A kind of antimicrobial sealing circle
Technical field
The present invention relates generally to a kind of sealing-ring, relates in particular to a kind of antimicrobial sealing circle.
Background technology
Fluoroelastomer is that the performance at excellent flame retardant resistance, excellent resistance to air loss, high temperature resistant, resistance to ozone, weather, resistance to oxidation, resistance to mineral oil, fuel oil resistance, hydraulic pressure resistant oil, resistance to aromatic series and many organic solvents and chemicals is famous with it, the sealing-ring made from viton is widely used, superior performance.
Summary of the invention
The object of the invention is just to provide a kind of antimicrobial sealing circle.
The present invention is achieved by the following technical solutions:
A circle, it is comprised of the raw material of following weight parts:
Fluororubber 26 100-110, polyurethane(s) 10-12, sepiolite powder 20-25, Fluorspar Powder 10-15, dioctyl maleate 4-5, glass powder 2-3, antiseptic-germicide 4-6, Jojoba oil 2-3, ammonium molybdate 1-2, linking agent TAC0.8-1,3-aminopropyl trimethoxysilane 1-2, antioxidant A W1-2, altax 1-2, accelerant CZ 1-2, vulcanizing agent DCBP0.8-1, modified particle 10-15;
Described antiseptic-germicide is nano antibacterial agent, and this nano antibacterial agent is for take inorganic nano material as carrier, carrier band silver, zinc, copper, titanium metal and ion thereof;
Described modified particle is comprised of the raw material of following weight parts:
Polyvinyl chloride resin 90-100, aluminium nitride 10-15, saturated fatty alcohol dibasic acid ester 2-3, γ-aminopropyl triethoxysilane 1-2, TDE 1-2, lead cyanurate 0.1-0.2;
Above-mentioned polyvinyl chloride resin sealing is ground, then the dicarboxylic ester, the lead cyanurate that add saturated fatty alcohol, blending and stirring 10-12 minute at 100-120 ℃, reduction temperature is 50-60 ℃, adds aluminium nitride, γ-aminopropyl triethoxysilane, 600-800 rev/min of dispersed with stirring 4-6 minute, add each raw material of residue, fully stir, add twin screw extruder extruding pelletization, obtaining particle diameter is 2-3 μ m.
A preparation method for antimicrobial sealing circle, comprises the following steps:
Above-mentioned sepiolite powder, Fluorspar Powder, glass powder are mixed, after fully stirring, add antiseptic-germicide, Jojoba oil, 3-aminopropyl trimethoxysilane, 200-300 rev/min of dispersed with stirring 3-5 minute, rising temperature is 60-70 ℃, insulation 20-30 minute, be cooled to normal temperature, add each raw material of residue except vulcanizing agent DCBP, altax, accelerant CZ, mixing, compression moulding, add each raw material of residue, carry out sulfidizing, obtain described antimicrobial sealing circle.
Advantage of the present invention is:
Sealing-ring of the present invention can guarantee dispersed in rubber of a small amount of ultra-fine pulvis aborning, and in manufacturing processed, avoids the generation of the phenomenons such as ultra-fine pulvis flies upward, and is conducive to environment protection, makes product good anti-bacterial effect, long service life.
Embodiment
Embodiment 1
A circle, it by following weight parts (kilogram) raw material form:
Fluororubber 26 110, polyurethane(s) 12, sepiolite powder 25, Fluorspar Powder 15, dioctyl maleate 5, glass powder 2-3, antiseptic-germicide 4, Jojoba oil 3, ammonium molybdate 1, linking agent TAC1,3-aminopropyl trimethoxysilane 1, antioxidant A W2, altax 2, accelerant CZ 1, vulcanizing agent DCBP0.8, modified particle 15;
Described antiseptic-germicide is nano antibacterial agent, and this nano antibacterial agent is for take inorganic nano material as carrier, carrier band silver, zinc, copper, titanium metal and ion thereof;
Described modified particle is comprised of the raw material of following weight parts:
Polyvinyl chloride resin 100, aluminium nitride 15, saturated fatty alcohol dibasic acid ester 2, γ-aminopropyl triethoxysilane 2, TDE 2, lead cyanurate 0.2;
Above-mentioned polyvinyl chloride resin sealing is ground, then the dicarboxylic ester, the lead cyanurate that add saturated fatty alcohol, at 120 ℃, blending and stirring is 12 minutes, reducing temperature is 60 ℃, adds aluminium nitride, γ-aminopropyl triethoxysilane, 800 revs/min of dispersed with stirring 6 minutes, add each raw material of residue, fully stir, add twin screw extruder extruding pelletization, obtaining particle diameter is 3 μ m.
A preparation method for antimicrobial sealing circle, comprises the following steps:
Above-mentioned sepiolite powder, Fluorspar Powder, glass powder are mixed, after fully stirring, add antiseptic-germicide, Jojoba oil, 3-aminopropyl trimethoxysilane, 300 revs/min of dispersed with stirring 5 minutes, rising temperature is 70 ℃, be incubated 30 minutes, be cooled to normal temperature, add each raw material of residue except vulcanizing agent DCBP, altax, accelerant CZ, mixing, compression moulding, add each raw material of residue, carry out sulfidizing, obtain described antimicrobial sealing circle.
Performance test: