CN103531807A - Doping modified lithium ion phosphate positive pole material and preparation method thereof - Google Patents
Doping modified lithium ion phosphate positive pole material and preparation method thereof Download PDFInfo
- Publication number
- CN103531807A CN103531807A CN201310523853.9A CN201310523853A CN103531807A CN 103531807 A CN103531807 A CN 103531807A CN 201310523853 A CN201310523853 A CN 201310523853A CN 103531807 A CN103531807 A CN 103531807A
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- powder
- silver powder
- parts
- oxide
- phosphate positive
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/628—Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses a doping modified lithium ion phosphate positive pole material and a preparation method thereof. The doping modified lithium ion phosphate positive pole material is characterized by comprising, by weight, 500 parts of lithium iron phosphate, 3-4 parts of copper oxide, 2-3 parts of cobalt oxide, 5-6 parts of nickel oxide, 2-3 parts of vanadium pentoxide, 1-2 pats of white alum, 4-5 parts of modified silver powder and a proper amount of water. The modified silver powder is added, the conductivity of the material is improved, growth of a crystal is effectively inhibited, and the evenly-scattered lithium iron phosphate material is obtained. Doping ions are evenly distributed, the discharge capacity is large, consistence of power battery industrialization and endurance are guaranteed, the doping modified lithium ion phosphate positive pole material is low in price, non-toxic and good in safety, sources of raw materials are wide, and environment pollution cannot be caused.
Description
Technical field
The present invention relates to lithium iron phosphate positive material of chemical energy source Material Field, particularly a kind of doping vario-property and preparation method thereof.
Background technology
Iron phosphate lithium electrode material is mainly used in various lithium ion batteries.With traditional lithium ion secondary battery anode material, the LiMn2O4 of spinel structure compares with the LiCoO2 of layer structure, and the raw material source of LiMPO4 more extensively, price is cheaper and non-environmental-pollution.Currently available technology, LiFePO4 has its unique advantage as a kind of anode material for lithium-ion batteries: the theoretical specific capacity 170mAh/g that (1) is relatively high; (2) good thermal stability and chemical stability; (3) low cost, the security performance that hypotoxicity is become reconciled; (4) have extended cycle life.But because LiFePO4 exists the low and low defect of lithium ion conductivity of conductivity, thus cause the poor performance at low temperatures of battery and multiplying power discharging property poor.
Summary of the invention
The object of this invention is to provide lithium iron phosphate positive material of a kind of doping vario-property and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A lithium iron phosphate positive material for doping vario-property, is made by the raw material of following weight portion: LiFePO4 500, cupric oxide 3-4, cobalt oxide 2-3, nickel oxide 5-6, vanadic oxide 2-3, alum 1-2, modification silver powder 4-5, water are appropriate;
Described modification silver powder is made by the raw material of following weight portion: silver powder 100, nano-sized carbon 1-2, antimonous oxide 2-3, shitosan 2-3, crosslinking agent TAC2-3, mica powder 3-4, niobium (Nb) boride 1-2, Nb
2o
51-2, potash 2-3; Each raw material is mixed, be heated to 50-55 ℃, grind 1-2 hour, be uniformly dispersed into powder, send in calciner at 550-580 ℃ sintering 2-3 hour and get final product.
The lithium iron phosphate positive material of doping vario-property of the present invention, by following concrete steps, made: other raw material except modification silver powder is mixed, add suitable quantity of water, grind and within 2-3 hour, obtain 200-400 order slurry, spraying is dry, after oven dry, mix with modification silver powder, add the Tissuemat E powder that is equivalent to powder total weight 2-3%, stir, under 12-15Mpa pressure, be pressed into base, put into calciner and calcine 4-5 hour at 650-700 ℃, take out, cooling, be ground into 300-400 order powder.
The invention has the beneficial effects as follows: the present invention adds modification silver powder, improved material conductivity, and effectively suppress growing up of crystal, obtain homodisperse LiFePO 4 material; The present invention's being evenly distributed of ion of adulterating, discharge capacity is large, has guaranteed consistency and the flying power of electrokinetic cell industrialization, cheap, nontoxicity, security performance is good, raw material wide material sources, does not cause environmental pollution.
Embodiment
Below by instantiation, the present invention is described in detail.
The LiFePO 4 material that this example adopts preparation method's patented technology of 201010226073.4 1 kinds of lithium iron phosphate nano materials to prepare.
