiment 17 10% fipronil bisamide+10% fluorobenzene urea missible oil
Fipronil bisamide 10%
Fluorobenzene urea 10%
Ethoxylated castor oil 5%
Calcium dodecyl benzene sulfonate 3%
Solvesso100 complements to 100%
Above-mentioned each component is mixed, be stirred to and obtain transparent homogeneous phase.
Embodiment 18 0.5% fipronil bisamide+0.5% fluorobenzene urea dashing agents
Biphenyl polyester 0.5%
Fluorobenzene urea 0.5%
1-METHYLPYRROLIDONE complements to 100%
Above-mentioned each component is mixed, be stirred to and obtain transparent homogeneous phase.
Embodiment 19 1% fipronil bisamide+1% fluorobenzene urea drops
Biphenyl polyester 1%
Fluorobenzene urea 1%
Solvesso 100 complements to 100%
Above-mentioned each component is mixed, be stirred to and obtain transparent homogeneous phase.
Embodiment 20 5% fipronil bisamide+5% fluorobenzene urea suspension seed-coating agents
Fipronil bisamide 5%
Fluorobenzene urea 5%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
PVP-K30 1%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, be prepared into suspension seed-coating agent.
Embodiment 21 50% fipronil bisamide+50% fluorobenzene ureas
Fipronil bisamide 50%
Fluorobenzene urea 50%
Fipronil bisamide and fluorobenzene urea are proportionally mixed.
Proportioning in above embodiment is weight per distribution ratio.
biological test example
When the effect of active compound combinations surpasses the summation of the effect when each reactive compound is used separately, there is collaborative desinsection and acaricidal action.The predictive role of the particular combination of two kinds of reactive compounds can be used so-called " Colby formula " (referring to S.R. Colby, " Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 1967,15,20-22) calculate as follows: if
X is the kill ratio when using consumption for m g/ha or the concentration reactive compound A that is m ppm, is expressed as the percentage that accounts for untreated control,
Y is the kill ratio when using consumption for n g/ha or the concentration reactive compound B that is nppm, is expressed as the percentage that accounts for untreated control,
E is the kill ratio when using consumption for m and n g/ha or the concentration reactive compound A that is m and n ppm and B, is expressed as the percentage that accounts for untreated control,
So
If actual desinsection lethality rate surpasses calculated value, the lethal effect of composition be super add and, there is synergy.In this case, the kill ratio that actual observation is arrived must surpass the value of the expection kill ratio value (E) of using above-mentioned formula calculating.
The 1 cotten aphid test of biological test example
Solvent 7 weight portion dimethyl formamides
Emulsifier 2 weight portion alkaryl polyglycol ethers
For manufacturing the appropriate formulation of reactive compound, 1 weight portion reactive compound is mixed with solvent and the emulsifier of described amount, water is diluted to desired concn by concentrate.
To be impregnated in the active agent preparations of wishing concentration it is processed by the cotton leaf of cotten aphid severe infections.
After the time of hope, measure killing rate %.100% represents that all aphids are killed; 0% represents that on treated blade, the quantity of aphid is suitable with the Aphed population of unprocessed control group.The lethality of measuring is used Colby formula to calculate.
Cotten aphid test
The activity of *=discovery of finding
The activity that the * * calculating=applicable Colby formula calculates
In this test, active agent combinations of the present invention is used separately to compare with described reactive compound and has been showed collaborative enhanced activity.
The chrysomelid larva test of biological test 2 ape
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
For preparing suitable active agent preparations, the reactive compound of 1 weight portion is mixed with solvent and the emulsifier of described amount, and described dope is diluted with water to desired concn.
Cabbage leaves is processed by the active agent preparations of spraying desired concn, and with the chrysomelid larva of ape, inoculated when blade is still moist.
After required time, determine the lethality in %.100% represents that whole mealworms are killed; 0% represents do not have mealworm to be killed.Definite lethality substitution Colby formula is calculated.
