CN103525011A - Magnetic anti-aging plastic - Google Patents

Magnetic anti-aging plastic Download PDF

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Publication number
CN103525011A
CN103525011A CN201310442320.8A CN201310442320A CN103525011A CN 103525011 A CN103525011 A CN 103525011A CN 201310442320 A CN201310442320 A CN 201310442320A CN 103525011 A CN103525011 A CN 103525011A
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CN
China
Prior art keywords
magnetic
aging
parts
coupling agent
antioxidant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201310442320.8A
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Chinese (zh)
Inventor
肖伟荣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wujiang Tianyuan Plastic Co Ltd
Original Assignee
Wujiang Tianyuan Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wujiang Tianyuan Plastic Co Ltd filed Critical Wujiang Tianyuan Plastic Co Ltd
Priority to CN201310442320.8A priority Critical patent/CN103525011A/en
Publication of CN103525011A publication Critical patent/CN103525011A/en
Withdrawn legal-status Critical Current

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  • Compositions Of Macromolecular Compounds (AREA)
  • Hard Magnetic Materials (AREA)
  • Soft Magnetic Materials (AREA)

Abstract

The invention discloses a magnetic anti-aging plastic which is composed of the following raw materials in parts by mass: 80-95 parts of magnetic powder, 5-10 parts of thermosetting resin, 1-4 parts of anti-aging agent, 2-6 parts of synthetic vegetable butter, 0.1-0.5 part of butyl stearate and 0.5-1 part of coupling agent, wherein the magnetic powder is ferrite magnetic powder of which the fineness is 1-1.5 mu m; the thermosetting resin is epoxy resin or phenolic resin; the anti-aging agent is one of antioxidant 1010, antioxidant 1076, triphenyl phosphite and triphenyl phosphite; and the coupling agent is titanate or silane. The prepared magnetic anti-aging plastic is low in cost, excellent in magnetic performance and aging resistance and wide in application area, and can be easily subjected to machine shaping.

Description

The anti-aging plastics of a kind of magnetic
Technical field
The present invention relates to a kind of plastics, relate in particular to the anti-aging plastics of a kind of magnetic.
Background technology
Plastics duration of service is long easily aging, and can not biological degradation in physical environment, very large to the destruction of natural ecological environment after therefore discarded.In addition, some plastics are as there is no the material of mutual adhesion in block toy, thereby easily cave in, and easy-formation not can not meet modern people's life requirement.
Magnetic plastics is compared with magnet, except magnetic energy is general, use temperature low, other performances are all than more excellent.It is easy to, and machine-shaping is all kinds of complicated shape goods, dimensional precision is high, mechanical property good, relative density is low, easy integrally combined, can be used for the less demanding occasion of some magnetic, as sensor, magnetotherapy appliance and the sports goods etc. of the loud speaker of refrigerator sealing strip, children's magnetic writing board, motor part, stereo set, earphone, telephone set, televisor accessory, instrument, communication equipment.The object of magnetic plastics exploitation is mainly for overcoming the unworkability of pure magneticsubstance, and this is also magneticsubstance developing direction from now on.
Summary of the invention
The technical problem solving: for the deficiencies in the prior art, the invention provides a kind of magnetic aging-resistant plastics, abundant raw material, cheap, magnetic property good, and being easy to machine-shaping is all kinds of complicated shape goods.
Technical scheme: the invention provides the anti-aging plastics of a kind of magnetic, formed by the raw material of following mass fraction: magnetic 80-95 part, thermosetting resin 5-10 part, antiaging agent 1-4 part, synthetic vegetable tallow 2-6 part, stearic acid butyl ester 0.1-0.5 part, coupling agent 0.5-1 part.
Described magnetic is ferrite magnetic class magnetic, and fineness is 1-1.5 μ m; Described thermosetting resin is epoxy resin or resol; Described antiaging agent is a kind of in antioxidant 1010, antioxidant 1076, triphenyl phosphite, triphenyl phosphite.Described coupling agent is titanic acid ester or silane.
Beneficial effect: because the present invention has adopted technique scheme, the anti-aging plastics cost of magnetic making is low, magnetic property and ageing resistance are excellent, are easy to machine-shaping, and Application Areas is extensive.
Embodiment
Mode below by embodiment further illustrates the present invention, but therefore the present invention is not confined to following embodiment.
Embodiment 1
The anti-aging plastics of a kind of magnetic of the present invention, are comprised of the raw material of following mass fraction: magnetic 80-95 part, 5 parts of thermosetting resins, 1 part of antiaging agent, 2 parts of synthetic vegetable tallows, 0.1 part of stearic acid butyl ester, 0.5 part of coupling agent.
According to above-mentioned mass percent, raw material is mixed, with injecting method, process.During the front 0.5-1.5s of injection, to ruhmkorff coil, magnetic is sent out in energising, and mould is placed in high magnetic environment, die temperature 110-120 ℃, and injection pressure is 105Mpa, and screw speed is 250r/min, and barrel temperature is 280-290 ℃, and shaping cycle is 35s.
Embodiment 2
The anti-aging plastics of a kind of magnetic of the present invention, are comprised of the raw material of following mass fraction: magnetic 80-95 part, 7.5 parts of thermosetting resins, 2.5 parts of antiaging agents, 4 parts of synthetic vegetable tallows, 0.3 part of stearic acid butyl ester, 0.7 part of coupling agent.
According to above-mentioned mass percent, raw material is mixed, with injecting method, process.During the front 0.5-1.5s of injection, to ruhmkorff coil, magnetic is sent out in energising, and mould is placed in high magnetic environment, die temperature 110-120 ℃, and injection pressure is 105Mpa, and screw speed is 250r/min, and barrel temperature is 280-290 ℃, and shaping cycle is 35s.
Embodiment 3
The anti-aging plastics of a kind of magnetic of the present invention, are comprised of the raw material of following mass fraction: magnetic 80-95 part, 10 parts of thermosetting resins, 4 parts of antiaging agents, 6 parts of synthetic vegetable tallows, 0.5 part of stearic acid butyl ester, 1 part of coupling agent.
According to above-mentioned mass percent, raw material is mixed, with injecting method, process.During the front 0.5-1.5s of injection, to ruhmkorff coil, magnetic is sent out in energising, and mould is placed in high magnetic environment, die temperature 110-120 ℃, and injection pressure is 105Mpa, and screw speed is 250r/min, and barrel temperature is 280-290 ℃, and shaping cycle is 35s.
The anti-aging plastics correlated performance of the various embodiments described above gained magnetic is tested, and result is as follows:
Test event Maximum magnetic energy area (kTA/m) Residual flux intensity/T Coercive force/(kA/m)
Embodiment 1 9 0.15 87
Embodiment 2 12 2.5 90
Embodiment 3 15 1.5 88