A lithium iron phosphate positive material for doping vario-property, by following weight portion (kilogram) raw material make: LiFePO4 500, cupric oxide 3, cobalt oxide 2, nickel oxide 5, vanadic oxide 2, alum 1, modification silver powder 4, water are appropriate;
Described modification silver powder by following weight portion (kilogram) raw material make: silver powder 100, nano-sized carbon 1, antimonous oxide 3, shitosan 2, crosslinking agent TAC2, mica powder 4, niobium (Nb) boride 1, Nb
2o
51, potash 3; Each raw material is mixed, be heated to 50-55 ℃, grind 1-2 hour, be uniformly dispersed into powder, send in calciner at 550-580 ℃ sintering 2-3 hour and get final product.
The lithium iron phosphate positive material of doping vario-property of the present invention, by following concrete steps, made: other raw material except modification silver powder is mixed, add suitable quantity of water, grind and within 2-3 hour, obtain 200-400 order slurry, spraying is dry, after oven dry, mix with modification silver powder, add the Tissuemat E powder that is equivalent to powder total weight 2-3%, stir, under 12-15Mpa pressure, be pressed into base, put into calciner and calcine 4-5 hour at 650-700 ℃, take out, cooling, be ground into 300-400 order powder.
Lithium iron phosphate positive material of the present invention, its first discharge capacity reach 164mAh/g; The relative lithium electrode current potential of its charge and discharge platform is about 3.5V, and initial discharge capacity surpasses 176mAh/g, capacity 2.8% left and right of approximately decaying after 100 charge and discharge cycles.
Claims (2)
1. a lithium iron phosphate positive material for doping vario-property, is characterized in that, by the raw material of following weight portion, is made: LiFePO4 500, cupric oxide 3-4, cobalt oxide 2-3, nickel oxide 5-6, vanadic oxide 2-3, alum 1-2, modification silver powder 4-5, water are appropriate;
Described modification silver powder is made by the raw material of following weight portion: silver powder 100, nano-sized carbon 1-2, antimonous oxide 2-3, shitosan 2-3, crosslinking agent TAC2-3, mica powder 3-4, niobium (Nb) boride 1-2, Nb
2o
51-2, potash 2-3; Each raw material is mixed, be heated to 50-55 ℃, grind 1-2 hour, be uniformly dispersed into powder, send in calciner at 550-580 ℃ sintering 2-3 hour and get final product.
2. the lithium iron phosphate positive material of doping vario-property according to claim 1, it is characterized in that, by following concrete steps, made: other raw material except modification silver powder is mixed, add suitable quantity of water, grind and within 2-3 hour, obtain 200-400 order slurry, spraying is dry, after oven dry, mix with modification silver powder, add the Tissuemat E powder that is equivalent to powder total weight 2-3%, stir, under 12-15Mpa pressure, be pressed into base, put into calciner and calcine 4-5 hour at 650-700 ℃, take out, cooling, be ground into 300-400 order powder.
Priority Applications (1)
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CN201310523853.9A CN103531807A (en) | 2013-10-30 | 2013-10-30 | Doping modified lithium ion phosphate positive pole material and preparation method thereof |
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CN201310523853.9A CN103531807A (en) | 2013-10-30 | 2013-10-30 | Doping modified lithium ion phosphate positive pole material and preparation method thereof |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1736636A (en) * | 2005-09-12 | 2006-02-22 | 昆明理工恒达科技有限公司 | Low loose density sheet-like silver powder preparation method |
CN101162776A (en) * | 2007-10-26 | 2008-04-16 | 深圳市贝特瑞新能源材料股份有限公司 | Lithium iron phosphate suitable for high multiplying power electrokinetic cell and method for producing the same |
CN102414876A (en) * | 2009-04-24 | 2012-04-11 | 大日本印刷株式会社 | Electrode plate for nonaqueous electrolyte secondary battery, method for producing electrode plate for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery |
-
2013
- 2013-10-30 CN CN201310523853.9A patent/CN103531807A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1736636A (en) * | 2005-09-12 | 2006-02-22 | 昆明理工恒达科技有限公司 | Low loose density sheet-like silver powder preparation method |
CN101162776A (en) * | 2007-10-26 | 2008-04-16 | 深圳市贝特瑞新能源材料股份有限公司 | Lithium iron phosphate suitable for high multiplying power electrokinetic cell and method for producing the same |
CN102414876A (en) * | 2009-04-24 | 2012-04-11 | 大日本印刷株式会社 | Electrode plate for nonaqueous electrolyte secondary battery, method for producing electrode plate for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery |
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Application publication date: 20140122 |
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