In this test, for example, the application's following active agent combinations is compared with the reactive compound of using separately, shows the collaborative activity improving:
The chrysomelid larva test of ape
Biological test 3 cotton bollworm tests
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
For preparing suitable active agent preparations, the reactive compound of 1 weight portion is mixed with solvent and the emulsifier of described amount, and described dope is diluted with water to desired concn.
Cabbage leaves is processed by the active agent preparations of spraying desired concn, and with the larva of cotton bollworm, inoculated when blade is still moist.
After required time, determine the lethality in %.100% represents that whole larvas are killed; 0% represents do not have larva to be killed.Definite lethality substitution Colby formula is calculated.
In this test, for example, the application's following active agent combinations is compared with the reactive compound of using separately, shows the collaborative activity improving:
Cotton bollworm test
The greedy noctuid test in biological test 4 meadows
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
For preparing suitable active agent preparations, the reactive compound of 1 weight portion is mixed with solvent and the emulsifier of described amount, and described dope is diluted with water to desired concn.
Cabbage leaves is processed by the active agent preparations of spraying desired concn, and with the caterpillar of the greedy noctuid in meadow, inoculated when blade is still moist.
After required time, determine the lethality in %.100% represents that whole caterpillars are killed; 0% represents do not have caterpillar to be killed.Definite lethality substitution Colby formula is calculated.
In this test, for example, the application's following active agent combinations is compared with the reactive compound of using separately, shows the collaborative activity improving:
The greedy noctuid test in meadow
The 5 beet armyworm experiments of biological test example
Solvent 7 weight portion dimethyl formamides
Emulsifier 2 weight portion alkaryl polyglycol ethers
For manufacturing the appropriate formulation of reactive compound, 1 weight portion reactive compound is mixed with solvent and the emulsifier of described amount, water is diluted to desired concn by concentrate.
Cabbage leaves is processed by the active agent preparations of spraying desired concn, and the caterpillar of garden beet noctuid inoculates when blade is still moist.
After the time of hope, measure killing rate %.100% represents that all caterpillars are killed; 0% represents that on treated blade, the quantity of caterpillar is suitable with the caterpillar quantity of unprocessed control group.The killing rate of measuring is used Colby formula to calculate.
In this test, for example, the application's following active agent combinations is compared with the reactive compound of using separately, shows the collaborative activity improving:
Beet armyworm experiment
The activity of *=discovery of finding
The activity that the * * calculating=applicable Colby formula calculates.
Biological test example 6 diamond-back moth test sensitive strains
Solvent 7 weight portion dimethyl formamides
Emulsifier 2 weight portion alkaryl polyglycol ethers
For manufacturing the appropriate formulation of reactive compound, 1 weight portion reactive compound is mixed with solvent and the emulsifier of described amount, water is diluted to desired concn by concentrate.
Cabbage leaves is impregnated into and in the active agent preparations of wishing concentration, it is processed and with diamond-back moth (sensitive strain) caterpillar, infect when blade is still moist.
After the time of hope, measure killing rate %.100% represents that all caterpillars are killed; 0% represents that on treated blade, the quantity of caterpillar is suitable with the caterpillar quantity of unprocessed control group.The killing rate of measuring is used Colby formula to calculate.In this test, for example, the application's following active agent combinations is compared with the reactive compound of using separately, shows the collaborative activity improving:
Diamond-back moth test, sensitive strain
The activity of *=discovery of finding
The activity that the * * calculating=applicable Colby formula calculates
In this test, active agent combinations of the present invention is used separately to compare with described reactive compound and has been showed collaborative enhanced activity.
The test of biological test example 7 tea lesser leafhoppers
Solvent 7 weight portion dimethyl formamides
Emulsifier 2 weight portion alkaryl polyglycol ethers
For manufacturing the appropriate formulation of reactive compound, 1 weight portion reactive compound is mixed with solvent and the emulsifier of described amount, water is diluted to desired concn by concentrate.