Claims (5)

1. the anti-aging plastics of magnetic, is characterized in that being comprised of the raw material of following mass fraction: magnetic 80-95 part, thermosetting resin 5-10 part, antiaging agent 1-4 part, synthetic vegetable tallow 2-6 part, stearic acid butyl ester 0.1-0.5 part, coupling agent 0.5-1 part.
2. the anti-aging plastics of magnetic according to claim 1, is characterized in that described magnetic is ferrite magnetic class magnetic, and fineness is 1-1.5 μ m.
3. the anti-aging plastics of magnetic according to claim 1, is characterized in that described thermosetting resin is epoxy resin or resol.
4. anti-aging plastics of magnetic according to claim 1, is characterized in that described antiaging agent is a kind of in antioxidant 1010, antioxidant 1076, triphenyl phosphite, triphenyl phosphite.
5. the anti-aging plastics of magnetic according to claim 1, is characterized in that described coupling agent is titanic acid ester or silane.
CN201310442320.8A 2013-09-25 2013-09-25 Magnetic anti-aging plastic Withdrawn CN103525011A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310442320.8A CN103525011A (en) 2013-09-25 2013-09-25 Magnetic anti-aging plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310442320.8A CN103525011A (en) 2013-09-25 2013-09-25 Magnetic anti-aging plastic

Publications (1)

Publication Number Publication Date
CN103525011A true CN103525011A (en) 2014-01-22

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Family Applications (1)

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CN201310442320.8A Withdrawn CN103525011A (en) 2013-09-25 2013-09-25 Magnetic anti-aging plastic

Country Status (1)

Country Link
CN (1) CN103525011A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103965580A (en) * 2014-05-06 2014-08-06 南京信息工程大学 Magnetic compound polymer plastic alloy material and preparation method thereof
CN103965579A (en) * 2014-05-06 2014-08-06 南京信息工程大学 Combined regenerated substance and magnetic compound material and preparation method thereof
CN105286268A (en) * 2014-07-08 2016-02-03 纪伊产业株式会社 Wide-mouth container with assistive devices

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102181129A (en) * 2011-03-31 2011-09-14 广州友益电子科技有限公司 Epoxy resin composition for semiconductor encapsulation
CN102352101A (en) * 2011-06-08 2012-02-15 深圳市科聚新材料有限公司 Plastic magnetic conductive material and preparation method thereof
CN103288458A (en) * 2013-06-09 2013-09-11 苏州禾昌聚合材料股份有限公司 High-property bonded ferrite injection granular material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102181129A (en) * 2011-03-31 2011-09-14 广州友益电子科技有限公司 Epoxy resin composition for semiconductor encapsulation
CN102352101A (en) * 2011-06-08 2012-02-15 深圳市科聚新材料有限公司 Plastic magnetic conductive material and preparation method thereof
CN103288458A (en) * 2013-06-09 2013-09-11 苏州禾昌聚合材料股份有限公司 High-property bonded ferrite injection granular material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
贾明武和张敏刚: "黏结永磁材料用热固性树脂黏结剂", 《山西冶金》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103965580A (en) * 2014-05-06 2014-08-06 南京信息工程大学 Magnetic compound polymer plastic alloy material and preparation method thereof
CN103965579A (en) * 2014-05-06 2014-08-06 南京信息工程大学 Combined regenerated substance and magnetic compound material and preparation method thereof
CN103965579B (en) * 2014-05-06 2015-12-02 南京信息工程大学 A kind of regrowth magnetic compound matrix material and preparation method thereof
CN103965580B (en) * 2014-05-06 2016-01-20 南京信息工程大学 A kind of magnetic compound high molecular plastic alloy material and preparation method thereof
CN105286268A (en) * 2014-07-08 2016-02-03 纪伊产业株式会社 Wide-mouth container with assistive devices
CN105286268B (en) * 2014-07-08 2019-08-16 纪伊产业株式会社 Large container with auxiliary implement

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Application publication date: 20140122