To be impregnated in the active agent preparations of wishing concentration it is processed by the tealeaves of tea lesser leafhopper severe infections.
After the time of hope, measure killing rate %.100% represents that all leaf worms are killed; 0% represents that on treated blade, the quantity of leafhopper is suitable with the leafhopper quantity of unprocessed control group.The killing rate of measuring is used Colby formula to calculate.
In this test, active agent combinations of the present invention is used separately to compare with described reactive compound and has been showed collaborative enhanced activity.
The test of tea lesser leafhopper
The activity of *=discovery of finding
The activity that the * * calculating=applicable Colby formula calculates.
The test of biological test example 8 paddy rice rice leaf roller
Solvent 7 weight portion dimethyl formamides
Emulsifier 2 weight portion alkaryl polyglycol ethers
For manufacturing the appropriate formulation of reactive compound, 1 weight portion reactive compound is mixed with solvent and the emulsifier of described amount, water is diluted to desired concn by concentrate.
Rice leaf by rice leaf roller severe infections is impregnated in the active agent preparations of wishing concentration it is processed.
After the time of hope, measure killing rate %.100% represents that all cnaphalocrocis snout moth's larvas are killed; 0% represents that on treated blade, the quantity of rice leaf roller is suitable with the rice leaf roller quantity of unprocessed control group.The killing rate of measuring is used Colby formula to calculate.
In this test, active agent combinations of the present invention is used separately to compare with described reactive compound and has been showed collaborative enhanced activity.
Rice leaf roller test
The activity of *=discovery of finding
The activity that the * * calculating=applicable Colby formula calculates.
The test of biological test example 9 rice fulgorids
Solvent 7 weight portion dimethyl formamides
Emulsifier 2 weight portion alkaryl polyglycol ethers
For manufacturing the appropriate formulation of reactive compound, 1 weight portion reactive compound is mixed with solvent and the emulsifier of described amount, water is diluted to desired concn by concentrate.
Rice leaf by rice fulgorid severe infections is impregnated in the active agent preparations of wishing concentration it is processed.
After the time of hope, measure killing rate %.100% represents that all rice fulgorids are killed; 0% represents that on treated blade, the quantity of rice fulgorid is suitable with the rice fulgorid quantity of unprocessed control group.The killing rate of measuring is used Colby formula to calculate.
In this test, active agent combinations of the present invention is used separately to compare with described reactive compound and has been showed collaborative enhanced activity.
Rice fulgorid test
The activity of *=discovery of finding
The activity that the * * calculating=applicable Colby formula calculates.
The test of biological test example 10 striped rice borer
Solvent 7 weight portion dimethyl formamides
Emulsifier 2 weight portion alkaryl polyglycol ethers
For manufacturing the appropriate formulation of reactive compound, 1 weight portion reactive compound is mixed with solvent and the emulsifier of described amount, water is diluted to desired concn by concentrate.
Rice leaf by striped rice borer severe infections is impregnated in the active agent preparations of wishing concentration it is processed.
After the time of hope, measure killing rate %.100% represents that all striped rice borer are killed; 0% represents that on treated blade, the quantity of striped rice borer is suitable with the striped rice borer quantity of unprocessed control group.The killing rate of measuring is used Colby formula to calculate.
In this test, active agent combinations of the present invention is used separately to compare with described reactive compound and has been showed collaborative enhanced activity.
Striped rice borer test
The activity of *=discovery of finding
The activity that the * * calculating=applicable Colby formula calculates
In test, active agent combinations of the present invention is used separately to compare with described reactive compound and has been showed collaborative enhanced activity.
Claims (15)
1. containing an agricultural insecticide composition for fipronil bisamide and fluorobenzene urea, it is characterized in that: contain active component fipronil bisamide and fluorobenzene urea.
2. according to a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea of claim 1, it is characterized in that: the weight ratio of described fipronil bisamide and fluorobenzene urea be or 50:1 to 1:150.
3. according to a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea of claim 1, it is characterized in that: the weight ratio of described fipronil bisamide and fluorobenzene urea be or 25:1 to 1:100.
4. according to a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea of claim 1, it is characterized in that: the weight ratio of described fipronil bisamide and fluorobenzene urea be or 10:1 to 1:50.
5. according to a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea of claim 1, it is characterized in that: the weight ratio of described fipronil bisamide and fluorobenzene urea be or 5:1 to 1:25.
6. according to a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea of claim 1, it is characterized in that: the weight ratio of described fipronil bisamide and fluorobenzene urea be or 1:1 to 1:5.
7. according to a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea of claim 1, it is characterized in that: described fipronil bisamide and fluorobenzene urea account for described composition 1%-90% by weight altogether.
8. according to a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea of claim 1, it is characterized in that: described fipronil bisamide and fluorobenzene urea account for described composition 5%-80% by weight altogether.
9. according to a kind of agricultural insecticide composition containing fipronil bisamide and fluorobenzene urea of claim 1, it is characterized in that: described fipronil bisamide and fluorobenzene urea account for described composition 10%-50% by weight altogether.
10. according to a kind of fipronil bisamide and fluorobenzene urea agricultural insecticide composition of containing of claim 1, it is characterized in that: also comprises surfactant and/or extender.
11. a kind of fipronil bisamides according to claim 1 and fluorobenzene urea agricultural insecticide composition, is characterized in that: described formulation is missible oil, suspending agent, seed coat agent, water dispersible granules, wetting powder, suspension emulsion, extrudes granule, coated granule, aerosol, aqueous emulsion, microcapsule suspending agent.
12. composition pesticides claimed in claim 1 are for preventing or control the purposes of animal pest.
13. 1 kinds of methods of preventing or controlling animal pest, is characterized in that: the propagating materials by the agricultural insecticide composition of claim 1 for target useful plant, target animal insect or its environment, target useful plant.
14. according to the method for a kind of prevention of claim 12 or control animal pest, it is characterized in that: described plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
15. 1 kinds of cover crops in case the method for animal pest invasion and attack it is characterized in that: comprise crop is contacted with agricultural insecticide composition claimed in claim 1.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310400411.5A CN103535363B (en) | 2013-09-05 | 2013-09-05 | Pesticide insecticidal composition containing flubendiamide and teflubenzuron |
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| CN201310400411.5A CN103535363B (en) | 2013-09-05 | 2013-09-05 | Pesticide insecticidal composition containing flubendiamide and teflubenzuron |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104938511A (en) * | 2015-06-24 | 2015-09-30 | 浙江省化工研究院有限公司 | Insecticide composition containing teflubenzuron and cyhalodiamide |
| CN107114389A (en) * | 2017-06-23 | 2017-09-01 | 安徽德昌苗木有限公司 | Pesticidal combination, preparation for Chinese chestnut tree |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007169221A (en) * | 2005-12-22 | 2007-07-05 | Nippon Nohyaku Co Ltd | Pest-controlling agent composition |
-
2013
- 2013-09-05 CN CN201310400411.5A patent/CN103535363B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007169221A (en) * | 2005-12-22 | 2007-07-05 | Nippon Nohyaku Co Ltd | Pest-controlling agent composition |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104938511A (en) * | 2015-06-24 | 2015-09-30 | 浙江省化工研究院有限公司 | Insecticide composition containing teflubenzuron and cyhalodiamide |
| CN104938511B (en) * | 2015-06-24 | 2017-12-29 | 浙江省化工研究院有限公司 | A kind of Pesticidal combination containing Teflubenzuron and chlorine fluorine cyanogen insect amide |
| CN107114389A (en) * | 2017-06-23 | 2017-09-01 | 安徽德昌苗木有限公司 | Pesticidal combination, preparation for Chinese chestnut tree |
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| CN103535363B (en) | 2015-05-27 |
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